CN108520827A - Carbon fiber/NiCo2O4The preparation method of/graphene composite material - Google Patents
Carbon fiber/NiCo2O4The preparation method of/graphene composite material Download PDFInfo
- Publication number
- CN108520827A CN108520827A CN201810081472.2A CN201810081472A CN108520827A CN 108520827 A CN108520827 A CN 108520827A CN 201810081472 A CN201810081472 A CN 201810081472A CN 108520827 A CN108520827 A CN 108520827A
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- carbon fiber
- nico
- composite material
- graphene
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- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 86
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 86
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 86
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 62
- 239000002131 composite material Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229910005949 NiCo2O4 Inorganic materials 0.000 claims abstract description 34
- 229910003266 NiCo Inorganic materials 0.000 claims abstract description 22
- 239000002070 nanowire Substances 0.000 claims abstract description 13
- 239000002086 nanomaterial Substances 0.000 claims abstract description 11
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 238000004146 energy storage Methods 0.000 claims abstract description 5
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 4
- 238000011065 in-situ storage Methods 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims abstract description 3
- 230000002195 synergetic effect Effects 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 20
- 239000004202 carbamide Substances 0.000 claims description 20
- 230000003647 oxidation Effects 0.000 claims description 16
- 238000007254 oxidation reaction Methods 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 235000019441 ethanol Nutrition 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 239000012153 distilled water Substances 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 10
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 9
- 150000002815 nickel Chemical class 0.000 claims description 9
- 150000001868 cobalt Chemical class 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 238000001994 activation Methods 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 claims description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 238000000527 sonication Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims 1
- 230000009975 flexible effect Effects 0.000 abstract description 12
- 239000007772 electrode material Substances 0.000 abstract description 10
- 239000003990 capacitor Substances 0.000 abstract description 9
- 239000000758 substrate Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(II) nitrate Inorganic materials [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002077 nanosphere Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/24—Electrodes characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/40—Fibres
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810081472.2A CN108520827A (en) | 2018-01-29 | 2018-01-29 | Carbon fiber/NiCo2O4The preparation method of/graphene composite material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810081472.2A CN108520827A (en) | 2018-01-29 | 2018-01-29 | Carbon fiber/NiCo2O4The preparation method of/graphene composite material |
Publications (1)
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CN108520827A true CN108520827A (en) | 2018-09-11 |
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Family Applications (1)
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CN201810081472.2A Pending CN108520827A (en) | 2018-01-29 | 2018-01-29 | Carbon fiber/NiCo2O4The preparation method of/graphene composite material |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109273278A (en) * | 2018-10-23 | 2019-01-25 | 陕西科技大学 | A kind of preparation method of cobalt acid nickel nano wire cladding carbon fiber flexible electrode material |
CN110112006A (en) * | 2019-05-07 | 2019-08-09 | 哈尔滨工业大学(威海) | A kind of cobalt-nickel oxide/graphite flake composite material and preparation method and application |
CN110508314A (en) * | 2019-09-06 | 2019-11-29 | 温州涂屋信息科技有限公司 | A kind of Co2N-Ni3N loads graphene oxide-carbon cloth and analyses its preparation method of oxygen material |
CN110729134A (en) * | 2019-10-25 | 2020-01-24 | 陕西科技大学 | Nano NiCo2O4/rGO/ANF composite film and preparation method and application thereof |
CN111764155A (en) * | 2020-06-17 | 2020-10-13 | 武汉纺织大学 | Two-dimensional transition metal carbide/conductive carbon fiber composite material and preparation method and application thereof |
CN113213555A (en) * | 2021-05-19 | 2021-08-06 | 国网天津市电力公司电力科学研究院 | Needle-like NiCo2O4Preparation method of super-electric material |
CN114551892A (en) * | 2022-04-27 | 2022-05-27 | 浙江清华柔性电子技术研究院 | Cobalt niobate oxide-loaded graphene composite material and preparation method and application thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120321953A1 (en) * | 2011-06-17 | 2012-12-20 | Nanotek Instruments, Inc. | Graphene-enabled vanadium oxide cathode and lithium cells containing same |
CN102891016A (en) * | 2012-10-19 | 2013-01-23 | 常州大学 | Nickel cobaltate-graphene composite material and application and preparation method thereof |
CN104240972A (en) * | 2014-09-11 | 2014-12-24 | 江苏大学 | Method for manufacturing porous flaky NiCo2O4 and grapheme composite capacitive material |
CN104616914A (en) * | 2014-12-31 | 2015-05-13 | 江苏江大环保科技开发有限公司 | Preparation method for 3D coralloid grapheme/NiCo2O4 composite materials |
CN106299271A (en) * | 2016-08-23 | 2017-01-04 | 南京理工大学 | Nano nickel cobaltate/graphene composite material and preparation method thereof |
CN106710891A (en) * | 2017-02-04 | 2017-05-24 | 徐靖才 | NiCo2O4/active carbon composite material preparation method |
CN107424847A (en) * | 2017-07-21 | 2017-12-01 | 张娟 | A kind of preparation method of nitrogen-doped carbon nano-fiber Supported Co acid nickel combination electrode material |
-
2018
- 2018-01-29 CN CN201810081472.2A patent/CN108520827A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120321953A1 (en) * | 2011-06-17 | 2012-12-20 | Nanotek Instruments, Inc. | Graphene-enabled vanadium oxide cathode and lithium cells containing same |
CN102891016A (en) * | 2012-10-19 | 2013-01-23 | 常州大学 | Nickel cobaltate-graphene composite material and application and preparation method thereof |
CN104240972A (en) * | 2014-09-11 | 2014-12-24 | 江苏大学 | Method for manufacturing porous flaky NiCo2O4 and grapheme composite capacitive material |
CN104616914A (en) * | 2014-12-31 | 2015-05-13 | 江苏江大环保科技开发有限公司 | Preparation method for 3D coralloid grapheme/NiCo2O4 composite materials |
CN106299271A (en) * | 2016-08-23 | 2017-01-04 | 南京理工大学 | Nano nickel cobaltate/graphene composite material and preparation method thereof |
CN106710891A (en) * | 2017-02-04 | 2017-05-24 | 徐靖才 | NiCo2O4/active carbon composite material preparation method |
CN107424847A (en) * | 2017-07-21 | 2017-12-01 | 张娟 | A kind of preparation method of nitrogen-doped carbon nano-fiber Supported Co acid nickel combination electrode material |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109273278A (en) * | 2018-10-23 | 2019-01-25 | 陕西科技大学 | A kind of preparation method of cobalt acid nickel nano wire cladding carbon fiber flexible electrode material |
CN110112006A (en) * | 2019-05-07 | 2019-08-09 | 哈尔滨工业大学(威海) | A kind of cobalt-nickel oxide/graphite flake composite material and preparation method and application |
CN110508314A (en) * | 2019-09-06 | 2019-11-29 | 温州涂屋信息科技有限公司 | A kind of Co2N-Ni3N loads graphene oxide-carbon cloth and analyses its preparation method of oxygen material |
CN110729134A (en) * | 2019-10-25 | 2020-01-24 | 陕西科技大学 | Nano NiCo2O4/rGO/ANF composite film and preparation method and application thereof |
CN110729134B (en) * | 2019-10-25 | 2021-07-23 | 陕西科技大学 | Nano NiCo2O4/rGO/ANF composite film and preparation method and application thereof |
CN111764155A (en) * | 2020-06-17 | 2020-10-13 | 武汉纺织大学 | Two-dimensional transition metal carbide/conductive carbon fiber composite material and preparation method and application thereof |
CN111764155B (en) * | 2020-06-17 | 2022-11-04 | 武汉纺织大学 | Two-dimensional transition metal carbide/conductive carbon fiber composite material and preparation method and application thereof |
CN113213555A (en) * | 2021-05-19 | 2021-08-06 | 国网天津市电力公司电力科学研究院 | Needle-like NiCo2O4Preparation method of super-electric material |
CN114551892A (en) * | 2022-04-27 | 2022-05-27 | 浙江清华柔性电子技术研究院 | Cobalt niobate oxide-loaded graphene composite material and preparation method and application thereof |
CN114551892B (en) * | 2022-04-27 | 2022-08-02 | 浙江清华柔性电子技术研究院 | Cobalt niobate oxide-loaded graphene composite material and preparation method and application thereof |
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CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Li Sumin Inventor after: Yang Kang Inventor after: Jiang Hui Inventor after: Luo Nanhui Inventor after: Li Songjun Inventor before: Li Sumin Inventor before: Jiang Hui Inventor before: Yang Kang Inventor before: Luo Nanhui Inventor before: Li Songjun |
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Application publication date: 20180911 |