CN108485573A - A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect - Google Patents
A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect Download PDFInfo
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- CN108485573A CN108485573A CN201810424582.4A CN201810424582A CN108485573A CN 108485573 A CN108485573 A CN 108485573A CN 201810424582 A CN201810424582 A CN 201810424582A CN 108485573 A CN108485573 A CN 108485573A
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- pyknosis
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Sealing Material Composition (AREA)
Abstract
The present invention relates to adhesive techniques fields, and in particular to a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect.The ingredient of glass cement includes：Epoxy resin, isophthalic unsaturated polyester resin, inorganic filler, convergence modifying agent, titanium dioxide, amine curing agent, toughener, cobalt iso-octoate, ultra-violet absorber and antifoaming agent.Wherein, convergence modifying agent is prepared by components such as polystyrene emulsion, ethylene glycol, nanometer aquamaine mountain flour, toluene di-isocyanate(TDI) and hydroxymethyl propionic acids；Inorganic filler includes talcum powder, silicon powder and andalusite powder；Curing accelerator is benzoyl peroxide, methyl ethyl ketone peroxide or isopropyl benzene hydroperoxide；Toughener is polypropylene glycol diglycidyl ether, and antifoaming agent is organic silicon defoamer.The property of the type glass cement is stable, antiageing effect is good and has outstanding anti-pyknosis effect, can keep prolonged waterproof sealing effect in use.
Description
Technical field
The present invention relates to adhesive techniques fields, and in particular to a kind of seal glass with anti-ageing chemoprevention pyknosis effect
Glue.
Background technology
Glass cement is a kind of common binder, and main component is sodium metasilicate, soluble easily in water, toughness, and south claims water glass
Glass, the north claim sodium silicate；It is that various glass are subjected to material that is be bonded and sealing with other base materials.In door glass installation process
In, it is often necessary to metal edge frame and vacuum glass or angle glass are sealed fixation using glass cement, to improve door
Sealing, waterproof and the soundproof effect of window.Glass cement can be also used for the bonding between stone material and other construction materials and sealing.
Conventional glass cement all has outstanding adhesive property and weather resistance, it is ensured that effective connection between base material
And fixation, and prolonged meat service life is kept, but glass cement is as most bonding agent, after prolonged use
There are pyconsises, although remaining to that effective fixation, seam crossing is kept to will produce tiny between bonding agent pyknosis rear substrate
Crack or gap, to reduce the sealing effect of bonding agent.Door and window etc. is needed to keep for the structure of good sealing, then
It can influence the water resistance of the structure.
Invention content
For problems of the prior art, the present invention provides a kind of sealing glass with anti-ageing chemoprevention pyknosis effect
Glass glue；The property of the type glass cement is stable, antiageing effect is good and has outstanding anti-pyknosis effect, can use
Prolonged waterproof sealing effect is kept in journey.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect, according to mass fraction, the ingredient of glass cement includes：Asphalt mixtures modified by epoxy resin
60-70 parts of fat, 10-20 parts of isophthalic unsaturated polyester resin, 10-30 parts of inorganic filler restrain 6-10 parts of modifying agent, titanium dioxide 3-
5 parts, 15-18 parts of amine curing agent, 1-2 parts of toughener, 0.5-0.7 parts of cobalt iso-octoate, 1-3 parts of ultra-violet absorber, antifoaming agent
1-2 parts.
Preferably, according to mass fraction, the ingredient of the glass cement includes：65-68 parts of epoxy resin, isophthalic unsaturated polyester (UP)
12-15 parts of resin, 20-25 parts of inorganic filler restrain 7-8 parts of modifying agent, 4-5 parts of titanium dioxide, and 16-17 parts of amine curing agent increases
Tough dose 1.5-1.7 parts, 0.5-0.6 parts of curing accelerator, 2-3 parts of ultra-violet absorber, 1.4-1.7 parts of antifoaming agent.
In the present invention, the ingredient for restraining modifying agent includes：10-12 parts of polystyrene emulsion, 3-6 parts of ethylene glycol, nanometer are blue
6-7 parts of spar powder, 2-3 parts of toluene di-isocyanate(TDI), 2-4 parts of dihydromethyl propionic acid, preparation method are：It, will according to mass fraction
Ethylene glycol and polystyrene emulsion are added in reaction kettle and are uniformly mixed, and reactor temperature is heated to 60-70 DEG C, and dihydroxy is added
Methylpropanoic acid is stirred to react 20-30min, and nanometer aquamaine mountain flour and toluene di-isocyanate(TDI) are then added into reaction kettle, with
The rotating speed of 650-700r/min is uniformly dispersed, and required convergence modifying agent is obtained after cooling.
Preferably, inorganic filler includes talcum powder, silicon powder and andalusite powder, and the mesh number of inorganic filler is 300-400 mesh.
Preferably, curing accelerator is benzoyl peroxide, methyl ethyl ketone peroxide or isopropyl benzene hydroperoxide.
Preferably, ultra-violet absorber is ultraviolet absorbent UV-531, ultra-violet absorber UV-9 or ultraviolet radiation absorption
Agent UVP-327.
Preferably, toughener is polypropylene glycol diglycidyl ether, and antifoaming agent is organic silicon defoamer.
The preparation method of glass cement provided by the invention includes the following steps：
According to mass fraction, epoxy resin and isophthalic unsaturated polyester resin are added in reaction kettle, at room temperature with 250-
The rotating speed of 300r/min stirs 8-10min, and titanium dioxide and inorganic filler are then added into reaction kettle, stirs evenly, and with 5-7
DEG C/reactor temperature is increased to 70-75 DEG C, after heating by the heating rate of min, convergence modifying agent is added and keeps the temperature and stirs
Reaction 15-20min is mixed, amine curing agent, curing accelerator, toughener, ultraviolet radiation absorption are then sequentially added into reaction kettle
Agent and antifoaming agent, and 6-8min is handled with the rotating speed high speed dispersion of 500-600r/min, after the completion of dispersion, product is cooled to room
Temperature obtains required glass cement.
The present invention has following advantageous effect：
Using epoxy resin and isophthalic unsaturated polyester resin as the material of main part of bonding agent in the type glass cement, the type polymer
Opposite more preferable with stability for polyurethane tackifier, anti-aging property is more outstanding, and thermal expansion system has been used in glass cement
The lower talcum powder of number, silicon powder and andalusite powder can reduce influence of the temperature change to glass cement character as filler.Its
In, the convergence modifying agent dosed can significantly improve the pyconsis of bonding agent, improve the weather resistance of glass cement so that this is viscous
Pyknosis will not be occurred during long-time use by connecing agent, can keep good sealing and waterproof effect.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect, according to mass fraction, the ingredient of glass cement includes：Asphalt mixtures modified by epoxy resin
60 parts of fat, 10 parts of isophthalic unsaturated polyester resin, 10 parts of inorganic filler restrain 6 parts of modifying agent, 3 parts of titanium dioxide, amine curing agent
15 parts, 1 part of toughener, 0.5 part of cobalt iso-octoate, 1 part of ultra-violet absorber, 1 part of antifoaming agent.
In the present embodiment, the ingredient for restraining modifying agent includes：10 parts of polystyrene emulsion, 3 parts of ethylene glycol, nanometer kyanite
6 parts of powder, 2 parts of toluene di-isocyanate(TDI), 2 parts of dihydromethyl propionic acid, preparation method are：According to mass fraction, by ethylene glycol and gather
Styrene emulsion is added in reaction kettle and is uniformly mixed, and reactor temperature is heated to 60 DEG C, and dihydromethyl propionic acid stirring is added
20min is reacted, nanometer aquamaine mountain flour and toluene di-isocyanate(TDI) are then added into reaction kettle, is disperseed with the rotating speed of 650r/min
Uniformly, modifying agent is restrained needed for being obtained after cooling.
Wherein, inorganic filler includes talcum powder, silicon powder and andalusite powder, and the mesh number of inorganic filler is 300 mesh.
Curing accelerator is benzoyl peroxide.
Ultra-violet absorber is ultraviolet absorbent UV-531.
Toughener is polypropylene glycol diglycidyl ether, and antifoaming agent is organic silicon defoamer.
The preparation method of glass cement provided in this embodiment includes the following steps：
According to mass fraction, epoxy resin and isophthalic unsaturated polyester resin are added in reaction kettle, at room temperature with 250r/
The rotating speed of min stirs 8min, and titanium dioxide and inorganic filler are then added into reaction kettle, stirs evenly, and with the liter of 5 DEG C/min
Reactor temperature is increased to 70 DEG C, after heating by warm rate, and convergence modifying agent is added and insulated and stirred reacts 15min,
Then amine curing agent, curing accelerator, toughener, ultra-violet absorber and antifoaming agent are sequentially added into reaction kettle, and with
The rotating speed high speed dispersion of 500r/min handles 6min, and after the completion of dispersion, product is cooled to room temperature, obtains required glass cement.
Embodiment 2
A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect, according to mass fraction, the ingredient of glass cement includes：Asphalt mixtures modified by epoxy resin
70 parts of fat, 20 parts of isophthalic unsaturated polyester resin, 30 parts of inorganic filler restrain 10 parts of modifying agent, 5 parts of titanium dioxide, amine-type cure
18 parts of agent, 2 parts of toughener, 0.7 part of cobalt iso-octoate, 3 parts of ultra-violet absorber, 2 parts of antifoaming agent.
In the present embodiment, the ingredient for restraining modifying agent includes：12 parts of polystyrene emulsion, 6 parts of ethylene glycol, nanometer kyanite
7 parts of powder, 3 parts of toluene di-isocyanate(TDI), 4 parts of dihydromethyl propionic acid, preparation method are：According to mass fraction, by ethylene glycol and gather
Styrene emulsion is added in reaction kettle and is uniformly mixed, and reactor temperature is heated to 70 DEG C, and dihydromethyl propionic acid stirring is added
30min is reacted, nanometer aquamaine mountain flour and toluene di-isocyanate(TDI) are then added into reaction kettle, is disperseed with the rotating speed of 700r/min
Uniformly, modifying agent is restrained needed for being obtained after cooling.
Wherein, inorganic filler includes talcum powder, silicon powder and andalusite powder, and the mesh number of inorganic filler is 400 mesh.
Curing accelerator is methyl ethyl ketone peroxide.
Ultra-violet absorber is ultra-violet absorber UV-9.
Toughener is polypropylene glycol diglycidyl ether, and antifoaming agent is organic silicon defoamer.
The preparation method of glass cement provided in this embodiment includes the following steps：
According to mass fraction, epoxy resin and isophthalic unsaturated polyester resin are added in reaction kettle, at room temperature with 300r/
The rotating speed of min stirs 10min, and titanium dioxide and inorganic filler are then added into reaction kettle, stirs evenly, and with 7 DEG C/min's
Reactor temperature is increased to 75 DEG C, after heating by heating rate, and convergence modifying agent and insulated and stirred reaction is added
Then 20min sequentially adds amine curing agent, curing accelerator, toughener, ultra-violet absorber and defoaming into reaction kettle
Agent, and 8min is handled with the rotating speed high speed dispersion of 600r/min, after the completion of dispersion, product is cooled to room temperature, obtains required glass
Glass glue.
Embodiment 3
A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect, according to mass fraction, the ingredient of glass cement includes：Asphalt mixtures modified by epoxy resin
65 parts of fat, 15 parts of isophthalic unsaturated polyester resin, 20 parts of inorganic filler restrain 8 parts of modifying agent, 4 parts of titanium dioxide, amine curing agent
17 parts, 1.5 parts of toughener, 0.6 part of cobalt iso-octoate, 2 parts of ultra-violet absorber, 1.5 parts of antifoaming agent.
In the present embodiment, the ingredient for restraining modifying agent includes：11 parts of polystyrene emulsion, 5 parts of ethylene glycol, nanometer kyanite
6.5 parts of powder, 2.5 parts of toluene di-isocyanate(TDI), 3 parts of dihydromethyl propionic acid, preparation method are：According to mass fraction, by ethylene glycol
It is added in reaction kettle and is uniformly mixed with polystyrene emulsion, reactor temperature is heated to 65 DEG C, and dihydromethyl propionic acid is added
It is stirred to react 25min, nanometer aquamaine mountain flour and toluene di-isocyanate(TDI) are then added into reaction kettle, with the rotating speed of 680r/min
It is uniformly dispersed, required convergence modifying agent is obtained after cooling.
Wherein, inorganic filler includes talcum powder, silicon powder and andalusite powder, and the mesh number of inorganic filler is 350 mesh.
Curing accelerator is isopropyl benzene hydroperoxide.
Ultra-violet absorber is ultra-violet absorber UVP-327.
Toughener is polypropylene glycol diglycidyl ether, and antifoaming agent is organic silicon defoamer.
The preparation method of glass cement provided in this embodiment includes the following steps：
According to mass fraction, epoxy resin and isophthalic unsaturated polyester resin are added in reaction kettle, at room temperature with 280r/
The rotating speed of min stirs 9min, and titanium dioxide and inorganic filler are then added into reaction kettle, stirs evenly, and with the liter of 6 DEG C/min
Reactor temperature is increased to 73 DEG C, after heating by warm rate, and convergence modifying agent is added and insulated and stirred reacts 17min,
Then amine curing agent, curing accelerator, toughener, ultra-violet absorber and antifoaming agent are sequentially added into reaction kettle, and with
The rotating speed high speed dispersion of 550r/min handles 7min, and after the completion of dispersion, product is cooled to room temperature, obtains required glass cement.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect, it is characterised in that：According to mass fraction, the glass cement
Ingredient include：60-70 parts of epoxy resin, 10-20 parts of isophthalic unsaturated polyester resin, 10-30 parts of inorganic filler, convergence are modified
6-10 parts of agent, 3-5 parts of titanium dioxide, 15-18 parts of amine curing agent, 1-2 parts of toughener, 0.5-0.7 parts of cobalt iso-octoate, ultraviolet light are inhaled
Receive 1-3 parts of agent, 1-2 parts of antifoaming agent.
2. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect according to claim 1, it is characterised in that：According to
The ingredient of mass fraction, the glass cement includes：65-68 parts of epoxy resin, 12-15 parts of isophthalic unsaturated polyester resin are inorganic
20-25 parts of filler, 7-8 parts of modifying agent of convergence, 4-5 parts of titanium dioxide, 16-17 parts of amine curing agent, 1.5-1.7 parts of toughener, Gu
Change 0.5-0.6 parts of accelerating agent, 2-3 parts of ultra-violet absorber, 1.4-1.7 parts of antifoaming agent.
3. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect according to claim 1, it is characterised in that：It is described
Convergence modifying agent ingredient include：10-12 parts of polystyrene emulsion, 3-6 parts of ethylene glycol, 6-7 parts of nanometer aquamaine mountain flour, toluene two
2-3 parts of isocyanates, 2-4 parts of dihydromethyl propionic acid, preparation method are：According to mass fraction, by ethylene glycol and polystyrene breast
Liquid is added in reaction kettle and is uniformly mixed, and reactor temperature is heated to 60-70 DEG C, and dihydromethyl propionic acid is added and is stirred to react
Then nanometer aquamaine mountain flour and toluene di-isocyanate(TDI) is added, with the rotating speed of 650-700r/min in 20-30min into reaction kettle
It is uniformly dispersed, required convergence modifying agent is obtained after cooling.
4. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect according to claim 1, it is characterised in that：It is described
Inorganic filler includes talcum powder, silicon powder and andalusite powder, and the mesh number of inorganic filler is 300-400 mesh.
5. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect according to claim 1, it is characterised in that：It is described
Curing accelerator is benzoyl peroxide, methyl ethyl ketone peroxide or isopropyl benzene hydroperoxide.
6. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect according to claim 1, it is characterised in that：Institute
It is ultraviolet absorbent UV-531, ultra-violet absorber UV-9 or ultra-violet absorber UVP-327 to state ultra-violet absorber.
7. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect according to claim 1, it is characterised in that：Institute
It is polypropylene glycol diglycidyl ether to state toughener, and antifoaming agent is organic silicon defoamer.
8. a kind of seal glass glue with anti-ageing chemoprevention pyknosis effect according to claim 1, it is characterised in that：It is described
The preparation method of glass cement includes the following steps：
According to mass fraction, epoxy resin and isophthalic unsaturated polyester resin are added in reaction kettle, at room temperature with 250-
The rotating speed of 300r/min stirs 8-10min, and titanium dioxide and inorganic filler are then added into reaction kettle, stirs evenly, and with 5-7
DEG C/reactor temperature is increased to 70-75 DEG C, after heating by the heating rate of min, convergence modifying agent is added and keeps the temperature and stirs
Reaction 15-20min is mixed, amine curing agent, curing accelerator, toughener, ultraviolet radiation absorption are then sequentially added into reaction kettle
Agent and antifoaming agent, and 6-8min is handled with the rotating speed high speed dispersion of 500-600r/min, after the completion of dispersion, product is cooled to room
Temperature obtains required glass cement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810424582.4A CN108485573A (en) | 2018-05-07 | 2018-05-07 | A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810424582.4A CN108485573A (en) | 2018-05-07 | 2018-05-07 | A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect |
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| CN108485573A true CN108485573A (en) | 2018-09-04 |
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| CN201810424582.4A Pending CN108485573A (en) | 2018-05-07 | 2018-05-07 | A kind of seal glass glue with anti-ageing chemoprevention pyknosis effect |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112834299A (en) * | 2020-12-31 | 2021-05-25 | 中铁十八局集团有限公司 | Sealing material based on fly ash machine-made sand mortar impermeability test and use method thereof |
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| CN102643549A (en) * | 2012-02-20 | 2012-08-22 | 江苏天辰硅材料有限公司 | Dealcoholized flame-retardant silicone sealant and preparation method thereof |
| CN103173175A (en) * | 2013-03-23 | 2013-06-26 | 广东新展化工新材料有限公司 | Organic silicone modified epoxy resin sealant and preparation method thereof |
| CN103965826A (en) * | 2013-01-25 | 2014-08-06 | 锋泾（中国）建材集团有限公司 | Fire retardation type double component silicone structure adhesive |
| CN107227134A (en) * | 2017-06-13 | 2017-10-03 | 湖北新海鸿化工有限公司 | A kind of curtain wall glass structure glue and preparation method thereof |
-
2018
- 2018-05-07 CN CN201810424582.4A patent/CN108485573A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643549A (en) * | 2012-02-20 | 2012-08-22 | 江苏天辰硅材料有限公司 | Dealcoholized flame-retardant silicone sealant and preparation method thereof |
| CN103965826A (en) * | 2013-01-25 | 2014-08-06 | 锋泾（中国）建材集团有限公司 | Fire retardation type double component silicone structure adhesive |
| CN103173175A (en) * | 2013-03-23 | 2013-06-26 | 广东新展化工新材料有限公司 | Organic silicone modified epoxy resin sealant and preparation method thereof |
| CN107227134A (en) * | 2017-06-13 | 2017-10-03 | 湖北新海鸿化工有限公司 | A kind of curtain wall glass structure glue and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112834299A (en) * | 2020-12-31 | 2021-05-25 | 中铁十八局集团有限公司 | Sealing material based on fly ash machine-made sand mortar impermeability test and use method thereof |
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