CN108485150A - A kind of Polymer Optoelectronic new material - Google Patents
A kind of Polymer Optoelectronic new material Download PDFInfo
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- CN108485150A CN108485150A CN201810440301.4A CN201810440301A CN108485150A CN 108485150 A CN108485150 A CN 108485150A CN 201810440301 A CN201810440301 A CN 201810440301A CN 108485150 A CN108485150 A CN 108485150A
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- parts
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- new material
- polymer optoelectronic
- fullerene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08L39/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of Polymer Optoelectronic new materials, are made of the raw material of following parts by weight：20 30 parts of polymethacrylates, 20 30 parts of polyvinylpyrrolidone, 46 parts of polyethylene oxide, N, 12 23 parts of 10 20 parts of N dimethylformamides, 7 21 parts of polyphenyl sulfonic acid, 9 14 parts of polyaniline, 17 35 parts of porphyrin compound, fullerene and its derivative receive 20 30 parts of 9 18 parts of graphene, 10 20 parts of cyano polypara-phenylene vinylene and analog derivative, 7 11 parts of accelerating agent.The stability and photoelectric conversion efficiency of photoelectric material produced by the present invention are higher, and production cost is low, while being added in photoelectric material and choosing the photoelectric conversion efficiency that imines bithiophene copolymer improves photoelectric material as raw material in analog derivative.
Description
Technical field
The present invention relates to photoelectricity new material technology fields, and in particular to a kind of Polymer Optoelectronic new material.
Background technology
It (includes mainly various active and passive photoelectric sensor optical informations that photoelectric material, which refers to for manufacturing various optoelectronic devices,
Processing and storage device and optic communication etc.) material, mainly include infra-red material, laser material, fiber optic materials, nonlinear optics
Material etc..
Photoelectric material can be divided into organic photoelectrical material and inorganic photovoltaic material by group constituent class, and organic photoelectrical material is one
Class has the special organic material of photoelectric activity.It is typically rich in carbon atom, there is the organic molecule of big pi bond conjugated bonds and is gathered
Object is closed, compared with inorganic photovoltaic material, organic photoelectric functional material may be implemented large area and prepare and be prepared during flexible；Have
Diversified structure composition and broader property regulation space can carry out MOLECULE DESIGN to obtain required performance, and
The molecular level even device of Nano grade are prepared by way of self assembly；Density of material is small, and cheap and structure is easily modified
By force, become one of the Disciplinary Frontiers of the most rich vigor of global new material, new energy and electronic information field.
Invention content
The present invention is intended to provide a kind of Polymer Optoelectronic new material.
The present invention provides the following technical solutions：
A kind of Polymer Optoelectronic new material, is made of the raw material of following parts by weight：Polymethacrylates 20-30
Part, 20-30 parts of polyvinylpyrrolidone, 4-6 parts of polyethylene oxide, 10-20 parts of n,N-Dimethylformamide, polyphenyl sulfonic acid 7-21
Part, 9-14 parts of polyaniline, 17-35 parts of porphyrin compound, fullerene and its 12-23 parts of derivative receive 9-18 parts of graphene, cyano
10-20 parts of polypara-phenylene vinylene and 20-30 parts of analog derivative, 7-11 parts of accelerating agent.
The accelerating agent uses nano zine oxide.
The analog derivative is imines bithiophene copolymer.
The fullerene and its derivative are diazosulfide, benzotriazole, naphtho- thiadiazoles, aphthotriazoles, pyrrolo-
Pyrroledione, indigo, bioxindol, quinoxaline, benzene-naphthalene diimide, imidodicarbonic diamide, thieno acid imide or quinoxaline.
Compared with prior art, the beneficial effects of the invention are as follows：The stability and photoelectricity of photoelectric material produced by the present invention
Transfer efficiency is higher, and production cost is low, while being added in photoelectric material and choosing imines bithiophene in analog derivative
Copolymer improves the photoelectric conversion efficiency of photoelectric material as raw material.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
A kind of 1 Polymer Optoelectronic new material of embodiment, is made of the raw material of following parts by weight：Polymethylacrylic acid
20 parts of ester, 4 parts of polyethylene oxide, 20 parts of n,N-Dimethylformamide, 21 parts of polyphenyl sulfonic acid, gathers 20 parts of polyvinylpyrrolidone
23 parts of 14 parts of aniline, 35 parts of porphyrin compound, fullerene and its derivative receive 18 parts of graphene, cyano polypara-phenylene vinylene
20 parts and 30 parts of analog derivative, 11 parts of accelerating agent.
The accelerating agent uses nano zine oxide.
The analog derivative is imines bithiophene copolymer.
The fullerene and its derivative are diazosulfide, benzotriazole, naphtho- thiadiazoles, aphthotriazoles, pyrrolo-
Pyrroledione, indigo, bioxindol, quinoxaline, benzene-naphthalene diimide, imidodicarbonic diamide, thieno acid imide or quinoxaline.
A kind of 2 Polymer Optoelectronic new material of embodiment, is made of the raw material of following parts by weight：Polymethylacrylic acid
30 parts of ester, 6 parts of polyethylene oxide, 20 parts of n,N-Dimethylformamide, 21 parts of polyphenyl sulfonic acid, gathers at polyvinylpyrrolidone 30 part
23 parts of 14 parts of aniline, 35 parts of porphyrin compound, fullerene and its derivative receive 18 parts of graphene, cyano polypara-phenylene vinylene
20 parts and 30 parts of analog derivative, 11 parts of accelerating agent.
The accelerating agent uses nano zine oxide.
The analog derivative is imines bithiophene copolymer.
The fullerene and its derivative are diazosulfide, benzotriazole, naphtho- thiadiazoles, aphthotriazoles, pyrrolo-
Pyrroledione, indigo, bioxindol, quinoxaline, benzene-naphthalene diimide, imidodicarbonic diamide, thieno acid imide or quinoxaline.
A kind of 3 Polymer Optoelectronic new material of embodiment, is made of the raw material of following parts by weight：Polymethylacrylic acid
25 parts of ester, 5 parts of polyethylene oxide, 15 parts of n,N-Dimethylformamide, 14 parts of polyphenyl sulfonic acid, gathers 25 parts of polyvinylpyrrolidone
17 parts of 11 parts of aniline, 20 parts of porphyrin compound, fullerene and its derivative receive 14 parts of graphene, cyano polypara-phenylene vinylene
15 parts and 4 parts of analog derivative, 9 parts of accelerating agent.
The accelerating agent uses nano zine oxide.
The analog derivative is imines bithiophene copolymer.
The fullerene and its derivative are diazosulfide, benzotriazole, naphtho- thiadiazoles, aphthotriazoles, pyrrolo-
Pyrroledione, indigo, bioxindol, quinoxaline, benzene-naphthalene diimide, imidodicarbonic diamide, thieno acid imide or quinoxaline.
It is obvious to a person skilled in the art that the present invention is not limited to the details of the exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit require rather than it is described illustrate to limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.In addition, it should be understood that although this specification is described in terms of embodiments, but it is not each
Embodiment only contains an independent technical solution, and this description of the specification is merely for the sake of clarity, this field
Technical staff should consider the specification as a whole, and the technical solutions in the various embodiments may also be suitably combined, form this
The other embodiment that field technology personnel are appreciated that.
Claims (4)
1. a kind of Polymer Optoelectronic new material, which is characterized in that it is made of the raw material of following parts by weight：Polymethyl
20-30 parts of acid esters, 4-6 parts of polyethylene oxide, 10-20 parts of n,N-Dimethylformamide, gathers 20-30 parts of polyvinylpyrrolidone
12-23 parts of 7-21 parts of benzene sulfonic acid, 9-14 parts of polyaniline, 17-35 parts of porphyrin compound, fullerene and its derivative, graphene of receiving
20-30 parts of 9-18 parts, 10-20 parts of cyano polypara-phenylene vinylene and analog derivative, 7-11 parts of accelerating agent.
2. a kind of Polymer Optoelectronic new material according to claim 1, it is characterised in that：The accelerating agent uses nano oxygen
Change zinc.
3. a kind of Polymer Optoelectronic new material according to claim 1, it is characterised in that：The analog derivative is Asia
Amine bithiophene copolymer.
4. a kind of Polymer Optoelectronic new material according to claim 1, it is characterised in that：The fullerene and its derivative
For diazosulfide, benzotriazole, naphtho- thiadiazoles, aphthotriazoles, pyrrolo-pyrrole-dione, indigo, bioxindol, quinoxaline,
Benzene-naphthalene diimide, imidodicarbonic diamide, thieno acid imide or quinoxaline.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810440301.4A CN108485150A (en) | 2018-05-10 | 2018-05-10 | A kind of Polymer Optoelectronic new material |
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| CN201810440301.4A CN108485150A (en) | 2018-05-10 | 2018-05-10 | A kind of Polymer Optoelectronic new material |
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| CN201810440301.4A Pending CN108485150A (en) | 2018-05-10 | 2018-05-10 | A kind of Polymer Optoelectronic new material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109777050A (en) * | 2018-12-05 | 2019-05-21 | 广东炜田环保新材料股份有限公司 | A kind of degradable environment-friendly type photoelectricity new material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107658383A (en) * | 2017-10-18 | 2018-02-02 | 苏州贝龙光电科技有限公司 | A kind of photoelectric material |
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2018
- 2018-05-10 CN CN201810440301.4A patent/CN108485150A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107658383A (en) * | 2017-10-18 | 2018-02-02 | 苏州贝龙光电科技有限公司 | A kind of photoelectric material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109777050A (en) * | 2018-12-05 | 2019-05-21 | 广东炜田环保新材料股份有限公司 | A kind of degradable environment-friendly type photoelectricity new material |
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Address after: 801 Jiekang Road, Jieshi Town, Banan District, Chongqing Applicant after: Chongqing China membrane composite material Co., Ltd Address before: 401320 3, 4-2, Shek Gui Road, Jieshi Town, Banan District, Chongqing, 4-2 Applicant before: CHONGQING XINKANGYI DAHL NEW MATERIALS Co.,Ltd. |
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Application publication date: 20180904 |