CN108516703A - A kind of preparation method of glass fiber infiltration agent - Google Patents
A kind of preparation method of glass fiber infiltration agent Download PDFInfo
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- CN108516703A CN108516703A CN201810543844.9A CN201810543844A CN108516703A CN 108516703 A CN108516703 A CN 108516703A CN 201810543844 A CN201810543844 A CN 201810543844A CN 108516703 A CN108516703 A CN 108516703A
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- glass fiber
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/465—Coatings containing composite materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/36—Epoxy resins
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of preparation methods of glass fiber infiltration agent, are as follows：Step 1 configures hydrating solution；Step 2 configures dispersion liquid；Step 3, lubricant configuration liquid；Step 4 configures mixed liquor：Binder, lubricating fluid, antistatic agent and epoxy emulsion are sequentially added in dispersion liquid and stirred；Step 5 dilutes homogeneous：Soft water will be added in mixed liquor, obtain dilution, dilution is put into homogenizer stirring refinement uniformly to get to finished product.The present invention by lubricant status by emulsion form be processed into it is liquid after be added again; and active water molecular additives are added in size; homogenizer is increased to solution; to achieve the effect that adjust the performance of epoxy water solution system row; the surface energy for reducing glass fiber single filament and size interface, makes precursor be adsorbed in impregnation process and is more prone to, adsorption plane is more uniform; outage rate height and the easily damaged disadvantage of fiber are avoided, the economic benefit of the producer can be improved.
Description
Technical field
The present invention relates to glass fibre production field, the preparation method of specifically a kind of glass fiber infiltration agent.
Background technology
Glass fibre is a kind of inorganic non-metallic material of superior performance, and fiberglass products have excellent intensity, just
Degree, has the characteristics such as portability, corrosion resistance, durability, weatherability, and it is raw material through high temperature that it, which is using glass marble or discarded glass,
What the techniques such as melted, wire drawing, doff, woven fabric were manufactured into, a diameter of several microns of monofilament are equivalent to twenties microns
The 1/20-1/5 of a piece hairline is made of hundreds of even thousands of monofilament per bundle fiber precursor, is widely used in building, hands over
The fields such as logical, electronics, electrical, chemical industry metallurgical, environmental protection, national defence.Size is key factor place when producing such product.
Size used in 7781# glass fabrics generally uses epoxy aqueous solution series at present, and lubricant is emulsion form, this
Class size easily causes glass pulley adhesion precursor in drawing process, to cause the shortcomings of outage rate is high, fiber is easily damaged, this
Just reduce the economic benefit of the glass fibre producer.
Invention content
The purpose of the present invention is to provide a kind of preparation methods of glass fiber infiltration agent, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides the following technical solutions：
A kind of preparation method of glass fiber infiltration agent, is as follows：
Step 1 configures hydrating solution：Glacial acetic acid and soft water are stirred evenly and obtain hydrating solution, glacial acetic acid and soft water
Mass ratio be 1-3：997-999；
Step 2 configures dispersion liquid：Coupling agent is added in hydrating solution and supersonic oscillations are uniform, coupling agent and water
The mass ratio for solving solution is 2-4.5:995-998 obtains dispersion liquid；
Step 3, lubricant configuration liquid：By soft water, ethoxy alcohol disodium sulfosuccinate, polyethylene glycol and cation
Film is according to mass ratio 86-91：2.6-3.5:3.8-4.4:6.6-7.5 is mixed and is stirred evenly with the rotating speed of 90-150rpm,
Obtain lubricating fluid；
Step 4 configures mixed liquor：Binder, lubricating fluid, antistatic agent and epoxy emulsion are sequentially added into dispersion
In liquid and stir 30-45 minutes, dispersion liquid, lubricating fluid, bonding agent, antistatic agent and epoxy emulsion mass ratio be
1.6-1.9:9.5-10.8:2.7-3.4:0.15-0.28:83-86.6 obtaining mixed liquor；
Step 5 dilutes homogeneous：Soft water will be added in mixed liquor, obtains dilution, the mass ratio of mixed liquor and soft water
For 13.2-14.6:86, dilution is put into homogenizer stirring refinement uniformly to get to finished product.
As a further solution of the present invention：Coupling agent uses r- methacryloxypropyl trimethoxy silanes.
As a further solution of the present invention：The power of supersonic oscillations is 160-200W, and the frequency of supersonic oscillations is
36-40KHz。
As a further solution of the present invention：Binder uses vinyl acetate-acrylate, antistatic agent to use chlorination
Lithium, epoxy emulsion use bis-phenol A glycidyl ether lotion.
As a further solution of the present invention：The mixing speed of homogenizer is 900-1500rpm.
Compared with prior art, the beneficial effects of the invention are as follows：Raw material sources of the present invention are extensive, and preparation process is simple, will
Lubricant status by emulsion form be processed into it is liquid after be added again, and in size add active water molecular additives,
Homogenizer is increased to solution, to achieve the effect that adjust the performance of epoxy water solution system row, reduces glass fiber single filament and leaching
The surface energy for moistening agent interface, makes precursor adsorb in impregnation process and is more prone to, and adsorption plane is more uniform, avoid outage rate height with
The easily damaged disadvantage of fiber, can improve the economic benefit of the producer, and prospect of the application is wide.
Description of the drawings
Fig. 1 is the flow chart of the preparation method of glass fiber infiltration agent.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of preparation method of glass fiber infiltration agent, is as follows：
Step 1 configures hydrating solution：Glacial acetic acid and soft water are stirred evenly and obtain hydrating solution, glacial acetic acid and soft water
Mass ratio be 1.6：997；
Step 2 configures dispersion liquid：R- methacryloxypropyl trimethoxy silanes are added in hydrating solution simultaneously
And supersonic oscillations are uniform, the mass ratio of r- methacryloxypropyl trimethoxy silanes and hydrating solution is 2.3:
995, obtain dispersion liquid；
Step 3, lubricant configuration liquid：By soft water, ethoxy alcohol disodium sulfosuccinate, polyethylene glycol and cation
Film is according to mass ratio 86：2.6:3.8:6.6 are mixed and are stirred evenly with the rotating speed of 120rpm, and lubricating fluid is obtained；
Step 4 configures mixed liquor：Binder, lubricating fluid, antistatic agent and epoxy emulsion are sequentially added into dispersion
In liquid and stir 36 minutes, dispersion liquid, lubricating fluid, bonding agent, antistatic agent and epoxy emulsion mass ratio be
1.6:9.5:2.7:0.15:83, obtain mixed liquor；
Step 5 dilutes homogeneous：Soft water will be added in mixed liquor, obtains dilution, the mass ratio of mixed liquor and soft water
It is 13.2:86, dilution is put into in the homogenizer of 1200rpm stirring refinement uniformly to get to finished product.
Embodiment 2
A kind of preparation method of glass fiber infiltration agent, is as follows：
Step 1 configures hydrating solution：Glacial acetic acid and soft water are stirred evenly and obtain hydrating solution, glacial acetic acid and soft water
Mass ratio be 1：499；
Step 2 configures dispersion liquid：Coupling agent is added in hydrating solution and supersonic oscillations are uniform, supersonic oscillations
Power be 175W, the frequencies of supersonic oscillations is 38KHz, and the mass ratio of coupling agent and hydrating solution is 3:997, divided
Dispersion liquid；
Step 3, lubricant configuration liquid：By soft water, ethoxy alcohol disodium sulfosuccinate, polyethylene glycol and cation
Film is according to mass ratio 89：3:4:7 are mixed and are stirred evenly with the rotating speed of 135rpm, and lubricating fluid is obtained；
Step 4 configures mixed liquor：Vinyl acetate-acrylate, lubricating fluid, lithium chloride and bisphenol-A are shunk sweet
Oily ether lotion is sequentially added in dispersion liquid and is stirred 42 minutes, dispersion liquid, vinyl acetate-acrylate, lubricating fluid, chlorine
The mass ratio for changing lithium and bis-phenol A glycidyl ether lotion is 1.8:10:3:0.2:85, obtain mixed liquor；
Step 5 dilutes homogeneous：Soft water will be added in mixed liquor, obtains dilution, the mass ratio of mixed liquor and soft water
It is 14:86, dilution is put into homogenizer stirring refinement uniformly to get to finished product.
As a further solution of the present invention：Coupling agent uses r- methacryloxypropyl trimethoxy silanes.
As a further solution of the present invention：.
As a further solution of the present invention：Binder uses vinyl acetate-acrylate, antistatic agent to use chlorination
Lithium, epoxy emulsion use bis-phenol A glycidyl ether lotion.
As a further solution of the present invention：The mixing speed of homogenizer is 900-1500rpm
Embodiment 3
A kind of preparation method of glass fiber infiltration agent, is as follows：
Step 1 configures hydrating solution：Glacial acetic acid and soft water are stirred evenly and obtain hydrating solution, glacial acetic acid and soft water
Mass ratio be 3：999；
Step 2 configures dispersion liquid：R- methacryloxypropyl trimethoxy silanes are added in hydrating solution simultaneously
And supersonic oscillations are uniform, the power of supersonic oscillations is 190W, and the frequency of supersonic oscillations is 36-40KHz, r- metering systems
The mass ratio of acryloxypropylethoxysilane trimethoxy silane and hydrating solution is 4.5:998, obtain dispersion liquid；
Step 3, lubricant configuration liquid：By soft water, ethoxy alcohol disodium sulfosuccinate, polyethylene glycol and cation
Film is according to mass ratio 91：3.5:4.4:7.5 are mixed and are stirred evenly with the rotating speed of 90rpm, and lubricating fluid is obtained；
Step 4 configures mixed liquor：Vinyl acetate-acrylate, lubricating fluid, lithium chloride and bisphenol-A are shunk sweet
Oily ether lotion is sequentially added in dispersion liquid and is stirred 40 minutes, dispersion liquid, vinyl acetate-acrylate, lubricating fluid, chlorine
The mass ratio for changing lithium and bis-phenol A glycidyl ether lotion is 1.9:10.8:3.4:0.28:86.6, obtain mixed liquor；
Step 5 dilutes homogeneous：Soft water will be added in mixed liquor, obtains dilution, the mass ratio of mixed liquor and soft water
It is 14.6:86, dilution is put into in the homogenizer of 1200rpm stirring refinement uniformly to get to finished product.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (5)
1. a kind of preparation method of glass fiber infiltration agent, which is characterized in that be as follows：
Step 1 configures hydrating solution：Glacial acetic acid and soft water are stirred evenly and obtain hydrating solution, the matter of glacial acetic acid and soft water
The ratio between amount is 1-3：997-999；
Step 2 configures dispersion liquid：Coupling agent is added in hydrating solution and supersonic oscillations are uniform, coupling agent and hydrolysis are molten
The mass ratio of liquid is 2-4.5:995-998 obtains dispersion liquid；
Step 3, lubricant configuration liquid：By soft water, ethoxy alcohol disodium sulfosuccinate, polyethylene glycol and cationic film
According to mass ratio 86-91：2.6-3.5:3.8-4.4:6.6-7.5 is mixed and is stirred evenly with the rotating speed of 90-150rpm, is obtained
Lubricating fluid；
Step 4 configures mixed liquor：Binder, lubricating fluid, antistatic agent and epoxy emulsion are sequentially added in dispersion liquid
And stir 30-45 minutes, dispersion liquid, lubricating fluid, bonding agent, antistatic agent and epoxy emulsion mass ratio be 1.6-
1.9:9.5-10.8:2.7-3.4:0.15-0.28:83-86.6 obtaining mixed liquor；
Step 5 dilutes homogeneous：Soft water will be added in mixed liquor, obtain dilution, the mass ratio of mixed liquor and soft water is
13.2-14.6:86, dilution is put into homogenizer stirring refinement uniformly to get to finished product.
2. the preparation method of glass fiber infiltration agent according to claim 1, which is characterized in that the coupling agent uses r-
Methacryloxypropyl trimethoxy silane.
3. the preparation method of glass fiber infiltration agent according to claim 1 or 2, which is characterized in that the ultrasonic wave shakes
The power swung is 160-200W, and the frequency of supersonic oscillations is 36-40KHz.
4. the preparation method of glass fiber infiltration agent according to claim 1, which is characterized in that the binder uses vinegar
Sour ethylene-acrylate, antistatic agent use lithium chloride, epoxy emulsion to use bis-phenol A glycidyl ether lotion.
5. the preparation method of glass fiber infiltration agent according to claim 1,2 or 4, which is characterized in that the homogenizer
Mixing speed be 900-1500rpm.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810543844.9A CN108516703B (en) | 2018-05-31 | 2018-05-31 | Preparation method of glass fiber impregnating compound |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810543844.9A CN108516703B (en) | 2018-05-31 | 2018-05-31 | Preparation method of glass fiber impregnating compound |
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| CN108516703A true CN108516703A (en) | 2018-09-11 |
| CN108516703B CN108516703B (en) | 2021-03-30 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110040984A (en) * | 2019-05-09 | 2019-07-23 | 成都中玻复合材料有限公司 | A kind of basalt fibre rubber composite material size |
| WO2020125814A1 (en) * | 2018-12-18 | 2020-06-25 | 中材科技股份有限公司 | Sizing agent, coloured glass fibre, and preparation method therefor and application thereof |
| CN114717849A (en) * | 2022-05-10 | 2022-07-08 | 五河县维佳复合材料有限公司 | Modified glass fiber winding wire and reinforced composite material prepared from same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101376570A (en) * | 2008-09-26 | 2009-03-04 | 江苏九鼎新材料股份有限公司 | Treating compound special for high textile performance weft yarn and preparation thereof |
| WO2011024021A1 (en) * | 2009-08-31 | 2011-03-03 | Ovc Intellectual Capital, Llc | Sizing composition containing a biodegradable polymer |
| CN102978938A (en) * | 2012-11-29 | 2013-03-20 | 山东玻纤复合材料有限公司 | Special impregnating compound for glass fiber swelled yarn and preparation method thereof |
| CN103896500A (en) * | 2012-12-31 | 2014-07-02 | 泰山玻璃纤维邹城有限公司 | Impregnating compound for cake yarn for cord thread and preparation method of impregnating compound |
-
2018
- 2018-05-31 CN CN201810543844.9A patent/CN108516703B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101376570A (en) * | 2008-09-26 | 2009-03-04 | 江苏九鼎新材料股份有限公司 | Treating compound special for high textile performance weft yarn and preparation thereof |
| WO2011024021A1 (en) * | 2009-08-31 | 2011-03-03 | Ovc Intellectual Capital, Llc | Sizing composition containing a biodegradable polymer |
| CN102978938A (en) * | 2012-11-29 | 2013-03-20 | 山东玻纤复合材料有限公司 | Special impregnating compound for glass fiber swelled yarn and preparation method thereof |
| CN103896500A (en) * | 2012-12-31 | 2014-07-02 | 泰山玻璃纤维邹城有限公司 | Impregnating compound for cake yarn for cord thread and preparation method of impregnating compound |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020125814A1 (en) * | 2018-12-18 | 2020-06-25 | 中材科技股份有限公司 | Sizing agent, coloured glass fibre, and preparation method therefor and application thereof |
| CN110040984A (en) * | 2019-05-09 | 2019-07-23 | 成都中玻复合材料有限公司 | A kind of basalt fibre rubber composite material size |
| CN114717849A (en) * | 2022-05-10 | 2022-07-08 | 五河县维佳复合材料有限公司 | Modified glass fiber winding wire and reinforced composite material prepared from same |
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| CN108516703B (en) | 2021-03-30 |
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