CN108486930A - The method for sorting of the cation-modified reactive dyeing of single bath process - Google Patents
The method for sorting of the cation-modified reactive dyeing of single bath process Download PDFInfo
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- CN108486930A CN108486930A CN201810441540.1A CN201810441540A CN108486930A CN 108486930 A CN108486930 A CN 108486930A CN 201810441540 A CN201810441540 A CN 201810441540A CN 108486930 A CN108486930 A CN 108486930A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/66—Natural or regenerated cellulose using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
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- Chemical & Material Sciences (AREA)
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Abstract
The present invention relates to the method for sorting of the cation-modified reactive dyeing of single bath process, it is soaped to obtain Fabrics Dyed with Reactive Dyes after the treatment fluid of cation modifying agent and reactive dye is organized on cellulose base fiber fabric by pad dyeing or exhaust process, wherein, when using knot dyeing technology, cellulose base fiber fabric carries out decatize before being soaped, bakes or cold pad--batch；Cation modifier be 100 30000 containing reactive group and positive charge group and number-average molecular weight in molecular structure molecule, its reactive group is one or more in epoxy group, s-triazine, pyridine and alkene, and positive charge group includes one or more in quaternary ammonium salt and ammonium chloride structure.The cation-modified fixation with reactive dye of cotton fabric is combined into a step and carried out by the method for the present invention, is shortened technological process, is improved the color strength and degree of fixation of fabric, and avoid the addition of inorganic salts in dyeing course, so as to avoid the pollution to environment.
Description
Technical field
The invention belongs to textile printing and dyeing field, it is related to that a kind of cationization one-step method meets degree of fixation and color strength is wanted
The colouring method of the salt-free pad dyeing or dip dyeing asked, and in particular to the method for sorting of the cation-modified reactive dyeing of single bath process.
Background technology
Cotton fabric has the good characteristics such as comfortable and easy to wear, hygroscopicity, warmth retention property, good permeability, easy to clean, by more next
The favor of more consumers.Reactive dye have many advantages, such as that bright-colored, chromatography is complete and dyefastness is good.Therefore, wide
It is general to apply in the dyeing of cotton and other cellulose base fiber fabrics.But due between cotton fiber and electronegative reactive dye
There is coulomb repulsions, influence the upper dye of reactive dye, and dyeing needs that a large amount of salt rush dye is added and alkali fixation is added, causes to give up
Reactive dye and salt containing a large amount of non-fixation or hydrolysis, serious pollution is caused to environment in water.
In order to improve the dye-uptake and degree of fixation of reactive dye, usually there are two types of methods：It is a large amount of one is being added in dye bath
Salt, shield the coulomb repulsion between cotton fabric and reactive dye, add consolidating for alkali carries high activity dyestuff and cellulose hydroxyl group
Colour response, to improve the dye-uptake and degree of fixation of reactive dye；Another is two-step process：To first to cotton fabric into
Row is cation-modified, improves dye-uptake to the charge attraction contaminated on reactive dye to improve, then carry out salt-free dyeing.By sun from
When sub- method of modifying is applied in reactive dyeing, technological process is long, and energy consumption is big, and specific two-step process is as follows：First
Cotton fabric is handled with cation modifier by way of impregnating or padding, uses sodium hydroxide to complete cationization at this time anti-
Answer, using bake and pickling neutralization and washing and drying after obtain cationization cotton fabric；Cationization cotton fabric passes through again
Reactive dye salt-free is disseminated or the mode of pad dyeing dyes, and obtains Fabrics Dyed with Reactive Dyes.During above-mentioned two-step process,
Although cation modifier and reactive dye can all react with the hydroxyl on cotton fabric, its it is corresponding cationization and
Reactive dye color fixing process carries out successively, and competitive relation is not present between the two, will not fight for the hydroxyl on cotton fabric.Two
Footwork technological process is long, needs to consume a large amount of energy and water resource, is unfavorable for industrialized production.
Currently, the method by the way that a large amount of electrolyte are added, the degree of fixation of cotton fabric by utilizing reactive dye dyeing can reach
70~80% or so.It is although increased using the cotton fabric by utilizing reactive dye dyeing degree of fixation of cationization two step method, but
It is that the addition of a large amount of electrolyte can cause environmental pollution.And the two-step process long flow path being cationized, need consumption a large amount of
The energy and water resource, be unfavorable for industrialized production.
Therefore, research and develop that a kind of degree of fixation is high, color strength is had excellent performance, technological process is short and a free of contamination bath
The method for sorting of the cation-modified reactive dyeing of method becomes a technical problem to be solved urgently.
Invention content
Technical problem to be solved by the invention is to provide a kind of cationization one-step method to meet degree of fixation and apparent color
The colouring method for measuring desired salt-free pad dyeing or dip dyeing, be specifically related to a kind of cation-modified reactive pad dyeing of single bath process or
The colouring method of dip dyeing.The technology of the present invention is cationization one-step method, not only save the time shorten technique save a large amount of water and
The energy, and color strength and degree of fixation are higher than the method for adding salt to promote dye, it is identical as cationization two-step method effect.
In order to achieve the above object, the technical solution adopted by the present invention is：
The method for sorting of the cation-modified reactive dyeing of single bath process, is changed cation by pad dyeing or exhaust process
After the dye liquor of property agent and reactive dye is organized on cellulose base fiber fabric, soaped to obtain Fabrics Dyed with Reactive Dyes,
In, when using knot dyeing technology, cellulose base fiber fabric carries out decatize before being soaped, bakes or cold pad--batch；
The cation modifier is in molecular structure
The molecule of 100-30000, reactive group are one or more, the positive charge in epoxy group, s-triazine, pyridine and alkene
Group includes one or more in quaternary ammonium salt and ammonium chloride structure.
As preferred technical solution：
Method for sorting as described above, the padding liquor include 10~150g/L cation Gai Ji ﹑, 5~40g/L activity
The deionized water of Ran Liao 10~70g/L of ﹑ alkaline agents, 30~150g/L urea and surplus.
Method for sorting as described above, the cation modifier are specially 2,3- epoxypropyl trimethylammonium chloride An ﹑ 2,
The chloro- 2- hydroxypropyls triethylammonium chloride ﹑ of the three chloro- 2- hydroxyls oxypropyl trimethyl chlorine ammonium ﹑ 3- of ethylmercury chloride ammonium ﹑ 3- of 3- glycidyl mono-
In chloro-s-triazine type quaternary ammonium salt compound ﹑ azetidiniums compound, choline chloride and polyepichlorohydrin amine compound
One or more of mixtures.
Method for sorting as described above, the reactive dye are Jun tri- Qin ﹑ pyrimidines, vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) or phosphonic acids type reactive dye.
Method for sorting as described above, the alkaline agent are one or more of Qing Yangization Na ﹑ sodium bicarbonates and sodium carbonate
Mixture.Alkaline agent type is without being limited thereto, further includes potassium hydroxide, saleratus, potassium carbonate, potassium phosphate, potassium silicate, sodium metasilicate
Or sodium phosphate.
The process of method for sorting as described above, the knot dyeing technology is：Cellulose fibre is knitted using the mode padded
Object carries out pad dyeing processing, and guarantee fabric liquid carrying rate is 60~100wt%；The process of the exhaust process is：Use the side of dip dyeing
Formula handles cellulose base fiber fabric, and 30~90min is disseminated at 60~90 DEG C.
Method for sorting as described above, the cellulose base fiber fabric include cotton, fiber crops, viscose fiber, tencel and Modal
Fabric.
Method for sorting as described above, the decatize or bake directly carry out or the fabric drying that will pad that treated after
It carries out.
Method for sorting as described above, the decatize refer to 100~180 DEG C of 1~15min of saturated vapor decatize；The baking
Roasting refers to 100~180 DEG C and bakes 1~15min；The cold pad--batch refers to banking up 6~18h at 15~35 DEG C.Decatize bakes or cold
It is to ensure cation modifier and the same cotton of reactive dye to roll heap temperature and time to be arranged in the main purpose of this range
The reaction of fabric.Temperature is excessively high or overlong time, and the covalent bond formed between reactive dye and cotton fabric can be made to be broken, led
K/S values and degree of fixation is caused to decline；Temperature is too low or the time is too short, and the reaction being unfavorable between reactive dye and cotton fabric obtains
K/S values and degree of fixation it is relatively low.
Invention mechanism：
Present invention firstly provides the dyeing that reactive dye are improved using the cation-modified reactive dyeing process of single bath process
Effect.Cation-modified and reactive dye fixation are combined into a step and carried out by the technique, highly shortened technological process, are saved
The energy.The technique (abbreviation one-step technology) dyes the two-step process phase of reactive dye again after being first cationized with fabric
Than chemical reaction process is different.The prior art use two-step process for cotton fabric first through it is cation-modified obtain sun from
The cotton fabric of sonization, then pads reactive dye dye liquor, and cotton fabric hair of the reactive dye with cationization is made in steaming procedure
It is raw fixed.The fixation of the cation-modified and reactive dye of cotton fabric be divided into two steps progress, although cation modifier and
Reactive dye can all react with the hydroxyl on cotton fabric, but its corresponding cationization and reactive dye color fixing process are
It carries out successively, therefore, there is competitive relations between the two.The cation-modified activity dye of single bath process that the present invention uses
Expect in dyeing, cation-modified and reactive dye fixation are combined into step progress, and they both can same cotton fabric
On hydroxyl react, therefore there is competitive relations between the two.In order to probe into cation modifier and work in one-step method
For property dyestuff with the reaction process of cotton fabric, the present invention calculates separately out cation modifier with the anti-of cotton fabric using Gauss software
Answer thermodynamics and kinetics data and reactive dye thermodynamics of reactions and dynamics data with cotton fabric.Following reaction structures
Formula lists the reaction process of reactant R1, R2, R3, transition state TS1, TS2 and product P1, P2, as follows：
In order to simplify calculating process, indicate that cation modifier, R2 indicate that reactive dye, R3 indicate cotton fabric with R1,
Wherein TS1 and TS2 is respectively the transition state reacted, and P1 and P2 indicate product.Reaction for R1 and R3, Gaussian Computation result
Show C-O keys by reactant R1'sIt is increased in transition state TS1O-H keys are by reactant R3'sIncrease
In greatly transition state TS1Newly-generated C-O keys are by transition state TS1It is reduced in product P1Newly-generated O-H keys are by transition state TS1It is reduced in product P1Therefore, for R1 and
The reaction of R3, reaction mechanism are to be connected with oxygen in the oxygen atom attack R1 in R3 and the not no carbon atom of branch, and parent occurs
Nuclear reaction generates product P1.Reaction for R2 and R3, Gaussian Computation result show C-Cl keys by reactant R2'sIncrease
In greatly transition state TS2O-H keys are by reactant R3'sIt is increased in transition state TS2It is newborn
At C-O keys by transition state TS2It is reduced in product P2Therefore, for the reaction of R2 and R3,
Its reaction mechanism is the carbon atom being connected with chlorine in the oxygen atom attack R2 in R3, and necleophilic reaction occurs and generates product P2.
Thermodynamics of reactions and dynamics data of the cation modifier and reactive dye that b3lyp/6-31g methods calculate with cotton fabric
As shown in the table：
As can be seen from the table, the reaction enthalpy (Δ H) of R1 and R3 is -121.6814KJmol-1, the reaction enthalpy of R2 and R3
For -69.9570KJmol-1, the reaction of R2 and R3 is compared, the reaction of R1 and R3 send out more heats.Gibbs free energy
When (Δ G) is negative value, imply that chemical reaction spontaneous can carry out, be compared to the Gibbs free energy that R2 and R3 react-
53.6521KJ·mol-1, the Gibbs free energy that R1 and R3 react is -74.1205KJmol-1, what Gibbs free energy was born
It is more, it is possible to which that chemical reaction is more easy to happen.The reaction activity (Ea) of R1 and R3 is 125.7208KJmol-1, R2 and R3
Reaction activity (Ea) be 172.1007KJmol-1, reaction activity is lower to imply the easier progress of chemical reaction.It is comprehensive
Upper described, the reactivity of cation modifier and cotton fabric is to be better than the reactivity of reactive dye and cotton fabric.In single bath process
In cation-modified reactive pad dyeing technique, cation modifier can preferentially react with cotton fabric, with the reaction time
Increase, the zeta current potentials of fabric being become just from negative slowly then just attract the suction of electronegative reactive dye on the fabric
It is accompanied by and fixation, to improve the color strength and degree of fixation of fabric.
Advantageous effect：
(1) method of the cation-modified reactive dyeing of single bath process of the invention, in practical applications, since it is by cotton
The cation-modified fixation with reactive dye of fabric is combined into step progress, greatly shortens technological process, improves fabric
Color strength and degree of fixation；
(2) method of the cation-modified reactive dyeing of single bath process of the invention, this method is in entire dyeing course
The addition for avoiding inorganic salts avoids the pollution to environment to alleviate the content of salt in waste water.
Specific implementation mode
The invention will be further elucidated with reference to specific embodiments.It should be understood that these embodiments are merely to illustrate this hair
It is bright rather than limit the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, art technology
Personnel can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Fixed range.
Embodiment 1
Treatment fluid is adsorbed on cotton and is knitted by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On object, guarantee fabric liquid carrying rate is 60wt%, then will pad that treated fabric directly carries out decatize, is finally soaped to obtain
Reactive pad dyeing fabric, wherein treatment fluid includes 2, the 3- epoxypropyl trimethylammonium chloride An ﹑ 15g/L s-triazine of 100g/L
The deionized water of Huo Ran Liao ﹑ 20g/L sodium hydroxides, 80g/L urea and surplus, wherein decatize refers to 100 DEG C of saturated vapor vapour
15min is steamed, is soaped including following five stages：1) room temperature rinses 3min；2) 40 DEG C of warm water wash 1min；3) 1g/L soaping agents D-
301 90 DEG C of 5min that soap；4) 40 DEG C of warm water wash 3min；5) room temperature rinses 1-5min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 14.7, degree of fixation
It is 80.8%.
Embodiment 2
Treatment fluid is adsorbed on hemp by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On object, guarantee fabric liquid carrying rate is 70wt%, then will pad that treated fabric directly carries out decatize, is finally soaped to obtain
Reactive pad dyeing fabric, wherein treatment fluid includes that 2, the 3- glycidyl San ethylmercury chloride An ﹑ 25g/L s-triazine of 80g/L is lived
The deionized water of property Ran Liao ﹑ 50g/L sodium bicarbonates, 30g/L urea and surplus, wherein decatize refers to 160 DEG C of saturated vapor decatizes
1min soaped including following five stages：1) room temperature rinses 5min；2) 40 DEG C of warm water wash 3min；3) 2g/L soaping agents D-301
92 DEG C of 6min that soap；4) 50 DEG C of warm water wash 1min；5) room temperature rinses 1min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 18.8, degree of fixation
It is 83.2%.
Embodiment 3
Treatment fluid is adsorbed on viscose by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On fabric, guarantee fabric liquid carrying rate is 80wt%, then will pad that treated fabric directly bakes, and finally carries out soap
It washes to obtain reactive pad dyeing fabric, wherein treatment fluid includes the chloro- 2- Qiang oxypropyl trimethyls Lvization An ﹑ 35g/L of 3- of 130g/L
The deionized water of pyrimidine active Ran Liao ﹑ 40g/L sodium carbonate, 90g/L urea and surplus bakes wherein baking and referring to 100 DEG C
15min soaped including following five stages：1) room temperature rinses 1min；2) 40 DEG C of warm water wash 2min；3) 3g/L soaping agents D-301
97 DEG C of 5min that soap；4) 60 DEG C of warm water wash 3min；5) room temperature rinses 12min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 23.1, degree of fixation
It is 93.2%.
Embodiment 4
Treatment fluid is adsorbed on tencel by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On fabric, guarantee fabric liquid carrying rate is 90wt%, then will pad that treated fabric directly bakes, and finally carries out soaping
To reactive pad dyeing fabric, wherein treatment fluid includes the chloro- 2- hydroxypropyls triethylammonium chloride ﹑ 40g/L pyrimidines of 3- of 150g/L
Mixture (the mass ratio 1 of Huo Ran Liao ﹑ 30g/L sodium hydroxides and sodium bicarbonate:2), 100g/L urea and surplus go from
Sub- water bakes 3min wherein baking and referring to 120 DEG C, soaps including following five stages：1) room temperature rinses 2min；2) 50 DEG C of warm water
Wash 1min；3) 94 DEG C of 7min that soap of 4g/L soaping agents D-301；4) 50 DEG C of warm water wash 4min；5) room temperature rinses 3min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 24.6, degree of fixation
It is 95.3%.
Embodiment 5
Treatment fluid is adsorbed on not generation by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On your fabric, guarantees fabric liquid carrying rate is 100wt%, then will pad that treated fabric directly bakes, and finally carries out soap
It washes to obtain reactive pad dyeing fabric, wherein treatment fluid includes chloro- 4, the 6- diaminostilbenes of 2- of 60g/L, 3,5- tri- Qin ﹑ 5g/L
Mixture (the mass ratio 1 of vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) Huo Ran Liao ﹑ 10g/L sodium bicarbonates and sodium carbonate:3), 110g/L urea and surplus
Deionized water bakes 1min wherein baking and referring to 180 DEG C, soaps including following five stages：1) room temperature rinses 4min；2)60℃
Warm water washes 5min；3) 93 DEG C of 10min that soap of 1g/L soaping agents D-301；4) 40 DEG C of warm water wash 5min；5) room temperature rinses 4min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 8.6, degree of fixation
It is 75.5%.
Embodiment 6
The method of the cation-modified reactive dyeing of single bath process, using the mode padded, by treatment fluid be adsorbed on cotton and
Blended (the mass ratio 1 of fiber crops:1) on fabric, guarantee fabric liquid carrying rate is 60wt%, then will pad that treated fabric directly carries out
Decatize is finally soaped to obtain reactive pad dyeing fabric, wherein treatment fluid includes the N- dimethyl azetidins of 30g/L
Mixture (the mass ratio 3 of alkane Lvization Wu ﹑ 10g/L vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) Huo Ran Liao ﹑ 70g/L sodium hydroxides and sodium carbonate:2)、140g/
The deionized water of L urea and surplus, wherein decatize refer to 180 DEG C of saturated vapor decatize 1min, are soaped including following five stages：
1) room temperature rinses 1min；2) 40 DEG C of warm water wash 3min；3) 98 DEG C of 5min that soap of 3g/L soaping agents D-301；4) 40 DEG C of warm water are washed
4min；5) room temperature rinses 5min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 11.6, degree of fixation
It is 81.6%.
Embodiment 7
Treatment fluid is adsorbed on cotton and is knitted by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On object, guarantee fabric liquid carrying rate is 100wt%, then is baked after the fabric drying that will pad that treated, is finally soaped
Obtain reactive pad dyeing fabric, wherein treatment fluid includes 10g/L Lvization Dan Jian ﹑ 5g/L phosphonic acids type Huo Ran Liao ﹑ 50g/L hydrogen
Mixture (the mass ratio 1 of Yangization Na ﹑ sodium bicarbonates and sodium carbonate:1:3), the deionized water of 150g/L urea and surplus,
Middle baking refers to 150 DEG C and bakes 1.5min, soaps including following five stages：1) room temperature rinses 4min；2) 50 DEG C of warm water are washed
4min；3) 95 3 DEG C of 10min that soap of 3g/L soaping agents D-301；4) 50 DEG C of warm water wash 5min；5) room temperature rinses 5min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 10.9, degree of fixation
It is 80.3%.
Embodiment 8
Treatment fluid is adsorbed on viscose glue by the method for the cation-modified reactive dyeing of single bath process using the mode padded
Fiber and tencel blended (mass ratio 1:1) on fabric, guarantee fabric liquid carrying rate is 80wt%, then the fabric that will pad that treated
Decatize is carried out after drying, is finally soaped to obtain reactive pad dyeing fabric, wherein treatment fluid includes 100g/L polycyclic oxygen chlorine
The deionized water of propane Er Jia An ﹑ 35g/L phosphonic acids type Huo Ran Liao ﹑ 30g/L sodium hydroxides, 30g/L urea and surplus, wherein vapour
Steaming refers to 100 DEG C of saturated vapor decatize 10min, is soaped including following five stages：1) room temperature rinses 3min；2) 60 DEG C of warm water are washed
1min；3) 90 DEG C of 10min that soap of 4g/L soaping agents D-301；4) 60 DEG C of warm water wash 2min；5) room temperature rinses 4min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 22.2, degree of fixation
It is 90.5%.
Embodiment 9
Treatment fluid is adsorbed on tencel by the method for the cation-modified reactive dyeing of single bath process using the mode padded
With the blended (mass ratio 1 of Modal:1) on fabric, guarantee fabric liquid carrying rate is 70wt%, then will pad that treated fabric dries
Decatize is carried out after dry, is finally soaped to obtain reactive pad dyeing fabric, wherein treatment fluid includes 2, the 3- epoxies of 120g/L
Mixture (the mass ratio 2 of hydroxypropyltrimonium chloride and 2,3- Epoxypropyl triethyl ammonium chlorides:3) ﹑ 30g/L s-triazine is lived
The deionized water of property Ran Liao ﹑ 10g/L sodium hydroxides, 150g/L urea and surplus, wherein decatize refers to 130 DEG C of saturated vapor decatizes
3min soaped including following five stages：1) room temperature rinses 5min；2) 50 DEG C of warm water wash 2min；3) 4g/L soaping agents D-301
98 DEG C of 5min that soap；4) 40 DEG C of warm water wash 2min；5) room temperature rinses 3min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 20.3, degree of fixation
It is 89.8%.
Embodiment 10
Treatment fluid is adsorbed on cotton, fiber crops by the method for the cation-modified reactive dyeing of single bath process using the mode padded
With viscose fiber blending (mass ratio 1:1:1) on fabric, guarantee fabric liquid carrying rate is 60wt%, then will pad that treated knits
Decatize is carried out after object drying, is finally soaped to obtain reactive pad dyeing fabric, wherein treatment fluid includes the 3- of 50g/L chloro-
Mixture (the mass ratio 1 of 2- hydroxypropyl-trimethyl ammonium chlorides and the chloro- 2- hydroxypropyls triethylammonium chloride of 3-:1) ﹑ 20g/L are equal
The deionized water of triazine Huo Ran Liao ﹑ 40g/L sodium bicarbonates, 50g/L urea and surplus, wherein decatize refer to that 120 DEG C of saturations are steamed
Vapour decatize 3min soaped including following five stages：1) room temperature rinses 5min；2) 50 DEG C of warm water wash 5min；3) 2g/L soaping agents
90 DEG C of 10min that soap of D-301；4) 40 DEG C of warm water wash 5min；5) room temperature rinses 2min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 16.9, degree of fixation
It is 84.2%.
Embodiment 11
Treatment fluid is organized in by the method for sorting of the cation-modified reactive dyeing of single bath process using the mode padded
Viscose rayon, tencel and the blended (mass ratio 1 of Modal:1:1) on fabric, guarantee fabric liquid carrying rate is 100wt%, then will leaching
It is baked after the fabric drying that rolls that treated, is finally soaped to obtain reactive pad dyeing fabric, wherein treatment fluid includes
The mixture of the chloro- 4,6- diaminostilbenes of 90g/L 2-, 3,5- tri- Qin ﹑ N- dimethyl azetidinium Chlorides and choline chloride
(mass ratio 2:1:1) the deionized water of ﹑ 20g/L pyrimidine actives Ran Liao ﹑ 30g/L sodium carbonate, 30g/L urea and surplus, wherein
Baking refers to 140 DEG C and bakes 2min, soaps including following five stages：1) room temperature rinses 1min；2) 60 DEG C of warm water wash 3min；3)
96 DEG C of 5min that soap of 3g/L soaping agents D-301；4) 60 DEG C of warm water wash 1min；5) room temperature rinses 1min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 15.8, degree of fixation
It is 82.8%.
Embodiment 12
Treatment fluid is adsorbed on viscose glue by the method for the cation-modified reactive dyeing of single bath process using the mode padded
Fiber, tencel and the blended (mass ratio 1 of Modal:1:1) on fabric, guarantee fabric liquid carrying rate is 70wt%, then will pad place
Fabric after reason directly carries out cold pad--batch, is finally soaped to obtain reactive pad dyeing fabric, wherein treatment fluid includes 70g/
Mixture (the matter of the chloro- 4,6- diaminostilbenes of L 2-, 3,5- tri- Qin ﹑ N- dimethyl azetidinium Chlorides and choline chloride
Amount is than being 2:1:1) the deionized water of ﹑ 5g/L s-triazine Huo Ran Liao ﹑ 20g/L sodium bicarbonates, 60g/L urea and surplus, wherein
Cold pad--batch refers to 15 DEG C and banks up 6h, soaps including following five stages：1) room temperature rinses 1min；2) 60 DEG C of warm water wash 3min；3)
96 DEG C of 5min that soap of 3g/L soaping agents D-301；4) 60 DEG C of warm water wash 1min；5) room temperature rinses 1min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 10.2, degree of fixation
It is 78.5%.
Embodiment 13
Treatment fluid is adsorbed on cotton and is knitted by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On object, guarantee fabric liquid carrying rate is 90wt%, then will pad that treated fabric directly carries out cold pad--batch, finally carries out soaping
To reactive pad dyeing fabric, wherein treatment fluid includes the chloro- 2- Qiang oxypropyl trimethyls Lvization An ﹑ 15g/L phosphonic acids types of 90g/L3-
The deionized water of Huo Ran Liao ﹑ 40g/L sodium carbonate, 30g/L urea and surplus, wherein cold pad--batch refer to 15 DEG C and bank up 18h, soap
Including following five stages：1) room temperature rinses 1min；2) 60 DEG C of warm water wash 3min；3) 96 DEG C of 3g/L soaping agents D-301 soaps
5min；4) 60 DEG C of warm water wash 1min；5) room temperature rinses 1min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 15.8, degree of fixation
It is 82.2%.
Embodiment 14
Treatment fluid is organized in cotton and is knitted by the method for the cation-modified reactive dyeing of single bath process using the mode padded
On object, guarantee fabric liquid carrying rate is 100wt%, then carries out cold pad--batch after the fabric drying that will pad that treated, finally carries out soap
It washes to obtain reactive pad dyeing fabric, wherein treatment fluid includes the chloro- 2- Qiang oxypropyl trimethyls Lvization An ﹑ 30g/L of 100g/L 3-
The deionized water of pyrimidine active Ran Liao ﹑ 60g/L sodium hydroxides, 100g/L urea and surplus, wherein cold pad--batch refer to 25 DEG C and bank up
16h soaped including following five stages：1) room temperature rinses 3min；2) 60 DEG C of warm water wash 3min；3) 3g/L soaping agents D-301 96
DEG C soap 5min；4) 60 DEG C of warm water wash 1min；5) room temperature rinses 3min.
Final obtained reactive pad dyeing fabric DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 21.9, degree of fixation
It is 90.1%.
Embodiment 15
The method of the cation-modified reactive dyeing of single bath process, using the mode of dip dyeing, viscose fiber fabric is certain
A period of time is disseminated in the treatment fluid of temperature, is finally soaped to obtain reactive pad dyeing fabric, wherein treatment fluid includes
The chloro- 2- Qiang oxypropyl trimethyls Lvization An ﹑ 30g/L pyrimidine actives Ran Liao ﹑ 60g/L sodium hydroxides of 3- of 120g/L, 30g/L urea and
The deionized water of surplus is soaped wherein dip dyeing temperature is 90 DEG C, time 90min including following five stages：1) room temperature is rinsed
1min；2) 40 DEG C of warm water wash 3min；3) 97 DEG C of 3min that soap of 3g/L soaping agents D-301；4) 60 DEG C of warm water wash 3min；5) room temperature
Rinse 10min.
Final obtained Fabrics Dyed with Reactive Dyes DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 22.1, degree of fixation
It is 92.2%.
Embodiment 16
The method of the cation-modified reactive dyeing of single bath process, using the mode of dip dyeing, cotton fabric is in certain temperature
A period of time is disseminated in treatment fluid, is finally soaped to obtain reactive dyestuffs in exhaustion fabric, wherein treatment fluid includes 30g/L's
The deionized water of Lvization Dan Jian ﹑ 10g/L pyrimidine active Ran Liao ﹑ 10g/L sodium carbonate, 60g/L urea and surplus, wherein disseminating temperature
It is 60 DEG C, time 30min, soaps including following five stages：1) room temperature rinses 1min；2) 40 DEG C of warm water wash 5min；3)3g/
97 DEG C of 5min that soap of L soaping agents D-301；4) 60 DEG C of warm water wash 5min；5) room temperature rinses 10min.
Final obtained Fabrics Dyed with Reactive Dyes DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 11.1, degree of fixation
It is 81.2%.
Embodiment 17
The method of the cation-modified reactive dyeing of single bath process, using the mode of dip dyeing, cotton fabric is in certain temperature
A period of time is disseminated in treatment fluid, is finally soaped to obtain reactive dyestuffs in exhaustion fabric, wherein treatment fluid includes 90g/L's
The chloro- 2- Qiang oxypropyl trimethyls Lvization An ﹑ 20g/L phosphonic acids type Huo Ran Liao ﹑ 30g/L sodium hydroxides of 3-, 90g/L urea and surplus
Deionized water is soaped wherein dip dyeing temperature is 75 DEG C, time 60min including following five stages：1) room temperature rinses 3min；
2) 40 DEG C of warm water wash 3min；3) 97 DEG C of 5min that soap of 3g/L soaping agents D-301；4) 60 DEG C of warm water wash 5min；5) room temperature is rinsed
15min。
Final obtained Fabrics Dyed with Reactive Dyes DataColor testers tested K/(K/S values represent fabric table to S values
See tinctorial yield), then its degree of fixation is surveyed, the K/S values for measuring the ink-jet printed fabric of final reactive dye obtained are 17.9, degree of fixation
It is 87.7%.
Claims (9)
1. the method for sorting of the cation-modified reactive dyeing of single bath process, it is characterized in that：It will be contained by pad dyeing or exhaust process
The treatment fluid of cation modifier and reactive dye is soaped to obtain reactive dye dye after being organized on cellulose base fiber fabric
Yarn dyed fabric, wherein when using knot dyeing technology, cellulose base fiber fabric carries out decatize before being soaped, bakes or cold pad--batch；
It containing reactive group and positive charge group and number-average molecular weight is 100- that the cation modifier, which is in molecular structure,
30000 molecule, reactive group are one or more, the positive charge group in epoxy group, s-triazine, pyridine and alkene
Including one or more in quaternary ammonium salt and ammonium chloride structure.
2. method for sorting according to claim 1, which is characterized in that the treatment fluid changes including 10~150g/L cations
The deionized water of Xing Ji ﹑ 5~40g/L Huo Ran Liao 10~70g/L of ﹑ alkaline agents, 30~150g/L urea and surplus.
3. method for sorting according to claim 1 or 2, which is characterized in that the cation modifier is specially 2,3- rings
The three chloro- chloro- 2- of 2- hydroxyls oxypropyl trimethyl chlorine ammonium ﹑ 3- of ethylmercury chloride ammonium ﹑ 3- of oxygen propyl group front three ammonium chloride ﹑ 2,3- glycidyl
Mono- chloro-s-triazine type quaternary ammonium salt compound ﹑ azetidiniums compounds of hydroxypropyl triethylammonium chloride ﹑, choline chloride and
The mixture of one or more of polyepichlorohydrin amine compound.
4. method for sorting according to claim 3, which is characterized in that the reactive dye are Jun tri- Qin ﹑ pyrimidines, vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan)
Or phosphonic acids type reactive dye.
5. method for sorting according to claim 2, which is characterized in that the alkaline agent is Qing Yangization Na ﹑ sodium bicarbonates and carbon
The mixture of one or more of sour sodium.
6. method for sorting according to claim 1, which is characterized in that the process of knot dyeing technology is：Use the mode padded
Pad dyeing processing is carried out to cellulose base fiber fabric, guarantee fabric liquid carrying rate is 60~100wt%；The process of exhaust process is：Make
Cellulose base fiber fabric is handled with the mode of dip dyeing, 30~90min is disseminated at 60~90 DEG C.
7. method for sorting according to claim 6, which is characterized in that the cellulose base fiber fabric includes cotton, fiber crops, viscose
Fiber, tencel and modal fabric.
8. method for sorting according to claim 6, which is characterized in that the decatize, bake or cold pad--batch directly carry out or
It is carried out after person will pad that treated fabric drying.
9. method for sorting according to claim 8, which is characterized in that the decatize refers to 100~180 DEG C of saturated vapor vapour
Steam 1~15min；The baking refers to 100~180 DEG C and bakes 1~15min；The cold pad--batch refer to bank up 6 at 15~35 DEG C~
18h。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109577032A (en) * | 2018-10-25 | 2019-04-05 | 安徽亚源印染有限公司 | A kind of military aramid fiber blended yarn weaved fabric of anti-infrared and its salt-free dyeing technique |
| CN110952348A (en) * | 2019-12-05 | 2020-04-03 | 鲁丰织染有限公司 | Processing method for improving dyeing depth of cation modified piece-dyed fabric |
| CN112647323A (en) * | 2020-11-24 | 2021-04-13 | 长胜纺织科技发展(上海)有限公司 | Dyeing promoter, preparation thereof and dyeing method |
| CN112796123A (en) * | 2020-12-29 | 2021-05-14 | 石狮市港溢染整织造有限公司 | Dyeing method of novel nostalgic style fabric and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1265715A (en) * | 1997-06-02 | 2000-09-06 | Dcv公司 | Method for treating fibrous cellulosic materials |
| CN101864676A (en) * | 2010-06-08 | 2010-10-20 | 上海工程技术大学 | Cation modified dyeing method of ceiba fiber textiles |
| CN102002868A (en) * | 2010-11-30 | 2011-04-06 | 常熟市宝沣特种纤维有限公司 | Normal-pressure dyeing method of meta-aramid yarn |
| CN103333332A (en) * | 2013-07-01 | 2013-10-02 | 达利(中国)有限公司 | Preparation method and application off dyeing promoter |
| CN104233866A (en) * | 2014-09-17 | 2014-12-24 | 华南理工大学 | Method for cation modification and salt-free dyeing of cellulose fiber fabric |
| CN106638036A (en) * | 2016-12-19 | 2017-05-10 | 华南理工大学 | Method for cation modification and salt-free dyeing of cellulose fabric through one bath |
| CN106638035A (en) * | 2016-12-15 | 2017-05-10 | 上海市纺织科学研究院 | One-step-method differential dyeing process for cellulosic fiber textile |
-
2018
- 2018-05-10 CN CN201810441540.1A patent/CN108486930B/en active Active
- 2018-11-02 WO PCT/CN2018/113623 patent/WO2019214185A1/en active Application Filing
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1265715A (en) * | 1997-06-02 | 2000-09-06 | Dcv公司 | Method for treating fibrous cellulosic materials |
| CN101864676A (en) * | 2010-06-08 | 2010-10-20 | 上海工程技术大学 | Cation modified dyeing method of ceiba fiber textiles |
| CN102002868A (en) * | 2010-11-30 | 2011-04-06 | 常熟市宝沣特种纤维有限公司 | Normal-pressure dyeing method of meta-aramid yarn |
| CN103333332A (en) * | 2013-07-01 | 2013-10-02 | 达利(中国)有限公司 | Preparation method and application off dyeing promoter |
| CN104233866A (en) * | 2014-09-17 | 2014-12-24 | 华南理工大学 | Method for cation modification and salt-free dyeing of cellulose fiber fabric |
| CN104233866B (en) * | 2014-09-17 | 2016-07-06 | 华南理工大学 | A kind of cellulose base fiber fabric is cation-modified and the method for salt-free dyeing |
| CN106638035A (en) * | 2016-12-15 | 2017-05-10 | 上海市纺织科学研究院 | One-step-method differential dyeing process for cellulosic fiber textile |
| CN106638036A (en) * | 2016-12-19 | 2017-05-10 | 华南理工大学 | Method for cation modification and salt-free dyeing of cellulose fabric through one bath |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109577032A (en) * | 2018-10-25 | 2019-04-05 | 安徽亚源印染有限公司 | A kind of military aramid fiber blended yarn weaved fabric of anti-infrared and its salt-free dyeing technique |
| CN109577032B (en) * | 2018-10-25 | 2023-07-14 | 安徽亚源印染有限公司 | Infrared-resistant military aramid fiber blended fabric and salt-free dyeing process thereof |
| CN110952348A (en) * | 2019-12-05 | 2020-04-03 | 鲁丰织染有限公司 | Processing method for improving dyeing depth of cation modified piece-dyed fabric |
| CN112647323A (en) * | 2020-11-24 | 2021-04-13 | 长胜纺织科技发展(上海)有限公司 | Dyeing promoter, preparation thereof and dyeing method |
| WO2022110623A1 (en) * | 2020-11-24 | 2022-06-02 | 长胜纺织科技发展(上海)有限公司 | Dyeing accelerator, preparation thereof, and dyeing method |
| CN112796123A (en) * | 2020-12-29 | 2021-05-14 | 石狮市港溢染整织造有限公司 | Dyeing method of novel nostalgic style fabric and application thereof |
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