CN108483621A - A kind of optimal region and method of adjustment of determining sewage disposal multi-section water-inlet technique - Google Patents

A kind of optimal region and method of adjustment of determining sewage disposal multi-section water-inlet technique Download PDF

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CN108483621A
CN108483621A CN201810343613.3A CN201810343613A CN108483621A CN 108483621 A CN108483621 A CN 108483621A CN 201810343613 A CN201810343613 A CN 201810343613A CN 108483621 A CN108483621 A CN 108483621A
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李志华
杭朝曦
秋亮
韩冬
李姝凝
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Qinhuangdao Zhongyu Road Tongda Environmental Protection Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Abstract

本发明公开了一种确定污水处理多段进水工艺的最优区域及调整方法,包括:测量待测活性污泥的浓度,进行呼吸图谱测试,分别得到5个耗氧速率:OURs、OURq、OURe、OURen和OURenc;确定不同多段进水工艺中非好氧水力停留时间最小值、异养菌耗氧速率最小值和自养菌耗氧速率最小值;用作图软件制作关系图;将关系图分成不同区域;确定满足条件的区域为污水处理最优区域,通过非好氧水力停留时间变化调节异养菌耗氧速率和自养菌耗氧速率向最优区域靠近。该方法可以根据耗氧速率来调节运行参数,提高处理效率,为污水处理厂的优化、平稳运行及节能降耗等提供一种可行的方法。The invention discloses an optimal area and an adjustment method for determining the multi-stage water inflow process of sewage treatment, including: measuring the concentration of activated sludge to be tested, and performing a breath spectrum test to obtain five oxygen consumption rates: OURs, OURq, OURe , OURen and OURenc; determine the minimum non-aerobic hydraulic retention time, the minimum oxygen consumption rate of heterotrophic bacteria and the minimum oxygen consumption rate of autotrophic bacteria in different multi-stage influent processes; use it as a graph software to make a relationship diagram; convert the relationship diagram Divided into different areas; the area that meets the conditions is determined to be the optimal area for sewage treatment, and the oxygen consumption rate of heterotrophic bacteria and oxygen consumption rate of autotrophic bacteria are adjusted to approach the optimal area through the change of non-aerobic hydraulic retention time. The method can adjust the operating parameters according to the oxygen consumption rate, improve the treatment efficiency, and provide a feasible method for the optimization, stable operation, energy saving and consumption reduction of sewage treatment plants.

Description

一种确定污水处理多段进水工艺的最优区域及调整方法A Method for Determining the Optimal Zone and Adjustment of Multi-stage Water Inlet Process for Sewage Treatment

技术领域technical field

本发明属于污水处理领域,涉及一种通过对OUR与AHRT之间关系分析,得到污水处理多段进水工艺的最优工况区域,并通过控制AHRT进行最优调控的方法。The invention belongs to the field of sewage treatment, and relates to a method for obtaining the optimal working condition area of a multi-stage water inflow process for sewage treatment by analyzing the relationship between OUR and AHRT, and controlling the AHRT for optimal regulation.

背景技术Background technique

目前我国大部分城市生活污水都是低C/N比污水,传统的活性污泥法在处理低C/N污水时常常力不从心,面临碳源不足,运行调节复杂,费用高等问题。At present, most of the urban domestic sewage in my country is low C/N ratio sewage. The traditional activated sludge method is often unable to deal with low C/N sewage, facing problems such as insufficient carbon source, complicated operation and regulation, and high cost.

很多学者为了解决污水厂碳源不足的问题,提出了很多改进型工艺。进行优化利用碳源,同时完成脱氮和除磷的同时高效去除。但是由于工艺调节参数复杂,无法知晓在不同多段进水工艺不同进水条件下的最优参数,在实际的污水处理厂实施时存在较大的困难。因此,提出一种准确、高效的利用OUR与AHRT得到最优区域,并简单利用AHRT进行工况调节的方法,成为目前亟需解决的技术难题。In order to solve the problem of insufficient carbon sources in sewage plants, many scholars have proposed many improved processes. Optimize the use of carbon sources, and simultaneously complete the efficient removal of nitrogen and phosphorus removal. However, due to the complexity of process adjustment parameters, it is impossible to know the optimal parameters under different influent conditions of different multi-stage influent processes, and there are great difficulties in the implementation of actual sewage treatment plants. Therefore, proposing an accurate and efficient method of using OUR and AHRT to obtain the optimal area, and simply using AHRT to adjust the working conditions has become a technical problem that needs to be solved urgently.

发明内容Contents of the invention

为解决现有技术中存在的上述缺陷,本发明的目的在于提供一种利用工艺参数得到最优工况区域,控制运行参数的变化进行最优调控的方法。在不同的多段进水工艺中,通过对OUR与AHRT之间关系分析,得到不同的工况下的分布区域,并找出最优区域,通过调控AHRT的大小,影响OURc和OURn,从而进行最优调节,可用于复杂的多段进水工艺的最优调控。In order to solve the above-mentioned defects existing in the prior art, the purpose of the present invention is to provide a method for obtaining the optimal working condition area by using process parameters, and controlling the change of operating parameters for optimal regulation. In different multi-stage water inflow processes, through the analysis of the relationship between OUR and AHRT, the distribution area under different working conditions is obtained, and the optimal area is found. By adjusting the size of AHRT, OURc and OURn are affected, so as to optimize Optimal regulation, which can be used for the optimal regulation of complex multi-stage water inflow process.

本发明是通过下述技术方案来实现的。The present invention is achieved through the following technical solutions.

一种确定污水处理多段进水工艺的最优区域及调整方法,包括下述步骤:A method for determining the optimal area and adjustment of a multi-stage water inflow process for sewage treatment, comprising the following steps:

1)取未经任何处理的污水厂活性污泥;1) Take the activated sludge from the sewage plant without any treatment;

2)对污水厂活性污泥进行呼吸图谱测试,分别得到5个耗氧速率:现状耗氧速率OURs、准内源耗氧速率OURq、内源耗氧速率OURe、加氮源后耗氧速率OURen和总耗氧速率OURenc;2) The respiration spectrum test was carried out on the activated sludge of the sewage plant, and 5 oxygen consumption rates were obtained respectively: the current oxygen consumption rate OURs, the quasi-endogenous oxygen consumption rate OURq, the endogenous oxygen consumption rate OURe, and the oxygen consumption rate OURen after adding a nitrogen source and the total oxygen consumption rate OURenc;

3)确定不同的污水处理多段进水工艺中非好氧水力停留时间AHRT最小值AHRTmin、异养菌耗氧速率最小值OURcmin和自养菌耗氧速率最小值OURnmin3) Determine the minimum non-aerobic hydraulic retention time AHRT AHRT min , the minimum oxygen consumption rate of heterotrophic bacteria OURc min and the minimum oxygen consumption rate of autotrophic bacteria OURn min in different sewage treatment multi-stage influent processes;

4)以非好氧水力停留时间AHRT为X轴,以异养菌耗氧速率OURc和自养菌耗氧速率OURn分别为Y轴,用作图软件制作出关系图;4) Take the non-aerobic hydraulic retention time AHRT as the X-axis, take the oxygen consumption rate OURc of the heterotrophic bacteria and the oxygen consumption rate OURn of the autotrophic bacteria as the Y-axis respectively, and use the graph software to make a relational diagram;

5)根据非好氧水力停留时间AHRT最小值AHRTmin、异养菌耗氧速率最小值OURcmin和自养菌耗氧速率最小值OURnmin曲线将关系图分成不同区域;5) Divide the graph into different regions according to the curves of the minimum value of the non-aerobic hydraulic retention time AHRT AHRT min , the minimum value of the oxygen consumption rate of the heterotrophic bacteria OURc min and the minimum value of the oxygen consumption rate of the autotrophic bacteria OURn min ;

6)满足下述条件的区域为污水处理最优区域:6) The area that meets the following conditions is the optimal area for sewage treatment:

同时满足AHRT>AHRTmin、OURc>OURcmin、OURn>OURnmin的区域;At the same time satisfy the area of AHRT>AHRT min , OURc>OURc min , OURn>OURn min ;

7)通过控制工艺中非好氧水力停留时间AHRT的变化,调节异养菌耗氧速率OURc和自养菌耗氧速率OURn向最优区域靠近。7) By controlling the change of the non-aerobic hydraulic retention time AHRT in the process, the oxygen consumption rate OURc of heterotrophic bacteria and the oxygen consumption rate OURn of autotrophic bacteria are adjusted to approach the optimal area.

进一步,所述步骤2)中,呼吸图谱测试的具体过程为:Further, in the step 2), the specific process of the breath map test is:

取污水厂曝气池中污泥0.3L并用自来水稀释至1.2L,测定现场OURs;之后将污泥样品通过搅拌15s、沉淀10min、去上清液定容至0.6L,用缓冲溶液PBS洗泥3次,测定污泥的准内源OURq;然后用自来水将反应器内活性污泥混合液定容至1.2L,通过对污泥样品曝气2h测定其内源OURe,再加入50g/L的氯化铵测OURen=OURe+OURn,最后加入200g/L的无水乙酸钠,保证基质充足,测定总呼吸速率OURenc=OURe+OURc+OURn。Take 0.3L of sludge from the aeration tank of the sewage plant and dilute it to 1.2L with tap water to measure the OURs on site; after that, the sludge sample is stirred for 15s, settled for 10min, and the supernatant is removed to make up to 0.6L, and the sludge is washed with buffer solution PBS 3 times, the quasi-endogenous OURq of the sludge was measured; then the volume of the activated sludge mixture in the reactor was adjusted to 1.2L with tap water, and the endogenous OURe was measured by aerating the sludge sample for 2 hours, and then 50g/L of Measure OURen=OURe+OURn with ammonium chloride, and finally add 200g/L anhydrous sodium acetate to ensure sufficient matrix, and measure the total respiration rate OURenc=OURe+OURc+OURn.

进一步,所述OURc和OURn分别是异养菌呼吸速率和自养菌呼吸速率。Further, the OURc and OURn are the respiration rate of heterotrophic bacteria and respiration rate of autotrophic bacteria, respectively.

进一步,所述OURcmin应是满足活性污泥自身生长增值的最低耗氧呼吸速率;OURnmin是工艺满足最低脱氮要求时的自养菌最低耗氧呼吸速率;AHRTmin代表满足COD在厌氧和缺氧区合理利用的最低非好氧水力停留时间。Further, the OURc min should be the minimum aerobic respiration rate to meet the value -added growth of activated sludge itself; OURn min is the minimum aerobic respiration rate of autotrophic bacteria when the process meets the minimum denitrification requirements; and the minimum non-aerobic hydraulic retention time for reasonable use in the anoxic zone.

进一步,所述调控工艺中非好氧水力停留时间AHRT的方式为调整进水量、回流量及池容量。Further, the method of adjusting the non-aerobic hydraulic retention time AHRT in the process is to adjust the inflow, return flow and pool capacity.

本发明具有以下优点:The present invention has the following advantages:

1)快速准确,找出多段进水工艺工况最优运行区间。1) Quickly and accurately, find out the optimal operating range of multi-stage water inlet process conditions.

基于工艺参数OUR和AHRT的确定,能够迅速准确地判断出该工艺最佳工况区域,将偏离的工况进行工艺调控。Based on the determination of the process parameters OUR and AHRT, the optimum working condition area of the process can be quickly and accurately judged, and the deviation working condition can be adjusted for the process.

2)调控方式简单快速。2) The control method is simple and fast.

通过对工艺的运行参数进行调控,使得AHRT发生变化,使其向最优工况区域调节。By adjusting the operating parameters of the process, the AHRT changes and adjusts to the optimal working condition area.

3)经济实用,适用范围广。3) Economical and practical, with a wide range of applications.

本发明可缓解污水厂碳源不足的问题,使污水处理中多段进水工艺能够进行高效利用碳源,同时完成脱氮和除磷的同时高效去除,经济有效。The invention can alleviate the problem of insufficient carbon sources in sewage plants, enable the multi-stage water inflow process in sewage treatment to efficiently utilize carbon sources, simultaneously complete denitrification and phosphorus removal, and is economical and effective.

本发明可适用于大多数运行的污水处理中多段进水工艺,还可根据进水量、水质特性和环境条件的变化,灵活的调整进水比、回流比和池容以达到最佳工况,是一种有效帮助污水厂管理运行的方法。The present invention is applicable to the multi-stage water inflow process in most operating sewage treatment, and can also flexibly adjust the inflow ratio, reflux ratio and pool capacity according to the change of inflow volume, water quality characteristics and environmental conditions to achieve the best working condition. It is an effective method to help the management and operation of sewage plants.

附图说明Description of drawings

此处所说明的附图用来提供对本发明的进一步理解,构成本申请的一部分,并不构成对本发明的不当限定,在附图中:The accompanying drawings described here are used to provide a further understanding of the present invention, constitute a part of the application, and do not constitute an improper limitation of the present invention. In the accompanying drawings:

图1为为MAAO工艺原理图;Figure 1 is a schematic diagram of the MAAO process;

图2为MAAO工艺参数分区图。Figure 2 is a zoning diagram of MAAO process parameters.

具体实施方式Detailed ways

下面将结合附图以及具体实施例来详细说明本发明,在此本发明的示意性实施例以及说明用来解释本发明,但并不作为对本发明的限定。The present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments, where the schematic embodiments and descriptions of the present invention are used to explain the present invention, but not to limit the present invention.

本发明确定污水处理多段进水工艺的最优区域及调整方法,包括以下步骤:The present invention determines the optimal area and adjustment method of the sewage treatment multi-stage water inflow process, comprising the following steps:

1)取未经任何处理的污水厂活性污泥;1) Take the activated sludge from the sewage plant without any treatment;

2)对污水厂活性污泥进行呼吸图谱测试,分别得到5个耗氧速率:现状耗氧速率OURs、准内源耗氧速率OURq、内源耗氧速率OURe、加氮源后耗氧速率OURen和总耗氧速率OURenc;2) The respiration spectrum test was carried out on the activated sludge of the sewage plant, and 5 oxygen consumption rates were obtained respectively: the current oxygen consumption rate OURs, the quasi-endogenous oxygen consumption rate OURq, the endogenous oxygen consumption rate OURe, and the oxygen consumption rate OURen after adding a nitrogen source and the total oxygen consumption rate OURenc;

呼吸图谱测试的具体过程为:The specific process of breath map test is as follows:

取污水厂曝气池中污泥0.3L并用自来水稀释至1.2L,测定现场OURs;之后将污泥样品通过搅拌15s、沉淀10min、去上清液定容至0.6L,用缓冲溶液PBS洗泥3次,测定污泥的准内源OURq;然后用自来水将反应器内活性污泥混合液定容至1.2L,通过对污泥样品曝气2h测定其内源OURe,再加入50g/L的氯化铵测OURen=OURe+OURn,最后加入200g/L的无水乙酸钠,保证基质充足,测定总呼吸速率OURenc=OURe+OURc+OURn。Take 0.3L of sludge from the aeration tank of the sewage plant and dilute it to 1.2L with tap water to measure the OURs on site; after that, the sludge sample is stirred for 15s, settled for 10min, and the supernatant is removed to make up to 0.6L, and the sludge is washed with buffer solution PBS 3 times, the quasi-endogenous OURq of the sludge was measured; then the volume of the activated sludge mixture in the reactor was adjusted to 1.2L with tap water, and the endogenous OURe was measured by aerating the sludge sample for 2 hours, and then 50g/L of Measure OURen=OURe+OURn with ammonium chloride, and finally add 200g/L anhydrous sodium acetate to ensure sufficient matrix, and measure the total respiration rate OURenc=OURe+OURc+OURn.

其中,OURc和OURn分别是异养菌呼吸速率和自养菌呼吸速率。Among them, OURc and OURn are the respiration rate of heterotrophic bacteria and autotrophic bacteria, respectively.

3)确定不同的污水处理中多段进水工艺中非好氧水力停留时间最小值(AHRTmin)、OURcmin、OURnmin;其中,OURcmin应是满足活性污泥自身生长增值的最低耗氧呼吸速率;OURnmin是工艺满足最低脱氮要求时的自养菌最低耗氧呼吸速率;AHRTmin代表满足COD在厌氧和缺氧区合理利用的最低非好氧水力停留时间。3) Determine the minimum value of non-aerobic hydraulic retention time (AHRT min ), OURc min and OURn min in the multi-stage influent process in different sewage treatment; among them, OURc min should be the minimum oxygen-consuming respiration that meets the value-added growth of activated sludge itself rate; OURn min is the minimum aerobic respiration rate of autotrophic bacteria when the process meets the minimum denitrification requirements; AHRT min represents the minimum non-aerobic hydraulic retention time that meets the reasonable utilization of COD in anaerobic and anoxic zones.

4)以AHRT为X轴,以OURc和OURn分别为Y轴,用作图软件制作出关系图;4) Take AHRT as the X-axis, and OURc and OURn as the Y-axis respectively, and use the graph software to make a relationship diagram;

5)根据AHRTmin、OURcmin和OURnmin曲线将关系图分成不同区域;5) According to the AHRT min , OURc min and OURn min curves, the relationship diagram is divided into different regions;

6)满足下述条件的区域为污水处理最优区域:6) The area that meets the following conditions is the optimal area for sewage treatment:

同时满足AHRT>AHRTmin、OURc>OURcmin、OURn>OURnmin的区域;At the same time satisfy the area of AHRT>AHRT min , OURc>OURc min , OURn>OURn min ;

7)通过控制工艺中AHRT的变化,进而影响OURc和OURn,调节OURc和OURn向最优区域靠近。7) By controlling the change of AHRT in the process, and then affecting OURc and OURn, adjust OURc and OURn to approach the optimal area.

调控工艺中非好氧水力停留时间AHRT的方式具体为:调整进水量、回流量及池容量。The method of regulating the non-aerobic hydraulic retention time AHRT in the process is as follows: adjusting the influent flow, return flow and pool capacity.

下面通过具体实施例进一步说明本发明效果。The effect of the present invention is further illustrated below through specific examples.

实施例MAAO工艺应用见图1所示。Examples The MAAO process application is shown in FIG. 1 .

1)对来源于陕西MAAO工艺污水处理厂曝气池中污泥进行取样;1) Sampling the sludge from the aeration tank of Shaanxi MAAO Process Wastewater Treatment Plant;

2)选择西安绿标水环境科技有限公司提供的WBM400型污水处理智慧运行工作站作为检测污泥OUR的仪器。取污水厂曝气池中污泥0.3L并用自来水稀释至1.2L,测定现场OURs;之后将污泥样品通过搅拌15s、沉淀10min、去上清液定容至0.6L,用缓冲溶液(PBS)洗泥3次,测定污泥的准内源OURq;然后用自来水将反应器内活性污泥混合液定容至1.2L,通过对污泥样品曝气2h测定其内源OURe,再加入50g/L的氯化铵测OURen=OURe+OURn,最后加入200g/L的无水乙酸钠,保证基质充足,测定总呼吸速率OURenc=OURe+OURc+OURn;分别得到5个耗氧速率:现状耗氧速率OURs、准内源耗氧速率OURq、内源耗氧速率OURe、加氮源后耗氧速率OURen和总耗氧速率OURenc;2) The WBM400 sewage treatment intelligent operation workstation provided by Xi'an Lvbiao Water Environment Technology Co., Ltd. was selected as the instrument for detecting sludge OUR. Take 0.3L of the sludge in the aeration tank of the sewage plant and dilute it to 1.2L with tap water to measure the OURs on site; after that, the sludge sample is stirred for 15s, settled for 10min, and the supernatant is removed to make up to 0.6L, and the buffer solution (PBS) Wash the sludge 3 times, measure the quasi-endogenous OURq of the sludge; then use tap water to adjust the volume of the activated sludge mixture in the reactor to 1.2L, measure the endogenous OURe by aerating the sludge sample for 2 hours, then add 50g/ L ammonium chloride to measure OURen=OURe+OURn, and finally add 200g/L anhydrous sodium acetate to ensure sufficient matrix, measure the total respiration rate OURenc=OURe+OURc+OURn; respectively get 5 oxygen consumption rates: current oxygen consumption Rate OURs, quasi-endogenous oxygen consumption rate OURq, endogenous oxygen consumption rate OURe, oxygen consumption rate OURen after adding nitrogen source, and total oxygen consumption rate OURenc;

3)在MAAO处理工艺中,确定AHRTmin、OURcmin和OURnmin参数数值。OURCmin值为0.24mgO2·L-1·min-1,OURnmin值为0.12mgO2·L-1·min-1,AHRTmin在工艺中越大越好,一般MAAO工艺中,COD在非好氧区最低消耗60%以上时,可以达到COD的合理利用。此时选定AHRTmin值为95.8min。3) In the MAAO treatment process, determine the parameter values of AHRT min , OURc min and OURn min . OUR Cmin value is 0.24mgO 2 ·L -1 ·min -1 , OURn min value is 0.12mgO 2 ·L -1 ·min -1 , the larger the AHRT min in the process, the better. Generally, in the MAAO process, COD in the non-aerobic The reasonable utilization of COD can be achieved when the minimum consumption of the area is more than 60%. At this time, the selected AHRT min value is 95.8min.

4)以AHRT为X轴,以OURc和OURn分别为Y轴,用作图软件制作出关系图,并分成不同区域,如图2所示;4) Take AHRT as the X-axis, and use OURc and OURn as the Y-axis respectively, use the diagram software to make a relationship diagram, and divide it into different regions, as shown in Figure 2;

5)根据AHRTmin、OURcmin和OURnmin曲线将关系图分成不同区域;5) According to the AHRT min , OURc min and OURn min curves, the relationship diagram is divided into different regions;

6)从图2中可以看出,①区域为最优区域,其中,AHRT较大,可以完成COD在厌氧和缺氧条件下大量去除,同时OURc在满足自身生长增殖的基础上较小,不会与自养菌发生很大的竞争,OURn较大可以有较高的脱氮效率,所以满足下述条件的区域为污水处理最优区域:同时满足AHRT>AHRTmin、OURc>OURcmin、OURn>OURnmin的区域;6) It can be seen from Figure 2 that area ① is the optimal area, in which AHRT is relatively large, and COD can be removed in large quantities under anaerobic and anoxic conditions, and OURc is relatively small on the basis of satisfying its own growth and proliferation. There will be no great competition with autotrophic bacteria, and a larger OURn can have a higher nitrogen removal efficiency, so the area that meets the following conditions is the optimal area for sewage treatment: simultaneously satisfy AHRT>AHRT min , OURc>OURc min , OURn>OURn min area;

7)通过控制工艺中AHRT的变化,进而影响OURc和OURn,调节其向最优区域靠近。调控AHRT的方式具体为:调整进水量、回流量及池容量。7) By controlling the change of AHRT in the process, and then affecting OURc and OURn, adjust them to approach the optimal area. The way to regulate AHRT is as follows: adjust the water inflow, return flow and pool capacity.

实施例分析:Example analysis:

我们可以发现在现有固定的水质条件下,不同区域的呼吸图谱参数和AHRT所代表的MAAO工艺性能的特点,决定每个区域大小和位置。图2分为6个区域,分别是由AHRTmin、OURcmin和OURnmin区分的。We can find that under the existing fixed water quality conditions, the parameters of the respiration map in different regions and the characteristics of the MAAO process performance represented by AHRT determine the size and location of each region. Figure 2 is divided into 6 regions, which are distinguished by AHRT min , OURc min and OURn min .

①号区域为现有水质条件下的合理配置区域,AHRT比较大,可以完成COD大量消耗在厌氧缺氧区的目标,OURc不是很小,可以完成污泥所必须的生长增值要求,OURn较大,可以完成脱氮要求,代表工况为工况一与工况二,在此区域内,AHRT与OURn越大,则系统脱氮能力越高。①号区域是同时满足AHRT>AHRTmin、OURc>OURcmin、OURn>OURnmin的区域,为最优区域。Area ① is a reasonable allocation area under the existing water quality conditions. AHRT is relatively large, which can achieve the goal of COD consumption in anaerobic and anoxic areas. OURc is not small, and can complete the growth and value-added requirements necessary for sludge. Larger, the denitrification requirements can be fulfilled, and the representative working conditions are working condition 1 and working condition 2. In this area, the larger AHRT and OURn are, the higher the denitrification capacity of the system is. Area ① is the area that satisfies AHRT>AHRT min , OURc>OURc min , OURn>OURn min at the same time, which is the optimal area.

②号区域的AHRT太短,无法完成COD的合理配置,会在好氧池消耗一定的COD。此时OURc太大,OURn太小,脱氮效果非常差,代表工况为工况三和工况四。③号区域和④号区域都是②号区域下的不同分区,均为AHRT太小,OURc太大,但是③号区域的OURn较高,符合一定的脱氮要求,而④号区域的OURn较低,脱氮效率较低。此时最有效的调节方法是通过减少进水量或增大池容,从而增大AHRT,使其达到最优区域;② The AHRT in area No. 2 is too short to complete the reasonable allocation of COD, and a certain amount of COD will be consumed in the aerobic pool. At this time, OURc is too large, OURn is too small, and the denitrification effect is very poor, and the representative working conditions are working conditions 3 and 4. Area ③ and Area ④ are different divisions under Area ②, both of which have too small AHRT and too large OURc, but the OURn of Area ③ is relatively high, which meets certain denitrification requirements, while the OURn of Area ④ is relatively high. Low, the denitrification efficiency is low. At this time, the most effective adjustment method is to increase the AHRT by reducing the water inflow or increasing the pool capacity, so that it reaches the optimal area;

⑤号区域的AHRT较大,但是OURc或OURn很小,一般不会出现此种情况;The AHRT of area ⑤ is relatively large, but OURc or OURn is small, which generally does not occur;

⑥号区域的AHRT合适,OURn也满足脱氮的要求,但是此种情况的AHRT特别大,由于污泥在厌氧缺氧和好氧条件下的能量转化效率不同,其完成必要的生长增殖时必须要有一定的OURc要求,而本区域的OURc太小,对污泥生长不利,这种情况的代表工况为工况五。此时,需要在保证足够的AHRT的条件下,减小AHRT,增大进水量或者减少池容量,从而增加OURc,来保证污泥的生长。The AHRT of area ⑥ is suitable, and OURn also meets the requirements of denitrification. However, the AHRT in this case is particularly large. Due to the difference in energy conversion efficiency of sludge under anaerobic-anoxic and aerobic conditions, it takes time for the sludge to complete the necessary growth and proliferation. There must be certain OURc requirements, but the OURc in this area is too small, which is not conducive to the growth of sludge. The representative working condition of this situation is working condition five. At this time, under the condition of ensuring sufficient AHRT, it is necessary to reduce AHRT, increase water intake or reduce tank capacity, thereby increasing OURc to ensure the growth of sludge.

MAAO工艺运行工况表及运行参数见表1所示。The operating conditions and operating parameters of the MAAO process are shown in Table 1.

表1 MAAO工艺运行工况表及运行参数Table 1 MAAO process operating conditions table and operating parameters

本发明并不局限于上述实施例,在本发明公开的技术方案的基础上,本领域的技术人员根据所公开的技术内容,不需要创造性的劳动就可以对其中的一些技术特征作出一些替换和变形,这些替换和变形均在本发明的保护范围内。The present invention is not limited to the above-mentioned embodiments. On the basis of the technical solutions disclosed in the present invention, those skilled in the art can make some replacements and modifications to some of the technical features according to the disclosed technical content without creative work. Deformation, these replacements and deformations are all within the protection scope of the present invention.

Claims (5)

1.一种确定污水处理多段进水工艺的最优区域及调整方法,其特征在于,包括下述步骤:1. An optimal area and an adjustment method for determining a multi-stage water inflow process for sewage treatment, is characterized in that, comprising the following steps: 1)取未经任何处理的污水厂活性污泥;1) Take the activated sludge from the sewage plant without any treatment; 2)对污水厂活性污泥进行呼吸图谱测试,分别得到5个耗氧速率:现状耗氧速率OURs、准内源耗氧速率OURq、内源耗氧速率OURe、加氮源后耗氧速率OURen和总耗氧速率OURenc;2) The respiration spectrum test was carried out on the activated sludge of the sewage plant, and 5 oxygen consumption rates were obtained respectively: the current oxygen consumption rate OURs, the quasi-endogenous oxygen consumption rate OURq, the endogenous oxygen consumption rate OURe, and the oxygen consumption rate OURen after adding a nitrogen source and the total oxygen consumption rate OURenc; 3)确定不同的多段进水工艺中非好氧水力停留时间AHRT最小值AHRTmin、异养菌耗氧速率最小值OURcmin和自养菌耗氧速率最小值OURnmin3) Determine the minimum non-aerobic hydraulic retention time AHRT AHRT min , the minimum oxygen consumption rate of heterotrophic bacteria OURc min and the minimum oxygen consumption rate of autotrophic bacteria OURn min in different multi-stage influent processes; 4)以非好氧水力停留时间AHRT为X轴,以异养菌耗氧速率OURc和自养菌耗氧速率OURn分别为Y轴,用作图软件制作出关系图;4) Take the non-aerobic hydraulic retention time AHRT as the X-axis, take the oxygen consumption rate OURc of the heterotrophic bacteria and the oxygen consumption rate OURn of the autotrophic bacteria as the Y-axis respectively, and use the graph software to make a relational diagram; 5)根据非好氧水力停留时间AHRT最小值AHRTmin、异养菌耗氧速率最小值OURcmin和自养菌耗氧速率最小值OURnmin曲线将关系图分成不同区域;5) Divide the graph into different regions according to the curves of the minimum value of the non-aerobic hydraulic retention time AHRT AHRT min , the minimum value of the oxygen consumption rate of the heterotrophic bacteria OURc min and the minimum value of the oxygen consumption rate of the autotrophic bacteria OURn min ; 6)满足下述条件的区域为污水处理最优区域:6) The area that meets the following conditions is the optimal area for sewage treatment: 同时满足AHRT>AHRTmin、OURc>OURcmin、OURn>OURnmin的区域;At the same time satisfy the area of AHRT>AHRT min , OURc>OURc min , OURn>OURn min ; 7)通过控制工艺中非好氧水力停留时间AHRT的变化,调节异养菌耗氧速率OURc和自养菌耗氧速率OURn向最优区域靠近。7) By controlling the change of the non-aerobic hydraulic retention time AHRT in the process, the oxygen consumption rate OURc of heterotrophic bacteria and the oxygen consumption rate OURn of autotrophic bacteria are adjusted to approach the optimal area. 2.根据权利要求1所述的确定污水处理多段进水工艺的最优区域及调整方法,其特征在于,所述步骤2)中,呼吸图谱测试的具体过程为:2. according to claim 1, determine optimal area and adjustment method of sewage treatment multistage water inflow process, it is characterized in that, in described step 2), the specific process of breath spectrum test is: 取污水厂曝气池中污泥0.3L并用自来水稀释至1.2L,测定现场OURs;之后将污泥样品通过搅拌15s、沉淀10min、去上清液定容至0.6L,用缓冲溶液PBS洗泥3次,测定污泥的准内源OURq;然后用自来水将反应器内活性污泥混合液定容至1.2L,通过对污泥样品曝气2h测定其内源OURe,再加入50g/L的氯化铵测OURen=OURe+OURn,最后加入200g/L的无水乙酸钠,保证基质充足,测定总呼吸速率OURenc=OURe+OURc+OURn。Take 0.3L of sludge from the aeration tank of the sewage plant and dilute it to 1.2L with tap water to measure the OURs on site; after that, the sludge sample is stirred for 15s, settled for 10min, and the supernatant is removed to make up to 0.6L, and the sludge is washed with buffer solution PBS 3 times, the quasi-endogenous OURq of the sludge was measured; then the volume of the activated sludge mixture in the reactor was adjusted to 1.2L with tap water, and the endogenous OURe was measured by aerating the sludge sample for 2 hours, and then 50g/L of Measure OURen=OURe+OURn with ammonium chloride, and finally add 200g/L anhydrous sodium acetate to ensure sufficient matrix, and measure the total respiration rate OURenc=OURe+OURc+OURn. 3.根据权利要求2所述的确定污水处理多段进水工艺的最优区域及调整方法,其特征在于,所述OURc和OURn分别是异养菌呼吸速率和自养菌呼吸速率。3. The optimal area and adjustment method for determining the multi-stage water inflow process of sewage treatment according to claim 2, characterized in that, said OURc and OURn are the respiration rate of heterotrophic bacteria and respiration rate of autotrophic bacteria, respectively. 4.根据权利要求1所述的确定污水处理多段进水工艺的最优区域及调整方法,其特征在于,所述OURcmin应是满足活性污泥自身生长增值的最低耗氧呼吸速率;OURnmin是工艺满足国家规定的出水标准中最低脱氮要求时的自养菌最低耗氧呼吸速率;AHRTmin代表满足COD在厌氧和缺氧区合理利用的最低非好氧水力停留时间。4. according to claim 1, determine optimal area and adjustment method of sewage treatment multistage water inflow process, it is characterized in that, described OURc min should be to satisfy the minimum oxygen-consuming respiration rate of activated sludge self-growth increment; OURn min It is the minimum aerobic respiration rate of autotrophic bacteria when the process meets the minimum denitrification requirements in the effluent standard stipulated by the state; AHRT min represents the minimum non-aerobic hydraulic retention time that meets the reasonable utilization of COD in anaerobic and anoxic areas. 5.根据权利要求1所述的确定污水处理多段进水工艺的最优区域及调整方法,其特征在于,所述调控工艺中非好氧水力停留时间AHRT的方式为通过调整进水量、回流量及池容量。5. The optimal area and adjustment method for determining the multi-stage water inflow process of sewage treatment according to claim 1, is characterized in that, the mode of the non-aerobic hydraulic retention time AHRT in the described control process is by adjusting the water inflow, the return flow and pool capacity.
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