CN108517474A - A kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE - Google Patents

A kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE Download PDF

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Publication number
CN108517474A
CN108517474A CN201810793667.XA CN201810793667A CN108517474A CN 108517474 A CN108517474 A CN 108517474A CN 201810793667 A CN201810793667 A CN 201810793667A CN 108517474 A CN108517474 A CN 108517474A
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China
Prior art keywords
high temperature
resistance
amorphous alloy
alloy material
transient high
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CN201810793667.XA
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Inventor
丁鸿飞
柯强
胡昌才
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Wuhu Jun Hua Materials Co Ltd
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Wuhu Jun Hua Materials Co Ltd
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Priority to CN201810793667.XA priority Critical patent/CN108517474A/en
Publication of CN108517474A publication Critical patent/CN108517474A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C45/00Amorphous alloys
    • C22C45/02Amorphous alloys with iron as the major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/003Making ferrous alloys making amorphous alloys

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

The invention discloses a kind of amorphous alloy materials of resistance to TRANSIENT HIGH TEMPERATURE, include the element of following mass percent:The ferro element of element silicon 0.3%~1.2%, bismuth element 0.1%~0.5%, elemental lithium 1.5%~2.2%, aluminium element 3.0%~5.0%, nickel element 15%~18%, Zn-ef ficiency 8%~12%, manganese element 2.6%~3.0% and surplus.A kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE provided by the present invention, exciting power when saturation magnetic induction is 1.6 T~2.4 T, 1.35T/50Hz are the VA/kg of 0.23 VA/kg~0.47;And keep then taking out for 10 minutes at a high temperature of being placed in 500 DEG C and be placed in room temperature natural cooling, repeat aforesaid operations 20 times, saturation magnetic induction, coercivity and exciting power are without significant change.

Description

A kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE
Technical field
The present invention relates to a kind of amorphous alloy material technical field, especially a kind of non-crystaline amorphous metal material of resistance to TRANSIENT HIGH TEMPERATURE Material.
Background technology
Amorphous alloy material is a kind of magnetic material with high saturated magnetic induction, is mostly used for manufacturing mutual inductance Device magnetic core.Amorphous alloy material prepares band-like or powder raw material by being usually quenched and solidified technique by surpassing, then will be band-like Raw material coiling and molding, or by powder raw material encapsulation or plasticizing forming, to obtain the main element of transformer core.
The transformer core made of amorphous alloy material is during processing and use, inevitably by certain High temperature impact, such as transformer core is welded to inside mutual inductor, and mutual inductor is welded and fixed in electric power network;This Outside, the surge in electric power network also has certain probability electric power assembly is caused to burn, and also will produce larger heat among these With of short duration high temperature;For this reason, it is necessary to provide a kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE, can bear in a short time compared with High temperature, without irreversible Performance Decay occurs.
Invention content
It for overcome the deficiencies in the prior art, can the present invention provides a kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE Higher temperature is born in a short time, without irreversible Performance Decay occurs.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE, includes the element of following mass percent:Element silicon 0.3%~1.2%, bismuth Element 0.1%~0.5%, elemental lithium 1.5%~2.2%, aluminium element 3.0%~5.0%, nickel element 15%~18%, Zn-ef ficiency 8%~ 12%, manganese element 2.6%~3.0% and the ferro element of surplus.
As the further preferred of above-mentioned technical proposal, include the element of following mass percent:Element silicon 0.6%, bismuth member The ferro element of element 0.2%, elemental lithium 1.9%, aluminium element 4.4%, nickel element 16%, Zn-ef ficiency 8%, manganese element 2.8% and surplus.
Compared with prior art, the beneficial effects of the invention are as follows:
A kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE provided by the present invention, saturation magnetic induction are 1.6 T~2.4 T, 1.35T/ Exciting power when 50Hz is the VA/kg of 0.23 VA/kg~0.47;And it keeps then taking for 10 minutes at a high temperature of being placed in 500 DEG C Go out to be placed in room temperature natural cooling, repeat aforesaid operations 20 times, saturation magnetic induction, coercivity and exciting power are without significant change.
Specific implementation mode
Carry out the technology contents that present invention be described in more detail below in conjunction with specific embodiments.
Specific embodiment 1
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment is provided, includes the element of following mass percent:Silicon Element 0.6%, bismuth element 0.2%, elemental lithium 1.9%, aluminium element 4.4%, nickel element 16%, Zn-ef ficiency 8%, manganese element 2.8% and The ferro element of surplus.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment is provided, preparation method includes the following steps:
Step 1: by the big raw material of combined content accounting, weighed according to the proportioning of element mass percent with simple substance form, then It puts into the medium frequency induction melting furnace with air-tightness, then to being vacuumized in medium frequency induction melting furnace, then heating magnetically Material preparation raw material makes magnetic material prepare the abundant melting mixing of raw material to 1300~1500 DEG C;
The big raw material of the combined content accounting is elemental lithium, pure aluminum, elemental nickel, simple substance zinc, simple substance manganese and fe.
Step 2: by the small raw material of combined content accounting, according to element mass percent in the form of oxidate nano powder Proportioning weigh, then put into the medium frequency induction melting furnace of vacuum, mixed with the raw material melted in step 1, and carbon is added Powder reduced oxide, it is then cooling that magnetic material alloy mother's ingot is made;
The small raw material of the combined content accounting is nano grade silica particles and nanometer bismuth oxide powder.
Step 3: magnetic material alloy mother's ingot made from step 2 is put into the medium frequency induction melting furnace with air-tightness In, then to being vacuumized in medium frequency induction melting furnace, then heating magnetically material alloys mother ingot waits for magnetism to 1300~1350 DEG C After the melting completely of material alloys mother ingot, the aluminium alloy of melting is cast on fast quenching list roller, the amorphous that resistance to TRANSIENT HIGH TEMPERATURE is made closes Golden material.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment prepares, saturation magnetic induction are 2.1 T~2.4 Exciting power when T, 1.35T/50Hz is the VA/kg of 0.23 VA/kg~0.25.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment prepares is placed at a high temperature of 500 DEG C and is kept Then take out within 10 minutes and be placed in room temperature natural cooling, repeat aforesaid operations 20 times, saturation magnetic induction, coercivity and exciting power without Significant change.
Specific embodiment 2
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment is provided, includes the element of following mass percent:Silicon Element 0.3%, bismuth element 0.5%, elemental lithium 1.5%, aluminium element 5.0%, nickel element 15%, Zn-ef ficiency 10%, manganese element 2.6% and The ferro element of surplus.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment is provided, preparation method and specific embodiment 1 It is identical.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment prepares, saturation magnetic induction are 2.0 T~2.2 Exciting power when T, 1.35T/50Hz is the VA/kg of 0.39 VA/kg~0.47.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment prepares is placed at a high temperature of 500 DEG C and is kept Then take out within 10 minutes and be placed in room temperature natural cooling, repeat aforesaid operations 20 times, saturation magnetic induction, coercivity and exciting power without Significant change.
Specific embodiment 3
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment is provided, includes the element of following mass percent:Silicon Element 1.2%, bismuth element 0.1%, elemental lithium 2.2%, aluminium element 3.0%, nickel element 18%, Zn-ef ficiency 12%, manganese element 3.0% and The ferro element of surplus.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment is provided, preparation method and specific embodiment 1 It is identical.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment prepares, saturation magnetic induction are 1.6 T~1.9 Exciting power when T, 1.35T/50Hz is the VA/kg of 0.35 VA/kg~0.39.
A kind of amorphous alloy material for resistance to TRANSIENT HIGH TEMPERATURE that the present embodiment prepares is placed at a high temperature of 500 DEG C and is kept Then take out within 10 minutes and be placed in room temperature natural cooling, repeat aforesaid operations 20 times, saturation magnetic induction, coercivity and exciting power without Significant change.
Above to the present invention better embodiment illustrated, certainly, the present invention can also use with it is above-mentioned The different form of embodiment, those skilled in the art under the premise of without prejudice to spirit of that invention made by it is equivalent Transformation or corresponding change, should all belong to the scope of protection of the present invention interior.

Claims (2)

1. a kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE, which is characterized in that include the element of following mass percent:Element silicon 0.3%~1.2%, bismuth element 0.1%~0.5%, elemental lithium 1.5%~2.2%, aluminium element 3.0%~5.0%, nickel element 15%~18%, The ferro element of Zn-ef ficiency 8%~12%, manganese element 2.6%~3.0% and surplus.
2. a kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE according to claim 1, which is characterized in that including following quality The element of percentage:Element silicon 0.6%, bismuth element 0.2%, elemental lithium 1.9%, aluminium element 4.4%, nickel element 16%, Zn-ef ficiency 8%, The ferro element of manganese element 2.8% and surplus.
CN201810793667.XA 2018-07-19 2018-07-19 A kind of amorphous alloy material of resistance to TRANSIENT HIGH TEMPERATURE Withdrawn CN108517474A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6468446A (en) * 1987-09-09 1989-03-14 Hitachi Metals Ltd Fe based amorphous alloy
EP0695812A1 (en) * 1994-08-01 1996-02-07 Hitachi Metals, Ltd. Nanocrystalline alloy with insulating coating, magnetic core made thereof, and process for forming insulating coating on a nanocrystalline alloy
JP2000073148A (en) * 1998-08-25 2000-03-07 Alps Electric Co Ltd Iron base soft magnetic alloy
CN1270861A (en) * 1999-04-15 2000-10-25 日立金属株式会社 Soft magnetic alloy thin band, magnetic part made therefrom and its making method
CN101432827A (en) * 2006-04-28 2009-05-13 日立金属株式会社 Magnetic core for current transformer, current transformer, and watt-hour meter
CN104131243A (en) * 2014-07-28 2014-11-05 安泰科技股份有限公司 Iron-based amorphous alloy being not brittle after annealing and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6468446A (en) * 1987-09-09 1989-03-14 Hitachi Metals Ltd Fe based amorphous alloy
EP0695812A1 (en) * 1994-08-01 1996-02-07 Hitachi Metals, Ltd. Nanocrystalline alloy with insulating coating, magnetic core made thereof, and process for forming insulating coating on a nanocrystalline alloy
JP2000073148A (en) * 1998-08-25 2000-03-07 Alps Electric Co Ltd Iron base soft magnetic alloy
CN1270861A (en) * 1999-04-15 2000-10-25 日立金属株式会社 Soft magnetic alloy thin band, magnetic part made therefrom and its making method
CN101432827A (en) * 2006-04-28 2009-05-13 日立金属株式会社 Magnetic core for current transformer, current transformer, and watt-hour meter
CN104131243A (en) * 2014-07-28 2014-11-05 安泰科技股份有限公司 Iron-based amorphous alloy being not brittle after annealing and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
尹克宁: "影响硅钢片电磁性能的主要因素", 《变压器设计原理》 *

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