CN108485020A - A kind of halogen-free flameproof gel coating resin - Google Patents
A kind of halogen-free flameproof gel coating resin Download PDFInfo
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- CN108485020A CN108485020A CN201810238545.4A CN201810238545A CN108485020A CN 108485020 A CN108485020 A CN 108485020A CN 201810238545 A CN201810238545 A CN 201810238545A CN 108485020 A CN108485020 A CN 108485020A
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- halogen
- free flameproof
- gel coating
- coating resin
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- 229920005989 resin Polymers 0.000 title claims abstract description 61
- 239000011347 resin Substances 0.000 title claims abstract description 61
- 239000011248 coating agent Substances 0.000 title claims abstract description 35
- 238000000576 coating method Methods 0.000 title claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 39
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 21
- 229920001577 copolymer Polymers 0.000 claims abstract description 19
- 239000000835 fiber Substances 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 19
- 239000002184 metal Substances 0.000 claims abstract description 19
- 150000003839 salts Chemical class 0.000 claims abstract description 19
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 19
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims abstract description 17
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004615 ingredient Substances 0.000 claims abstract description 16
- 229940005657 pyrophosphoric acid Drugs 0.000 claims abstract description 16
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 8
- 238000004898 kneading Methods 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 claims 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- 229920003192 poly(bis maleimide) Polymers 0.000 claims 3
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract description 8
- 150000002366 halogen compounds Chemical class 0.000 abstract description 5
- 239000002341 toxic gas Substances 0.000 abstract description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 229920006305 unsaturated polyester Polymers 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- QBWKPGNFQQJGFY-QLFBSQMISA-N 3-[(1r)-1-[(2r,6s)-2,6-dimethylmorpholin-4-yl]ethyl]-n-[6-methyl-3-(1h-pyrazol-4-yl)imidazo[1,2-a]pyrazin-8-yl]-1,2-thiazol-5-amine Chemical group N1([C@H](C)C2=NSC(NC=3C4=NC=C(N4C=C(C)N=3)C3=CNN=C3)=C2)C[C@H](C)O[C@H](C)C1 QBWKPGNFQQJGFY-QLFBSQMISA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- OJRUSAPKCPIVBY-KQYNXXCUSA-N C1=NC2=C(N=C(N=C2N1[C@H]3[C@@H]([C@@H]([C@H](O3)COP(=O)(CP(=O)(O)O)O)O)O)I)N Chemical group C1=NC2=C(N=C(N=C2N1[C@H]3[C@@H]([C@@H]([C@H](O3)COP(=O)(CP(=O)(O)O)O)O)O)I)N OJRUSAPKCPIVBY-KQYNXXCUSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical group OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of halogen-free flameproof gel coating resin, the present invention relates to resin processing and fabricating technical fields；It is made of following parts by weight ingredient：50 80 parts of vistanex, 50 80 parts of barium sulfate, 30 50 parts of silica, 10 20 parts of bimaleimide resin, 10 30 parts of polyepoxides, 50 80 parts of benzoxazine colophony, 5 15 parts of pyrophosphoric acid metal salt, 1 10 parts of fibre reinforced materials, 1 15 parts of ethylene octene copolymer.It can solve the generation of toxic gas caused by halogen compounds existing for anti-flammability unsaturated polyester resin at present on the market, greatly improve its safety, expand its scope of application, practicability is stronger.
Description
Technical field
The present invention relates to resin processing and fabricating technical fields, and in particular to a kind of halogen-free flameproof gel coating resin.
Background technology
Gel coating resin is the special resin for making glass fiber reinforced plastics product gel coating resin, is a specialty goods in unsaturated polyester (UP)
Kind, it is mainly used for the surface of resin, is in successional covering thin layer, thickness is generally 0.4 mm or so.Gel coating resin
Mainly obtained through mixing dispersion using unsaturated polyester resin as matrix resin, using aerosil as thixotropic agent；
In order to improve the performance of gel coating resin, some auxiliary agents are usually also added.Since unsaturated polyester resin is combustible material,
A large amount of heat is released in combustion process, and generates dense smoke, release poisonous gas, becomes the hidden danger of fire generation, therefore is ground
System exploitation anti-flammability unsaturated polyester (UP) gel coating resin is of great immediate significance.
It is proposed several flame-retardant type unsaturated polyester resins in the market in recent years, but contains in most of unsaturated polyester resins
Halogen compounds can discharge toxic gas at high temperature, and prodigious office is had in the use of public transport and structure material
It is sex-limited, it would be highly desirable to improve.
Invention content
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of ingredient is simple, reasonable design
Halogen-free flameproof gel coating resin can solve halogen compounds institute existing for anti-flammability unsaturated polyester resin at present on the market
The generation of the toxic gas brought greatly improves its safety, expands its scope of application, and practicability is stronger.
To achieve the above object, the technical solution adopted by the present invention is：It is made of following parts by weight ingredient：Polyolefin tree
50-80 parts of fat, 50-80 parts of barium sulfate, 30-50 parts of silica, 10-20 parts of bimaleimide resin, polyepoxides 10-
30 parts, 50-80 parts of benzoxazine colophony, 5-15 parts of pyrophosphoric acid metal salt, 1-10 parts of fibre reinforced materials, ethylene octene copolymer
1-15 parts.
Further, the halogen-free flameproof gel coating resin, is made of following parts by weight ingredient：Vistanex 50-
70 parts, 50-70 parts of barium sulfate, 30-40 parts of silica, 10-15 parts of bimaleimide resin, 10-20 parts of polyepoxides,
50-60 parts of benzoxazine colophony, 5-10 parts of pyrophosphoric acid metal salt, 1-5 parts of fibre reinforced materials, ethylene octene copolymer 1-10
Part.
Further, the halogen-free flameproof gel coating resin, is made of following parts by weight ingredient：Vistanex 70-
80 parts, 70-80 parts of barium sulfate, 40-50 parts of silica, 15-20 parts of bimaleimide resin, 20-30 parts of polyepoxides,
60-80 parts of benzoxazine colophony, 10-15 parts of pyrophosphoric acid metal salt, 5-10 parts of fibre reinforced materials, ethylene octene copolymer 10-
15 parts.
Further, the halogen-free flameproof gel coating resin, is made of following parts by weight ingredient：Vistanex 55
Part, 55 parts of barium sulfate, 35 parts of silica, 12 parts of bimaleimide resin, 15 parts of polyepoxides, benzoxazine colophony 60
Part, 12 parts of pyrophosphoric acid metal salt, 5 parts of fibre reinforced materials, 12 parts of ethylene octene copolymer.
The preparation method of heretofore described halogen-free flameproof gel coating resin is as follows：
1, by the vistanex of parts by weight, barium sulfate, silica, bimaleimide resin, polyepoxides, Ben Bing Evil
Piperazine resin, pyrophosphoric acid metal salt, fibre reinforced materials, ethylene octene copolymer are added to be mixed in kneading machine and be kneaded；
2, the mixture after mixing is sent into high speed dispersor dispersion mixing processing to get to above-mentioned halogen-free flameproof gel coat tree
Fat.
Further, the melting temperature of the kneading machine in the step 1 is 120-150 DEG C, mixing time 5-10h.
Further, the rotating speed of the high speed dispersor in the step 2 is 1500-2000r/min, which can protect
The generation of bubble during card mixed processing.
The present invention has the beneficial effect that：A kind of halogen-free flameproof gel coating resin of the present invention, can solve current market
On anti-flammability unsaturated polyester resin existing for toxic gas caused by halogen compounds generation, greatly improve its safety
Property, expand its scope of application, the advantages that practicability is stronger, and the present invention has ingredient simple, and setting is reasonable, low manufacture cost.
Specific implementation mode
Specific implementation mode（Embodiment one）, the halogen-free flameproof gel coating resin described in present embodiment, by as follows
Parts by weight ingredient forms：50 parts of vistanex, 50 parts of barium sulfate, 30 parts of silica, 10 parts of bimaleimide resin, polycyclic
10 parts of oxygen compound, 50 parts of benzoxazine colophony, 5 parts of pyrophosphoric acid metal salt, 1 part of fibre reinforced materials, ethylene octene copolymer 1
Part.
The preparation method of halogen-free flameproof gel coating resin described in present embodiment is as follows：
1, by 50 parts of vistanex, 50 parts of barium sulfate, 30 parts of silica, 10 parts of bimaleimide resin, poly- epoxy compound
1 part of 10 parts of object, 50 parts of benzoxazine colophony, 5 parts of pyrophosphoric acid metal salt, 1 part of fibre reinforced materials, ethylene octene copolymer addition
It is mixed and is kneaded in kneading machine（Melting temperature is 125 DEG C, mixing time 5h）；
2, the mixture after mixing dispersion mixing in high speed dispersor is sent into handle（Rotating speed is 1550r/min）To get to upper
State halogen-free flameproof gel coating resin.
Present embodiment has the beneficial effect that：A kind of halogen-free flameproof gel coating resin described in present embodiment,
It can solve the production of toxic gas caused by halogen compounds existing for anti-flammability unsaturated polyester resin at present on the market
It is raw, its safety is greatly improved, its scope of application is expanded, practicability is stronger, and the present invention has ingredient simple, and setting is reasonable, system
Make the advantages such as cost is low.
Embodiment two：
Halogen-free flameproof gel coating resin described in the present embodiment, is made of following parts by weight ingredient：70 parts of vistanex, sulphur
70 parts of sour barium, 40 parts of silica, 15 parts of bimaleimide resin, 20 parts of polyepoxides, 60 parts of benzoxazine colophony, coke
10 parts of phosphate metal salt, 5 parts of fibre reinforced materials, 10 parts of ethylene octene copolymer.
The preparation method of halogen-free flameproof gel coating resin described in present embodiment is as follows：
1, by 70 parts of vistanex, 70 parts of barium sulfate, 40 parts of silica, 15 parts of bimaleimide resin, poly- epoxy compound
20 parts of object, 60 parts of benzoxazine colophony, 10 parts of pyrophosphoric acid metal salt, 5 parts of fibre reinforced materials, 10 parts of ethylene octene copolymer.
It is added to be mixed in kneading machine and be kneaded（Melting temperature is 130 DEG C, mixing time 6h）；
2, the mixture after mixing dispersion mixing in high speed dispersor is sent into handle（Rotating speed is 2000r/min）To get to upper
State halogen-free flameproof gel coating resin.
Embodiment three：
Halogen-free flameproof gel coating resin described in the present embodiment, is made of following parts by weight ingredient：77 parts of vistanex, sulphur
77 parts of sour barium, 45 parts of silica, 18 parts of bimaleimide resin, 25 parts of polyepoxides, 68 parts of benzoxazine colophony, coke
15 parts of phosphate metal salt, 8 parts of fibre reinforced materials, 13 parts of ethylene octene copolymer.
The preparation method of halogen-free flameproof gel coating resin described in present embodiment is as follows：
1, by 77 parts of vistanex, 77 parts of barium sulfate, 45 parts of silica, 18 parts of bimaleimide resin, poly- epoxy compound
25 parts of object, 68 parts of benzoxazine colophony, 15 parts of pyrophosphoric acid metal salt, 8 parts of fibre reinforced materials, 13 parts of ethylene octene copolymer.
It is added to be mixed in kneading machine and be kneaded（Melting temperature is 145 DEG C, mixing time 6h）；
2, the mixture after mixing dispersion mixing in high speed dispersor is sent into handle（Rotating speed is 1800r/min）To get to upper
State halogen-free flameproof gel coating resin.
Example IV：
Halogen-free flameproof gel coating resin described in the present embodiment, is made of following parts by weight ingredient：55 parts of vistanex, sulphur
55 parts of sour barium, 35 parts of silica, 12 parts of bimaleimide resin, 15 parts of polyepoxides, 60 parts of benzoxazine colophony, coke
12 parts of phosphate metal salt, 5 parts of fibre reinforced materials, 12 parts of ethylene octene copolymer.
The preparation method of halogen-free flameproof gel coating resin described in present embodiment is as follows：
1, by 55 parts of vistanex, 55 parts of barium sulfate, 35 parts of silica, 12 parts of bimaleimide resin, poly- epoxy compound
15 parts of object, 60 parts of benzoxazine colophony, 12 parts of pyrophosphoric acid metal salt, 5 parts of fibre reinforced materials, 12 parts of ethylene octene copolymer add
Enter to be mixed in kneading machine and be kneaded（Melting temperature is 138 DEG C, mixing time 8h）；
2, the mixture after mixing dispersion mixing in high speed dispersor is sent into handle（Rotating speed is 1900r/min）To get to upper
State halogen-free flameproof gel coating resin.
The above is merely illustrative of the technical solution of the present invention and unrestricted, and those of ordinary skill in the art are to this hair
The other modifications or equivalent replacement that bright technical solution is made, as long as it does not depart from the spirit and scope of the technical scheme of the present invention,
It is intended to be within the scope of the claims of the invention.
Claims (7)
1. a kind of halogen-free flameproof gel coating resin, it is characterised in that：It is made of following parts by weight ingredient：Vistanex 50-80
Part, 50-80 parts of barium sulfate, 30-50 parts of silica, 10-20 parts of bimaleimide resin, 10-30 parts of polyepoxides, benzene
50-80 parts of Bing oxazine resins, 5-15 parts of pyrophosphoric acid metal salt, 1-10 parts of fibre reinforced materials, 1-15 parts of ethylene octene copolymer.
2. a kind of halogen-free flameproof gel coating resin according to claim 1, it is characterised in that：The halogen-free flameproof gel coat tree
Fat is made of following parts by weight ingredient：50-70 parts of vistanex, 50-70 parts of barium sulfate, 30-40 parts of silica, span
10-15 parts of bismaleimide resin, 10-20 parts of polyepoxides, 50-60 parts of benzoxazine colophony, pyrophosphoric acid metal salt 5-10
Part, 1-5 parts of fibre reinforced materials, 1-10 parts of ethylene octene copolymer.
3. a kind of halogen-free flameproof gel coating resin according to claim 1, it is characterised in that：The halogen-free flameproof gel coat tree
Fat is made of following parts by weight ingredient：70-80 parts of vistanex, 70-80 parts of barium sulfate, 40-50 parts of silica, span
15-20 parts of bismaleimide resin, 20-30 parts of polyepoxides, 60-80 parts of benzoxazine colophony, pyrophosphoric acid metal salt 10-15
Part, 5-10 parts of fibre reinforced materials, 10-15 parts of ethylene octene copolymer.
4. a kind of halogen-free flameproof gel coating resin according to claim 1, it is characterised in that：The halogen-free flameproof gel coat tree
Fat is made of following parts by weight ingredient：55 parts of vistanex, 55 parts of barium sulfate, 35 parts of silica, bismaleimide tree
12 parts of fat, 15 parts of polyepoxides, 60 parts of benzoxazine colophony, 12 parts of pyrophosphoric acid metal salt, 5 parts of fibre reinforced materials, second
12 parts of alkene octene copolymer.
5. a kind of halogen-free flameproof gel coating resin according to claim 1, it is characterised in that：Its preparation method is as follows：
(1), by the vistanex of parts by weight, barium sulfate, silica, bimaleimide resin, polyepoxides, benzo
Oxazine resin, pyrophosphoric acid metal salt, fibre reinforced materials, ethylene octene copolymer are added to be mixed in kneading machine and be kneaded；
(2), the mixture after mixing is sent into high speed dispersor dispersion mixing processing to get to above-mentioned halogen-free flameproof gel coat tree
Fat.
6. a kind of halogen-free flameproof gel coating resin according to claim 5, it is characterised in that：It is mixed in the step (1)
The melting temperature of mill is 120-150 DEG C, mixing time 5-10h.
7. a kind of halogen-free flameproof gel coating resin according to claim 51, it is characterised in that：Height in the step (2)
The rotating speed of fast dispersion machine is 1500-2000r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810238545.4A CN108485020A (en) | 2018-03-22 | 2018-03-22 | A kind of halogen-free flameproof gel coating resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810238545.4A CN108485020A (en) | 2018-03-22 | 2018-03-22 | A kind of halogen-free flameproof gel coating resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108485020A true CN108485020A (en) | 2018-09-04 |
Family
ID=63318988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810238545.4A Pending CN108485020A (en) | 2018-03-22 | 2018-03-22 | A kind of halogen-free flameproof gel coating resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108485020A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834168A (en) * | 2014-02-25 | 2014-06-04 | 广东生益科技股份有限公司 | Halogen-free flame retardant type resin composition |
| CN107513209A (en) * | 2016-06-16 | 2017-12-26 | 汉达精密电子(昆山)有限公司 | Halogen-free polypropylene flame redardant resin combination and its products formed |
-
2018
- 2018-03-22 CN CN201810238545.4A patent/CN108485020A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834168A (en) * | 2014-02-25 | 2014-06-04 | 广东生益科技股份有限公司 | Halogen-free flame retardant type resin composition |
| CN107513209A (en) * | 2016-06-16 | 2017-12-26 | 汉达精密电子(昆山)有限公司 | Halogen-free polypropylene flame redardant resin combination and its products formed |
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Application publication date: 20180904 |