CN108485544A - Laminated flex composite material - Google Patents

Laminated flex composite material Download PDF

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Publication number
CN108485544A
CN108485544A CN201810195994.5A CN201810195994A CN108485544A CN 108485544 A CN108485544 A CN 108485544A CN 201810195994 A CN201810195994 A CN 201810195994A CN 108485544 A CN108485544 A CN 108485544A
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CN
China
Prior art keywords
composite material
adhesive linkage
layer
far
fibrous layer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810195994.5A
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Chinese (zh)
Inventor
方坦
刘传超
荣海春
张军红
李翔
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CETC 38 Research Institute
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CETC 38 Research Institute
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Application filed by CETC 38 Research Institute filed Critical CETC 38 Research Institute
Priority to CN201810195994.5A priority Critical patent/CN108485544A/en
Publication of CN108485544A publication Critical patent/CN108485544A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21Paper; Textile fabrics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00Presence of inorganic and organic materials
    • C09J2400/20Presence of organic materials
    • C09J2400/26Presence of textile or fabric
    • C09J2400/263Presence of textile or fabric in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2427/00Presence of halogenated polymer
    • C09J2427/006Presence of halogenated polymer in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • C09J2475/006Presence of polyurethane in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of laminated flex composite materials, including:Load fibrous layer and adhesive linkage on two surfaces of load fibrous layer is set, wherein the load fibrous layer is formed using fibrous material and sensing material mixed weaving, and the sensing element is the material with information transmission or sensor function.The laminated flex composite material of the present invention has the performances such as high intensity, tear-proof, air-tightness, ultraviolet radiation preventing and anti-environmental aging, while can carry out the monitoring of Common Parameters.

Description

Laminated flex composite material
Technical field
The present invention relates to technical field of composite materials more particularly to a kind of laminated flex composite materials.
Background technology
It is to represent aerostatics due in military surveillance, space early warning, communication relay and space exploration with captive balloon, dirigible The application advantage in equal fields, was increasingly subject to the concern of people in recent years.Master of its laminated flex composite material as aerostatics The height of body structural material, performance directly affects the effectiveness of aerostatics, as floating height, the follow-on mission time, effectively Load, service life etc..
How laminated flex composite material stress is monitored in real time in use, especially some key positions Stressing conditions, as aerostat nose cone binding position, drag-line are tethered in position, major-minor air bag connecting portion and building membrane structure Bearing position etc..These positions are also always the difficult point in soft structure design process.Therefore it is multiple to be badly in need of a kind of intelligent laminated flex Condensation material can be used for the Common Parameters such as real-time monitor stress strain, temperature.
Invention content
Based on the above issues, the present invention provides a kind of laminated flex composite material, have high intensity, tear-proof, air-tightness, The performances such as ultraviolet radiation preventing and anti-environmental aging, while the monitoring of Common Parameters can be carried out.
To solve the above problems, the present invention provides a kind of laminated flex composite materials, which is characterized in that including:Load Fibrous layer and adhesive linkage on two surfaces of load fibrous layer is set, wherein
The load fibrous layer is formed using fibrous material and sensing material mixed weaving, the sensing element be with Information is transmitted or the material of sensor function.
Wherein, the composite material further includes:
In the weathering layer far from load fibrous layer side of any layer adhesive linkage.
Wherein, the composite material further includes:
In the resistance heliosphere far from load fibrous layer side of any layer adhesive linkage.
Wherein, the composite material further includes:
The second adhesive linkage is provided on the side far from the adhesive linkage of the resistance heliosphere, and viscous described second It connects and is provided with weathering layer on the side far from the resistance heliosphere of layer.
Wherein, the weathering layer is made of materials such as polyvinyl fluoride or weather-proof polyurethanes.
Wherein, the resistance heliosphere is made of polyester terephthalate, polyethylene glycol or polyethylene glycol ethylene copolymer.
Wherein, the adhesive linkage is made of polyurethane.
In an alternative embodiment of the invention, a kind of laminated flex composite material is provided, which is characterized in that including:It is weather-proof Layer is arranged the sensing element in the weathering layer side with reticular structure and fills the netted knot of the sensing element The third adhesive linkage of the gap area of structure;
Wherein, the sensing element with information by transmitting or the material of sensor function weaves.
Wherein, the composite material further includes:
In the resistance heliosphere far from weathering layer side setting of the sensing element, in the separate institute of the resistance heliosphere The 4th adhesive linkage for stating the setting of sensing element side, in the fibre far from resistance heliosphere side setting of the 4th adhesive linkage Tie up layer, and the 5th adhesive linkage far from the 4th adhesive linkage side setting in the fibrous layer.
Wherein, the weathering layer is made of ultraviolet radiation preventing and the material of environmental aging, and the resistance heliosphere is by airtight modeling Material resin material is made.
Laminated flex composite material of the present invention, including surfaces externally and internally and multiple function layers are existed using resin bonding Together, while by resin bonding layer the inner surface in material is set, there is high intensity, tear-proof, air-tightness, ultraviolet radiation preventing With the performances such as anti-environmental aging, while the monitoring of Common Parameters can be carried out.
Description of the drawings
Fig. 1 shows the structural schematic diagram of the laminated flex composite material of first embodiment of the invention.
Fig. 2 shows the structural schematic diagrams of the laminated flex composite material of second embodiment of the invention.
Fig. 3 shows the structural schematic diagram of the laminated flex composite material of third embodiment of the invention.
Fig. 4 shows the structural schematic diagram of the laminated flex composite material of fourth embodiment of the invention.
Fig. 5 shows the structural schematic diagram of the laminated flex composite material of fifth embodiment of the invention.
Specific implementation mode
With reference to the accompanying drawings and examples, the specific implementation mode of the present invention is described in further detail.Implement below Example is not limited to the scope of the present invention for illustrating the present invention.
Fig. 1 shows the structural schematic diagram of the laminated flex composite material of first embodiment of the invention.
Referring to Fig.1, the laminated flex composite material of the present embodiment, specifically includes:Load fibrous layer 1 and setting are in load The adhesive linkage 2 and 3 on two surfaces of fibrous layer 1.
In the present embodiment, load fibrous layer 1 is weaved with made of sensing material mixed weaving by high tensile strength fibrous material Cloth, sensing material can be the materials that ess-strain piece, metallic fiber wire material, optical fiber etc. may be used as information transmission or sensor Material, so as to measure ess-strain, the Common Parameters such as pressure, temperature in utricule.
In addition, in a second embodiment, which further includes the separate load fibrous layer 1 one in any layer adhesive linkage The weathering layer of side or barrier layer.As shown in Fig. 2, on another surface of adhesive linkage 3, it is provided with resistance heliosphere 4 or weathering layer 6. In addition, this layer can also use while take into account weathering layer and hinder membrane structure made of the polyurethane material of the function of heliosphere.
Further, in the third embodiment, as shown in figure 3, based on the composite wood for increasing resistance heliosphere 4 in second embodiment Expect on architecture basics, which can also be arranged the second adhesive linkage 5 on the side of the separate adhesive linkage 3 of resistance heliosphere 4, and It is provided with weathering layer 6 on the side of the separate resistance heliosphere 4 of the second adhesive linkage 5.
In above-described embodiment, adhesive linkage 2,3 and the second adhesive linkage 5 can be polyurethane or with load fibrous layer 1, weathering layer 6 and resistance the preferable resin adhesive of 4 chemical compatibility of heliosphere.
Further, load fibrous layer 1 can be woven by high tensile strength fibrous material, such as the poly- virtue of thermotropic liquid crystal (melt spinning) Ester fiber (Vectran), lysotropic liquid crystal (solution-polymerized SBR) aromatic series aromatic polyamide fibre (Kevlar) etc. such as can be aramid fiber fibres The fibrous materials such as dimension, Vectran fibers, polyparaphenylene's benzo dioxazole (PBO) fiber, glass fibre.
In addition, adhesive linkage provides interconnection between each layer, high frequency heat seal, directly-heated heat seal etc., this layer of material may be used Material can be polyester material, such as polyurethane resin (DACRON).Wherein, adhesive linkage 3 can be by load fibrous layer 1 and resistance heliosphere 4 It bonds together and there is good compatibility, the common heliosphere that hinders is polyester terephthalate (MYLAR), polyethylene glycol film Deng.Second adhesive linkage 5 resistance heliosphere thin-film material 4 bonds together with weather-proof layer membrane materials 6, common weather-proof layer membrane materials Mainly there is polyvinyl fluoride.
In the fourth embodiment of the present invention, another laminated flex composite material is provided, as shown in figure 4, the composite wood Material includes:Sensing element 9 and filling sensing element 9 in 6 side of weathering layer with reticular structure is arranged in weathering layer 6 Reticular structure gap area third adhesive linkage 7;Wherein, sensing element 9 with information by transmitting or sensor function Material weave.
Further, in the 5th embodiment, which further includes on the basis of fourth embodiment:
Heliosphere 4 is hindered what 6 side of separate weathering layer of sensing element 9 was arranged, in the separate sensing material of resistance heliosphere 4 4th adhesive linkage 8 of 9 side of layer setting, in the fibrous layer 10, Yi Ji that separate 4 side of resistance heliosphere of the 4th adhesive linkage 8 is arranged The 5th adhesive linkage 11 far from the setting of 8 side of the 4th adhesive linkage of fibrous layer 10.
In above-mentioned all embodiments, weathering layer 6 is made of the material of ultraviolet radiation preventing and anti-environmental aging, such as can be with It is the materials such as polyvinyl fluoride (Polyvinyl fluoride) or weather-proof polyurethane.
Further, resistance heliosphere 4 is made of tight-proof plastic resin material, such as can be polyester terephthalate, poly- second two The materials such as alcohol or polyethylene glycol ethylene copolymer.
Laminated flex composite material of the present invention, including surfaces externally and internally and multiple function layers, it will be each using resin Layer bonds together, while the inner surface in material is arranged in resin bonding layer, has high intensity, tear-proof, air-tightness, anti-purple The performances such as UV radiation and anti-environmental aging.
The laminated flex composite material of the present invention, can be used in the soft structures such as aerostatics, membrane structure building, inflatable, such as Captive balloon, dirigible utricule, membrane building field etc..The present invention composite material include by polymer fiber material, metallic fiber, Optical fiber or carbon fiber it is composite braided at load fibrous layer, will hinder heliosphere, weathering layer by adhesives such as polyurethane and be adhered to fibre It ties up and forms lamination flexible composite on material, which is mainly characterized by metal, optical fiber or carbon fiber and passes Sensor is woven in fibrous layer, and forms one with fibrous layer;Or by metallic fiber, optical fiber or carbon fiber be printed on resistance heliosphere or On weathering layer, be compounded in layers of braided fibers by adhesive, one formed with resistance heliosphere or weathering layer, wherein metallic fiber, Optical fiber or carbon fiber can measure ess-strain, the aerostatics Common Parameters such as pressure, temperature in utricule, can also be to be used for transmission The cable of flare up electric signal, it may also be used in building film material material and the parameters such as ess-strain that building film material material is provided.
Embodiment of above is merely to illustrate the present invention, and not limitation of the present invention, in relation to the common of technical field Technical staff can also make a variety of changes and modification without departing from the spirit and scope of the present invention, therefore all Equivalent technical solution also belongs to scope of the invention, and scope of patent protection of the invention should be defined by the claims.

Claims (10)

1. a kind of laminated flex composite material, which is characterized in that including:Load fibrous layer and setting are in the load fibrous layer The adhesive linkage on two surfaces, wherein
The load fibrous layer is formed using fibrous material and sensing material mixed weaving, and the sensing material is to be passed with information Defeated or sensor function material.
2. composite material as described in claim 1, which is characterized in that the composite material further includes:
In the weathering layer far from load fibrous layer side of any layer adhesive linkage.
3. composite material as described in claim 1, which is characterized in that the composite material further includes:
In the resistance heliosphere far from load fibrous layer side of any layer adhesive linkage.
4. composite material as claimed in claim 3, which is characterized in that the composite material further includes:
It is provided with the second adhesive linkage on the side far from the adhesive linkage of the resistance heliosphere, and in second adhesive linkage Far from it is described resistance heliosphere side on be provided with weathering layer.
5. composite material as claimed in claim 2, which is characterized in that the weathering layer is by polyvinyl fluoride or weather-proof polyurethane system At.
6. composite material as claimed in claim 3, which is characterized in that the resistance heliosphere is by polyester terephthalate, poly- second two Alcohol or polyethylene glycol ethylene copolymer materials are made.
7. composite material as claimed in claim 4, which is characterized in that the adhesive linkage is made of polyurethane.
8. a kind of laminated flex composite material, which is characterized in that including:Having in the weathering layer side is arranged in weathering layer The third adhesive linkage of the gap area of the sensing element of reticular structure and the reticular structure of the filling sensing element;
Wherein, the sensing element with information by transmitting or the material of sensor function weaves.
9. composite material as claimed in claim 8, which is characterized in that the composite material further includes:
In the resistance heliosphere far from weathering layer side setting of the sensing element, in the separate biography of the resistance heliosphere The 4th adhesive linkage for feeling the setting of material layer side, in the fiber far from resistance heliosphere side setting of the 4th adhesive linkage Layer, and the 5th adhesive linkage far from the 4th adhesive linkage side setting in the fibrous layer.
10. composite material as claimed in claim 9, which is characterized in that the weathering layer is old by ultraviolet radiation preventing and environment The material of change is made, and the resistance heliosphere is made of tight-proof plastic resin material.
CN201810195994.5A 2018-03-09 2018-03-09 Laminated flex composite material Pending CN108485544A (en)

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Application Number Priority Date Filing Date Title
CN201810195994.5A CN108485544A (en) 2018-03-09 2018-03-09 Laminated flex composite material

Publications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110641676A (en) * 2019-09-25 2020-01-03 中南大学 Stratospheric floating platform and deployment method thereof
CN113897147A (en) * 2021-10-19 2022-01-07 东莞凌空遥感科技有限公司 Lightweight high-strength aerostat skin and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110641676A (en) * 2019-09-25 2020-01-03 中南大学 Stratospheric floating platform and deployment method thereof
CN110641676B (en) * 2019-09-25 2021-07-13 中南大学 Stratospheric floating platform and deployment method thereof
CN113897147A (en) * 2021-10-19 2022-01-07 东莞凌空遥感科技有限公司 Lightweight high-strength aerostat skin and preparation method thereof
CN113897147B (en) * 2021-10-19 2023-09-05 铱格斯曼航空科技集团股份有限公司 Light high-strength aerostat skin and preparation method thereof

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Application publication date: 20180904