CN108503898A - A method of producing high performance plastic film - Google Patents
A method of producing high performance plastic film Download PDFInfo
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- CN108503898A CN108503898A CN201810391109.0A CN201810391109A CN108503898A CN 108503898 A CN108503898 A CN 108503898A CN 201810391109 A CN201810391109 A CN 201810391109A CN 108503898 A CN108503898 A CN 108503898A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2303/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2303/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2403/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2403/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2429/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2429/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
Abstract
The invention discloses a kind of methods producing high performance plastic film using montmorillonite, include the following steps:Step 1, starch and polyvinyl alcohol (PVA) are calculated into required starch and PVA by the first mass ratio, starch is gelatinized in the hot water of the first temperature, PVA is dissolved in water, after starch and the PVA of gelatinization are mixed, obtains the first liquid;Step 2, the first liquid is added in the montmorillonite of certain additive percentage composition (phr), obtains second liquid;Step 3, after second liquid being stirred 30 60min under the first mixing speed, third liquid is obtained;Step 4, after third liquid being heated 20 60min in the water-bath of second temperature, the 4th liquid is obtained;Step 5, the 4th liquid is poured into culture dish, is removed after dry 12 48h under the first drying temperature, obtains plastic film.The technological process of the present invention is simple, processing time is short.Obtained plastic film is environmentally protective, and performance is good.
Description
Technical field
The invention belongs to Material Fields, and in particular to a method of producing high performance plastic film using montmorillonite
Background technology
Today's society, Gas Prices rise steadily, and totally, Non-biodegradable plastic can cause sternly Fossil fuel consumption
Heavily contaminated.Therefore need environmentally friendly sustainable material, i.e., it is edible and biodegradable made of biopolymer
Film, to replace petroleum-based plastics.Since starch has recyclability, biodegradable, extensive availability and lower
Cost makes it have as the potentiality of biodegradable plastics material.And polyvinyl alcohol (PVA) is due to its filming performance, it can
Biological degradability, crystallinity and mechanical performance and suitable for packaging industry synthesizing biological degradable polymer.PVA can be with shallow lake
Powder mixing makes it have more economy and increases its biodegradable.But the major defect of PVA/ starch films is PVA and shallow lake
The scrambling of powder molecular size can influence structured packing, to weaken mechanical strength.It is therefore desirable to find a kind of new method
PVA/ starch films are modified, the mechanical performance of blend film is further increased.
Invention content
The present invention is to carry out to solve the above-mentioned problems, and it is an object of the present invention to provide a kind of producing high property using montmorillonite
The method of energy plastic film
A kind of method producing high performance plastic film using montmorillonite provided by the invention, has the feature that, wraps
Include following steps:
Step 1, starch and polyvinyl alcohol (PVA) are calculated into required starch and polyvinyl alcohol by the first mass ratio
(PVA), starch is gelatinized in the hot water of the first temperature, polyvinyl alcohol (PVA) is dissolved in water, after gelatinization starch with it is molten
After the polyvinyl alcohol (PVA) of water mixes, the first liquid is obtained;
Step 2, the montmorillonite of scheduled additive percentage composition (phr) is added in the first liquid, obtains the second liquid
Body;
Step 3, after second liquid being stirred 30-90min under the first mixing speed, third liquid is obtained;
Step 4, after third liquid being heated 20-60min in the water-bath of second temperature, the 4th liquid is obtained;
Step 5, the 4th liquid is poured into culture dish, is removed, is obtained after dry 12-48h under the first drying temperature
Plastic film.
In addition, in a kind of method producing high performance plastic film provided by the invention, there can also be such spy
Sign:In step 1, the first mass ratio is 80wt.%:20wt.%, 70wt.%:30wt.%, 60wt.%:40wt.%,
50wt.%:50wt.% and 0wt.%:Any one in 100wt.%.
In addition, in a kind of method producing high performance plastic film using montmorillonite provided by the invention, can also have
Such feature:In step 1, ranging from 50-100 DEG C of the first temperature.
In addition, in a kind of method producing high performance plastic film using montmorillonite provided by the invention, can also have
Such feature:In step 2, additive percentage composition is any one in 0-10.
In addition, in a kind of method producing high performance plastic film using montmorillonite provided by the invention, can also have
Such feature:In step 3, the first mixing speed is 800rpm.
In addition, in a kind of method producing high performance plastic film using montmorillonite provided by the invention, can also have
Such feature:In step 4, ranging from 80-120 DEG C of second temperature.
In addition, in a kind of method producing high performance plastic film using montmorillonite provided by the invention, can also have
Such feature:In step 5, ranging from 40-80 DEG C of the first drying temperature.
The effect of invention
According to a kind of method producing high performance plastic film using montmorillonite according to the present invention.Using montmorillonite,
It by mixing, stirring, heating, drying, removes these processes and obtains plastic film, the technological process of this method is simple, when processing
Between it is short.In addition, using starch, polyvinyl alcohol for raw material, biodegradable starch material and polyvinyl alcohol are taken full advantage of,
Its mechanical performance is improved in conjunction with modified montmorillonoid, can effectively substitute traditional petroleum-based plastics, it is not only environmentally protective, but also
Prodigious economic benefit can be created.
Specific implementation mode
In order to which the technological means for making the present invention realize is easy to understand with effect, with reference to embodiments to the present invention
It is specifically addressed.
<Embodiment one>
Step 1,10gPVA is dissolved in 90 DEG C of water, obtains solution I.
Step 2, solution I is added in the montmorillonite of 1phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film I.
Testing result is:Tensile strength 1.83MPa, elongation at break 23.4%.
<Embodiment two>
Step 1,10gPVA is dissolved in 90 DEG C of water, obtains solution I.
Step 2, solution I is added in the montmorillonite of 3phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film II.
Testing result is:Tensile strength 14.29MPa, elongation at break 58.2%.
<Embodiment three>
Step 1,10gPVA is dissolved in 90 DEG C of water, obtains solution I.
Step 2, solution I is added in the montmorillonite of 5phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, outstanding suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film III.
Testing result is:Tensile strength 15.98MPa, elongation at break 82.7%.
<Example IV>
Step 1,10gPVA is dissolved in 90 DEG C of water, obtains solution I.
Step 2, solution I is added in the montmorillonite of 7phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film IV.
Testing result is:Tensile strength 13.77MPa, elongation at break 70.4%.
<Embodiment five>
Step 1,10gPVA is dissolved in 90 DEG C of water, obtains solution I.
Step 2, solution I is added in the montmorillonite of 9phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film V.
Testing result is:Tensile strength 10.84MPa, elongation at break 54.2%.
<Embodiment six>
Step 1,5gPVA is soluble in water, and 5g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 1phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film VI.
Testing result is:Tensile strength 20.82MPa, elongation at break 9.23%.
<Embodiment seven>
Step 1,5gPVA is soluble in water, and 5g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 3phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film VII.
Testing result is:Tensile strength 21.73MPa, elongation at break 10.47%.
<Embodiment eight>
Step 1,5gPVA is soluble in water, and 5g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 5phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film VIII.
Testing result is:Tensile strength 24.25MPa, elongation at break 11.73%.
<Embodiment nine>
Step 1,5gPVA is soluble in water, and 5g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 7phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film IX.
Testing result is:Tensile strength 23.88MPa, elongation at break 11.28%.
<Embodiment ten>
Step 1,5gPVA is soluble in water, and 5g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 9phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film X.
Testing result is:Tensile strength 27.37MPa, elongation at break 12.31%.
Testing result is:Tensile strength 27.37MPa, elongation at break 12.31%.
<Embodiment 11>
Step 1,2gPVA is soluble in water, and 8g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, mixed liquor I is stirred into 60min with 800rpm, obtains mixed liquor I I.
Step 3, mixed liquor I I is heated into 30min in 100 DEG C of water-bath, obtains mixed liquor I II.
Step 4, mixed liquor I II is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XI.
Testing result is:Tensile strength 2.12MPa, elongation at break 2.27%.
<Embodiment 12>
Step 1,3gPVA is soluble in water, and 7g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, mixed liquor I is stirred into 60min with 800rpm, obtains mixed liquor I I.
Step 3, mixed liquor I I is heated into 30min in 100 DEG C of water-bath, obtains mixed liquor I II.
Step 4, mixed liquor I II is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XII.
Testing result is:Tensile strength 7.89MPa, elongation at break 3.18%.
<Embodiment 13>
Step 1,4gPVA is soluble in water, and 6g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, mixed liquor I is stirred into 60min with 800rpm, obtains mixed liquor I I.
Step 3, mixed liquor I I is heated into 30min in 100 DEG C of water-bath, obtains mixed liquor I II.
Step 4, mixed liquor I II is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XIII.
Testing result is:Tensile strength 12.78MPa, elongation at break 4.03%.
<Embodiment 14>
Step 1,5gPVA is soluble in water, and 5g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, mixed liquor I is stirred into 60min with 800rpm, obtains mixed liquor I I.
Step 3, mixed liquor I I is heated into 30min in 100 DEG C of water-bath, obtains mixed liquor I II.
Step 4, mixed liquor I II is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XIV.
Testing result is:Tensile strength 14.97MPa, elongation at break 5.02%.
<Embodiment 15>
Step 1,10gPVA is dissolved in 90 DEG C of water, obtains solution I.
Step 2, mixed liquor I is stirred into 60min with 800rpm, obtains mixed liquor I I.
Step 3, mixed liquor I I is heated into 30min in 100 DEG C of water-bath, obtains mixed liquor I II.
Step 4, mixed liquor I II is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XV.
Testing result is:Tensile strength 1.27MPa, elongation at break 24.11%.
<Embodiment 16>
Step 1,2gPVA is soluble in water, and 8g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 1phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XVI.
Testing result is:Tensile strength 2.77MPa, elongation at break 3.15%.
<Embodiment 17>
Step 1,3gPVA is soluble in water, and 7g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 1phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XVII.
Testing result is:Tensile strength 13.11MPa, elongation at break 5.03%.
<Embodiment 18>
Step 1,4gPVA is soluble in water, and 6g starch is dissolved in gelatinization in 90 DEG C of hot water and is mixed with PVA solution, it obtains
Mixed liquor I.
Step 2, solution I is added in the montmorillonite of 1phr, obtains suspension I.
Step 3, suspension I is stirred into 60min with 800rpm, obtains suspension II.
Step 4, suspension II is heated into 30min in 100 DEG C of water-bath, obtains suspension II I.
Step 5, suspension II I is poured into culture dish, it is dry at 65 DEG C to remove afterwards for 24 hours, obtain plastic film XVIII.
Testing result is:Tensile strength 17.23MPa, elongation at break 8.27%.
The characterization result of table 1 plastic film I to plastic film XVIII
As shown in Table 1, different amounts of montmorillonite is added in embodiment one to embodiment five, it is de- is only prepared for PVA/ illiteracies
Native film, when mixing the amount of montmorillonite of PVA in 1-5phr, tensile strength, elongation at break gradually increase, when montmorillonite exists
When 5-9phr, tensile strength, elongation at break are all gradually reduced;Different amounts of cover is added in embodiment six to embodiment ten to take off
Soil is prepared for PVA/ starch/montmorillonite tri compound film, with the increase of montmorillonite content, the tensile strength of composite membrane and
Incremental trend is totally presented in elongation at break;Not montmorillonoid-containing is only prepared in embodiment 11 to embodiment 15 to add
Add the PVA/ starch films of object;Embodiment 16 to embodiment 18 is added on the basis of embodiment 11 to embodiment 13
Add the montmorillonite of 1phr as additive, is prepared for tri compound film.It is added to the composite membrane after the montmorillonite of 1phr,
Tensile strength and elongation at break are better than the PVA/ starch films without additive.
According to embodiment one to embodiment 17 it is found that the plastic film being prepared using montmorillonite is for petroleum base
Plastic material has alternative well.Compared to the plastic film not containing montmorillonite, with the addition of montmorillonite, plastics
The tensile strength and elongation at break of film get a promotion.The reason is that with the addition of montmorillonite, tensile strength increases main
It is due to by forming strong interaction of the hydrogen bond between hypothallus and silicate layer.And montmorillonite filler can lead to
The regularity that release effect improves interchain arrangement is crossed, keeps interchain smoother, water-wet behavior also acts the elongation for improving PVA
Important role.
Therefore, tensile strength, elongation at break and water absorption rate are considered, when modified montmorillonoid content is 9phr, PVA
Starch ratio is 1:The effect of the plastic film prepared when 1 is best.
The effect of embodiment
According to a kind of method producing high performance plastic film using montmorillonite involved in the present embodiment.Using illiteracy
De- soil by mixing, stirring, heating, drying, removes these processes and obtains plastic film, and the technological process of this method is simple,
Processing time is short.In addition, using montmorillonite for raw material, biodegradable starch material and polyvinyl alcohol are taken full advantage of, is tied
It closes modified montmorillonoid and improves its mechanical performance, can effectively substitute traditional petroleum-based plastics, not only environmentally protective, Er Qieneng
Create prodigious economic benefit.
The above embodiment is the preferred case of the present invention, is not intended to limit protection scope of the present invention.
Claims (7)
1. a kind of method producing high performance plastic film using montmorillonite, which is characterized in that include the following steps:
Step 1, starch and polyvinyl alcohol (PVA) are calculated into the required starch and the polyvinyl alcohol by the first mass ratio
(PVA), the starch is gelatinized in the hot water of the first temperature, the polyvinyl alcohol (PVA) is dissolved in water, the institute after gelatinization
State starch and be dissolved in water the polyvinyl alcohol (PVA) mix after, obtain the first liquid;
Step 2, the montmorillonite of scheduled additive percentage composition (phr) is added in first liquid, obtains second liquid;
Step 3, after the second liquid being stirred 30-90min under the first mixing speed, third liquid is obtained;
Step 4, after the third liquid being heated 20-60min in the water-bath of second temperature, the 4th liquid is obtained;
Step 5, the 4th liquid is poured into culture dish, is removed, is obtained after dry 12-48h under the first drying temperature
Plastic film.
2. a kind of method producing high performance plastic film using montmorillonite according to claim 1, it is characterised in that:
Wherein, in the step 1, first mass ratio is 80wt.%:20wt.%, 70wt.%:30wt.%, 60wt.%:
40wt.%, 50wt.%:50wt.% and 0wt.%:Any one in 100wt.%.
3. a kind of method producing high performance plastic film using montmorillonite according to claim 1, it is characterised in that:
Wherein, in the step 1, ranging from 50-100 DEG C of first temperature.
4. a kind of method producing high performance plastic film using montmorillonite according to claim 1, it is characterised in that:
Wherein, in the step 2, the additive percentage composition is any one in 0-10.
5. a kind of method producing high performance plastic film using montmorillonite according to claim 1, it is characterised in that:
Wherein, in the step 3, first mixing speed is 800rpm.
6. a kind of method producing high performance plastic film using montmorillonite according to claim 1, it is characterised in that:
Wherein, in the step 4, ranging from 80-120 DEG C of the second temperature.
7. a kind of method producing high performance plastic film using montmorillonite according to claim 1, it is characterised in that:
Wherein, in the step 5, ranging from 40-80 DEG C of first drying temperature.
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CN114561125A (en) * | 2022-02-08 | 2022-05-31 | 河南师范大学 | Preparation method of biodegradable starch-based film material |
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