CN108485394A - A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating - Google Patents
A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating Download PDFInfo
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- CN108485394A CN108485394A CN201810344767.4A CN201810344767A CN108485394A CN 108485394 A CN108485394 A CN 108485394A CN 201810344767 A CN201810344767 A CN 201810344767A CN 108485394 A CN108485394 A CN 108485394A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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Abstract
The present invention provides a kind of stain resistant type Ludox acrylic acid ester emulsion composite exterior wall insulating moulding coating, and raw material includes following components by weight：40 60 parts of styrene-acrylic emulsion, 10 20 parts of eakleite active slurry, 58 parts of hollow glass micropearl, 8 12 parts of titanium dioxide, 20 25 parts of bentonite slurry, 10 15 powder of calcined kaolin, 6 10 powder of mica powder, 20 40 parts of Ludox, 20 25 parts of stain resistant type dispersion liquid, altogether 25 parts of thickener soln, 0.1 0.3 parts of mould inhibitor, 23 parts of propylene glycol, 0.9 1.5 parts of dispersant, 0.3 0.8 parts of antifoaming agent, 2.0 3.5 parts of coalescents, 0.5 0.9 parts of dispersant, 13 parts of PH conditioning agents.The composite exterior wall insulating moulding coating not only has good low-temperature stability, water resistance, alkali resistance, abrasion resistance, polluting proofing property and ageing resistance, but also have good coating temperature-change resistance, reflective insulation, high dirt resistance, the advantages such as the feature of environmental protection, aesthetics, high thermal resistance, thermal coefficient be low.
Description
Technical field
The present invention relates to a kind of insulating moulding coatings, and in particular to a kind of stain resistant type silica sol-acrylic emulsion is compound outer
Wall insulating moulding coating.
Background technology
Insulating moulding coating "：Refer to a kind of blocking to grow up in recent years, reflection, the function of radiating sunlight near-infrared heat
Property water paint, enables roof insulation cool down, energy-saving.With heat-insulated, waterproof, antirust, anti-corrosion, short time limit, quick spy
Property, replace water sprinkler system, heat-preservation cotton, foam sponge, interlayer iron sheet etc. comprehensively.Insulating moulding coating mainly has from the classification of characteristic principle
Three kinds, isolation conduction type insulating moulding coating, reflective insulation coating and Radiation Heat-insulated Paint.In addition to the heat-insulated painting of above-mentioned three types
Have there is a kind of thermal insulation paint in material, external heat insulating function coating, other than having the advantages of above-mentioned insulating moulding coating, more
Has peculiar heat insulation effect.Insulating moulding coating can be divided into 3 kinds of isolation-type, reflection-type and radial pattern according to insulating mechanism, wherein hindering
Belong to thick matter traditional coating every type insulating moulding coating, insulating mechanism is that impedance heat is transmitted, technology relative maturity；Radiation type heat-insulation
Coating be the sunshine light heat that building absorbs is emitted to certain wavelength in air by the form of radiation reach every
Heat drop temperature；The insulating mechanism of reflective insulation coating is reflected sunlight.
Currently, insulating moulding coating type is various, it is widely used in many fields.The big portion in existing insulating moulding coating
Point be all single effect insulating moulding coating it is relatively more, there are no a qualification, security performance is high, high dirt resistance, coating
Temperature-change resistance, high-barrier heat-proof quality stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating sale.
Invention content
It is compound to provide a kind of stain resistant type silica sol-acrylic emulsion aiming at existing issue for the purpose of the present invention
Outer wall heat-insulating coating, a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating with styrene-acrylic emulsion be at
Membrane substance, the stain resistant type Ludox and stain resistant type dispersion liquid of addition are added to the heat-insulated substance eakleite of composite exterior wall simultaneously
Simultaneously part of auxiliary is added in active slurry, hollow glass micropearl, titanium dioxide, mica powder, bentonite slurry, calcined kaolin etc., prepares
A kind of obtained stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating.A kind of stain resistant type Ludox-the third
Olefin(e) acid ester lotion composite exterior wall insulating moulding coating not only has good low-temperature stability, water resistance, alkali resistance, abrasion resistance, resistance to
Pickup and ageing resistance, but also have good coating temperature-change resistance, reflective insulation, high dirt resistance, the feature of environmental protection,
The advantages such as aesthetics, high thermal resistance, thermal coefficient be low.
Above-mentioned purpose to realize the present invention, a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall of the present invention every
Hot coating uses following technical scheme：A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating, raw material
Include following components by weight：40-60 parts of styrene-acrylic emulsion, 10-20 parts of eakleite active slurry, hollow glass micropearl 5-
8 parts, 8-12 parts of titanium dioxide, 20-25 parts of bentonite slurry, calcined kaolin 10-15 powder, mica powder 6-10 powder, Ludox 20-40
Part, 20-25 parts of stain resistant type dispersion liquid, altogether 2-5 parts of thickener soln, 0.1-0.3 parts of mould inhibitor, 2-3 parts of propylene glycol, dispersant
0.9-1.5 parts, 0.3-0.8 parts of antifoaming agent, 2.0-3.5 parts of coalescents, 0.5-0.9 parts of dispersant, 1-3 parts of PH conditioning agents.
Further, the preparation method of the eakleite active slurry is the temperature by carbide slag at 800-1000 DEG C
Lower calcination 2-3h, is then cleared up with boiling water, and the amount ratio according still further to CaO and SiO2 substances is 1.5：1, the mass ratio of water and solid phase
40：The calcareous raw material of preparation, silicon ash and water are added high-pressure reactor, stirred, the speed control of stirring by 1 ratio
System is warming up to 200-250 DEG C in 200-300r/min, with the speed of 1.5 DEG C/min, and low whipping speed is 50-70r/min conditions
Under, heat preservation 10-15h carries out hydrothermal synthesis reaction, and eakleite active slurry is prepared.
Further, the titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
Further, the mica powder uses 1500 mesh.
Further, the total thickener soln is that deionized water, propylene glycol and thickener three press 2：2：1 weight
The mixture of proportioning.
Further, the coalescents are Texannol ester alcohols.
Further, the dispersant is OROTAN 731A（Polycarboxylate sodium）Property dispersant.
Further, the PH conditioning agents are ammonium hydroxide.
It is compared with the prior art, the invention has the advantages that：
1, rutile titanium dioxide is used in a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating of the present invention
Powder and hollow glass micropearl play good reflex to solar radiation, there is the reflectivity of superelevation, can reduce the tired of heat
There is lower thermal coefficient, rutile type titanium white to have as auxiliary packing preferable anti-for product, wherein hollow glass micropearl
Rate is penetrated, above-mentioned material is added in coating and plays the role of reflective insulation；
2, eakleite activity is starched in a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating of the present invention
Material, hollow glass micropearl and rutile type titanium white can further increase the heat-proof quality of coating, hollow glass micropearl, golden red
Stone-type titanium dioxide, eakleite active slurry and heat-reflecting heat-insulating powder play synergistic effect, further improve the heat-insulated of coating
Performance.By detection, a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating traditional performance of the invention
It can be up to state standards requirement with heat-proof quality, and have heat insulation more better than single thermal insulating filling；
3, a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating of the invention not only has good low
Temperature stability, water resistance, alkali resistance, abrasion resistance, polluting proofing property and ageing resistance, but also the good coating heatproof having
Denaturation, reflective insulation, high dirt resistance, the advantages such as the feature of environmental protection, aesthetics, high thermal resistance, thermal coefficient be low.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.The specific embodiments described herein are merely illustrative of the present invention, is not used to limit
The present invention.
Embodiment 1
A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating, raw material include with the following group by weight
Point：40 parts of styrene-acrylic emulsion, 10 parts of eakleite active slurry, 5 parts of hollow glass micropearl, 8 parts of titanium dioxide, 20 parts of bentonite slurry,
10 powder of calcined kaolin, 6 powder of mica powder, 20 parts of Ludox, 20 parts of stain resistant type dispersion liquid, altogether 2 parts of thickener soln, mould inhibitor
0.1 part, 2 parts of propylene glycol, 0.9 part of dispersant, 0.3 part of antifoaming agent, 2.0 parts of coalescents, 0.5 part of dispersant, PH conditioning agents 1
Part.
The preparation method of the eakleite active slurry is that carbide slag is calcined 3h at a temperature of 800 DEG C, then
It is cleared up with boiling water, the amount ratio according still further to CaO and SiO2 substances is 1.5：1, water and the mass ratio of solid phase 40：1 ratio will be prepared
Calcareous raw material, silicon ash and water high-pressure reactor is added, stirs, the speed control of stirring is in 200r/min, with 1.5
DEG C/speed of min is warming up to 250 DEG C, under the conditions of low whipping speed is 50r/min, heat preservation 10h carries out hydrothermal synthesis reaction, system
It is standby to obtain eakleite active slurry.
The titanium dioxide is rutile type titanium white, and grain size is 100 μm.
The mica powder uses 1500 mesh.
The total thickener soln is that deionized water, propylene glycol and thickener three press 2：2：1 weight proportion mixes
Close object.
The coalescents are Texannol ester alcohols.
The dispersant is OROTAN 731A（Polycarboxylate sodium）Property dispersant.
The PH conditioning agents are ammonium hydroxide.
Embodiment 2
A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating, raw material include with the following group by weight
Point：60 parts of styrene-acrylic emulsion, 20 parts of eakleite active slurry, 8 parts of hollow glass micropearl, 12 parts of titanium dioxide, bentonite slurry 25
Part, total 5 parts of thickener soln, is prevented 15 powder of calcined kaolin, 10 powder of mica powder, 40 parts of Ludox, 25 parts of stain resistant type dispersion liquid
Mould dose 0.3 part, 3 parts of propylene glycol, 1.5 parts of dispersant, 0.8 part of antifoaming agent, 3.5 parts of coalescents, 0.9 part of dispersant, PH adjust
3 parts of agent.
The preparation method of the eakleite active slurry is that carbide slag is calcined 2h at a temperature of 1000 DEG C, then
It is cleared up with boiling water, the amount ratio according still further to CaO and SiO2 substances is 1.5：1, water and the mass ratio of solid phase 40：1 ratio will be prepared
Calcareous raw material, silicon ash and water high-pressure reactor is added, stirs, the speed control of stirring is in 300r/min, with 1.5
DEG C/speed of min is warming up to 250 DEG C, under the conditions of low whipping speed is 70r/min, heat preservation 15h carries out hydrothermal synthesis reaction, system
It is standby to obtain eakleite active slurry.
The titanium dioxide is rutile type titanium white, and grain size is 150 μm.
The mica powder uses 1500 mesh.
The total thickener soln is that deionized water, propylene glycol and thickener three press 2：2：1 weight proportion mixes
Close object.
The coalescents are Texannol ester alcohols.
The dispersant is OROTAN 731A（Polycarboxylate sodium）Property dispersant.
The PH conditioning agents are ammonium hydroxide.
Embodiment 3
A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating, raw material include with the following group by weight
Point：55 parts of styrene-acrylic emulsion, 16 parts of eakleite active slurry, 6 parts of hollow glass micropearl, 9 parts of titanium dioxide, 22 parts of bentonite slurry,
12 powder of calcined kaolin, 9 powder of mica powder, 28 parts of Ludox, 22 parts of stain resistant type dispersion liquid, altogether 3 parts of thickener soln, mould inhibitor
0.2 part, 2.5 parts of propylene glycol, 1.2 parts of dispersant, 0.6 part of antifoaming agent, 2.5 parts of coalescents, 0.6 part of dispersant, PH conditioning agents
2 parts.
The preparation method of the eakleite active slurry is that carbide slag is calcined 2.5h at a temperature of 900 DEG C, so
It is cleared up afterwards with boiling water, the amount ratio according still further to CaO and SiO2 substances is 1.5：1, water and the mass ratio of solid phase 40：1 ratio will be made
Standby calcareous raw material, silicon ash and water are added high-pressure reactor, stir, the speed control of stirring in 220-r/min, with
The speed of 1.5 DEG C/min is warming up to 220 DEG C, under the conditions of low whipping speed is 60r/min, and heat preservation 12h carries out hydrothermal synthesis reaction,
Eakleite active slurry is prepared.
The titanium dioxide is rutile type titanium white, and grain size is 120 μm.
The mica powder uses 1500 mesh.
The total thickener soln is that deionized water, propylene glycol and thickener three press 2：2：1 weight proportion mixes
Close object.
The coalescents are Texannol ester alcohols.
The dispersant is OROTAN 731A（Polycarboxylate sodium）Property dispersant.
The PH conditioning agents are ammonium hydroxide.
The following table 1 is a kind of the basic of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating of the present invention
Technical performance
The following table 2 be this present invention a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating coating every
Heat property test result
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to be said using the present invention
Equivalent structure or equivalent flow shift made by bright book content is applied directly or indirectly in other relevant technical fields,
Similarly it is included within the scope of the present invention.
Claims (8)
1. a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating, which is characterized in that its raw material is by weight
Part includes following components：40-60 parts of styrene-acrylic emulsion, 10-20 parts of eakleite active slurry, 5-8 parts of hollow glass micropearl, titanium
8-12 parts of white powder, calcined kaolin 10-15 powder, mica powder 6-10 powder, 20-40 parts of Ludox, resistance to is stained with 20-25 parts of bentonite slurry
20-25 parts of dirty type dispersion liquid, altogether 2-5 parts of thickener soln, 0.1-0.3 parts of mould inhibitor, 2-3 parts of propylene glycol, dispersant 0.9-1.5
Part, 0.3-0.8 parts of antifoaming agent, 2.0-3.5 parts of coalescents, 0.5-0.9 parts of dispersant, 1-3 parts of PH conditioning agents.
2. according to a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating described in claim 1,
It is characterized in that：The preparation method of the eakleite active slurry is that carbide slag is calcined 2- at a temperature of 800-1000 DEG C
Then 3h is cleared up with boiling water, the amount ratio according still further to CaO and SiO2 substances is 1.5：1, water and the mass ratio of solid phase 40：1 ratio
The calcareous raw material of preparation, silicon ash and water are added high-pressure reactor, stirred by example, and the speed control of stirring is in 200-
300r/min is warming up to 200-250 DEG C, under the conditions of low whipping speed is 50-70r/min, heat preservation with the speed of 1.5 DEG C/min
10-15h carries out hydrothermal synthesis reaction, and eakleite active slurry is prepared.
3. according to a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating described in claim 1,
It is characterized in that：The titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
4. according to a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating described in claim 1,
It is characterized in that：The mica powder uses 1500 mesh.
5. according to a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating described in claim 1,
It is characterized in that：The total thickener soln is that deionized water, propylene glycol and thickener three press 2：2：1 weight proportion mixes
Close object.
6. according to a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating described in claim 1,
It is characterized in that：The coalescents are Texannol ester alcohols.
7. according to a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating described in claim 1,
It is characterized in that：The dispersant is OROTAN 731A（Polycarboxylate sodium）Property dispersant.
8. according to a kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating described in claim 1,
It is characterized in that：The PH conditioning agents are ammonium hydroxide.
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| CN201810344767.4A CN108485394A (en) | 2018-04-17 | 2018-04-17 | A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating |
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| CN201810344767.4A CN108485394A (en) | 2018-04-17 | 2018-04-17 | A kind of stain resistant type silica sol-acrylic emulsion composite exterior wall insulating moulding coating |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234575A (en) * | 2019-07-11 | 2020-06-05 | 惠州市维尔康王漆化工有限公司 | Inorganic exterior wall coating and preparation method thereof |
| CN111978807A (en) * | 2020-09-18 | 2020-11-24 | 杨昊天 | Heat-preservation and heat-insulation coating and preparation method thereof |
| CN113174173A (en) * | 2021-05-19 | 2021-07-27 | 广西标牌化学科技有限公司 | Preparation process of environment-friendly stone-like paint |
| CN113416023A (en) * | 2021-07-29 | 2021-09-21 | 上海市建筑科学研究院有限公司 | Phase-change heat storage-reflection heat insulation composite functional cooling pavement material, preparation method and application thereof |
| CN115322591A (en) * | 2022-07-26 | 2022-11-11 | 江苏镇钛化工有限公司 | High-weather-resistance titanium dioxide for automobile panel |
| CN115678322A (en) * | 2022-11-02 | 2023-02-03 | 郑州市超前涂料有限公司 | Reflective heat-insulation stone-like coating and preparation method thereof |
-
2018
- 2018-04-17 CN CN201810344767.4A patent/CN108485394A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234575A (en) * | 2019-07-11 | 2020-06-05 | 惠州市维尔康王漆化工有限公司 | Inorganic exterior wall coating and preparation method thereof |
| CN111978807A (en) * | 2020-09-18 | 2020-11-24 | 杨昊天 | Heat-preservation and heat-insulation coating and preparation method thereof |
| CN113174173A (en) * | 2021-05-19 | 2021-07-27 | 广西标牌化学科技有限公司 | Preparation process of environment-friendly stone-like paint |
| CN113416023A (en) * | 2021-07-29 | 2021-09-21 | 上海市建筑科学研究院有限公司 | Phase-change heat storage-reflection heat insulation composite functional cooling pavement material, preparation method and application thereof |
| CN115322591A (en) * | 2022-07-26 | 2022-11-11 | 江苏镇钛化工有限公司 | High-weather-resistance titanium dioxide for automobile panel |
| CN115678322A (en) * | 2022-11-02 | 2023-02-03 | 郑州市超前涂料有限公司 | Reflective heat-insulation stone-like coating and preparation method thereof |
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Application publication date: 20180904 |
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| WD01 | Invention patent application deemed withdrawn after publication |