CN108503909A - A kind of Antiskid flame-proof automobile tire rubber material - Google Patents
A kind of Antiskid flame-proof automobile tire rubber material Download PDFInfo
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- CN108503909A CN108503909A CN201810457464.3A CN201810457464A CN108503909A CN 108503909 A CN108503909 A CN 108503909A CN 201810457464 A CN201810457464 A CN 201810457464A CN 108503909 A CN108503909 A CN 108503909A
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- antiskid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of Antiskid flame-proof automobile tire rubber materials, include the component of following portions by weight：50 60 parts of rare earth polybutadiene rubber, 30 35 parts of ethylene propylene diene rubber, 6 13 parts of polyurethane elastomer, 28 parts of nano-attapulgite/carbon black, 6 12 parts of carboxylated graphene oxide, 15 parts of silane coupling agent, 16 parts of age resister, 25 parts of elastomer, 37 parts of metakaolin, 14 parts of antiskid particles, 14 parts of heat stabilizer, 15 parts of turpentine oil, 15 parts of compatilizer, 14 parts of fire retardant, 12 parts of activating agent organic amine.Rubber good toughness of the present invention, good damping effect, good flame resistance, intensity are high, and anti-aging property is good, light-weight, endurance long lifespan.Metakaolin and carboxylated graphene oxide have highly conductive, rub resistance characteristic so that manufactured rubber product has excellent elastic, anti-flexibility, elongation rate of tensile failure, antistatic property and scratch-resistant performance.
Description
Technical field
The present invention relates to rubber materials, specifically a kind of Antiskid flame-proof automobile tire rubber material.
Background technology
Raw rubber is the material of main part of rubber product manufacture.Rubber is a kind of flexible polymer, according to mode is made
Difference, rubber can be divided into two class of synthetic rubber and rare earth polybutadiene rubber.Rare earth polybutadiene rubber is mainly derived from para ruber,
When the epidermis of this rubber tree is cut open, will flow out milky juice, referred to as latex, latex through cohesion, washing, at
Type is drying to obtain rare earth polybutadiene rubber.Prepared by synthetic rubber is by artificial synthesis can be closed using different raw materials
At going out different types of rubber, such as natural rubber, neoprene, butadiene-styrene rubber, butadiene rubber.
Tire is one of most important building block of automobile, its main function is the total weight for supporting vehicle, is held
By the load of automobile, the torsion of transmission traction and braking ensures the adhesive force of wheel and road surface, and what tire was mostly used greatly is rubber
Material.But the quantity of automobile was more and more with the development of economy in recent years, and the requirement to rubber is higher and higher, not only requires it
Wearability, and require anti-flammability.
Invention content
The purpose of the present invention is to provide a kind of Antiskid flame-proof automobile tire rubber materials, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides the following technical solutions：
A kind of Antiskid flame-proof automobile tire rubber material, includes the component of following portions by weight：
50-60 parts of rare earth polybutadiene rubber, 30-35 parts of ethylene propylene diene rubber, 6-13 parts of polyurethane elastomer, nano-attapulgite
Soil/2-8 parts of carbon black, 6-12 parts of carboxylated graphene oxide, 1-5 parts of silane coupling agent, 1-6 parts of age resister, elastomer 2-5
Part, 3-7 parts of metakaolin, 1-4 parts of antiskid particles, 1-4 parts of heat stabilizer, 1-5 parts of turpentine oil, 1-5 parts of compatilizer, fire retardant 1-
4 parts, 1-2 parts of activating agent organic amine.
A kind of Antiskid flame-proof automobile tire rubber material, includes the component of following portions by weight：
50 parts of rare earth polybutadiene rubber, 30 parts of ethylene propylene diene rubber, 6 parts of polyurethane elastomer, nano-attapulgite/carbon black 2
It is part, 6 parts of carboxylated graphene oxide, 1 part of silane coupling agent, 1 part of age resister, 2 parts of elastomer, 3 parts of metakaolin, anti-skidding
1 part of particle, 1 part of heat stabilizer, 1 part of turpentine oil, 1 part of compatilizer, 1 part of fire retardant, 1 part of activating agent organic amine.
A kind of Antiskid flame-proof automobile tire rubber material, includes the component of following portions by weight：
60 parts of rare earth polybutadiene rubber, 35 parts of ethylene propylene diene rubber, 13 parts of polyurethane elastomer, nano-attapulgite/carbon black 8
Part, is prevented 12 parts of carboxylated graphene oxide, 5 parts of silane coupling agent, 6 parts of age resister, 5 parts of elastomer, 7 parts of metakaolin
Sliding 4 parts of particle, 4 parts of heat stabilizer, 5 parts of turpentine oil, 5 parts of compatilizer, 4 parts of fire retardant, 2 parts of activating agent organic amine.
A kind of Antiskid flame-proof automobile tire rubber material, includes the component of following portions by weight：
56 parts of rare earth polybutadiene rubber, 33 parts of ethylene propylene diene rubber, 10 parts of polyurethane elastomer, nano-attapulgite/carbon black 5
Part, is prevented 9 parts of carboxylated graphene oxide, 3 parts of silane coupling agent, 4 parts of age resister, 3.5 parts of elastomer, 5 parts of metakaolin
Sliding 3 parts of particle, 2 parts of heat stabilizer, 3 parts of turpentine oil, 3 parts of compatilizer, 2 parts of fire retardant, 1.5 parts of activating agent organic amine.
The fire retardant is by ammonium polyphosphate, melamine and magnesium hydroxide in mass ratio 2:1:The mixture of 2 compositions.
The one kind of the elastomer in high resiliency lignin fibre, polyurethane fiber and herbage fiber.
The antiskid particles, including the component of following parts by weight are constituted：3-8 parts of ethylene glycol ether acetate, bamboo charcoal fiber
2-4 parts, 4-8 parts of polytetrafluoroethylene (PTFE), 1-4 parts of white carbon, 1-3 parts of zinc oxide, 2-5 parts of potassium feldspar, 5-10 parts of dispersant, acetic acid second
3-6 parts of ester.
Compared with prior art, the beneficial effects of the invention are as follows：
Rubber good toughness of the present invention, good damping effect, good flame resistance, intensity are high, and anti-aging property is good, light-weight, resistance to tired
Labor long lifespan；The present invention coordinates ethylene propylene diene rubber and polyurethane elastomer, wherein Rare-earth Cis based on rare earth polybutadiene rubber
Buna has higher elasticity, preferable tensile property, lower heat and rolling resistance and excellent abrasion performance and resists
Fatigability meets high-performance tire high speed, energy saving, safe and environment-friendly requirement, and polyurethane elastomer wearability is good, than common rubber
Rubber tire tyre uniformity is more preferable, and is not in tread detachment phenomenon；Addition nano-attapulgite/carbon black compounded mix is used in combination
Glue tensile strength and tearing strength are higher, and flexible resistance is preferable, and wear-resisting property is slightly worse；Metakaolin and carboxylated graphite oxide
Alkene has highly conductive, rub resistance characteristic, using rubber product made of such filler have it is excellent it is elastic, it is anti-it is flexibility,
Elongation rate of tensile failure, antistatic property and scratch-resistant performance have very high practical value；The addition of fire retardant so that rubber has
Excellent anti-flammability；The addition of antiskid particles, have promote between rubber and additive it is evenly dispersed, can preferably play increasing
It is molten, wear-resisting, wetting the effects that.
Specific implementation mode
Embodiment 1
A kind of Antiskid flame-proof automobile tire rubber material, includes the component of following portions by weight：
50 parts of rare earth polybutadiene rubber, 30 parts of ethylene propylene diene rubber, 6 parts of polyurethane elastomer, nano-attapulgite/carbon black 2
It is part, 6 parts of carboxylated graphene oxide, 1 part of silane coupling agent, 1 part of age resister, 2 parts of elastomer, 3 parts of metakaolin, anti-skidding
1 part of particle, 1 part of heat stabilizer, 1 part of turpentine oil, 1 part of compatilizer, 1 part of fire retardant, 1 part of activating agent organic amine.
The fire retardant is by ammonium polyphosphate, melamine and magnesium hydroxide in mass ratio 2:1:The mixture of 2 compositions.
The one kind of the elastomer in high resiliency lignin fibre, polyurethane fiber and herbage fiber.
The antiskid particles, including the component of following parts by weight are constituted：3-8 parts of ethylene glycol ether acetate, bamboo charcoal fiber
2-4 parts, 4-8 parts of polytetrafluoroethylene (PTFE), 1-4 parts of white carbon, 1-3 parts of zinc oxide, 2-5 parts of potassium feldspar, 5-10 parts of dispersant, acetic acid second
3-6 parts of ester.
Embodiment 2
A kind of Antiskid flame-proof automobile tire rubber material, includes the component of following portions by weight：
60 parts of rare earth polybutadiene rubber, 35 parts of ethylene propylene diene rubber, 13 parts of polyurethane elastomer, nano-attapulgite/carbon black 8
Part, is prevented 12 parts of carboxylated graphene oxide, 5 parts of silane coupling agent, 6 parts of age resister, 5 parts of elastomer, 7 parts of metakaolin
Sliding 4 parts of particle, 4 parts of heat stabilizer, 5 parts of turpentine oil, 5 parts of compatilizer, 4 parts of fire retardant, 2 parts of activating agent organic amine.
The fire retardant is by ammonium polyphosphate, melamine and magnesium hydroxide in mass ratio 2:1:The mixture of 2 compositions.
The one kind of the elastomer in high resiliency lignin fibre, polyurethane fiber and herbage fiber.
The antiskid particles, including the component of following parts by weight are constituted：3-8 parts of ethylene glycol ether acetate, bamboo charcoal fiber
2-4 parts, 4-8 parts of polytetrafluoroethylene (PTFE), 1-4 parts of white carbon, 1-3 parts of zinc oxide, 2-5 parts of potassium feldspar, 5-10 parts of dispersant, acetic acid second
3-6 parts of ester.
Embodiment 3
A kind of Antiskid flame-proof automobile tire rubber material, includes the component of following portions by weight：
56 parts of rare earth polybutadiene rubber, 33 parts of ethylene propylene diene rubber, 10 parts of polyurethane elastomer, nano-attapulgite/carbon black 5
Part, is prevented 9 parts of carboxylated graphene oxide, 3 parts of silane coupling agent, 4 parts of age resister, 3.5 parts of elastomer, 5 parts of metakaolin
Sliding 3 parts of particle, 2 parts of heat stabilizer, 3 parts of turpentine oil, 3 parts of compatilizer, 2 parts of fire retardant, 1.5 parts of activating agent organic amine.
The fire retardant is by ammonium polyphosphate, melamine and magnesium hydroxide in mass ratio 2:1:The mixture of 2 compositions.
The one kind of the elastomer in high resiliency lignin fibre, polyurethane fiber and herbage fiber.
The antiskid particles, including the component of following parts by weight are constituted：3-8 parts of ethylene glycol ether acetate, bamboo charcoal fiber
2-4 parts, 4-8 parts of polytetrafluoroethylene (PTFE), 1-4 parts of white carbon, 1-3 parts of zinc oxide, 2-5 parts of potassium feldspar, 5-10 parts of dispersant, acetic acid second
3-6 parts of ester.
Claims (7)
1. a kind of Antiskid flame-proof automobile tire rubber material, which is characterized in that the component including following portions by weight：
50-60 parts of rare earth polybutadiene rubber, 30-35 parts of ethylene propylene diene rubber, 6-13 parts of polyurethane elastomer, nano-attapulgite/
2-8 parts of carbon black, 6-12 parts of carboxylated graphene oxide, 1-5 parts of silane coupling agent, 1-6 parts of age resister, 2-5 parts of elastomer,
3-7 parts of metakaolin, 1-4 parts of antiskid particles, 1-4 parts of heat stabilizer, 1-5 parts of turpentine oil, 1-5 parts of compatilizer, fire retardant 1-4
Part, 1-2 parts of activating agent organic amine.
2. Antiskid flame-proof automobile tire rubber material according to claim 1, which is characterized in that including following portions by weight
Component：
50 parts of rare earth polybutadiene rubber, 30 parts of ethylene propylene diene rubber, 6 parts of polyurethane elastomer, 2 parts of nano-attapulgite/carbon black, carboxylic
6 parts of base graphene oxide, 1 part of silane coupling agent, 1 part of age resister, 2 parts of elastomer, 3 parts of metakaolin, antiskid particles 1
Part, 1 part of heat stabilizer, 1 part of turpentine oil, 1 part of compatilizer, 1 part of fire retardant, 1 part of activating agent organic amine.
3. Antiskid flame-proof automobile tire rubber material according to claim 1, which is characterized in that including following portions by weight
Component：
60 parts of rare earth polybutadiene rubber, 35 parts of ethylene propylene diene rubber, 13 parts of polyurethane elastomer, 8 parts of nano-attapulgite/carbon black,
12 parts of carboxylated graphene oxide, 5 parts of silane coupling agent, 6 parts of age resister, 5 parts of elastomer, 7 parts, anti-skidding of metakaolin
4 parts of grain, 4 parts of heat stabilizer, 5 parts of turpentine oil, 5 parts of compatilizer, 4 parts of fire retardant, 2 parts of activating agent organic amine.
4. Antiskid flame-proof automobile tire rubber material according to claim 1, which is characterized in that including following portions by weight
Component：
56 parts of rare earth polybutadiene rubber, 33 parts of ethylene propylene diene rubber, 10 parts of polyurethane elastomer, 5 parts of nano-attapulgite/carbon black,
It is 9 parts of carboxylated graphene oxide, 3 parts of silane coupling agent, 4 parts of age resister, 3.5 parts of elastomer, 5 parts of metakaolin, anti-skidding
3 parts of particle, 2 parts of heat stabilizer, 3 parts of turpentine oil, 3 parts of compatilizer, 2 parts of fire retardant, 1.5 parts of activating agent organic amine.
5. Antiskid flame-proof automobile tire rubber material according to claim 1, which is characterized in that the fire retardant is by poly- phosphorus
Sour ammonium, melamine and magnesium hydroxide in mass ratio 2:1:The mixture of 2 compositions.
6. Antiskid flame-proof automobile tire rubber material according to claim 1, which is characterized in that the elastomer is selected from
One kind in high resiliency lignin fibre, polyurethane fiber and herbage fiber.
7. Antiskid flame-proof automobile tire rubber material according to claim 1, which is characterized in that the antiskid particles, packet
The component for including following parts by weight is constituted：It is 3-8 parts of ethylene glycol ether acetate, 2-4 parts of bamboo charcoal fiber, 4-8 parts of polytetrafluoroethylene (PTFE), white
1-4 parts of carbon black, 1-3 parts of zinc oxide, 2-5 parts of potassium feldspar, 5-10 parts of dispersant, 3-6 parts of ethyl acetate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810457464.3A CN108503909A (en) | 2018-05-14 | 2018-05-14 | A kind of Antiskid flame-proof automobile tire rubber material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810457464.3A CN108503909A (en) | 2018-05-14 | 2018-05-14 | A kind of Antiskid flame-proof automobile tire rubber material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108503909A true CN108503909A (en) | 2018-09-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810457464.3A Pending CN108503909A (en) | 2018-05-14 | 2018-05-14 | A kind of Antiskid flame-proof automobile tire rubber material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111763360A (en) * | 2019-04-02 | 2020-10-13 | 中国石油化工股份有限公司 | Rubber composition, vulcanized rubber, and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106750631A (en) * | 2016-12-14 | 2017-05-31 | 天长市康宁甘油科技有限公司 | A kind of oil resistant fire-retardant rubber material and preparation method thereof |
| CN107501581A (en) * | 2017-07-26 | 2017-12-22 | 浙江吉利控股集团有限公司 | A kind of preparation method of modified rubber, modified rubber and bulletproof anti-puncturing wear tire |
| CN107857901A (en) * | 2017-10-26 | 2018-03-30 | 茂名高岭科技有限公司 | A kind of metakaolin gum filler and preparation method thereof |
-
2018
- 2018-05-14 CN CN201810457464.3A patent/CN108503909A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106750631A (en) * | 2016-12-14 | 2017-05-31 | 天长市康宁甘油科技有限公司 | A kind of oil resistant fire-retardant rubber material and preparation method thereof |
| CN107501581A (en) * | 2017-07-26 | 2017-12-22 | 浙江吉利控股集团有限公司 | A kind of preparation method of modified rubber, modified rubber and bulletproof anti-puncturing wear tire |
| CN107857901A (en) * | 2017-10-26 | 2018-03-30 | 茂名高岭科技有限公司 | A kind of metakaolin gum filler and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111763360A (en) * | 2019-04-02 | 2020-10-13 | 中国石油化工股份有限公司 | Rubber composition, vulcanized rubber, and preparation method and application thereof |
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Application publication date: 20180907 |