CN108484978A - A kind of slag with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler - Google Patents
A kind of slag with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler Download PDFInfo
- Publication number
- CN108484978A CN108484978A CN201810358660.5A CN201810358660A CN108484978A CN 108484978 A CN108484978 A CN 108484978A CN 201810358660 A CN201810358660 A CN 201810358660A CN 108484978 A CN108484978 A CN 108484978A
- Authority
- CN
- China
- Prior art keywords
- slag
- silica fume
- mixed
- rubber
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
- C08K11/005—Waste materials, e.g. treated or untreated sewage sludge
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Abstract
The invention discloses a kind of slag SILICA FUME compounded rubber filler and preparation method thereof with the fire-retardant synergisticing performance of reinforcement, belongs to solid waste resource circulation utilization field.The filler includes water, silane coupling agent, slag and SILICA FUME.The preparation method of above-mentioned filler is：Water is mixed with silane coupling agent first, is disperseed, silane coupler solution is obtained；Then slag is mixed with SILICA FUME, it is stirred, obtain slag SILICA FUME mixture；Slag SILICA FUME mixture is mixed with silane coupler solution finally, is stirred, slag SILICA FUME compounded rubber filler is obtained.The present invention not only solves the higher price of rubber industry main stuffing carbon black and white carbon and has a single function, and improves the mechanical property and flame retardant property of rubber；And recycling for industrial waste is realized, smelter synergy, rubber product industry cost declining are promoted, the industry development requirement of current energy conservation and environmental protection, circular economy is met.
Description
Technical field
The invention belongs to solid waste resource circulation utilization fields, and in particular to a kind of steel with the fire-retardant synergisticing performance of reinforcement-
Slag-SILICA FUME compounded rubber filler and preparation method thereof.
Background technology
Slag is the solid waste generated in steelmaking process, accounts for about the 15%~20% of steel-making yield.Slag mainly by
The oxide composition of calcium, iron, silicon, magnesium and a small amount of aluminium, manganese, phosphorus etc., i.e. SiO2、Fe2O3、Al2O3、ZnO、CaO、MgO、P2O5、
MnO、SO3Deng also containing free calcium oxide and metallic iron etc..SILICA FUME is ferroalloy in smelting duriron and industrial silicon (gold
Belong to silicon) when, the very strong SiO of a large amount of volatility is produced in ore-smelting electric furnace2With Si gases, gas discharge after with air rapid oxidation
Condensation precipitates.A large amount of stockpilings of slag and SILICA FUME at present, do not only take up valuable soil, and to ambient enviroment and underground
Water pollutes.Therefore, how on a large scale, efficiently utilize slag and SILICA FUME, realize environment Reduction of Students' Study Load, reducing enterprise cost is one
A problem in the urgent need to address.
Rubber needs largely using filler to improve as widely applied polymer material in preparing process
Its mechanical property, processing performance and filling increase-volume.Currently used gum filler is mainly including carbon black, white carbon etc., still
The production of carbon black and white carbon not only cumbersome, but also need to consume mass energy and resource, cause cost higher.In face of upper
Problem is stated, it is potential reinforced filling that there is slag high alkalinity, which to belong to porous mass with SILICA FUME,；The alkalinity of slag is right simultaneously
SILICA FUME has the effect of concerted reaction, and SILICA FUME is contributed to form fine and close fire-retardant unformed silicrete, is potential fire-retardant
Filler.
Invention content
In order to solve the higher price of existing rubber industry main stuffing carbon black and white carbon and have a single function, slag with it is micro-
Silica flour is directly added into easily reunites and the compatibility at slag-SILICA FUME inorganic interface and rubber organic interface in rubber
Poor problem, the present invention provides a kind of slag with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler, with
Phase solves problem above.
The present invention is achieved by the following technical programs.
The present invention provides a kind of slag with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler, the steel
Slag-SILICA FUME compounded rubber filler is formulated as follows by weight percentage：
The water is deionized water；The silane coupling agent is technical pure；The slag is desulfurizing iron tailings, more than casting
Slag, converter hot splashing slag, converter drum slag, electric furnace hot splashing slag, electric furnace roller slag and its mixture, grain size be 2.0 μm~
120.0μm；The SILICA FUME, grain size are 6.5 μm~43.8 μm.
Invention also provides the preparation method of above-mentioned slag-SILICA FUME compounded rubber filler, which includes
Following steps：
Water is mixed with silane coupling agent first, it is carried out using ultrasonic disperser dispersion 15min~
35min obtains silane coupler solution；Then slag is mixed with SILICA FUME, using constant temperature blender with magnetic force in room temperature
It is closed it is lower 7h~10h is stirred to it, obtain slag-SILICA FUME mixture；Finally by slag-SILICA FUME mixture and silane
Coupling agent solution is mixed, and using constant temperature blender with magnetic force at 60 DEG C~80 DEG C of whipping temp, is stirred 2h~4h, is obtained steel
Slag-SILICA FUME compounded rubber filler.
The principles of science of the present invention：
On the one hand, slag can improve the contact area with rubber with the porous structure that SILICA FUME all has, and reach reinforcement
Effect.The alkalinity of slag has the effect of concerted reaction to SILICA FUME, and SILICA FUME is contributed to form fine and close unformed silicrete,
Reach flame retardant effect.
On the other hand, silane coupler solution is modified processing to slag-SILICA FUME mixture surface, forms slag-
SILICA FUME compounded rubber filler, the drawback for overcoming the inorganic interface of slag-SILICA FUME poor with the compatibility of rubber organic interface, into
One step improves reinforcing effect.
Moreover, because slag-SILICA FUME is filled in rubber by slag as overbased material, rubber sulphur can be accelerated
Change speed.
Compared with prior art, the present invention has the following technical effects：
1, the present invention solves existing rubber industry main stuffing carbon black and the higher price of white carbon has a single function, slag
It is directly added into and easily reunites in rubber and the phase at slag-SILICA FUME inorganic interface and rubber organic interface with SILICA FUME
The poor problem of capacitive.
2, the present invention is carried out compound as gum filler using slag and SILICA FUME, is not only solved rubber industry and is mainly filled out
The higher price for expecting carbon black and white carbon, improves the mechanical property and flame retardant property of rubber；And realize industrial waste
It recycles, promotes smelter synergy, rubber product industry cost declining, meet the production of current energy conservation and environmental protection, circular economy
Industry demand for development.
Specific implementation mode
The present invention is described in detail below in conjunction with specific embodiment, but the present invention is not limited to following embodiments.
One, a kind of preparation of the slag with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler of the present invention
Embodiment 1
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure；The slag is desulfurizing iron tailings, grain size
It is 5.6 μm~110.4 μm；The SILICA FUME, grain size are 6.8 μm~35.2 μm.
Water is mixed with silane coupling agent first, dispersion 20min is carried out to it using ultrasonic disperser, obtains silicon
Alkane coupling agent solution；Then slag is mixed with SILICA FUME, using constant temperature blender with magnetic force room temperature it is closed it is lower to its into
Row stirring 9h, obtains slag-SILICA FUME mixture；Finally slag-SILICA FUME mixture is mixed with silane coupler solution
It closes, using constant temperature blender with magnetic force at 65 DEG C of whipping temp, stirs 4h, obtain slag-SILICA FUME compounded rubber filler.
Embodiment 2
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure；The slag is casting residue, and grain size is 4.5 μ
M~104.2 μm；The SILICA FUME, grain size are 7.8 μm~42.1 μm.
Water is mixed with silane coupling agent first, dispersion 30min is carried out to it using ultrasonic disperser, obtains silicon
Alkane coupling agent solution；Then slag is mixed with SILICA FUME, using constant temperature blender with magnetic force room temperature it is closed it is lower to its into
Row stirring 7h, obtains slag-SILICA FUME mixture；Finally slag-SILICA FUME mixture is mixed with silane coupler solution
It closes, using constant temperature blender with magnetic force at 75 DEG C of whipping temp, stirs 3h, obtain slag-SILICA FUME compounded rubber filler.
Embodiment 3
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure；The slag is converter hot splashing slag, and grain size is
2.6 μm~92.1 μm；The SILICA FUME, grain size are 8.3 μm~43.1 μm.
Water is mixed with silane coupling agent first, dispersion 25min is carried out to it using ultrasonic disperser, obtains silicon
Alkane coupling agent solution；Then slag is mixed with SILICA FUME, using constant temperature blender with magnetic force room temperature it is closed it is lower to its into
Row stirring 10h, obtains slag-SILICA FUME mixture；Finally slag-SILICA FUME mixture is mixed with silane coupler solution
It closes, using constant temperature blender with magnetic force at 60 DEG C of whipping temp, stirs 3h, obtain slag-SILICA FUME compounded rubber filler.
Embodiment 4
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure；The slag is converter drum slag and electric furnace heat
The mass fraction ratio of bold and vigorous slag, converter drum slag and electric furnace hot splashing slag is 50：50, grain size is 3.9 μm~115.2 μm；It is described micro-
Silica flour, grain size are 8.2 μm~36.5 μm.
Water is mixed with silane coupling agent first, dispersion 35min is carried out to it using ultrasonic disperser, obtains silicon
Alkane coupling agent solution；Then slag is mixed with SILICA FUME, using constant temperature blender with magnetic force room temperature it is closed it is lower to its into
Row stirring 8h, obtains slag-SILICA FUME mixture；Finally slag-SILICA FUME mixture is mixed with silane coupler solution
It closes, using constant temperature blender with magnetic force at 80 DEG C of whipping temp, stirs 2h, obtain slag-SILICA FUME compounded rubber filler.
Embodiment 5
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure；The slag is that electric furnace hot splashing slag is rolled with electric furnace
The mass fraction ratio of cylinder slag, electric furnace hot splashing slag and electric furnace roller slag is 50: 50, and grain size is 4.5 μm~116.6 μm；It is described micro-
Silica flour, grain size are 8.9 μm~42.9 μm.
Water is mixed with silane coupling agent first, dispersion 15min is carried out to it using ultrasonic disperser, obtains silicon
Alkane coupling agent solution；Then slag is mixed with SILICA FUME, using constant temperature blender with magnetic force room temperature it is closed it is lower to its into
Row stirring 9h, obtains slag-SILICA FUME mixture；Finally slag-SILICA FUME mixture is mixed with silane coupler solution
It closes, using constant temperature blender with magnetic force at 70 DEG C of whipping temp, stirs 4h, obtain slag-SILICA FUME compounded rubber filler.
Embodiment 6
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure；The slag is desulfurizing iron tailings, casting residue
Mass fraction ratio with converter hot splashing slag, desulfurizing iron tailings, casting residue and converter hot splashing slag is 30: 40: 30, and grain size is
3.1 μm~113.6 μm；The SILICA FUME, grain size are 7.4 μm~43.2 μm.
Water is mixed with silane coupling agent first, dispersion 30min is carried out to it using ultrasonic disperser, obtains silicon
Alkane coupling agent solution；Then slag is mixed with SILICA FUME, using constant temperature blender with magnetic force room temperature it is closed it is lower to its into
Row stirring 8h, obtains slag-SILICA FUME mixture；Finally slag-SILICA FUME mixture is mixed with silane coupler solution
It closes, using constant temperature blender with magnetic force at 75 DEG C of whipping temp, stirs 3h, obtain slag-SILICA FUME compounded rubber filler.
Comparative example 1
Component used and its quality proportioning are for preparing product 100g of the present invention：
The slag is desulfurizing iron tailings, casting residue and converter hot splashing slag, desulfurizing iron tailings, casting residue and converter heat
The mass fraction ratio for sprinkling slag is 30: 40: 30, and grain size is 3.1 μm~113.6 μm；The SILICA FUME, grain size be 7.4 μm~
43.2μm。
Slag is mixed with SILICA FUME, using constant temperature blender with magnetic force room temperature it is closed it is lower 8h is stirred to it,
Obtain slag-SILICA FUME compounded rubber filler.
Comparative example 2
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The slag is desulfurizing iron tailings, casting residue and converter hot splashing slag, desulfurizing iron tail
The mass fraction ratio of slag, casting residue and converter hot splashing slag is 30: 40: 30, and grain size is 3.1 μm~113.6 μm；Micro- silicon
Powder, grain size are 7.4 μm~43.2 μm.
Slag is mixed with SILICA FUME first, lower it is stirred using constant temperature blender with magnetic force room temperature is closed
8h obtains slag-SILICA FUME mixture；Slag-SILICA FUME mixture is mixed with water finally, utilizes temperature constant magnetic stirring
Device stirs 3h, obtains slag-SILICA FUME compounded rubber filler at 75 DEG C of whipping temp.
Comparative example 3
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure；The slag is desulfurizing iron tailings, casting residue
Mass fraction ratio with converter hot splashing slag, desulfurizing iron tailings, casting residue and converter hot splashing slag is 30: 40: 30, and grain size is
3.1 μm~113.6 μm.
Water is mixed with silane coupling agent first, dispersion 30min is carried out to it using ultrasonic disperser, obtains silicon
Alkane coupling agent solution；Then slag is mixed with silane coupler solution, using constant temperature blender with magnetic force in whipping temp
At 75 DEG C, 3h is stirred, slag gum filler is obtained.
Comparative example 4
Component used and its quality proportioning are for preparing product 100g of the present invention：
The water is deionized water；The silane coupling agent is technical pure.
Water is mixed with silane coupling agent, dispersion 30min is carried out to it using ultrasonic disperser, obtains silane idol
Join agent solution.
Two, the Mechanics Performance Testing after slag of the present invention-SILICA FUME compounded rubber filler addition rubber and flame retardant property are surveyed
Examination
Examples 1 to 6 and comparative example 1~4 are prepared, performance testing process is as follows：
After butadiene-styrene rubber (100 parts) is put into thin logical 3~5 times of open mill, mixer (smelting temperature is added in butadiene-styrene rubber
70 DEG C) it is kneaded 3min, it sequentially adds zinc oxide (2.5 parts) aggregate sample and is kneaded 1min, carbon black (25 parts) and slag-SILICA FUME is added
Compounded rubber filler (25 parts) aggregate sample is kneaded after (1.5 parts) of 1min, addition accelerating agent (1.0 parts) and sulphur are kneaded 1min and takes out
It is spare, i.e. mixing glue；It is logical 6~8 times thin that mixing glue is put into open mill, beats after triangle bag 5 times after parking 12h, weighs the close of 60g
Refining glue is vulcanized using four-column type vulcanizing press, and curing temperature is 145 DEG C, and vulcanization is placed for 24 hours after a certain period of time, is obtained
The compound butadiene-styrene rubber of slag-SILICA FUME.
《The measurement of vulcanized rubber or thermoplastic elastomer tensile stress-strain performance》(GB/T528-2009) test slag-is micro-
The tensile property of the compound butadiene-styrene rubber of silica flour；《The measurement of vulcanized rubber or thermoplastic elastomer tearing strength is (pants type, square, new
Month shape sample)》(GB/T529-2008) tearing strength of the compound butadiene-styrene rubber of slag-SILICA FUME is tested；《Vulcanized rubber or thermoplastic
Property rubber penetration hardness test method part 1：Shore durometer method (Shao Er hardness)》Test the compound butylbenzene of slag-SILICA FUME
The hardness of rubber；《Plastics Combustion method for testing performance oxygen index method》(GB/T2406-1993) slag-SILICA FUME composite T is tested
The limit oxygen index (LOI) of benzene rubber；《Equipment and device plastic material combustibility test method UL94》(ISBN 0-7629-
0082-2) test the vertical combustion rank of the compound butadiene-styrene rubber of slag-SILICA FUME.
The mechanical property and flame retardant property of the compound butadiene-styrene rubber of 1. slags of table-SILICA FUME
After natural rubber (100 parts) is put into thin logical 1~3 time of open mill, mixer (smelting temperature is added in natural rubber
70 DEG C) it is kneaded 3min, it sequentially adds zinc oxide (6.0 parts) aggregate sample and is kneaded 1min, carbon black (25 parts) and slag-SILICA FUME is added
Compounded rubber filler (25 parts) aggregate sample is kneaded after (2.5 parts) of 1min, addition accelerating agent (0.5 part) and sulphur are kneaded 1min and takes out
It is spare, i.e. mixing glue；It is logical 2~4 times thin that mixing glue is put into open mill, beats after triangle bag 3 times after parking 12h, weighs the close of 60g
Refining glue is vulcanized using four-column type vulcanizing press, and curing temperature is 145 DEG C, and vulcanization is placed for 24 hours after a certain period of time, is obtained
Slag-SILICA FUME composite natral rubber
《The measurement of vulcanized rubber or thermoplastic elastomer tensile stress-strain performance》(GB/T528-2009) test slag-is micro-
The tensile property of silica flour composite natral rubber；《The measurement of vulcanized rubber or thermoplastic elastomer tearing strength is (pants type, square, new
Month shape sample)》(GB/T529-2008) tearing strength of slag-SILICA FUME composite natral rubber is tested；《Vulcanized rubber or thermoplastic
Property rubber penetration hardness test method part 1：Shore durometer method (Shao Er hardness)》Test slag-SILICA FUME composite natral
The hardness of rubber；《Plastics Combustion method for testing performance oxygen index method》(GB/T2406-1993) the compound day of test slag-SILICA FUME
The limit oxygen index (LOI) of T PNR；《Equipment and device plastic material combustibility test method UL94》(ISBN 0-7629-
0082-2) test the vertical combustion rank of slag-SILICA FUME composite natral rubber.
The mechanical property and flame retardant property of 2. slags of table-SILICA FUME composite natral rubber
Claims (2)
1. a kind of slag with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler, which is characterized in that by weight hundred
Divide than meter, the slag-SILICA FUME compounded rubber filler composition is as follows：
The water is deionized water；The silane coupling agent is technical pure；The slag is desulfurizing iron tailings, casting residue, turns
Stove hot splashing slag, converter drum slag, electric furnace hot splashing slag, electric furnace roller slag it is one or more, grain size be 2.0 μm~120.0 μm；
The SILICA FUME, grain size are 6.5 μm~43.8 μm.
2. a kind of preparation of slag-SILICA FUME compounded rubber filler with the fire-retardant synergisticing performance of reinforcement-as described in claim 1
Method, it is characterised in that include the following steps：
Water is mixed with silane coupling agent first, dispersion 15min~35min is carried out to it using ultrasonic disperser, is obtained
To silane coupler solution；Then slag is mixed with SILICA FUME, it is closed lower right in room temperature using constant temperature blender with magnetic force
It is stirred 7h~10h, obtains slag-SILICA FUME mixture；It is finally that slag-SILICA FUME mixture and silane coupling agent is molten
Liquid is mixed, and using constant temperature blender with magnetic force at 60 DEG C~80 DEG C of whipping temp, is stirred 2h~4h, is obtained the micro- silicon of slag-
Powder compounded rubber filler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810358660.5A CN108484978B (en) | 2018-04-19 | 2018-04-19 | Steel slag-micro silicon powder composite rubber filler with reinforcing-flame-retardant synergistic performance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810358660.5A CN108484978B (en) | 2018-04-19 | 2018-04-19 | Steel slag-micro silicon powder composite rubber filler with reinforcing-flame-retardant synergistic performance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108484978A true CN108484978A (en) | 2018-09-04 |
| CN108484978B CN108484978B (en) | 2019-12-27 |
Family
ID=63312759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810358660.5A Active CN108484978B (en) | 2018-04-19 | 2018-04-19 | Steel slag-micro silicon powder composite rubber filler with reinforcing-flame-retardant synergistic performance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108484978B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110643074A (en) * | 2019-11-04 | 2020-01-03 | 安徽工业大学 | Reinforcing, flame-retardant and wear-resistant all-industrial solid waste type composite rubber filler and preparation method thereof |
| WO2022233032A1 (en) * | 2021-05-07 | 2022-11-10 | 德州学院 | Method for preparing composite pigment and filler for coating by using silica fume |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106543487A (en) * | 2015-09-16 | 2017-03-29 | 上海中冶环境工程科技有限公司 | A kind of rubber using slag micro powder as rubber filler |
| CN106893139A (en) * | 2017-03-30 | 2017-06-27 | 安徽工业大学 | A kind of modified porous slag for gum filler and preparation method thereof |
| JP6183256B2 (en) * | 2014-03-19 | 2017-08-23 | 三菱マテリアル株式会社 | Rubber composition and rubber molded body |
| CN107501611A (en) * | 2017-09-19 | 2017-12-22 | 安徽工业大学 | A kind of slag red mud compounded rubber filler with the fire-retardant synergisticing performance of reinforcement |
-
2018
- 2018-04-19 CN CN201810358660.5A patent/CN108484978B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6183256B2 (en) * | 2014-03-19 | 2017-08-23 | 三菱マテリアル株式会社 | Rubber composition and rubber molded body |
| CN106543487A (en) * | 2015-09-16 | 2017-03-29 | 上海中冶环境工程科技有限公司 | A kind of rubber using slag micro powder as rubber filler |
| CN106893139A (en) * | 2017-03-30 | 2017-06-27 | 安徽工业大学 | A kind of modified porous slag for gum filler and preparation method thereof |
| CN107501611A (en) * | 2017-09-19 | 2017-12-22 | 安徽工业大学 | A kind of slag red mud compounded rubber filler with the fire-retardant synergisticing performance of reinforcement |
Non-Patent Citations (1)
| Title |
|---|
| 谢刚: "《工业硅及硅铁生产》", 31 January 2016, 冶金工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110643074A (en) * | 2019-11-04 | 2020-01-03 | 安徽工业大学 | Reinforcing, flame-retardant and wear-resistant all-industrial solid waste type composite rubber filler and preparation method thereof |
| WO2022233032A1 (en) * | 2021-05-07 | 2022-11-10 | 德州学院 | Method for preparing composite pigment and filler for coating by using silica fume |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108484978B (en) | 2019-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107501611B (en) | A kind of steel slag with the fire-retardant synergisticing performance of reinforcement-- red mud compounded rubber filler | |
| CN106893139B (en) | A kind of modified porous steel slag and preparation method thereof for gum filler | |
| CN108467515A (en) | A kind of slag-composite diatomite gum filler with the fire-retardant synergisticing performance of reinforcement- | |
| Bellum et al. | Investigation on performance enhancement of fly ash-GGBFS based graphene geopolymer concrete | |
| Maslehuddin et al. | Effect of electric arc furnace dust on the properties of OPC and blended cement concretes | |
| CN109438766A (en) | A kind of modification lateritic nickel ore slag for fire-retardant reinforced rubber filler | |
| CN109293991A (en) | A kind of lateritic nickel ore slag with fire-retardant reinforcing property-ferrochrome slag compounded rubber filler | |
| CN108484983A (en) | A kind of red mud with high efficiency flame retardance-SILICA FUME compounded rubber filler and preparation method thereof | |
| CN110357548A (en) | A kind of full solid waste concrete of high-early-strength high-performance and preparation method thereof | |
| CN108410020A (en) | A kind of Desulphurization with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler | |
| CN109337118A (en) | A kind of ferrochrome slag with fire-retardant reinforcing property-red mud compounded rubber filler | |
| CN107573547B (en) | A kind of steel slag with phase-changing and temperature-regulating performance-fiber composite gum filler and preparation method thereof | |
| CN108484978A (en) | A kind of slag with the fire-retardant synergisticing performance of reinforcement-- SILICA FUME compounded rubber filler | |
| CN109337121A (en) | A kind of lateritic nickel ore slag with fire-retardant reinforcing property-red mud compounded rubber filler | |
| Feng et al. | Effects of recycled sand and nanomaterials on ultra-high performance concrete: Workability, compressive strength and microstructure | |
| Omur et al. | Characterization of ferrochrome ash and blast furnace slag based alkali-activated paste and mortar | |
| CN109534773A (en) | A kind of modified flying dust building latex material, mortar, concrete and preparation method | |
| CN109650918B (en) | Environment-friendly chromium-containing refractory castable and preparation method thereof | |
| CN109438767A (en) | A kind of montmorillonite with fire-retardant reinforcing property-ferrochrome slag compounded rubber filler | |
| CN110526604A (en) | A kind of energy saving cement and preparation method thereof | |
| CN116986849B (en) | High-strength high-wear-resistance asphalt concrete and preparation method and application thereof | |
| CN108484977A (en) | A kind of red mud with high efficiency flame retardance-composite diatomite gum filler and preparation method thereof | |
| CN109233037A (en) | A kind of modification ferrochrome slag for fire-retardant reinforced rubber filler | |
| CN106915951A (en) | A kind of environment-friendly composite mending material and preparation method thereof | |
| CN109337122A (en) | A kind of montmorillonite with fire-retardant reinforcing property-lateritic nickel ore slag compounded rubber filler |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220908 Address after: 541000 Yangtang Industrial Park, Xicheng Economic Development Zone, Guilin City, Guangxi Zhuang Autonomous Region Patentee after: GUILIN HONGCHENG MINING EQUIPMENT MANUFACTURE Co. Address before: 243002 No. 59 East Lake Road, Anhui, Ma'anshan Patentee before: ANHUI University OF TECHNOLOGY |
|
| TR01 | Transfer of patent right |