CN108486375A - A kind of method of waste and old anode plate hangers resource recycling - Google Patents
A kind of method of waste and old anode plate hangers resource recycling Download PDFInfo
- Publication number
- CN108486375A CN108486375A CN201810157169.6A CN201810157169A CN108486375A CN 108486375 A CN108486375 A CN 108486375A CN 201810157169 A CN201810157169 A CN 201810157169A CN 108486375 A CN108486375 A CN 108486375A
- Authority
- CN
- China
- Prior art keywords
- anode plate
- waste
- hangers
- copper bar
- plate hangers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
- C22B7/004—Dry processes separating two or more metals by melting out (liquation), i.e. heating above the temperature of the lower melting metal component(s); by fractional crystallisation (controlled freezing)
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/02—Obtaining lead by dry processes
- C22B13/025—Recovery from waste materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0056—Scrap treating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
The invention discloses a kind of method of the waste and old anode plate hangers resource recycling for electrolytic manganese, the technical issues of to solve the waste and old anode plate hangers wasting of resources of electrolytic manganese in the prior art.Include the following steps：1) it heats；2) it detaches；3) metal liquid recycles；4) copper bar recycles；A) shaping；B) pickling；C) tin is scalded.Compared with prior art, method provided by the invention, has saved resource, reduces environmental pollution.
Description
Technical field
The present invention relates to metals resources utilization technology field more particularly to a kind of waste and old anode plates for electrolytic manganese
The method of hangers resource recycling.
Background technology
Aluminothermic process, electrothermal way and electrolysis may be used in the production of manganese metal, wherein electrolysis, since poor manganese can be used
Mine obtains the application of high-purity as raw material and is used widely.Anode plate used in electrolytic manganese, by anode hangers, transition
Row and mainboard sequence are formed by welding；Wherein, anode plate hangers is made by pouring into a mould metal outside copper bar, metal be lead, silver, zinc and
The alloy of tin.Anode plate hangers passes through the use of certain time, on the one hand deforms upon, and impurity, nothing are adhered in another aspect surface
Method continues to come into operation, therefore becomes waste and old material.If not recycling, on the other hand the one side wasting of resources easily causes
Environmental pollution.
Invention content
The technical issues of to solve to be used for the waste and old anode plate hangers wasting of resources of electrolytic manganese in the prior art, the present invention carries
For a kind of method of waste and old anode plate hangers resource recycling, to economize on resources and improve resource utilization, avoid environment dirty
Dye.
The method of waste and old anode plate hangers resource recycling provided by the invention, includes the following steps：
1) it heats：Waste and old anode plate hangers is heated, 400~500 DEG C of heating temperature, the retention time 3~
10min；Under this heating temperature and heating time, metal, i.e. lead, silver, zinc and tin alloy can melt, and fusing point is higher
Copper still maintain solid-state, while the density of copper bar is less than metal, can swim on the metal liquid of fusing；According to heating
The retention time of the difference of method, heating can adjust.
2) it detaches：Copper bar and the metal liquid of melting are detached；The metal liquid after melting is swum in due to copper bar, it can be with
Copper bar is taken out from metal liquid.
3) metal liquid recycles：After metal liquid is carried out slag hitting filtering using strainer, the material as anode plate manufacture
It re-uses；Anode plate hangers will produce lead oxide and absorption manganese slag in use, and density is less than metal liquid, swims in
Above metal liquid, dregs are subjected to slag hitting filtering using strainer, leave the system that pure metal liquid is reused for anode plate
Producing material material.
4) copper bar recycles：
A) shaping：Copper bar is shaped as shape workable for anode plate hangers；Anode plate hangers is electrolysed in pyroprocess, meeting
It generates flexural deformation and copper bar is shaped as by shape workable for anode plate hangers by shaping.
B) pickling：Copper bar after shaping is immersed in pickle and carries out pickling；For copper bar in high-temperature heating, surface can be by oxygen
Change, its electric conductivity is reduced, by pickling, by the oxide removal on copper bar surface.
C) tin is scalded：Copper bar after pickling is put into tin liquor and scald tin processing, then anode plate hangers is used as to manufacture material
Material stores for future use.Copper bar after pickling is immediately placed in tin liquor carry out scald tin processing, make copper bar surface adhere to tin, to copper bar into
Row protection, keeps copper bar surface not oxidized, improves the electric conductivity of copper bar.Copper bar after boiling hot tin manufactures standby as anode plate hangers
It is stored with material.
Preferably, heated described in step 1), including：Carbon heating and electromagnetic heating method.Carbon heating, i.e., by waste and old sun
Pole plate hangers is placed in the pot of carbon heating, and preset certain metal liquid in pot adds the waste and old anode plate hangers in pot
Heat.Preset certain metal liquid is conducive to the fusing of metal, improves smelting efficiency.
Preferably, the electromagnetic heating method, including：It is heated using electromagnetic cooker or is heated using electromagnetic coil；Utilize electromagnetism
When pot heating, hangers is placed in pot body；When being heated using electromagnetic coil, hangers is placed in electromagnetic coil.It is heated using electromagnetic cooker
When, preset certain metal liquid in electromagnetic cooker improves smelting efficiency.When being heated using electromagnetic coil, wrapped up on waste and old hangers
The position of metal is placed in electromagnetic coil, and the position for not wrapping up metal is placed in outside electromagnetic coil, and pot is placed under electromagnetic coil
Body, pot body have heat insulation function, are used for the collection of molten Pb liquid, when being powered to electromagnetic coil, the waste and old hangers in coil
It is heated, the metal liquid of fusing is fallen into pot body.The aperture of electromagnetic coil is set as 20cm or more, can be simultaneously to multiple waste and old
Hangers is heated.When being heated using electromagnetic coil, heating time is shorter, and compared with carbon heating, the efficiency of heating surface is high, and
It economizes on resources, reduces environmental pollution.
Preferably, the aperture of strainer described in step 3) is 1~5mm.
Preferably, the pickle that uses of step 4) pickling for：The hydrochloric acid or sulfuric acid of concentration 5%~20% and hydrogen peroxide
Mixed liquor；Wherein, a concentration of the 5%~20% of sulfuric acid, a concentration of with 27.5%, the mixing ratio of sulfuric acid and hydrogen peroxide of hydrogen peroxide
Example is 9：1；Pickling temperature is 40~60 DEG C, and the immersion time is 1~3min.
Advantageous effect of the present invention includes：
The method of waste and old anode plate hangers resource recycling provided by the invention, compared with prior art, to waste and old sun
The metal and copper bar of pole plate hangers are recycled, and have been saved resource, have been reduced environmental pollution.
Specific implementation mode
With reference to specific embodiment, the method for waste and old anode plate hangers resource recycling provided by the invention is carried out
It further illustrates.
Embodiment 1
The method of waste and old anode plate hangers resource recycling provided in this embodiment, includes the following steps：
1) it heats：Waste and old anode plate hangers is heated, 400~500 DEG C of heating temperature using carbon heating, is protected
Hold time 10min；
2) it detaches：Copper bar and the metal liquid of melting are detached；
3) metal liquid recycles：After metal liquid is carried out slag hitting filtering using strainer, the material as anode plate manufacture
It re-uses；Aperture of filter screen is 1~5mm；
4) copper bar recycles：
A) shaping：Copper bar is shaped as shape workable for anode plate hangers；
B) pickling：Copper bar after shaping is immersed in pickle and carries out pickling；Use pickle for concentration 5%~20%
Hydrochloric acid；Pickling temperature is 40~60 DEG C, and the immersion time is 1~3min；
C) tin is scalded：Copper bar after pickling is put into tin liquor and scald tin processing, then anode plate hangers is used as to manufacture material
Material stores for future use.
Embodiment 2
The method of waste and old anode plate hangers resource recycling provided in this embodiment, includes the following steps：
1) it heats：Waste and old anode plate hangers is heated, 400~500 DEG C of heating temperature using electromagnetic cooker, is kept
Time 5min；
2) it detaches：Copper bar and the metal liquid of melting are detached；
3) metal liquid recycles：After metal liquid is carried out slag hitting filtering using strainer, the material as anode plate manufacture
It re-uses；Aperture of filter screen is 1~5mm；
4) copper bar recycles：
A) shaping：Copper bar is shaped as shape workable for anode plate hangers；
B) pickling：Copper bar after shaping is immersed in pickle and carries out pickling；Use pickle for concentration 5%~20%
Hydrochloric acid；Pickling temperature is 40~60 DEG C, and the immersion time is 1~3min；
C) tin is scalded：Copper bar after pickling is put into tin liquor and scald tin processing, then anode plate hangers is used as to manufacture material
Material stores for future use.
Embodiment 3
The method of waste and old anode plate hangers resource recycling provided in this embodiment, includes the following steps：
1) it heats：Waste and old anode plate hangers is heated, 400~500 DEG C of heating temperature using electromagnetic coil, is protected
Hold time 3min；
2) it detaches：Copper bar and the metal liquid of melting are detached；
3) metal liquid recycles：After metal liquid is carried out slag hitting filtering using strainer, the material as anode plate manufacture
It re-uses；Aperture of filter screen is 1~5mm；
4) copper bar recycles：
A) shaping：Copper bar is shaped as shape workable for anode plate hangers；
B) pickling：Copper bar after shaping is immersed in pickle and carries out pickling；Use pickle for sulfuric acid and hydrogen peroxide
Mixed liquor；Wherein, a concentration of the 5%~20% of sulfuric acid, a concentration of with 27.5%, the mixing ratio of sulfuric acid and hydrogen peroxide of hydrogen peroxide
Example is 9：1；Pickling temperature is 40~60 DEG C, and the immersion time is 1~3min；
C) tin is scalded：Copper bar after pickling is put into tin liquor and scald tin processing, then anode plate hangers is used as to manufacture material
Material stores for future use.
In conclusion scheme provided in an embodiment of the present invention compared with prior art closes the lead of waste and old anode plate hangers
Gold and copper bar are recycled, and have been saved resource, have been reduced environmental pollution.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art
God and range.In this way, if these modifications and changes of the present invention belongs to the range of the claims in the present invention and its equivalent technologies
Within, then the present invention is also intended to include these modifications and variations.
Claims (5)
1. a kind of method of waste and old anode plate hangers resource recycling, which is characterized in that include the following steps：
1) it heats：Waste and old anode plate hangers is heated, 400~500 DEG C of heating temperature, 3~10min of retention time；
2) it detaches：Copper bar and the metal liquid of melting are detached；
3) metal liquid recycles：After metal liquid is carried out slag hitting filtering using strainer, the material as anode plate manufacture is again
It utilizes；
4) copper bar recycles：
A) shaping：Copper bar is shaped as shape workable for anode plate hangers；
B) pickling：Copper bar after shaping is immersed in pickle and carries out pickling；
C) tin is scalded：Copper bar after pickling is put into tin liquor and scald tin processing, then anode plate hangers manufacture material is used as to store up
It deposits spare.
2. the method for waste and old anode plate hangers resource recycling as described in claim 1, which is characterized in that institute in step 1)
Heating is stated, including：Carbon heating and electromagnetic heating method.
3. the method for waste and old anode plate hangers resource recycling as claimed in claim 2, which is characterized in that the electromagnetism adds
Hot method, including：It is heated using electromagnetic cooker or is heated using electromagnetic coil；When being heated using electromagnetic cooker, hangers is placed in pot body；Profit
When being heated with electromagnetic coil, hangers is placed in electromagnetic coil.
4. the method for waste and old anode plate hangers resource recycling as described in claim 1, which is characterized in that institute in step 3)
The aperture for stating strainer is 1~5mm.
5. the method for waste and old anode plate hangers resource recycling as described in claim 1, which is characterized in that step 4) pickling
The pickle used for：The hydrochloric acid or sulfuric acid of concentration 5%~20% and the mixed liquor of hydrogen peroxide；Wherein, sulfuric acid is a concentration of
5%~20%, a concentration of the 27.5% of hydrogen peroxide, the mixed proportion of sulfuric acid and hydrogen peroxide is 9：1；Pickling temperature is 40~60
DEG C, the immersion time is 1~3min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810157169.6A CN108486375A (en) | 2018-02-24 | 2018-02-24 | A kind of method of waste and old anode plate hangers resource recycling |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810157169.6A CN108486375A (en) | 2018-02-24 | 2018-02-24 | A kind of method of waste and old anode plate hangers resource recycling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108486375A true CN108486375A (en) | 2018-09-04 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810157169.6A Pending CN108486375A (en) | 2018-02-24 | 2018-02-24 | A kind of method of waste and old anode plate hangers resource recycling |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114790550A (en) * | 2022-05-07 | 2022-07-26 | 云南驰宏资源综合利用有限公司 | Method for manufacturing anode beam |
Citations (5)
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|---|---|---|---|---|
| CN1072218A (en) * | 1991-11-09 | 1993-05-19 | 洛阳铜加工厂 | The recovery of copper and copper alloy products lead-tin on face |
| CN101092668A (en) * | 2006-06-23 | 2007-12-26 | 宝山钢铁股份有限公司 | Method for producing zinc alloy from zinc dross |
| CN203096196U (en) * | 2012-12-20 | 2013-07-31 | 罗传海 | Copper-lead mixed anode plate for copper electrolysis |
| CN106011536A (en) * | 2016-06-30 | 2016-10-12 | 济源市万洋绿色能源有限公司 | Hanging lug recycling method |
| CN106381390A (en) * | 2016-09-14 | 2017-02-08 | 南昌大学 | Waste LED lighting bulb recycling method |
-
2018
- 2018-02-24 CN CN201810157169.6A patent/CN108486375A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1072218A (en) * | 1991-11-09 | 1993-05-19 | 洛阳铜加工厂 | The recovery of copper and copper alloy products lead-tin on face |
| CN101092668A (en) * | 2006-06-23 | 2007-12-26 | 宝山钢铁股份有限公司 | Method for producing zinc alloy from zinc dross |
| CN203096196U (en) * | 2012-12-20 | 2013-07-31 | 罗传海 | Copper-lead mixed anode plate for copper electrolysis |
| CN106011536A (en) * | 2016-06-30 | 2016-10-12 | 济源市万洋绿色能源有限公司 | Hanging lug recycling method |
| CN106381390A (en) * | 2016-09-14 | 2017-02-08 | 南昌大学 | Waste LED lighting bulb recycling method |
Non-Patent Citations (5)
| Title |
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| 中国有色金属工业总公司: "《中国有色金属工业企业管理全书》", 31 December 1988, 经济科学出版社 * |
| 孟凡智: "《机械加工先进工艺窍门图示例解实用手册 第4卷》", 30 June 2015, 吉林电子出版社有限责任公司 * |
| 张盖楚等: "《电动机选择、安装、使用、维护与故障排除700个怎么办》", 28 February 1998, 北京：冶金工业出版社 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114790550A (en) * | 2022-05-07 | 2022-07-26 | 云南驰宏资源综合利用有限公司 | Method for manufacturing anode beam |
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| PB01 | Publication | ||
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Application publication date: 20180904 |