CN108516697A - A kind of super hydrophilic antireflecting coating, preparation method and glass - Google Patents
A kind of super hydrophilic antireflecting coating, preparation method and glass Download PDFInfo
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- CN108516697A CN108516697A CN201810355968.4A CN201810355968A CN108516697A CN 108516697 A CN108516697 A CN 108516697A CN 201810355968 A CN201810355968 A CN 201810355968A CN 108516697 A CN108516697 A CN 108516697A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/213—SiO2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/425—Coatings comprising at least one inhomogeneous layer consisting of a porous layer
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/111—Deposition methods from solutions or suspensions by dipping, immersion
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/114—Deposition methods from solutions or suspensions by brushing, pouring or doctorblading
Abstract
The present invention relates to technical field of function materials, disclose a kind of preparation method of super hydrophilic antireflecting coating, include the following steps：(1) at room temperature, 1~100 parts surfactant, 1000~20000 parts by weight of deionized water, 20~300 part by weight of catalyst and 1000~20000 parts by weight alcohols solvents are mixed, mixed liquor A is made；(2) at room temperature, 1~1000 parts by weight ethyl orthosilicate and 0~1000 parts by weight of ethanol are mixed, after stirring evenly, mixed liquid B is made；(3) under 15 DEG C~70 DEG C temperature conditions, mixed liquor A is added dropwise in mixed liquid B, is stirred to react 0.5~10 hour, discharges, obtains the SiO of a diameter of 3~200nm with mesoporous property2Nano spherical particle sol solution product, is denoted as product C；(4) at room temperature, 100 parts by weight product C are mixed with 1~20 parts by weight pore creating material and 1~100 parts by weight coalescents, stirs evenly, obtains mixture D；(5) mixture D is coated on glass, is sintered at 300 DEG C~600 DEG C, super hydrophilic antireflecting coating is obtained on glass.
Description
Technical field
The present invention relates to technical field of function materials, specifically a kind of super hydrophilic antireflecting coating, preparation method and glass
Glass.
Background technology
The general preparation method of self-cleaning fog glass is to cover one layer of organic or inorganic coating in glass article surface, from
And glass surface is made to generate a kind of unique physicochemical characteristics, so that the droplet for dropping in glass surface is paved rapidly (super hydrophilic
Characteristic), i.e., the contact angle of small water droplet on the glass surface levels off to zero degree, forms uniform moisture film, does not interfere with mirror thus
Face is imaged and translucency, and takes away spot by the gravity fall of uniform water film, reaches automatically cleaning effect.Glass is anti-reflection to exist
Glass surface plates a tunic, and the two-beam that film upper and lower surface reflects is made to generate destructive interference, and reflected light disappears, and transmitted light increases
By force.The preparation of high-performance anti-reflection film is crucial to be to design the nano coating with low-refraction.
As manufactured with super hydrophilic anti-reflective glass, when rainy day, can be formed in glass surface for windshield and rearview mirror
Uniform water film (non-water droplet) and keep good light permeability, mirror image, to considerably increase traffic safety.Skyscraper window
The cleaning of family glass is an intractable and dangerous job, and if using superhydrophilic self-cleaning glass manufacture, rain can be relied on
Water washes away or tap water flushing can keep cleaning, and reduces labor intensity significantly.If solar panels surface is increased using automatically cleaning
Saturating glass can greatly improve solar energy utilization ratio, first, the antireflective effect of coating can reduce the reflection of sunlight, increase sunlight
Absorption, second is that automatically cleaning effect can prevent solar panels surface from being polluted and being caused the sun of solar panels by dust, spot
Light utilization efficiency declines.
There is photic super hydrophilic TiO on the market at present2Coated glass utilizes TiO2Photocatalysis characteristic improve glass table
The hydrophily in face, this method have apparent limitation：It can just be shown first in the environment for having ultraviolet light good
Hydrophilicity and have no this effect, furthermore TiO in dark surrounds2Film does not reach super hydrophilic standard, and (i.e. contact angle is less than
5 °), and translucency is bad.In addition, also someone has successfully prepared super hydrophilic antifog porous silica silicon coating, though the coating
So there is excellent super hydrophilic anti-fog performance, but visible light transmittance is less than 90%, and preparation process is complicated.Therefore it provides one
Planting superhydrophilic self-cleaning, antifog, anti-reflective glass coating preparation method that simple for process, of low cost and performance is stablized has weight
Want realistic meaning.
Invention content
The object of the present invention is to provide a kind of super hydrophilic antireflecting coating, preparation method and glass.The preparation method raw material
It is easy to get, equipment and simple for process, of low cost, glass hard (HRC65Yi Shang) obtained is not high, easy to scratch, has high translucency and super close
It is aqueous.
A kind of preparation method of super hydrophilic antireflecting coating, includes the following steps：
(1) at room temperature, by 1~100 parts surfactant, 1000~20000 parts by weight of deionized water, 20~300
Part by weight of catalyst and the mixing of 1000~20000 parts by weight alcohols solvents, are made mixed liquor A；
(2) at room temperature, 1~1000 parts by weight ethyl orthosilicate and 0~1000 parts by weight of ethanol are mixed, is stirred evenly
Afterwards, mixed liquid B is made；
(3) under 15 DEG C~70 DEG C temperature conditions, mixed liquor A is added dropwise in mixed liquid B, it is small to be stirred to react 0.5~10
When, discharging obtains the SiO of a diameter of 3~200nm with mesoporous property2Nano spherical particle sol solution product, is denoted as production
Object C；
(4) at room temperature, 100 parts by weight product C and 1~20 parts by weight pore creating material and 1~100 parts by weight coalescents are mixed
It closes, stirs evenly, obtain mixture D；
(5) mixture D is coated on glass, is sintered at 300 DEG C~600 DEG C, super hydrophilic antireflecting coating is obtained on glass.
While super hydrophilic antireflecting coating is made in above-mentioned preparation method, superhydrophilic self-cleaning anti-reflective glass has also been made.
Preferably, the thickness of the super hydrophilic antireflecting coating is 200~5000nm.
Preferably, the catalyst described in step (1) is concentrated ammonia liquor, hydrochloric acid, sodium hydroxide, triethanolamine, triethylamine, nitre
One or more kinds of combinations of acid, acetic acid, phosphoric acid, boric acid, sulfuric acid.
Preferably, the alcohols solvent described in step (1) is ethyl alcohol, methanol, isopropanol, n-butanol, ethylene glycol, propylene glycol
One or more kinds of combinations.
Preferably, the surfactant described in step (2) is cetyl trimethylammonium bromide, cetyl trimethyl chlorine
Change ammonium, dodecyl trimethyl ammonium bromide, lauryl sodium sulfate, neopelex, PULLRONIC F68-
Polyoxyethylene triblock polyether (F127), alkyl phenol polyoxyethylene ether (APEO), high-carbon fatty alcohol polyoxyethylene ether (AEO), fat
Fat acid polyoxyethylene ester (AE), fatty acid methyl ester ethoxylate (FMEE), the ethylene oxide adduct of polypropylene glycol, alcohol ether sulphur
Hydrochlorate (AES), alcohol ether phosphate, alcohol ether sulphates salt (AS), sorbitan ester, citric acid, citrate, alkylol acyl
One or more kinds of combinations in amine, sucrose ester.
Preferably, the pore creating material described in step (4) is benzoic acid, citric acid, citrate, lauryl sodium sulfate, ten
In six alkyl trimethyl ammonium bromides, polyvinyl alcohol, white dextrin, stearic acid, ammonium hydrogen carbonate, polyethylene glycol, urea, paraformaldehyde
One or more kinds of combinations.
Preferably, the coalescents described in step (4) are isobutyrone, n,N-Dimethylformamide, ethylene glycol list
Butyl ether, butyl acrylate, dimethyl succinate, dimethyl glutarate, dimethyl adipate, ethylene glycol ethyl ether, cyclohexanone, poly- second
One or more kinds of combinations of enol, n-butanol, dipropylene glycol propyl ether, dimethyl ether.
Preferably, mixture D is coated in the coating method on glass in step (5) includes：Dip coating, spread coating or spray
Coating.
Preferably, sintering time is 0.5~8 hour.
Another object of the present invention is to open one kind passing through super hydrophilic antireflecting coating made from above-mentioned preparation method.
Another object of the present invention is to disclose a kind of superhydrophilic self-cleaning anti-reflective glass, contain by above-mentioned on the glass
Super hydrophilic antireflecting coating made from preparation method.
The super hydrophilic antireflecting coating of the present invention is assembled by inorganic mesoporous Nano particles of silicon dioxide, and coating surface has
Multistage composite pore space structure.Inner void and mesoporous dioxy of the multistage composite pore space structure by mesoporous silicon dioxide nano particle
Gap hole between SiClx is combined.The size of the inner void of mesoporous silicon dioxide nano particle be 0.2~
40nm.Gap hole between mesoporous silicon oxide is generated by removing pore creating material, and size is 1~150nm.
Compared with prior art, the invention has the advantages that：
The present invention removes pore creating material and coalescents obtains the mesopore between mesoporous silicon oxide by sintering processing
Hole, while removing the surfactant in mesoporous and obtaining the inner void of mesoporous silicon dioxide nano particle, one-step method is realized more
The formation of grade hole.The special compound pore space structure of the present invention assigns coating excellent super hydrophilicity, and transparency height,
Automatically cleaning and antireflective effect are notable.
The preparation method raw material of the present invention are easy to get, equipment and simple for process, of low cost.
The super hydrophilic antireflecting coating of the present invention has high translucency and Superhydrophilic simultaneously：Light transmittance is up to 95.0~
98.5%, coating is in air 0~5 ° to the contact angle of water.
The super hydrophilic antireflecting coating hardness of the present invention is not high, easy to scratch, can be used for needing automatically cleaning, antifog processing and increasing
On saturating glassware.
Description of the drawings
Fig. 1 is the schematic diagram that coating made from the embodiment of the present invention 1 has Superhydrophilic；
Fig. 2 is SiO in the embodiment of the present invention 12Meso-porous nano SiO made from nano spherical particle sol solution product2Particle
Projection electron microscope.
Specific implementation mode
With reference to embodiment, the invention will be further described, but it should be recognized that embodiment is not to this hair
Bright claimed range is construed as limiting.
Embodiment 1：By 1g cetyl trimethylammonium bromides, 100ml deionized waters, 0.4g sodium hydroxides and 100ml second
Alcohol is uniformly mixed and stirs 10min (obtaining mixed liquor A), and 30ml ethyl alcohol, 8g ethyl orthosilicates are mixed and stirred for 10min (
To mixed liquid B), mixed liquid B is instilled with the speed of 1 drop per second in mixed liquor A, (magnetic agitation) reacts 2h at 15 DEG C, obtains
To SiO2Nano spherical particle sol solution product (product C).It takes 50ml products C in beaker, 10ml n-butanols, 2g is added
PEG smears glass surface after stirring 10min, and the thickness of coating is 200~5000nm, and coating method includes：Dip coating, brushing
Method or spray coating method.It is sintered after solidification 30min.Sintering temperature is 300 DEG C~600 DEG C, and sintering time is 0.5~8 hour.
Obtained coating has Superhydrophilic, as shown in Fig. 1.
Wherein, by the SiO of preparation2Colloidal sol carries out centrifuge washing and is obtained to centrifugation with deionized water and ethyl alcohol centrifuge washing
SiO2The aqueous hydrochloric acid solution of middle addition 5%, 80 DEG C of insulation reaction 20h obtain meso-porous nano SiO2Particle.Using projection Electronic Speculum
It is observed, as shown in Fig. 2.
Embodiment 2：2g alcohol ether phosphate, 100ml deionized waters, 1g concentrated ammonia liquors and 50ml isopropanols are uniformly mixed and are stirred
10min (obtaining mixed liquor A) is mixed, 500ml ethyl alcohol, 10g ethyl orthosilicates are mixed and stirred for 10min (obtaining mixed liquid B), it will
Mixed liquid B is instilled with the speed of 1 drop per second in mixed liquor A, and (magnetic agitation) reacts 5h at 50 DEG C, obtains SiO2Ball shaped nano
Colloidal sol solution product (product C).It takes 50ml products C in beaker, 35ml isobutyrone, 5ml N, N- diformazans is added
Base formamide, 4g PEG smear glass surface after stirring 10min, and the thickness of coating is 200~5000nm, and coating method includes：
Dip coating, spread coating or spray coating method.It is sintered after solidification 30min.Sintering temperature is 300 DEG C~600 DEG C, and sintering time is
0.5~8 hour.
Embodiment 3：2g neopelexes, 50ml deionized waters, 0.02g nitric acid and 20ml n-butanols are mixed equal
Even and stir 10min (obtaining mixed liquor A), 150ml ethyl alcohol, 2g ethyl orthosilicates, which are mixed and stirred for 10min, (obtains mixed liquor
B), mixed liquid B is instilled with the speed of 1 drop per second in mixed liquor A, (magnetic agitation) reacts 10h at 25 DEG C, obtains SiO2Ball
Shape nanoparticle sol solution product (product C).It takes 50ml products C in beaker, 100ml n-butanols, 5ml ethylene glycol lists is added
Butyl ether, 4g citric acids smear glass surface after stirring 10min, and the thickness of coating is 200~5000nm, and coating method includes：Leaching
Coating, spread coating or spray coating method.It is sintered after solidification 30min.Sintering temperature is 300 DEG C~600 DEG C, and sintering time is
0.5~8 hour.
Embodiment 4：2g alkyl phenol polyoxyethylene ether, 50ml deionized waters, 3g triethanolamines and 200ml ethylene glycol are mixed
Uniformly and 10min (obtaining mixed liquor A) is stirred, 60ml ethyl alcohol, 5g methyl orthosilicates, which are mixed and stirred for 10min, (to be mixed
Liquid B), mixed liquid B is instilled with the speed of 1 drop per second in mixed liquor A, (magnetic agitation) reacts 0.5h at 30 DEG C, obtains
SiO2Nano spherical particle sol solution product (product C).It takes 50ml products C in beaker, 1ml N, N- dimethyl methyls is added
Amide, 5ml ethylene glycol monobutyl ethers, 10g cetyl trimethylammonium bromides smear glass surface, the thickness of coating after stirring 10min
Degree is 200~5000nm, and coating method includes：Dip coating, spread coating or spray coating method.It is sintered after solidification 30min.Sintering
Temperature is 300 DEG C~600 DEG C, and sintering time is 0.5~8 hour.
Embodiment 5：2g alkylolamides, 50ml deionized waters, 2.5g boric acid and 150ml isopropanols are uniformly mixed and are stirred
10min (obtaining mixed liquor A) is mixed, 320ml ethyl alcohol, 8g methyl orthosilicates are mixed and stirred for 10min (obtaining mixed liquid B), it will
Mixed liquid B is instilled with the speed of 1 drop per second in mixed liquor A, and (magnetic agitation) reacts 7h at 50 DEG C, obtains SiO2Ball shaped nano
Colloidal sol solution product (product C).It takes 50ml products C in beaker, 50ml dimethyl succinates, 5ml ethylene glycol lists is added
Butyl ether, 20g ammonium hydrogen carbonate smear glass surface after stirring 10min, and the thickness of coating is 200~5000nm, coating method packet
It includes：Dip coating, spread coating or spray coating method.It is sintered after solidification 30min.Sintering temperature is 300 DEG C~600 DEG C, when sintering
Between be 0.5~8 hour.
Embodiment 6：2g fatty acid methyl ester ethoxylates, 50ml deionized waters, 0.8g phosphoric acid and 80ml propylene glycol are mixed
It closes uniformly and stirs 10min (obtaining mixed liquor A), 80ml ethyl alcohol, 6g methyl orthosilicates, which are mixed and stirred for 10min, (to be mixed
Close liquid B), mixed liquid B is instilled with the speed of 1 drop per second in mixed liquor A, (magnetic agitation) reacts 2h at 70 DEG C, obtains
SiO2Nano spherical particle sol solution product (product C).Take 50ml products C in beaker, addition 80ml dipropylene glycol propyl ethers,
5ml ethylene glycol monobutyl ethers, 1g paraformaldehydes smear glass surface after stirring 10min, and the thickness of coating is 200~5000nm, apply
Film method includes：Dip coating, spread coating or spray coating method.It is sintered after solidification 30min.Sintering temperature is 300 DEG C~600
DEG C, sintering time is 0.5~8 hour.
Examples 1 to 6 coating obtained on glass is super hydrophilic antireflecting coating, and the glass containing the coating is
Superhydrophilic self-cleaning anti-reflective glass.
The performance of super hydrophilic antireflecting coating made from Examples 1 to 6 is as shown in table 1：
1 coating performance of table
As it can be seen from table 1 the super hydrophilic antireflecting coating of the present invention has high translucency and Superhydrophilic simultaneously：Thoroughly
Light rate is up to 95.0~98.5%, and coating is in air 0~5 ° to the contact angle of water.The super hydrophilic antireflecting coating of the present invention is hard
Spend it is high, not easy to scratch, can be used for needing automatically cleaning, it is antifog processing and antireflective glassware on.
The preparation method raw material of the present invention are easy to get, equipment and simple for process, of low cost.By sintering processing, remove
Pore creating material and coalescents obtain the gap hole between mesoporous silicon oxide, while the surfactant removed in mesoporous obtains
The inner void of mesoporous silicon dioxide nano particle, one-step method realize the formation of multistage hole.The special compound hole of the present invention
Structure assigns coating excellent super hydrophilicity, and transparency is high, automatically cleaning and antireflective effect are notable.
It is provided for the embodiments of the invention technical solution above to be described in detail, specific case used herein
The principle and embodiment of the embodiment of the present invention are expounded, the explanation of above example is only applicable to help to understand this
The principle of inventive embodiments；Meanwhile for those of ordinary skill in the art, embodiment according to the present invention, in specific embodiment party
There will be changes in formula and application range, in conclusion the content of the present specification should not be construed as limiting the invention.
Claims (10)
1. a kind of preparation method of super hydrophilic antireflecting coating, which is characterized in that include the following steps：
(1) at room temperature, by 1~100 parts surfactant, 1000~20000 parts by weight of deionized water, 20~300 weight
Part catalyst and the mixing of 1000~20000 parts by weight alcohols solvents, are made mixed liquor A；
(2) at room temperature, 1~1000 parts by weight ethyl orthosilicate and 0~1000 parts by weight of ethanol are mixed, after stirring evenly, system
Obtain mixed liquid B；
(3) under 15 DEG C~70 DEG C temperature conditions, mixed liquor A is added dropwise in mixed liquid B, is stirred to react 0.5~10 hour, goes out
Material, obtains the SiO of a diameter of 3~200nm with mesoporous property2Nano spherical particle sol solution product, is denoted as product C；
(4) at room temperature, 100 parts by weight product C are mixed with 1~20 parts by weight pore creating material and 1~100 parts by weight coalescents,
It stirs evenly, obtains mixture D；
(5) mixture D is coated on glass, is sintered at 300 DEG C~600 DEG C, super hydrophilic antireflecting coating is obtained on glass.
2. a kind of preparation method of super hydrophilic antireflecting coating according to claim 1, which is characterized in that the super hydrophilic increasing
The thickness of antireflective coating layer is 200~5000nm.
3. a kind of preparation method of super hydrophilic antireflecting coating according to claim 1, which is characterized in that step (1) is described
Catalyst be concentrated ammonia liquor, hydrochloric acid, sodium hydroxide, triethanolamine, triethylamine, nitric acid, acetic acid, phosphoric acid, boric acid, sulfuric acid one kind
Or more than one combination.
4. a kind of preparation method of super hydrophilic antireflecting coating according to claim 1, which is characterized in that step (1) is described
Alcohols solvent be ethyl alcohol, methanol, isopropanol, n-butanol, ethylene glycol, propylene glycol one or more kinds of combinations.
5. a kind of preparation method of super hydrophilic antireflecting coating according to claim 1, which is characterized in that step (2) is described
Surfactant be cetyl trimethylammonium bromide, hexadecyltrimethylammonium chloride, dodecyl trimethyl ammonium bromide,
Lauryl sodium sulfate, neopelex, polyoxyethylene-poly-oxypropylene polyoxyethylene triblock polyether (F127), alkane
Base phenol polyethenoxy ether (APEO), high-carbon fatty alcohol polyoxyethylene ether (AEO), polyoxyethylene carboxylate (AE), fatty acid methyl
Ester ethoxylate (FMEE), the ethylene oxide adduct of polypropylene glycol, ether alcohol sulfate (AES), alcohol ether phosphate, alcohol ether sulphur
It is one or more kinds of in acid esters salt (AS), sorbitan ester, citric acid, citrate, alkylolamides, sucrose ester
Combination.
6. a kind of preparation method of super hydrophilic antireflecting coating according to claim 1, which is characterized in that step (4) is described
Pore creating material be benzoic acid, citric acid, citrate, lauryl sodium sulfate, cetyl trimethylammonium bromide, polyethylene
One or more kinds of combinations in alcohol, white dextrin, stearic acid, ammonium hydrogen carbonate, polyethylene glycol, urea, paraformaldehyde.
7. a kind of preparation method of super hydrophilic antireflecting coating according to claim 1, which is characterized in that step (4) is described
Coalescents be isobutyrone, N,N-dimethylformamide, ethylene glycol monobutyl ether, butyl acrylate, succinic acid diformazan
Ester, dimethyl glutarate, dimethyl adipate, ethylene glycol ethyl ether, cyclohexanone, polyvinyl alcohol, n-butanol, dipropylene glycol propyl ether,
One or more kinds of combinations of dimethyl ether.
8. a kind of preparation method of super hydrophilic antireflecting coating according to claim 1, which is characterized in that will in step (5)
Mixture D is coated in the coating method on glass：Dip coating, spread coating or spray coating method；Sintering time is 0.5~8 hour.
9. super hydrophilic antireflecting coating made from the preparation method as described in any one of claim 1~8.
10. a kind of superhydrophilic self-cleaning anti-reflective glass, which is characterized in that containing as claimed in claim 9 super close on the glass
Water antireflecting coating.
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| CN201810355968.4A CN108516697A (en) | 2018-04-19 | 2018-04-19 | A kind of super hydrophilic antireflecting coating, preparation method and glass |
| CN201811636428.XA CN109650736A (en) | 2018-04-19 | 2018-12-29 | A kind of super hydrophilic antireflecting coating, preparation method and glass |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718609A (en) * | 2020-07-31 | 2020-09-29 | 宜宾环球光电节能科技有限公司 | Preparation method of self-cleaning coating based on super-hydrophilic principle |
| CN113772961A (en) * | 2021-10-20 | 2021-12-10 | 安徽工程大学 | Photovoltaic glass moth eye bionic anti-reflection film coating liquid and preparation method thereof, anti-reflection film and preparation method thereof |
| CN113943110A (en) * | 2021-10-20 | 2022-01-18 | 安徽工程大学 | Coating liquid and preparation method thereof, photovoltaic glass anti-reflection film and preparation method thereof |
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| US7985400B2 (en) * | 2004-01-26 | 2011-07-26 | Lummus Technology Inc. | Method for making mesoporous or combined mesoporous and microporous inorganic oxides |
| KR20090014457A (en) * | 2007-08-06 | 2009-02-11 | 연세대학교 산학협력단 | Method for manufacturing meso porous silica thin film by using electrostatic attraction |
| CN101214962A (en) * | 2008-01-11 | 2008-07-09 | 东南大学 | Method for preparing mesoporous silicon dioxide micro-sphere by combined template method |
| JP5437662B2 (en) * | 2008-03-03 | 2014-03-12 | 学校法人慶應義塾 | Antireflection film and method for forming the same |
| CN101786801A (en) * | 2009-01-22 | 2010-07-28 | 中国科学院理化技术研究所 | Ultra-hydrophilic antifogging antireflecting coating and preparation method and application thereof |
| CN102311234B (en) * | 2010-07-09 | 2013-05-01 | 中国科学院理化技术研究所 | Transparent self-cleaning SiO2 anti-fogging coating and preparation method thereof |
| CN102584024A (en) * | 2012-01-19 | 2012-07-18 | 蚌埠玻璃工业设计研究院 | Preparation method of efficient increased-transmission and antireflection glass |
| MY185109A (en) * | 2012-05-22 | 2021-04-30 | Dsm Ip Assets Bv | Composition and process for making a porous inorganic oxide coating |
| CN103508681B (en) * | 2012-06-21 | 2015-08-19 | 中国科学院理化技术研究所 | The preparation method of super hydrophilic antireflecting coating and super hydrophilic antireflecting coating |
| US9943826B2 (en) * | 2013-09-26 | 2018-04-17 | Regents Of The University Of Minnesota | Porous silica having high pore volume and methods of making and using same |
| CN106291779B (en) * | 2015-06-01 | 2018-05-08 | 中国科学院理化技术研究所 | A kind of preparation method with high intensity wet-heat resisting cleaning anti-reflection coating |
| GB201512468D0 (en) * | 2015-07-16 | 2015-08-19 | C Tex Ltd And University Of Brighton | Shaped nanoporous bodies |
| CN107200333B (en) * | 2017-06-08 | 2019-06-25 | 北京航空航天大学 | A kind of preparation method and application of silica hydrophilic particle |
| CN107381579A (en) * | 2017-06-28 | 2017-11-24 | 华东师范大学 | A kind of preparation method of mesoporous spherical nano Sio 2 particle |
| CN107325597A (en) * | 2017-07-29 | 2017-11-07 | 深圳孔雀科技开发有限公司 | A kind of preparation method of the ultra-hydrophilic transparent coating based on monodisperse nanosized mesoporous silica |
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2018
- 2018-04-19 CN CN201810355968.4A patent/CN108516697A/en not_active Withdrawn
- 2018-12-29 CN CN201811636428.XA patent/CN109650736A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718609A (en) * | 2020-07-31 | 2020-09-29 | 宜宾环球光电节能科技有限公司 | Preparation method of self-cleaning coating based on super-hydrophilic principle |
| CN113772961A (en) * | 2021-10-20 | 2021-12-10 | 安徽工程大学 | Photovoltaic glass moth eye bionic anti-reflection film coating liquid and preparation method thereof, anti-reflection film and preparation method thereof |
| CN113943110A (en) * | 2021-10-20 | 2022-01-18 | 安徽工程大学 | Coating liquid and preparation method thereof, photovoltaic glass anti-reflection film and preparation method thereof |
| CN113943110B (en) * | 2021-10-20 | 2023-08-15 | 安徽工程大学 | Coating liquid and preparation method thereof, photovoltaic glass anti-reflection film and preparation method thereof |
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