CN108486580A - A kind of drawing oil cleaning agent and its preparation method - Google Patents
A kind of drawing oil cleaning agent and its preparation method Download PDFInfo
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- CN108486580A CN108486580A CN201810670072.5A CN201810670072A CN108486580A CN 108486580 A CN108486580 A CN 108486580A CN 201810670072 A CN201810670072 A CN 201810670072A CN 108486580 A CN108486580 A CN 108486580A
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- cleaning agent
- drawing oil
- oil cleaning
- polyoxyethylene ether
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 24
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 22
- 230000007797 corrosion Effects 0.000 claims abstract description 20
- 238000005260 corrosion Methods 0.000 claims abstract description 20
- 239000000872 buffer Substances 0.000 claims abstract description 13
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000013556 antirust agent Substances 0.000 claims abstract description 9
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 9
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 9
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 7
- 239000012964 benzotriazole Substances 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 6
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 150000001721 carbon Chemical group 0.000 claims description 5
- 239000006210 lotion Substances 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 4
- 238000005070 sampling Methods 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 238000012797 qualification Methods 0.000 claims description 3
- 229940057402 undecyl alcohol Drugs 0.000 claims description 3
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 230000003139 buffering effect Effects 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 5
- 230000002378 acidificating effect Effects 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract description 2
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 22
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- NUUDMTGMAZJCBY-UHFFFAOYSA-N 1-decyl-3-methyl-2h-imidazole Chemical compound CCCCCCCCCCN1CN(C)C=C1 NUUDMTGMAZJCBY-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 238000004080 punching Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- DVNFMHWKXQEEAH-UHFFFAOYSA-N 1-dodecyl-3-methyl-2h-imidazole Chemical compound CCCCCCCCCCCCN1CN(C)C=C1 DVNFMHWKXQEEAH-UHFFFAOYSA-N 0.000 description 1
- VDDUQRTVFVQZQJ-UHFFFAOYSA-N 1-methyl-3-octadecyl-2h-imidazole Chemical compound CCCCCCCCCCCCCCCCCCN1CN(C)C=C1 VDDUQRTVFVQZQJ-UHFFFAOYSA-N 0.000 description 1
- MXYOPVWZZKEAGX-UHFFFAOYSA-N 1-phosphonoethylphosphonic acid Chemical compound OP(=O)(O)C(C)P(O)(O)=O MXYOPVWZZKEAGX-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of drawing oil cleaning agent and its preparation methods, it includes the component of following parts by weight：8 ~ 15 parts of isomery fatty alcohol polyoxyethylene ether；10 ~ 20 parts of 1 alkyl, 3 methylimidazole haloid；0.5 ~ 0.8 part of buffer；5 ~ 10 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid；5 ~ 10 parts of oxalic acid；3 ~ 5 parts of corrosion inhibiter；0.5 ~ 1 part of antirust agent；30 ~ 50 parts of water.It can effectively realize in this way to the buffering of acidic components and avoid corrosion of its highly acid to product；And can effectively realize emulsion dispersion to ingredients such as isomery fatty alcohol polyoxyethylene ether, improve cleaning performance.
Description
Technical field
Industrial cleaning agent field of the present invention, and in particular to a kind of drawing oil cleaning agent and its preparation method.
Background technology
Metal stretching oil selects high-quality mineral base oil, and it is host agent tune to compound high-performance sulfurized lard and sulfide aliphatic acid ester
With into, be dedicated to stainless steel punching stretch processing, have fabulous wear resistence, extreme pressure property, will not cause workpiece plucking, draw
Wound improves workpiece finish, effectively extends Life of Punch Die；Easy cleaning；Free from extraneous odour does not stimulate skin；Suitable for stainless steel, alloy
The techniques such as stretching, deep drawn, bulging stretching, multiple tracks stretching, punching press, the punching of the metal products such as steel, titanium alloy are processed, and profit is played
Sliding, cooling effect.Metal stretching oil usually has high viscosity to ensure the oil film thickness of continuous effective, and the part of mold is avoided to scrape
Wound or sintering；And strong adhesive force, effectively lubricate workpiece and mold；It can be to the high temperature generated when being rubbed by metal.It is existing
Metal stretching oil cleaning agent is typically strong acid or highly basic, although will produce one to metal surface when cleaning action obviously cleans
Fixed corrosion and metallicity may be caused there are risks.
Invention content
A kind of drawing oil cleaning agent is provided the invention aims to overcome the deficiencies in the prior art.
In order to achieve the above objectives, the technical solution adopted by the present invention is：A kind of drawing oil cleaning agent, it includes following weight
The component of number：
Optimally, the isomery fatty alcohol polyoxyethylene ether is poly- selected from heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol
The mixture of one or more compositions in ethylene oxide ether and isomerous tridecanol polyoxyethylene ether.
Optimally, the carbon atom number of alkyl is 10~18 in the 1- alkyl -3- methylimidazole haloids.
Further, the carbon atom number of the alkyl is 10~12, and halogen is chlorine element.
Optimally, the buffer is NaH2PO4And Na2HPO4In mass ratio 1:The mixture of 1 composition.
Optimally, the corrosion inhibiter is aqueous silica alkanone type aluminium corrosion inhibiter.
Optimally, the antirust agent is benzotriazole.
Another object of the present invention is to provide a kind of preparation method of above-mentioned drawing oil cleaning agent, it includes following step
Suddenly：
(a) water of formula ratio, buffer are added in reaction kettle, start blender；
(b) continue to sequentially add into reaction kettle the isomery fatty alcohol polyoxyethylene ether of formula ratio, 1-hydroxy ethylidene-1,1-diphosphonic acid,
Oxalic acid, 1- alkyl -3- methylimidazoles haloid, corrosion inhibiter and antirust agent；Lower one kind is added after the raw material stirring and dissolving of addition
Raw material is further continued for stirring to forming uniform lotion after whole raw materials are added；
(c) blowing is packed after sampling analysis qualification.
Since above-mentioned technical proposal is used, the present invention has following advantages compared with prior art：Drawing oil of the present invention is clear
Lotion is coordinated by using 1- alkyl -3- methylimidazoles haloid, the buffer of certain content with other components, in this way
It can effectively realize to the buffering of acidic components and avoid corrosion of its highly acid to product；And it can effectively realize to isomery
The emulsion dispersion of the ingredients such as fatty alcohol polyoxyethylene ether improves cleaning performance.
Specific implementation mode
Drawing oil cleaning agent of the present invention, it includes the component of following parts by weight：Isomery fatty alcohol polyoxyethylene ether 8~15
Part, 10~20 parts of 1- alkyl -3- methylimidazoles haloid, 0.5~0.8 part of buffer, 5~10 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid, grass
5~10 parts of acid, 3~5 parts of corrosion inhibiter, 0.5~1 part of antirust agent, 30~50 parts of water.By using the 1- alkyl -3- of certain content
Methylimidazole haloid, buffer and other components are coordinated, and can effectively be realized to the buffering of acidic components and be kept away in this way
Exempt from corrosion of its highly acid to product；And it can effectively realize the emulsification to ingredients such as isomery fatty alcohol polyoxyethylene ether point
It dissipates, improves cleaning performance.
Above-mentioned isomery fatty alcohol polyoxyethylene ether is routine, can be selected from heterogeneous ten alcohol polyoxyethylene ether, isomery
The mixture of one or more compositions in undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether, and isomerous tridecanol
The best results of polyoxyethylene ether.The carbon atom number of alkyl is usually 10~18 in the 1- alkyl -3- methylimidazole haloids；
Preferably 10~12, halogen is usually chlorine element.The buffer is NaH2PO4And Na2HPO4It is preferred that in mass ratio 1:1 composition
Mixture.The corrosion inhibiter is aqueous silica alkanone type aluminium corrosion inhibiter.The antirust agent is benzotriazole.Above-mentioned drawing oil
The preparation method of cleaning agent, it includes the following steps：(a) water of formula ratio, buffer are added in reaction kettle, start stirring
Device；(b) continue to sequentially add into reaction kettle the isomery fatty alcohol polyoxyethylene ether of formula ratio, 1-hydroxy ethylidene-1,1-diphosphonic acid, oxalic acid,
1- alkyl -3- methylimidazoles haloid, corrosion inhibiter and antirust agent；A kind of lower raw material is added after the raw material stirring and dissolving of addition,
Stirring is further continued for after whole raw materials are added to forming uniform lotion；(c) blowing is packed after sampling analysis qualification.
The preferred embodiment of the invention will be described in detail below：
Embodiment 1
The present embodiment provides a kind of drawing oil cleaning agents, it includes the component of following parts by weight：8kg isomerous tridecanols are poly-
Ethylene oxide ether, 10kg 1- decyl -3- methylimidazole villaumites, 0.5kg buffers (NaH2PO4And Na2HPO4Mass ratio be 1:
1), aqueous silica alkanone type aluminium corrosion inhibiter L102, the 0.5kg benzotriazole of 10kg 1-hydroxy ethylidene-1,1-diphosphonic acids, 10kg oxalic acid, 3kg；
30kg water；
The preparation method of above-mentioned drawing oil cleaning agent, it includes the following steps：(a) water of formula ratio, buffer are added
Into reaction kettle, start blender；(b) continue to sequentially add into reaction kettle formula ratio isomerous tridecanol polyoxyethylene ether,
1-hydroxy ethylidene-1,1-diphosphonic acid, oxalic acid, 1- decyl -3- methylimidazole villaumites, corrosion inhibiter and benzotriazole；The raw material stirring of addition is molten
A kind of lower raw material is added after solution, and stirring 2h is further continued for after whole raw materials are added to forming uniform lotion；(c) sampling point
Blowing is packed after analysis is qualified.
Embodiment 2
The present embodiment provides a kind of drawing oil cleaning agent, it with it is almost the same in embodiment 1, unlike including following
The component of parts by weight：15kg isomerous tridecanol polyoxyethylene ethers, 20kg 1- decyl -3- methylimidazole villaumites, 0.8kg bufferings
Agent (NaH2PO4And Na2HPO4Mass ratio be 1:1), the aqueous silica alkanone type of 5kg 1-hydroxy ethylidene-1,1-diphosphonic acids, 5kg oxalic acid, 5kg
Aluminium corrosion inhibiter L102,1kg benzotriazole；50kg water.
Embodiment 3
The present embodiment provides a kind of drawing oil cleaning agent, it with it is almost the same in embodiment 1, unlike including following
The component of parts by weight：10kg isomerous tridecanol polyoxyethylene ethers, 15kg 1- decyl -3- methylimidazole villaumites, 0.6kg bufferings
Agent (NaH2PO4And Na2HPO4Mass ratio be 1:1), the aqueous silica alkanone type of 8kg 1-hydroxy ethylidene-1,1-diphosphonic acids, 6kg oxalic acid, 5kg
Aluminium corrosion inhibiter L102,0.8kg benzotriazole；45kg water.
Embodiment 4
The present embodiment provides a kind of drawing oil cleaning agent, it with it is almost the same in embodiment 3, unlike：It uses
15kg 1- dodecyl -3- methylimidazole villaumites.
Embodiment 5
The present embodiment provides a kind of drawing oil cleaning agent, it with it is almost the same in embodiment 3, unlike：It uses
15kg 1- octadecyl -3- methylimidazole villaumites.
Comparative example 1
This example provides a kind of drawing oil cleaning agent, it with it is almost the same in embodiment 3, the difference is that：Buffering is not added
Agent.
Comparative example 2
This example provides a kind of drawing oil cleaning agent, it with it is almost the same in embodiment 3, the difference is that：The 1- last of the ten Heavenly stems is not added
Base -3- methylimidazole villaumites.
Comparative example 3
This example provides a kind of drawing oil cleaning agent, it with it is almost the same in embodiment 3, the difference is that：Hydroxyl is not added
Ethylidene diphosphonic acid and oxalic acid.
Be coated with the stainless steel plate of drawing oil SC8210 respectively with embodiment 1-5, comparative example 1-3 stretch oily cleaning agent into
Row processing, parameter comparison are as shown in table 1.
The performance test table of oily cleaning agent is stretched in 1 embodiment 1-5 of table, comparative example 1-3
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention, all according to the present invention
Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of drawing oil cleaning agent, which is characterized in that it includes the component of following parts by weight：
8 ~ 15 parts of isomery fatty alcohol polyoxyethylene ether；
10 ~ 20 parts of 1- alkyl -3- methylimidazoles haloid；
0.5 ~ 0.8 part of buffer；
5 ~ 10 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid；
5 ~ 10 parts of oxalic acid；
3 ~ 5 parts of corrosion inhibiter；
0.5 ~ 1 part of antirust agent；
30 ~ 50 parts of water.
2. drawing oil cleaning agent according to claim 1, it is characterised in that：The isomery fatty alcohol polyoxyethylene ether is choosing
From one or more in heterogeneous ten alcohol polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether and isomerous tridecanol polyoxyethylene ether
The mixture of composition.
3. drawing oil cleaning agent according to claim 1, it is characterised in that：1- alkyl -3- methylimidazole the haloids
The carbon atom number of middle alkyl is 10 ~ 18.
4. drawing oil cleaning agent according to claim 3, it is characterised in that：The carbon atom number of the alkyl is 10 ~ 12, halogen
Element is chlorine element.
5. drawing oil cleaning agent according to claim 1, it is characterised in that：The buffer is NaH2PO4And Na2HPO4
In mass ratio 1:The mixture of 1 composition.
6. drawing oil cleaning agent according to claim 1, it is characterised in that：The corrosion inhibiter is aqueous silica alkanone type aluminium
Corrosion inhibiter.
7. drawing oil cleaning agent according to claim 1, it is characterised in that：The antirust agent is benzotriazole.
8. the preparation method of any drawing oil cleaning agent in claim 1 to 7, which is characterized in that it includes the following steps：
（a）The water of formula ratio, buffer are added in reaction kettle, blender is started；
（b）Continue to sequentially add the isomery fatty alcohol polyoxyethylene ether of formula ratio, 1-hydroxy ethylidene-1,1-diphosphonic acid, grass into reaction kettle
Acid, 1- alkyl -3- methylimidazoles haloid, corrosion inhibiter and antirust agent；A kind of lower original is added after the raw material stirring and dissolving of addition
Material is further continued for stirring to forming uniform lotion after whole raw materials are added；
（c）Blowing is packed after sampling analysis qualification.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810670072.5A CN108486580A (en) | 2018-06-26 | 2018-06-26 | A kind of drawing oil cleaning agent and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810670072.5A CN108486580A (en) | 2018-06-26 | 2018-06-26 | A kind of drawing oil cleaning agent and its preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108486580A true CN108486580A (en) | 2018-09-04 |
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| CN201810670072.5A Pending CN108486580A (en) | 2018-06-26 | 2018-06-26 | A kind of drawing oil cleaning agent and its preparation method |
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| Country | Link |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102392263A (en) * | 2011-11-18 | 2012-03-28 | 东莞市东辉贸易有限公司 | Metal cleaning agent |
| CN102995032A (en) * | 2012-10-17 | 2013-03-27 | 张志明 | Preparation method of steel part cleaning agent |
| CN104047012A (en) * | 2014-06-23 | 2014-09-17 | 梧州恒声电子科技有限公司 | Metal oil removal agent and preparation method thereof |
-
2018
- 2018-06-26 CN CN201810670072.5A patent/CN108486580A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102392263A (en) * | 2011-11-18 | 2012-03-28 | 东莞市东辉贸易有限公司 | Metal cleaning agent |
| CN102995032A (en) * | 2012-10-17 | 2013-03-27 | 张志明 | Preparation method of steel part cleaning agent |
| CN104047012A (en) * | 2014-06-23 | 2014-09-17 | 梧州恒声电子科技有限公司 | Metal oil removal agent and preparation method thereof |
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