CN108500106A - A kind of 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell - Google Patents

A kind of 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell Download PDF

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Publication number
CN108500106A
CN108500106A CN201810344568.3A CN201810344568A CN108500106A CN 108500106 A CN108500106 A CN 108500106A CN 201810344568 A CN201810344568 A CN 201810344568A CN 108500106 A CN108500106 A CN 108500106A
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China
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explosion
stainless steel
groove
lug boss
shell
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CN201810344568.3A
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CN108500106B (en
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朱志刚
代江华
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WUHAN FUTE TECHNOLOGY Co Ltd
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WUHAN FUTE TECHNOLOGY Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02Stamping using rigid devices or tools
    • B21D22/04Stamping using rigid devices or tools for dimpling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00Tools as parts of machines covered by this subclass
    • B21D37/10Die sets; Pillar guides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/317Re-sealable arrangements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Gas Exhaust Devices For Batteries (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The invention discloses a kind of 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell, which is characterized in that step is:Carried out axially outwards at the shell bottom center of tubular shell it is one time punching molded, formed with anti-explosion groove lug boss, the ratio between the explosion-proof slot length L and lobes outside diameter D be 0.7 1:1, the anti-explosion groove is the dovetail groove of opening outwardly, and 304 stainless steel explosion-proof casings are obtained after detection is qualified.Cold stamping one-pass molding of the present invention directly obtains high spot and anti-explosion groove, and explosion-proof groove shape is regular, and high spot will not be affected by it, and the machining accuracy of anti-explosion groove is improved under the premise of saving process, energy-efficient.

Description

A kind of 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell
Technical field
The present invention relates to battery technology fields, anti-in particular to a kind of 304 stainless steels of lithium-thionyl chloride power type battery Quick-fried shell preparation method.
Background technology
Lithium thionyl chloride cell has high-energy-density and high-specific-power characteristic, the suitable TNT of chemical ratio energy of system fried 9-10 times of medicine, under normal circumstances, battery are outwardly to export energy under slave mode.When inside battery existing defects or outside Under portion's short circuit or abuse condition, it may occur however that pernicious explosion endangers personal safety, especially discharging surface and accumulates high power-type electricity The safety in pond, battery is the universal attention of people and concern.
Some battery cases also have Explosion-proof Design, the Chinese invention patent application of Publication No. CN101459230A public at present A kind of explosion prevention coiling type power lithium battery has been opened, at the bottom of cylindrical shell setting stainless steel case bottom, has been arranged on shell bottom and carves Trace type pressure relief opening, shell Bottom Shape are the ring of design outwardly convex in the groove of recessed battery, this shell bottom has the disadvantage that:1. shape Shape is complicated, processing difficulties, and the structure of recess and protrusion keeps its occupancy inside battery space larger, and same model design space is caused to become It is small;2. shell bottom needs to weld with housing seal, process is caused to increase, increases by 1 lap welding process and increase welding quality risk;3. Pressure relief opening is located on the recessed groove outer wall of reverse V-shaped ring edge, is arranged at rear cover radial direction both ends, this both ends are shorter and smaller to let out Pressure mouth can cause pressure release slow, to reduce the effect of directional pressure venting;4. the indentation of pressure relief opening is line style, width and depth all pole It is small, and rectangular cross-section, it can cause weak spot at this that can not open moment, detonation velocity is slow.Prevent made of above-mentioned 304 stainless steel Quick-fried shell will cause irregularly to tear since pressure relief opening is smaller, though reducing brisance, explosion is still formed, and has been unable to reach The effect of full directional explosion-proof pressure release.
Therefore, it is necessary to develop a kind of handling ease, have a safety feature, be not take up inside battery space lithium-thionyl chloride electricity The 304 stainless steel explosion-proof casing preparation methods in pond.
Invention content
Present invention aim to solve the deficiency of above-mentioned background technology, provide a kind of handling ease, have a safety feature, It is not take up 304 stainless steel explosion-proof casing preparation methods of inside battery space lithium thionyl chloride cell.
The technical scheme is that:A kind of 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell, it is special Sign is that step is:
Carry out one time punching molded, protrusion of the formation with anti-explosion groove axially outwards at the shell bottom center of tubular shell Portion, the ratio between the explosion-proof slot length L and lobes outside diameter D are 0.7-1:1, the anti-explosion groove is the dovetail groove of opening outwardly, inspection 304 stainless steel explosion-proof casings are obtained after surveying qualification.
This programme punching press at the center of shell bottom obtains the lug boss of anti-explosion groove, lug boss as tympanites primary deformation position, Larger internal pressure is alleviated, the anti-explosion groove at lug boss center is deformed when internal pressure continues to be increased to pressure threshold value to be torn, trapezoidal Slot number is extremely beneficial as weakness:1. comparison rectangular groove wall in the prior art, inclined trapezoidal cell wall is to slot bottom outwardly Attachment force is weaker, and when rupture is more easy to open, and pressure is in the emission state to scatter outwardly when 2. cell fracture, and trapezoidal cell wall is more sharp The ejection of internal gas and electrolyte, quick pressure releasing under the pressure state.
Preferably, the one time punching molded lower mold used includes opening up, inner circumferential and shell peripheral shape pair The first recessed portion answered, first recessed portion bottom surface is corresponding with shell bottom, first recessed portion bottom surface to have be used for shape At the second recessed portion of lug boss, second recessed portion bottom surface be equipped with upward protrusion, be used to form the trapezoidal radial direction of anti-explosion groove Rib;The one time punching molded upper mold used is outer diameter cylinder corresponding with lug boss internal diameter.In the prior art high spot with Indentation belongs to post forming, first on shell bottom at first stamped bumps, then is directly carved and is obtained with knife in outer surface, this technique will cause High spot easy compressive deformation when it is uneven to mark the depth, and marking;And this programme is cold stamping one-pass molding directly obtains protrusion Place and anti-explosion groove, explosion-proof groove shape is regular, and high spot will not be affected by it.This programme improves under the premise of saving process The machining accuracy of anti-explosion groove, it is energy-efficient.
Preferably, described one time punching molded to be:Shell is sheathed in the first recessed portion of lower mold, shell bottom and first recessed Concave portion bottom surface, for the upper mold downwardly toward the punching press of shell bottom, forming outer surface has the lug boss of anti-explosion groove.
Preferably, the shell by thickness 0.4-0.7mm, hardness 150-400HV 304 stainless steel belts through continuous drawing Technique, edge notches, cleaning, high temperature are consolidated melt processed and are obtained.This programme is processed using 304 stainless steel belts, thickness 0.4-0.7mm, hardness 150-400HV are entire battery weight to be made big if thickness is too big, difficulty of processing most useful for processing Greatly, the too big then punching press of hardness is more difficult, and since battery has internal pressure, hardness is too small, can make easily to deform at processing, It is unfavorable for packaging, transport and uses.
Preferably, the lug boss is the circle coaxial with shell bottom and anti-explosion groove radially passes through lug boss center.
Preferably, lug boss wall thickness C at anti-explosion groove does not open up the ratio between wall thickness H at anti-explosion groove with lug boss and is 0.2125-0.23:1.Wall thickness C is extremely critical at anti-explosion groove in this programme, and can complete packaging in daily resistance inner pressure of battery makes With, and can rapidly be torn when reaching pressure threshold value, it ensure that the safety of battery.
Preferably, the anti-explosion groove is that notch is wider than the isosceles trapezoid slot of slot bottom, angle X between two cell walls of the anti-explosion groove It it is 45-90 °, the slot bottom width W of the anti-explosion groove is 0.1-0.5mm.Included angle A too conference causes bottom surface deformation not between two cell walls It is flat, it is too small to increase pressure release resistance;Slot bottom width W too conferences cause it is daily it is yielding, rupture when deformation at irregular, too small meeting Increase pressure release resistance, 0.1-0.5mm, 45-90 ° of sections advantageously ensure that anti-explosion groove is uniformly split in pressure threshold value in this programme It opens.
Preferably, it is specially to be heated to the stainless steel to be quickly cooled to room temperature after 1100 DEG C to make that the high temperature, which consolidates melt processed, Carbon reaches hypersaturated state.Be conducive to make Carbide Phases all with this or basic dissolving, carbon are solid-solution in austenite, then quickly It is cooled to room temperature, carbon is made to reach hypersaturated state, purpose is mainly to improve the plasticity and toughness of steel and alloy, makes stainless steel alloy In various phases fully dissolve, Intensive intervention body, and improve toughness and etch resistant properties eliminates stress and softening, to continue to process Or molding.
The present invention also provides a kind of 304 stainless steel explosion-proof casing preparation methods of any of the above-described lithium thionyl chloride cell to be made 304 stainless steel explosion-proof casings, including shell, which is characterized in that the shell include cyclic annular body and with body one at The shell bottom of type is equipped with lug boss axially outwards at the center of the shell bottom, and the lug boss top surface is recessed anti-explosion groove, described Anti-explosion groove is the dovetail groove of opening outwardly.
Preferably, the lug boss is the circle coaxial with shell bottom and anti-explosion groove radially passes through lug boss center.
Preferably, the anti-explosion groove is that notch is wider than slot bottom, slot bottom the isosceles trapezoid slot parallel with lug boss top surface.
Preferably, included angle A is 45-90 ° between two cell walls of the anti-explosion groove.
Preferably, lug boss wall thickness C at anti-explosion groove does not open up the ratio between wall thickness H at anti-explosion groove with lug boss and is 0.2125-0.23:1。
Preferably, the explosion-proof slot length is less than or equal to lobes outside diameter.
Further, the ratio between described explosion-proof slot length L and lobes outside diameter D is 0.7-1:1.
Preferably, the lug boss height is 0.5-3mm.
Preferably, the slot bottom width W of the anti-explosion groove is 0.1-0.5mm.
Beneficial effects of the present invention are:
1. punching press obtains the lug boss of anti-explosion groove at the center of shell bottom, lug boss is alleviated as tympanites primary deformation position Larger internal pressure, the anti-explosion groove at lug boss center is deformed when internal pressure continues to be increased to pressure threshold value to be torn, and prevents battery from sending out Raw heavy explosion.
2. cold stamping one-pass molding directly obtains high spot and anti-explosion groove, explosion-proof groove shape is regular, and high spot will not be by It is influenced, and the machining accuracy of anti-explosion groove is improved under the premise of saving process, energy-efficient.
Description of the drawings
Fig. 1 is inventive shell Sheet Metal Forming Technology schematic diagram
Fig. 2 is that the present invention prepares gained shell upward view
Fig. 3 is A-A sectional views in Fig. 2
Fig. 4 is B-B sectional views in Fig. 2
Wherein:The first recessed portions of mold 6- 7- second is recessed under 1- shell 1.1- body 2- shells bottom 3- lug boss 4- anti-explosion grooves 5- The trapezoidal radial rib 9- upper molds of concave portion 8-.
Specific implementation mode
The present invention is described in further detail for specific embodiment below.
Embodiment 1
A kind of 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell provided by the invention, the specific steps are:
A. by thickness 0.4-0.7mm, hardness 150-400HV austenite 304DQ stainless steel belts through continuous deep-drawing technique Integrated molding obtains tubular shell 1, and shell 1 includes circular shell 1.1 and shell bottom 2, by shell 1 through edge notches, cleaning, high temperature Gu melt processed, it is specially to be quickly cooled to room temperature after stainless steel is heated to 1100 DEG C that high temperature, which consolidates melt processed,;
B. the lug boss 3 with anti-explosion groove 4 is formed through a Sheet Metal Forming Technology axially outwards at 2 center of shell bottom, such as Fig. 1 institutes Show, the one time punching molded lower mold 5 used includes opening up, inner circumferential the first recess corresponding with 1.1 peripheral shape of shell Portion 6,6 bottom surface of the first recessed portion is corresponding with shell bottom 2, and 6 bottom surface of the first recessed portion is used to form the second recessed of lug boss 3 to having Concave portion 7, the trapezoidal radial rib 8 that 7 bottom surface of the second recessed portion is equipped with protrusion upward, is used to form anti-explosion groove 4, trapezoidal radial direction rib 8 push up Face is not higher than 6 bottom of the first recessed portion;The one time punching molded upper mold 9 used is 3 internal diameter pair of lug boss of outer diameter and design The cylinder answered.
It is one time punching molded to be:Shell 1 is sheathed in 5 first recessed portion 6 of lower mold, 6 bottom of shell bottom 2 and the first recessed portion Face coordinates, and is gripped between shell 1 and lower mold 5, and upper mold 9 enters in shell from opening by the punching press outwardly of bottom plate 2, such as schemes Arrow direction in 1 forms anti-explosion groove 4 while shell bottom 2 is stamped out lug boss 3.The 4 length L of anti-explosion groove that punching press obtains It is 0.7-1 with the ratio between 3 outer diameter D of lug boss:1, anti-explosion groove 4 is the dovetail groove of opening outwardly, most qualified through pressure, size detection afterwards After obtain 304 stainless steel explosion-proof casings.
As in Figure 2-4, above-mentioned 304 stainless steel explosion-proof casing concrete structures being prepared are:Including shell 1, shell 1 Including cyclic annular body 1.1 and with 1.1 integrally formed shell bottom 2 of body, lug boss 3 axially outwards is equipped at 2 center of shell bottom, 3 top surface of lug boss is recessed anti-explosion groove 4, and anti-explosion groove 4 is that notch is wider than slot bottom, the slot bottom isosceles parallel with 3 top surface of lug boss Dovetail groove, 4 liang of cell walls of anti-explosion groove are symmetrically towards outer incline.Lug boss 3, which is that the circle and anti-explosion groove 4 coaxial with shell bottom 2 are radial, to be passed through 3 center of lug boss.Lug boss 3 wall thickness C and lug boss 3 at anti-explosion groove 4 do not open up at anti-explosion groove 4 wall thickness H (herein not for 304 Become rusty steel steel band original thickness) the ratio between be 0.2125-0.23:1.4 liang of cell walls of anti-explosion groove are symmetrically towards outer incline, angle X between two cell walls It it is 45-90 °, the slot bottom width W of anti-explosion groove 4 is 0.1-0.5mm.3 height of lug boss is 0.5-3mm, and raised top surface is shell diameter To plane.
In the present embodiment:
Raw material 304 stainless steel belt thickness 0.4mm, hardness 150HV;
Length L and outer diameter D=0.7:1;
Thickness ratio C:H=0.2125, i.e. H=0.4mm, thickness C=0.085mm;
X=60 ° of angle
Width W=0.3mm
3 height h of lug boss is 0.5mm.
304 stainless steel explosion-proof casing preparation methods of embodiment 2-8 lithium thionyl chloride cells are identical with embodiment 1, Structure is identical, variant in size, 304 stainless steel explosion-proof casing sizes such as the following table 1 institute that embodiment 1-8 is prepared Show.
The 304 stainless steel explosion-proof casing sizes that 1 embodiment 1-8 of table is prepared
Performance test
Shell obtained by embodiment 1-8 is subjected to blow-off pressure test, test result is as follows shown in table 2.
Shell blow-off pressure test result obtained by 2 embodiment 1-8 of table
It can be obtained from above-mentioned table 2, all of above shell Opening pressure being prepared is satisfied by requirement of explosion proof, Er Qiejun Rule is split from anti-explosion groove, meets the demand of battery security.

Claims (10)

1. a kind of 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell, which is characterized in that in tubular shell (1) Shell bottom (2) center at carry out axially outwards it is one time punching molded, formed with anti-explosion groove (4) lug boss (3), it is described explosion-proof The ratio between slot (4) length L and lug boss (3) outer diameter D are 0.7-1:1, the anti-explosion groove (4) is the dovetail groove of opening outwardly, detection 304 stainless steel explosion-proof casings are obtained after qualification.
2. 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell as described in claim 1, which is characterized in that The one time punching molded lower mold (5) used includes that opening up, inner circumferential is corresponding with shell (1) peripheral shape first recessed Concave portion (6), the first recessed portion (6) bottom surface is corresponding with shell bottom (2), and the first recessed portion (6) bottom surface is used for having Formed lug boss (3) the second recessed portion (7), the second recessed portion (7) bottom surface be equipped with upward protrusion, be used to form anti-explosion groove (4) trapezoidal radial rib (8);The one time punching molded upper mold (9) used is outer diameter cylinder corresponding with lug boss (3) internal diameter Body.
3. 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell as claimed in claim 2, which is characterized in that It is described one time punching molded to be:Shell (1) is sheathed in (5) first recessed portion (6) of lower mold, shell bottom (2) and the first recess Portion (6) bottom surface, for the upper mold (9) downwardly toward shell bottom (2) punching press, forming outer surface has the lug boss of anti-explosion groove (4) (3)。
4. 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell as described in claim 1, which is characterized in that The shell (1) by thickness 0.4-0.7mm, hardness 150-400HV 304 stainless steel belts through continuous deep-drawing technique one at Type, then consolidate melt processed through edge notches, cleaning, high temperature and obtain.
5. 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell as described in claim 1, which is characterized in that The lug boss (3) is the circle coaxial with shell bottom (2) and anti-explosion groove (4) radially passes through lug boss (3) center.
6. 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell as described in claim 1, which is characterized in that It is 0.2125- that the lug boss (3) wall thickness C and lug boss (3) at anti-explosion groove (4), which do not open up the ratio between wall thickness H at anti-explosion groove (4), 0.23:1。
7. 304 stainless steel explosion-proof casing preparation methods of lithium thionyl chloride cell as described in claim 1, which is characterized in that The anti-explosion groove (4) is wider than the isosceles trapezoid slot of slot bottom for notch, and angle X is 45-90 ° between two cell walls of the anti-explosion groove (4), The slot bottom width W of the anti-explosion groove (4) is 0.1-0.5mm.
8. in a kind of 1-7 such as claim made from 304 stainless steel explosion-proof casing preparation methods of any lithium thionyl chloride cell 304 stainless steel explosion-proof casings, including shell (1), which is characterized in that the shell (1) includes cyclic annular body (1.1) and and shell Body (1.1) integrally formed shell bottom (2) is equipped with lug boss (3) axially outwards, the lug boss at shell bottom (2) center (3) top surface is recessed anti-explosion groove (4), and the anti-explosion groove (4) is the dovetail groove of opening outwardly.
9. 304 stainless steel explosion-proof casings of lithium thionyl chloride cell as claimed in claim 8, which is characterized in that the protrusion Portion (3) is the circle coaxial with shell bottom (2) and anti-explosion groove (4) radially passes through lug boss (3) center.
10. 304 stainless steel explosion-proof casings of lithium thionyl chloride cell as claimed in claim 8, which is characterized in that described explosion-proof Slot (4) is that notch is wider than slot bottom, slot bottom the isosceles trapezoid slot parallel with lug boss (3) top surface.
CN201810344568.3A 2018-04-17 2018-04-17 Preparation method of 304 stainless steel explosion-proof shell of lithium thionyl chloride battery Active CN108500106B (en)

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CN109746318A (en) * 2019-01-22 2019-05-14 浙江锦泰电子有限公司 The manufacturing method of explosion rupture disk
CN110429214A (en) * 2019-08-07 2019-11-08 宁德时代新能源科技股份有限公司 Cap assembly for secondary battery and secondary battery
CN112719011A (en) * 2020-12-15 2021-04-30 重庆伟汉汽车部件有限公司 Forming process for positioning and mounting convex hull on electric control booster shell
CN114242462A (en) * 2021-12-27 2022-03-25 江苏奥星电子有限公司 Integrally-formed explosion-proof aluminum shell extrusion die and forming process thereof

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CN109746318A (en) * 2019-01-22 2019-05-14 浙江锦泰电子有限公司 The manufacturing method of explosion rupture disk
CN109746318B (en) * 2019-01-22 2020-08-21 浙江锦泰电子有限公司 Method for manufacturing explosion-proof sheet
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