CN108503926A - A kind of polyethylene insulated aerial cable material - Google Patents

A kind of polyethylene insulated aerial cable material Download PDF

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Publication number
CN108503926A
CN108503926A CN201810329308.9A CN201810329308A CN108503926A CN 108503926 A CN108503926 A CN 108503926A CN 201810329308 A CN201810329308 A CN 201810329308A CN 108503926 A CN108503926 A CN 108503926A
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CN
China
Prior art keywords
plasticizer
polyethylene
aerial cable
cable material
insulated aerial
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810329308.9A
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Chinese (zh)
Inventor
谢博民
孟相君
王茂刚
辛超
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SHANDONG DILONG CABLES CO Ltd
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SHANDONG DILONG CABLES CO Ltd
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Priority to CN201810329308.9A priority Critical patent/CN108503926A/en
Publication of CN108503926A publication Critical patent/CN108503926A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of polyethylene insulated aerial cable material, are made of the raw material of following parts by weight:Polyethylene, 70~80;Natural rubber, 15~20;Carbon black N550,35~45;Plasticizer Mediaplast NB 7,5~8;Plasticizer DEDB, 10~15;Antioxidant A, 3~5;Vulcanizing agent BP, 1~2;Vulcanizing agent DCP, 1~2;Diatomite, 20~40;White smoke active agent PEG 4000,0.6;Vulcanization accelerator TMTD, 1~2;Gas-phase silica, 12~16;Modified talc powder, 10~15.The polyethylene insulated aerial cable material of the present invention has good cold-resistant, heat-resisting, antifatigue, buckle resistance energy.

Description

A kind of polyethylene insulated aerial cable material
Technical field
The present invention relates to a kind of CABLE MATERIALS, specifically a kind of polyethylene insulated aerial cable material.
Background technology
China's high ferro enters the high-speed developing period, and the control of motor-car unit, high speed unit becomes increasingly complex, and electric-controlled is set up Standby more and more, cabling requirements amount necessarily increases, while being also increasingly stringenter therewith to the performance requirement of cable material. Currently on the market PE cable material there is bad mechanical property, weatherability is poor, resistance to ag(e)ing is poor the shortcomings of, be chronically exposed to Outdoor is susceptible to season cracking phenomenon, cannot be satisfied the market demand.
Invention content
The object of the present invention is to provide a kind of polyethylene insulated aerial cable material.
In order to solve the above technical problems, a kind of polyethylene insulated aerial cable material, is made of the raw material of following parts by weight:It is poly- Ethylene, 70~80;Natural rubber, 15~20;Carbon black N550,35~45;Plasticizer Mediaplast NB-7,5~8;Plasticizer DEDB, 10~15;Antioxidant A, 3~5;Vulcanizing agent BP, 1~2;Vulcanizing agent DCP, 1~2;Diatomite, 20~40;White cigarette activity Agent PEG 4000,0.6;Vulcanization accelerator TMTD, 1~2;Gas-phase silica, 12~16;Modified talc powder, 10~15.
The preparation method of the modified talc powder is:
(1)First talcum powder is crushed, until abrasive grain degree is less than 300 mesh, superfine talcum powder grinding distribution powder is obtained, then will slide Mountain flour is sufficiently mixed with nano-concrete and kaolin, obtains within 15 minutes baking mixes in 600 DEG C of vacuum kiln roastings, then will The technical hydrochloric acid by weight 1 of baking mixes and concentration 30%:3 dispensings, in 70 DEG C of acidleach 6 hours;
(2)Again by step(1)The mixed liquor of acidleach and particulate matter therein are neutralized, are filtered, washed, dry, and obtain preliminary Modified talcum powder;
(3)By step(2)Obtained talcum powder is placed in vacuum plasma spray coating equipment, using plasma spraying technology to talcum Powder sprays sodium tripolyphosphate and dispersant NNO, and modified talc powder is obtained after spraying.
Above-mentioned polyethylene insulated aerial cable material, preparation method are:
(1)Each material is taken by weight, by polyethylene, natural rubber, carbon black N550, plasticizer Mediaplast NB-7, vulcanization In agent BP input mixer, be added immediately modified vulcanizing agent DCP, diatomite, white smoke active agent PEG 4000, Vulcanization accelerator TMTD, Gas-phase silica is plasticated 3 minutes, and plasticizer DEDB, modified talc powder is then added, and is continued to be kneaded 3 minutes, is added anti-aging agent A, it is kneaded 3~5 minutes, when mixer temperature reaches 145~150 DEG C, starts to discharge, cooling is spare;
(2)By step(1)Gained mixture after cooling is sent into mixer, 5~8min is kneaded at 110~130 DEG C, then Mill in open mill is sent into after final mixture is cooled down, thin logical 6~7 times to get polyethylene insulated aerial cable material.
It is that natural rubber is added as auxiliary material in base material, and adds carbon black N550, a variety of acts on not that the present invention, which is using polyethylene, With the various auxiliary agents such as the plasticizer in stage, vulcanizing agent, make CABLE MATERIALS obtained that there is excellent mechanical performance, and with excellent Weatherability, heatproof oxidation performance adapt to outdoor various harsh natural conditions.By the order of addition for rationally controlling each component raw material And process time, further improve antifatigue, the buckle resistance energy of cable sleeve.
Specific implementation mode
Example 1
A kind of polyethylene insulated aerial cable material, is made of the raw material of following parts by weight:Polyethylene, 78;Natural rubber, 18;Charcoal Black N550,42;Plasticizer Mediaplast NB-7,6;Plasticizer DEDB, 12;Antioxidant A, 4;Vulcanizing agent BP, 2;Vulcanizing agent DCP, 1;Diatomite, 35;White smoke active agent PEG 4000,0.6;Vulcanization accelerator TMTD, 2;Gas-phase silica, 15;Modified talc powder, 13。
The preparation method of the modified talc powder is:
(1)First talcum powder is crushed, until abrasive grain degree is less than 300 mesh, superfine talcum powder grinding distribution powder is obtained, then will slide Mountain flour is sufficiently mixed with nano-concrete and kaolin, obtains within 15 minutes baking mixes in 600 DEG C of vacuum kiln roastings, then will The technical hydrochloric acid by weight 1 of baking mixes and concentration 30%:3 dispensings, in 70 DEG C of acidleach 6 hours;(2)Again by step(1) The mixed liquor of acidleach and particulate matter therein are neutralized, are filtered, washed, dry, the talcum powder being tentatively modified;
(3)By step(2)Obtained talcum powder is placed in vacuum plasma spray coating equipment, using plasma spraying technology to talcum Powder sprays sodium tripolyphosphate and dispersant NNO, and modified talc powder is obtained after spraying.
Above-mentioned polyethylene insulated aerial cable material, preparation method are:
(1)Each material is taken by weight, by polyethylene, natural rubber, carbon black N550, plasticizer Mediaplast NB-7, vulcanization In agent BP input mixer, be added immediately modified vulcanizing agent DCP, diatomite, white smoke active agent PEG 4000, Vulcanization accelerator TMTD, Gas-phase silica is plasticated 3 minutes, and plasticizer DEDB, modified talc powder is then added, and is continued to be kneaded 3 minutes, is added anti-aging agent A, it is kneaded 4 minutes, when mixer temperature reaches 148 DEG C, starts to discharge, cooling is spare;
(2)By step(1)Gained mixture after cooling is sent into mixer, and 7min is kneaded at 120 DEG C, then will be final Mill in open mill is sent into after mixture cooling, thin logical 7 times to get polyethylene insulated aerial cable material.
The CABLE MATERIALS test result of the present embodiment is shown in Table 1, table 2.
Table 1
Table 2
Detection project It is required that Actual measurement(Exemplar 1) Actual measurement(Exemplar 2)
Adhesive strength KN/m ≥3 5.05 5.06
Low temperature(-40℃×24h) Flawless Flawless Flawless
Pulse testing(Internal temperature:180 DEG C, external temperature:100 DEG C, test pressure: 2.5bar, frequency:0.5 ~ 1Hz media:Air) It recycles 200,000 times, Flawless It recycles 260,000 times, Flawless It recycles 260,000 times, Flawless
Example 2
A kind of polyethylene insulated aerial cable material, is made of the raw material of following parts by weight:Polyethylene, 70;Natural rubber, 15;Charcoal Black N550,35;Plasticizer Mediaplast NB-7,5;Plasticizer DEDB, 10;Antioxidant A, 3;Vulcanizing agent BP, 1;Vulcanizing agent DCP, 1;Diatomite, 20;White smoke active agent PEG 4000,0.6;Vulcanization accelerator TMTD, 1;Gas-phase silica, 12;Modified talc powder, 10。
The preparation method of the modified talc powder is:
(1)First talcum powder is crushed, until abrasive grain degree is less than 300 mesh, superfine talcum powder grinding distribution powder is obtained, then will slide Mountain flour is sufficiently mixed with nano-concrete and kaolin, obtains within 15 minutes baking mixes in 600 DEG C of vacuum kiln roastings, then will The technical hydrochloric acid by weight 1 of baking mixes and concentration 30%:3 dispensings, in 70 DEG C of acidleach 6 hours;(2)Again by step(1) The mixed liquor of acidleach and particulate matter therein are neutralized, are filtered, washed, dry, the talcum powder being tentatively modified;
(3)By step(2)Obtained talcum powder is placed in vacuum plasma spray coating equipment, using plasma spraying technology to talcum Powder sprays sodium tripolyphosphate and dispersant NNO, and modified talc powder is obtained after spraying.
Above-mentioned polyethylene insulated aerial cable material, preparation method are:
(1)Each material is taken by weight, by polyethylene, natural rubber, carbon black N550, plasticizer Mediaplast NB-7, vulcanization In agent BP input mixer, be added immediately modified vulcanizing agent DCP, diatomite, white smoke active agent PEG 4000, Vulcanization accelerator TMTD, Gas-phase silica is plasticated 3 minutes, and plasticizer DEDB, modified talc powder is then added, and is continued to be kneaded 3 minutes, is added anti-aging agent A, it is kneaded 4 minutes, when mixer temperature reaches 148 DEG C, starts to discharge, cooling is spare;
(2)By step(1)Gained mixture after cooling is sent into mixer, and 7min is kneaded at 120 DEG C, then will be final Mill in open mill is sent into after mixture cooling, thin logical 7 times to get polyethylene insulated aerial cable material.
The CABLE MATERIALS test result of the present embodiment is shown in Table 1, table 2.
Table 1
Table 2
Detection project It is required that Actual measurement(Exemplar 1) Actual measurement(Exemplar 2)
Adhesive strength KN/m ≥3 5.03 5.04
Low temperature(-40℃×24h) Flawless Flawless Flawless
Pulse testing(Internal temperature:180 DEG C, external temperature:100 DEG C, test pressure: 2.5bar, frequency:0.5 ~ 1Hz media:Air) Recycle 200,000 It is secondary, flawless Recycle 25.7 ten thousand It is secondary, flawless Recycle 25.8 ten thousand It is secondary, flawless
Example 3
A kind of polyethylene insulated aerial cable material, is made of the raw material of following parts by weight:Polyethylene, 80;Natural rubber, 20;Charcoal Black N550,45;Plasticizer Mediaplast NB-7,8;Plasticizer DEDB, 15;Antioxidant A, 5;Vulcanizing agent BP, 2;Vulcanizing agent DCP, 2;Diatomite, 40;White smoke active agent PEG 4000,0.6;Vulcanization accelerator TMTD, 2;Gas-phase silica, 16;Modified talc powder, 15。
The preparation method of the modified talc powder is:
(1)First talcum powder is crushed, until abrasive grain degree is less than 300 mesh, superfine talcum powder grinding distribution powder is obtained, then will slide Mountain flour is sufficiently mixed with nano-concrete and kaolin, obtains within 15 minutes baking mixes in 600 DEG C of vacuum kiln roastings, then will The technical hydrochloric acid by weight 1 of baking mixes and concentration 30%:3 dispensings, in 70 DEG C of acidleach 6 hours;(2)Again by step(1) The mixed liquor of acidleach and particulate matter therein are neutralized, are filtered, washed, dry, the talcum powder being tentatively modified;
(3)By step(2)Obtained talcum powder is placed in vacuum plasma spray coating equipment, using plasma spraying technology to talcum Powder sprays sodium tripolyphosphate and dispersant NNO, and modified talc powder is obtained after spraying.
Above-mentioned polyethylene insulated aerial cable material, preparation method are:
(1)Each material is taken by weight, by polyethylene, natural rubber, carbon black N550, plasticizer Mediaplast NB-7, vulcanization In agent BP input mixer, be added immediately modified vulcanizing agent DCP, diatomite, white smoke active agent PEG 4000, Vulcanization accelerator TMTD, Gas-phase silica is plasticated 3 minutes, and plasticizer DEDB, modified talc powder is then added, and is continued to be kneaded 3 minutes, is added anti-aging agent A, it is kneaded 4 minutes, when mixer temperature reaches 148 DEG C, starts to discharge, cooling is spare;
(2)By step(1)Gained mixture after cooling is sent into mixer, and 7min is kneaded at 120 DEG C, then will be final Mill in open mill is sent into after mixture cooling, thin logical 7 times to get polyethylene insulated aerial cable material.
The CABLE MATERIALS test result of the present embodiment is shown in Table 1, table 2.
Table 1
Table 2
Detection project It is required that Actual measurement(Exemplar 1) Actual measurement(Exemplar 2)
Adhesive strength KN/m ≥3 5.04 5.04
Low temperature(-40℃×24h) Flawless Flawless Flawless
Pulse testing(Internal temperature:180 DEG C, external temperature:100 DEG C, test pressure: 2.5bar, frequency:0.5 ~ 1Hz media:Air) Recycle 200,000 It is secondary, flawless Recycle 25.8 ten thousand It is secondary, flawless Recycle 25.8 ten thousand It is secondary, flawless
The foregoing is merely the schematical specific implementation modes of the present invention, are not limited to the scope of the present invention.Any ability The technical staff in domain, made equivalent variations and modification, should all belong under the premise of not departing from design and the principle of the present invention In the scope of protection of the invention.

Claims (4)

1. a kind of polyethylene insulated aerial cable material, which is characterized in that be made of the raw material of following parts by weight:Polyethylene, 70~ 80;Natural rubber, 15~20;Carbon black N550,35~45;Plasticizer Mediaplast NB-7,5~8;Plasticizer DEDB, 10~ 15;Antioxidant A, 3~5;Vulcanizing agent BP, 1~2;Vulcanizing agent DCP, 1~2;Diatomite, 20~40;White smoke active agent PEG 4000,0.6;Vulcanization accelerator TMTD, 1~2;Gas-phase silica, 12~16;Modified talc powder, 10~15.
2. a kind of polyethylene insulated aerial cable material as described in claim 1, which is characterized in that by the raw material of following parts by weight It is made:Polyethylene, 78;Natural rubber, 18;Carbon black N550,42;Plasticizer Mediaplast NB-7,6;Plasticizer DEDB, 12; Antioxidant A, 4;Vulcanizing agent BP, 2;Vulcanizing agent DCP, 1;Diatomite, 35;White smoke active agent PEG 4000,0.6;Vulcanization accelerator TMTD, 2;Gas-phase silica, 15;Modified talc powder, 13.
3. a kind of polyethylene insulated aerial cable material as claimed in claim 2, which is characterized in that the system of the modified talc powder Preparation Method is:
(1)First talcum powder is crushed, until abrasive grain degree is less than 300 mesh, superfine talcum powder grinding distribution powder is obtained, then will slide Mountain flour is sufficiently mixed with nano-concrete and kaolin, obtains within 15 minutes baking mixes in 600 DEG C of vacuum kiln roastings, then will The technical hydrochloric acid by weight 1 of baking mixes and concentration 30%:3 dispensings, in 70 DEG C of acidleach 6 hours;(2)Again by step(1) The mixed liquor of acidleach and particulate matter therein are neutralized, are filtered, washed, dry, the talcum powder being tentatively modified;
(3)By step(2)Obtained talcum powder is placed in vacuum plasma spray coating equipment, using plasma spraying technology to talcum Powder sprays sodium tripolyphosphate and dispersant NNO, and modified talc powder is obtained after spraying.
4. a kind of polyethylene insulated aerial cable material as described in claim 1, it is characterised in that:
Preparation method is:
(1)Each material is taken by weight, by polyethylene, natural rubber, carbon black N550, plasticizer Mediaplast NB-7, vulcanization In agent BP input mixer, be added immediately modified vulcanizing agent DCP, diatomite, white smoke active agent PEG 4000, Vulcanization accelerator TMTD, Gas-phase silica is plasticated 3 minutes, and plasticizer DEDB, modified talc powder is then added, and is continued to be kneaded 3 minutes, is added anti-aging agent A, it is kneaded 3~5 minutes, when mixer temperature reaches 145~150 DEG C, starts to discharge, cooling is spare;
(2)By step(1)Gained mixture after cooling is sent into mixer, 5~8min is kneaded at 110~130 DEG C, then Mill in open mill is sent into after final mixture is cooled down, thin logical 6~7 times to get polyethylene insulated aerial cable material.
CN201810329308.9A 2018-04-13 2018-04-13 A kind of polyethylene insulated aerial cable material Pending CN108503926A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810329308.9A CN108503926A (en) 2018-04-13 2018-04-13 A kind of polyethylene insulated aerial cable material

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Application Number Priority Date Filing Date Title
CN201810329308.9A CN108503926A (en) 2018-04-13 2018-04-13 A kind of polyethylene insulated aerial cable material

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030195279A1 (en) * 2002-04-09 2003-10-16 Crompton Corporation. Heterocyclic tin flame retardants/smoke suppressants and halogen-containing polymer composition containing same
CN105206337A (en) * 2015-09-29 2015-12-30 安徽蓝德集团股份有限公司 Power cable with excellent heat stability
CN105623111A (en) * 2016-03-04 2016-06-01 王金武 Anti-fatigue and anti-bending composite rubber cable sleeve
CN105802233A (en) * 2016-04-26 2016-07-27 韩静静 Mouse-proof optical cable rubber sleeve

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030195279A1 (en) * 2002-04-09 2003-10-16 Crompton Corporation. Heterocyclic tin flame retardants/smoke suppressants and halogen-containing polymer composition containing same
CN105206337A (en) * 2015-09-29 2015-12-30 安徽蓝德集团股份有限公司 Power cable with excellent heat stability
CN105623111A (en) * 2016-03-04 2016-06-01 王金武 Anti-fatigue and anti-bending composite rubber cable sleeve
CN105802233A (en) * 2016-04-26 2016-07-27 韩静静 Mouse-proof optical cable rubber sleeve

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Application publication date: 20180907

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