CN108504293A - A kind of corruggted wrapping case adhesive - Google Patents

A kind of corruggted wrapping case adhesive Download PDF

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Publication number
CN108504293A
CN108504293A CN201810497835.0A CN201810497835A CN108504293A CN 108504293 A CN108504293 A CN 108504293A CN 201810497835 A CN201810497835 A CN 201810497835A CN 108504293 A CN108504293 A CN 108504293A
Authority
CN
China
Prior art keywords
parts
water
wrapping case
corruggted wrapping
starch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810497835.0A
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Chinese (zh)
Inventor
邢建良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Zhen Rong Packaging Co Ltd
Original Assignee
Suzhou Zhen Rong Packaging Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Zhen Rong Packaging Co Ltd filed Critical Suzhou Zhen Rong Packaging Co Ltd
Priority to CN201810497835.0A priority Critical patent/CN108504293A/en
Publication of CN108504293A publication Critical patent/CN108504293A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00

Abstract

The invention discloses a kind of corruggted wrapping case adhesive, including:Nano-titanium dioxide, ethyl acetate, starch, methyl methacrylate, potassium peroxydisulfate, water-based hydroxyl polyurethane, water, sodium metasilicate and citric acid, parts by weight shared by each ingredient in the corruggted wrapping case adhesive:39 parts of 20 29 parts of nano-titanium dioxide, 16 26 parts of ethyl acetate, 50 80 parts of starch, 49 parts of methyl methacrylate, 3 10 parts of potassium peroxydisulfate, 6 12 parts of water-based hydroxyl polyurethane, 60 90 parts of water, 5 12 parts of sodium metasilicate and citric acid.By the above-mentioned means, corruggted wrapping case adhesive provided by the invention, significantly improves adhesive effect.

Description

A kind of corruggted wrapping case adhesive
Technical field
The present invention relates to Packaging Box fields, more particularly to a kind of corruggted wrapping case adhesive.
Background technology
The production and making of corrugated fibre box are the maximum application fields of adhesive in the world, wherein using starch as base-material Product because its is cheap, and have suitable characteristic, and occupy ascendancy.Adhesive is to determine box paper product and other packagings The important materials of container bonding quality.The adhesive strength of adhesive is relatively low at present.
Invention content
The invention mainly solves the technical problem of providing a kind of corruggted wrapping case adhesive, significantly improve bonding Effect.
In order to solve the above technical problems, one aspect of the present invention is:A kind of corruggted wrapping case use is provided Adhesive, including:The poly- ammonia of nano-titanium dioxide, ethyl acetate, starch, methyl methacrylate, potassium peroxydisulfate, water-based hydroxyl Ester, water, sodium metasilicate and citric acid, parts by weight shared by each ingredient in the corruggted wrapping case adhesive:Nano-silica Change 20-29 parts of titanium, 16-26 parts of ethyl acetate, 50-80 parts of starch, 4-9 parts of methyl methacrylate, 3-10 parts of potassium peroxydisulfate, water Property 3-9 parts of 6-12 parts of hydroxyl polyurethane, 60-90 parts of water, 5-12 parts of sodium metasilicate and citric acid.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the corruggted wrapping case adhesive Number:It is 20 parts of nano-titanium dioxide, 16 parts of ethyl acetate, 50 parts of starch, 4 parts of methyl methacrylate, 3 parts of potassium peroxydisulfate, aqueous 3 parts of 6 parts of hydroxyl polyurethane, 60 parts of water, 5 parts of sodium metasilicate and citric acid.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the corruggted wrapping case adhesive Number:It is 22 parts of nano-titanium dioxide, 17 parts of ethyl acetate, 55 parts of starch, 5 parts of methyl methacrylate, 4 parts of potassium peroxydisulfate, aqueous 4 parts of 7 parts of hydroxyl polyurethane, 65 parts of water, 6 parts of sodium metasilicate and citric acid.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the corruggted wrapping case adhesive Number:It is 24 parts of nano-titanium dioxide, 18 parts of ethyl acetate, 60 parts of starch, 6 parts of methyl methacrylate, 5 parts of potassium peroxydisulfate, aqueous 5 parts of 8 parts of hydroxyl polyurethane, 70 parts of water, 7 parts of sodium metasilicate and citric acid.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the corruggted wrapping case adhesive Number:It is 25 parts of nano-titanium dioxide, 19 parts of ethyl acetate, 65 parts of starch, 6 parts of methyl methacrylate, 6 parts of potassium peroxydisulfate, aqueous 5 parts of 9 parts of hydroxyl polyurethane, 75 parts of water, 7 parts of sodium metasilicate and citric acid.
In a preferred embodiment of the present invention, parts by weight shared by each ingredient in the corruggted wrapping case adhesive Number:It is 26 parts of nano-titanium dioxide, 21 parts of ethyl acetate, 70 parts of starch, 7 parts of methyl methacrylate, 7 parts of potassium peroxydisulfate, aqueous 6 parts of 10 parts of hydroxyl polyurethane, 80 parts of water, 8 parts of sodium metasilicate and citric acid.
The beneficial effects of the invention are as follows:A kind of corruggted wrapping case adhesive that the present invention points out, significantly improves viscous Connect effect.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common All other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1:Parts by weight shared by each ingredient in the corruggted wrapping case adhesive:Nano-titanium dioxide 20 Part, 16 parts of ethyl acetate, 50 parts of starch, 4 parts of methyl methacrylate, 3 parts of potassium peroxydisulfate, 6 parts of water-based hydroxyl polyurethane, water 60 3 parts of part, 5 parts of sodium metasilicate and citric acid.
Embodiment 2:Parts by weight shared by each ingredient in the corruggted wrapping case adhesive:Nano-titanium dioxide 22 Part, 17 parts of ethyl acetate, 55 parts of starch, 5 parts of methyl methacrylate, 4 parts of potassium peroxydisulfate, 7 parts of water-based hydroxyl polyurethane, water 65 4 parts of part, 6 parts of sodium metasilicate and citric acid.
Embodiment 3:Parts by weight shared by each ingredient in the corruggted wrapping case adhesive:Nano-titanium dioxide 24 Part, 18 parts of ethyl acetate, 60 parts of starch, 6 parts of methyl methacrylate, 5 parts of potassium peroxydisulfate, 8 parts of water-based hydroxyl polyurethane, water 70 5 parts of part, 7 parts of sodium metasilicate and citric acid.
Embodiment 4:Parts by weight shared by each ingredient in the corruggted wrapping case adhesive:Nano-titanium dioxide 25 Part, 19 parts of ethyl acetate, 65 parts of starch, 6 parts of methyl methacrylate, 6 parts of potassium peroxydisulfate, 9 parts of water-based hydroxyl polyurethane, water 75 5 parts of part, 7 parts of sodium metasilicate and citric acid.
Embodiment 5:Parts by weight shared by each ingredient in the corruggted wrapping case adhesive:Nano-titanium dioxide 26 Part, 21 parts of ethyl acetate, 70 parts of starch, 7 parts of methyl methacrylate, 7 parts of potassium peroxydisulfate, 10 parts of water-based hydroxyl polyurethane, water 6 parts of 80 parts, 8 parts of sodium metasilicate and citric acid.
Test case:The corruggted wrapping case of embodiment 1-5 is tested for the property with adhesive, test result such as 1 institute of table Show.
Table 1:
Binding speed(min) Adhesive strength(N/cm2
Embodiment 1 10.1 8.56
Embodiment 2 10.2 8.57
Embodiment 3 10.3 8.54
Embodiment 4 10.4 8.55
Embodiment 5 10.5 8.58
Existing product 11.2 7.15
In conclusion a kind of corruggted wrapping case adhesive that the present invention points out, significantly improves adhesive effect.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (6)

1. a kind of corruggted wrapping case adhesive, which is characterized in that including:Nano-titanium dioxide, ethyl acetate, starch, first Base methyl acrylate, potassium peroxydisulfate, water-based hydroxyl polyurethane, water, sodium metasilicate and citric acid, the corruggted wrapping case glue Parts by weight shared by each ingredient in stick:20-29 parts of nano-titanium dioxide, 16-26 parts of ethyl acetate, 50-80 parts of starch, methyl 4-9 parts of methyl acrylate, 3-10 parts of potassium peroxydisulfate, 6-12 parts of water-based hydroxyl polyurethane, 60-90 parts of water, 5-12 parts of sodium metasilicate With 3-9 parts of citric acid.
2. corruggted wrapping case adhesive according to claim 1, which is characterized in that the corruggted wrapping case glue Parts by weight shared by each ingredient in stick:20 parts of nano-titanium dioxide, 16 parts of ethyl acetate, 50 parts of starch, methyl methacrylate 3 parts of 4 parts of ester, 3 parts of potassium peroxydisulfate, 6 parts of water-based hydroxyl polyurethane, 60 parts of water, 5 parts of sodium metasilicate and citric acid.
3. corruggted wrapping case adhesive according to claim 1, which is characterized in that the corruggted wrapping case glue Parts by weight shared by each ingredient in stick:22 parts of nano-titanium dioxide, 17 parts of ethyl acetate, 55 parts of starch, methyl methacrylate 4 parts of 5 parts of ester, 4 parts of potassium peroxydisulfate, 7 parts of water-based hydroxyl polyurethane, 65 parts of water, 6 parts of sodium metasilicate and citric acid.
4. corruggted wrapping case adhesive according to claim 1, which is characterized in that the corruggted wrapping case glue Parts by weight shared by each ingredient in stick:24 parts of nano-titanium dioxide, 18 parts of ethyl acetate, 60 parts of starch, methyl methacrylate 5 parts of 6 parts of ester, 5 parts of potassium peroxydisulfate, 8 parts of water-based hydroxyl polyurethane, 70 parts of water, 7 parts of sodium metasilicate and citric acid.
5. corruggted wrapping case adhesive according to claim 1, which is characterized in that the corruggted wrapping case glue Parts by weight shared by each ingredient in stick:25 parts of nano-titanium dioxide, 19 parts of ethyl acetate, 65 parts of starch, methyl methacrylate 5 parts of 6 parts of ester, 6 parts of potassium peroxydisulfate, 9 parts of water-based hydroxyl polyurethane, 75 parts of water, 7 parts of sodium metasilicate and citric acid.
6. corruggted wrapping case adhesive according to claim 1, which is characterized in that the corruggted wrapping case glue Parts by weight shared by each ingredient in stick:26 parts of nano-titanium dioxide, 21 parts of ethyl acetate, 70 parts of starch, methyl methacrylate 6 parts of 7 parts of ester, 7 parts of potassium peroxydisulfate, 10 parts of water-based hydroxyl polyurethane, 80 parts of water, 8 parts of sodium metasilicate and citric acid.
CN201810497835.0A 2018-05-23 2018-05-23 A kind of corruggted wrapping case adhesive Withdrawn CN108504293A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810497835.0A CN108504293A (en) 2018-05-23 2018-05-23 A kind of corruggted wrapping case adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810497835.0A CN108504293A (en) 2018-05-23 2018-05-23 A kind of corruggted wrapping case adhesive

Publications (1)

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CN108504293A true CN108504293A (en) 2018-09-07

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109468072A (en) * 2018-12-05 2019-03-15 贵州众旺包装有限公司 A kind of adhesive of wrapping paper and preparation method thereof
CN109468071A (en) * 2018-11-28 2019-03-15 贵州众旺包装有限公司 A kind of carton environment-friendly adhesive
CN109486427A (en) * 2018-11-28 2019-03-19 贵州众旺包装有限公司 A kind of dedicated burning-resistant type adhesive of carton and preparation method thereof
CN109593496A (en) * 2018-12-05 2019-04-09 贵州众旺包装有限公司 A kind of adhesive of wrapping paper and preparation method thereof
CN110373119A (en) * 2019-07-19 2019-10-25 聚隆(福建)包装有限公司 Corrugated board makes environment-friendly modified starch adhesive, high-performance environment-friendly corrugated board and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109468071A (en) * 2018-11-28 2019-03-15 贵州众旺包装有限公司 A kind of carton environment-friendly adhesive
CN109486427A (en) * 2018-11-28 2019-03-19 贵州众旺包装有限公司 A kind of dedicated burning-resistant type adhesive of carton and preparation method thereof
CN109468072A (en) * 2018-12-05 2019-03-15 贵州众旺包装有限公司 A kind of adhesive of wrapping paper and preparation method thereof
CN109593496A (en) * 2018-12-05 2019-04-09 贵州众旺包装有限公司 A kind of adhesive of wrapping paper and preparation method thereof
CN110373119A (en) * 2019-07-19 2019-10-25 聚隆(福建)包装有限公司 Corrugated board makes environment-friendly modified starch adhesive, high-performance environment-friendly corrugated board and preparation method thereof
CN110373119B (en) * 2019-07-19 2021-07-20 聚隆(福建)包装有限公司 Environment-friendly modified starch adhesive for manufacturing corrugated board, high-performance environment-friendly corrugated board and manufacturing method thereof

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Application publication date: 20180907