CN108482016A - A kind of good solid tyre of wet type on-slip and its moulding process - Google Patents

A kind of good solid tyre of wet type on-slip and its moulding process Download PDF

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Publication number
CN108482016A
CN108482016A CN201810311349.5A CN201810311349A CN108482016A CN 108482016 A CN108482016 A CN 108482016A CN 201810311349 A CN201810311349 A CN 201810311349A CN 108482016 A CN108482016 A CN 108482016A
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CN
China
Prior art keywords
weight
parts
buffer layer
epidermis
slip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810311349.5A
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Chinese (zh)
Inventor
张小海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xinghsun New Mstar Technology Ltd Jinjiang
Original Assignee
Xinghsun New Mstar Technology Ltd Jinjiang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xinghsun New Mstar Technology Ltd Jinjiang filed Critical Xinghsun New Mstar Technology Ltd Jinjiang
Priority to CN201810311349.5A priority Critical patent/CN108482016A/en
Publication of CN108482016A publication Critical patent/CN108482016A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C2001/0075Compositions of belt cushioning layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C2001/0091Compositions of non-inflatable or solid tyres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Tires In General (AREA)
  • Tyre Moulding (AREA)

Abstract

The present invention discloses a kind of good solid tyre of wet type on-slip and its moulding process, the good solid tyre of wet type on-slip, epidermis, buffer layer and interior articulamentum including being in circular ring shape, the epidermis and interior articulamentum, which are respectively coated by, is connected to buffer layer outer rim side and inner ring side, there are outer annular gap is exposed to for buffer layer between the epidermis and interior articulamentum, the buffer layer is formed by ETPU particles through vapor foaming;The epidermis and interior articulamentum are made of following component:Thermoplastic polyurethane elastomer:55 75 parts by weight;Neoprene:15 30 parts by weight;Petropols:4 12 parts by weight;Paraffin oil:3 10 parts by weight;Antioxidant:12 parts by weight.The present invention allows between epidermis and buffer layer and can preferably be merged, and also has the characteristics that wet type anti-slip effect is good.

Description

A kind of good solid tyre of wet type on-slip and its moulding process
Technical field
The present invention relates to solid tyre fields, and in particular to be a kind of good solid tyre of wet type on-slip and its molding work Skill.
Background technology
According to Baidupedia, tire refers to the circular ring shape elasticity rubber rolled in various vehicles or the ground connection mechanically assembled Glue product, it is typically mounted on holder, can support vehicle body, buffering foreign impacts etc..Bicycle, perambulator and toy car etc. For light non-motor vehicle, own wt is small, and the load that tire is born is small, therefore tire used belongs to a kind of low load wheel Tire.For above-mentioned low load tire, the elasticity and portability of tire itself are to the handling particularly important of vehicle.Used in the market Low load tire includes mainly pneumatic tire and non-inflatable tyre.Subject to damage during pneumatic tire use, for small size Low load tire, replace more difficult, therefore pneumatic tire is rarely applied on baby carriage tires and toy tyre.Exempt from inflated wheel Tire can to avoid pneumatic tire there are the problem of, can be widely applied to the fields such as perambulator, toy.Non-inflatable tyre includes not foaming Solid tyre, foaming solid tyre and foaming body filled-type tire etc..
Rubber is usually used as epidermis, to play wear-resisting and on-slip effect, still in traditional solid tyre Since blending is poor each other between rubber and TPU expanded particles so that be often easy to happen positioned at internal layer TPU foaming bodies and The situation being disengaged from each other positioned at the rubber of epidermis, so that solid tyre encounters difficulty during practical industrialization Topic.
Based on the above considerations, the present inventor had once applied for a kind of thermoplastic polyurethane low load tire comprising uses It is hard higher than inner layer in the hardness of the epidermis directly contacted with ground and the inner layer inside epidermis, the epidermis Degree, the epidermis and inner layer are foaming-formed using TPU expanded particles.But whether how to be carried out using TPU expanded particles Molding, is promoted relatively limited on wear-resisting and non-skid property, is based on this, the applicant's hammer away regarding to the issue above, Then there is this case generation.
Invention content
The main purpose of the present invention is to provide a kind of good solid tyre of wet type on-slip and its moulding process, epidermis is allowed It can be preferably merged between buffer layer, and also have the characteristics that wet type anti-slip effect is good.
In order to achieve the above objectives, solution of the invention is:
A kind of good solid tyre of wet type on-slip, wherein epidermis, buffer layer and interior articulamentum including being in circular ring shape, The epidermis and interior articulamentum, which are respectively coated by, is connected to buffer layer outer rim side and inner ring side, the epidermis and interior articulamentum it Between there are outer annular gap is exposed to for buffer layer, the buffer layer is formed by ETPU particles through vapor foaming;
The epidermis and interior articulamentum are made of following component:
Thermoplastic polyurethane elastomer:55-75 parts by weight;
Neoprene:15-30 parts by weight;
Petropols:4-12 parts by weight;
Paraffin oil:3-10 parts by weight;
Antioxidant:1-2 parts by weight.
Further, several screw connecting holes are also formed on the interior articulamentum, in each screw connecting hole penetrates through The upper and lower surface of articulamentum.
Another object of the present invention is to provide a kind of moulding process of the good solid tyre of wet type on-slip, wherein including such as Lower step:
1. in the way of vapor hot briquetting, ETPU particle foamings are obtained into the buffer layer of annular;
2. the buffer layer of forming is placed into injection mold, it is provided in injection mold for blocking in the middle part of buffer layer The annular shutter of two of region;
3. uniform injection molding material will be blended, and injection molding obtains epidermis and interior articulamentum respectively at twice, to obtain into Product solid tyre;The injection molding material by the thermoplastic polyurethane elastomer of 55-75 parts by weight, 15-30 parts by weight neoprene, The Petropols of 4-12 parts by weight, the paraffin oil of 3-10 parts by weight and 1-2 parts by weight antioxidant composition.
Further, the moulding process of the solid tyre further include step 4.:In the interior articulamentum inner ring of forming also Processing is formed with screw connecting hole, and each screw connecting hole penetrates through the upper and lower surface of interior articulamentum.
With the above structure, the present invention relates to a kind of good solid tyre of wet type on-slip and its moulding process, with existing skill Art is compared, and is at least had the advantages that:
One, using thermoplastic polyurethane elastomer and neoprene as main material, wherein neoprene has the present invention Resistance to pulling force, wear-resisting and elastic good feature allow epidermis to have preferable in conjunction with the characteristic of upper thermoplastic polyurethane elastomer Comprehensive performance;Thermoplastic polyurethane elastomer and neoprene after being fully blended injection molding in the outside of buffer layer and Inside is respectively formed epidermis and interior articulamentum, since both thermoplastic polyurethane elastomer and ETPU particles belong to poly- ammonia Ester material belongs to identical material classification, has preferable blending, can make epidermis and interior articulamentum and buffer layer it Between can be connected to for an entirety, improve the quality of entire solid tyre.
Two, the solid tyre that the present invention is formed, epidermis is hard compared to buffer layer, and the buffer layer is compared to table Cortex is soft, and the prior art is essentially all that epidermis is soft, and the inside is hard, and practical damping effect is poor;In addition, this By allowing, there are annular gaps between epidermis and interior articulamentum for invention so that the active force that the inside articulamentum of epidermis transmits is complete Portion will pass through buffer layer, it is ensured that all active forces can all obtain the cushioning effect of buffer layer.
Three, the auxiliary agent used in the present invention is for promoting tire actual performance, and wherein Petropols and paraffin oil are to use In allowing two kinds of main materials of neoprene and thermoplastic polyurethane elastomer that there is preferable blended, to allow neoprene and heat Plastic polyurethane elastomer can merge more uniform, and the antioxidant is then used to prevent entire solid tyre from hardening, and is promoted Life of product.
Description of the drawings
Fig. 1 is that the present invention relates to a kind of structural schematic diagrams of the good solid tyre of wet type on-slip.
Fig. 2 is that the present invention relates to a kind of sectional views of the good solid tyre of wet type on-slip.
Fig. 3 is the schematic diagram that ETPU particles are shaped to buffer layer by the present invention by vapor.
Fig. 4 is the schematic diagram when present invention is sheltered from buffer layer by annular shutter.
Fig. 5 is that the present invention is molded the schematic diagram for sequentially forming out epidermis and interior articulamentum at twice.
In figure:
Epidermis -1;Buffer layer -2;ETPU particles -21;
Interior articulamentum -3;Screw connecting hole -31;Annular gap -4;
Annular shutter -5.
Specific implementation mode
In order to further explain the technical solution of the present invention, being explained in detail the present invention below by specific embodiment It states.
As depicted in figs. 1 and 2, it is a kind of good solid tyre of wet type on-slip of the present invention, including is in circular ring shape Epidermis 1, buffer layer 2 and interior articulamentum 3, the epidermis 1 and interior articulamentum 3, which are respectively coated by, is connected to the outer of buffer layer 2 Ring side and inner ring side, it is described there are the annular gap 4 outside being exposed to for buffer layer 2 between the epidermis 1 and interior articulamentum 3 Buffer layer 2 is formed by ETPU particles 21 through vapor foaming.It please refers to shown in Fig. 1 and Fig. 2, Fig. 1 is the knot of entire tire Structure schematic diagram, Fig. 2 are sectional view, are so clear that the epidermis 1 and interior articulamentum 3 are respectively coated by buffer layer 2 Outer rim side and inner ring side, the presence of the annular gap 4 allow buffer layer 2 that can from the outside be seen by people.
In the present invention, the epidermis 1 and interior articulamentum 3 are made of following component:
Thermoplastic polyurethane elastomer:55-75 parts by weight;
Neoprene:15-30 parts by weight;
Petropols:4-12 parts by weight;
Paraffin oil:3-10 parts by weight;
Antioxidant:1-2 parts by weight.
The thermoplastic polyurethane elastomer and the main material that neoprene is epidermis 1 and interior articulamentum 3, the oil Resin, paraffin oil and antioxidant are addition auxiliary agent.
In order to which entire solid tyre can be easily assembled on vehicle frame, it is also formed on the interior articulamentum 3 several A screw connecting hole 31, each screw connecting hole 31 penetrate through the upper and lower surface of interior articulamentum 3.
As shown in Figures 3 to 5, of the invention that a kind of moulding process of the good solid tyre of wet type on-slip is also provided, including such as Lower step:
1. in the way of vapor hot briquetting, 21 foaming of ETPU particles is obtained into the buffer layer 2 of annular;
2. the buffer layer 2 of forming is placed into injection mold, it is provided in injection mold for blocking in buffer layer 2 Two annular shutters 5 in portion region;
3. uniform injection molding material will be blended, and injection molding obtains epidermis 1 and interior articulamentum 3 respectively at twice, to obtain Finished solid tire;The injection molding material is by the thermoplastic polyurethane elastomer of 55-75 parts by weight, the neoprene rubber of 15-30 parts by weight Glue, the Petropols of 4-12 parts by weight, the paraffin oil of 3-10 parts by weight and 1-2 parts by weight antioxidant composition.
As shown in figure 3, as a preferred embodiment, the moulding process of the solid tyre further include step 4.:At Also processing is formed with screw connecting hole 31 in good 3 inner ring of interior articulamentum of type, and each screw connecting hole 31 penetrates through interior articulamentum 3 Upper and lower surface.
To sum up, compared with prior art, it at least has the advantages that:
One, using thermoplastic polyurethane elastomer and neoprene as main material, wherein neoprene has the present invention Resistance to pulling force, wear-resisting and elastic good feature allow epidermis 1 to have preferable in conjunction with the characteristic of upper thermoplastic polyurethane elastomer Comprehensive performance;Injection molding is in the outer of buffer layer 2 after thermoplastic polyurethane elastomer and neoprene pass through fully blending Side and inside are respectively formed epidermis 1 and interior articulamentum 3, both due to thermoplastic polyurethane elastomer and ETPU particles 21 Belong to polyurethane material, belong to identical material classification, there is preferable blending, can make epidermis 1 and interior articulamentum 3 It can be connected to for an entirety, improve the quality of entire solid tyre between buffer layer 2.
Two, the solid tyre that the present invention is formed, epidermis 1 is hard compared to buffer layer 2, and the buffer layer 2 is compared It is soft in epidermis 1, the prior art is essentially all that epidermis 1 is soft, and the inside is hard, and practical damping effect is poor; In addition, there are annular gaps 4 between epidermis 1 and interior articulamentum 3 by allowing by the present invention so that 1 inside articulamentum 3 of epidermis passes The active force passed will all pass through buffer layer 2, it is ensured that all active forces can all obtain the cushioning effect of buffer layer 2.
Three, the auxiliary agent used in the present invention is for promoting tire actual performance, and wherein Petropols and paraffin oil are to use In allowing two kinds of main materials of neoprene and thermoplastic polyurethane elastomer that there is preferable blended, to allow neoprene and heat Plastic polyurethane elastomer can merge more uniform, and the antioxidant is then used to prevent entire solid tyre from hardening, and is promoted Life of product.
The product form and style of above-described embodiment and schema and the non-limiting present invention, any technical field it is common The appropriate changes or modifications that technical staff does it all should be regarded as the patent category for not departing from the present invention.

Claims (4)

1. a kind of good solid tyre of wet type on-slip, which is characterized in that epidermis, buffer layer and interior connection including being in circular ring shape Layer, the epidermis and interior articulamentum are respectively coated by and are connected to buffer layer outer rim side and inner ring side, the epidermis and interior connection There are being exposed to outer annular gap for buffer layer between layer, the buffer layer by ETPU particles through vapor foaming and At;
The epidermis and interior articulamentum are made of following component:
Thermoplastic polyurethane elastomer:55-75 parts by weight;
Neoprene:15-30 parts by weight;
Petropols:4-12 parts by weight;
Paraffin oil:3-10 parts by weight;
Antioxidant:1-2 parts by weight.
2. a kind of good solid tyre of wet type on-slip as described in claim 1, which is characterized in that also formed on the interior articulamentum There are several screw connecting holes, each screw connecting hole to penetrate through the upper and lower surface of interior articulamentum.
3. a kind of moulding process of the good solid tyre of wet type on-slip, which is characterized in that include the following steps:
1. in the way of vapor hot briquetting, ETPU particle foamings are obtained into the buffer layer of annular;
2. the buffer layer of forming is placed into injection mold, it is provided in injection mold for blocking buffer layer central region Two annular shutters;
3. uniform injection molding material will be blended, and injection molding obtains epidermis and interior articulamentum respectively at twice, to obtain finished product reality Heart tire;The injection molding material is by the thermoplastic polyurethane elastomer of 55-75 parts by weight, the neoprene of 15-30 parts by weight, 4-12 The Petropols of parts by weight, the paraffin oil of 3-10 parts by weight and 1-2 parts by weight antioxidant composition.
4. a kind of moulding process of the good solid tyre of wet type on-slip as claimed in claim 3, which is characterized in that the solid wheel The moulding process of tire further include step 4.:Also processing is formed with screw connecting hole in the interior articulamentum inner ring of forming, each Screw connecting hole penetrates through the upper and lower surface of interior articulamentum.
CN201810311349.5A 2018-04-09 2018-04-09 A kind of good solid tyre of wet type on-slip and its moulding process Pending CN108482016A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810311349.5A CN108482016A (en) 2018-04-09 2018-04-09 A kind of good solid tyre of wet type on-slip and its moulding process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810311349.5A CN108482016A (en) 2018-04-09 2018-04-09 A kind of good solid tyre of wet type on-slip and its moulding process

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CN108482016A true CN108482016A (en) 2018-09-04

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120247634A1 (en) * 2011-03-01 2012-10-04 Gordon Liao Stuffed Tire For Lightweight Vehicles
CN102741336A (en) * 2009-12-01 2012-10-17 株式会社普利司通 Modified rubber compositions and methods of preparation
CN103270100A (en) * 2010-12-23 2013-08-28 米其林企业总公司 Tread tire, useful in motor vehicles including e.g. sport utility vehicles, comprises e.g. rubber composition comprising first elastomer comprising diene elastomer and second elastomer comprising thermoplastic polyurethane block copolymer
CN103649151A (en) * 2011-07-05 2014-03-19 巴斯夫欧洲公司 Filled elastomer comprising polyurethane
CN204296370U (en) * 2014-10-29 2015-04-29 台州市奇宇橡胶有限公司 A kind of band tyre
CN105034697A (en) * 2015-08-11 2015-11-11 大连华工创新科技股份有限公司 E-TPU (expanded thermoplastic polyurethane) tire and manufacturing method thereof
JP2016003265A (en) * 2014-06-16 2016-01-12 横浜ゴム株式会社 Thermoplastic elastomer composition for non-pneumatic tire and non-pneumatic tire
CN206690803U (en) * 2017-05-05 2017-12-01 张庆华 A kind of middle slow-moving vehicle multilayer solid tyre
WO2017213500A1 (en) * 2016-06-07 2017-12-14 Hsv Moulded Foams Group N.V. Wheel
CN107778521A (en) * 2017-09-12 2018-03-09 晋江创赢新材料科技有限公司 A kind of high-temperature resistant expanded bead tire, preparation method and expanded bead preparation method

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102741336A (en) * 2009-12-01 2012-10-17 株式会社普利司通 Modified rubber compositions and methods of preparation
CN103270100A (en) * 2010-12-23 2013-08-28 米其林企业总公司 Tread tire, useful in motor vehicles including e.g. sport utility vehicles, comprises e.g. rubber composition comprising first elastomer comprising diene elastomer and second elastomer comprising thermoplastic polyurethane block copolymer
US20120247634A1 (en) * 2011-03-01 2012-10-04 Gordon Liao Stuffed Tire For Lightweight Vehicles
CN103649151A (en) * 2011-07-05 2014-03-19 巴斯夫欧洲公司 Filled elastomer comprising polyurethane
JP2016003265A (en) * 2014-06-16 2016-01-12 横浜ゴム株式会社 Thermoplastic elastomer composition for non-pneumatic tire and non-pneumatic tire
CN204296370U (en) * 2014-10-29 2015-04-29 台州市奇宇橡胶有限公司 A kind of band tyre
CN105034697A (en) * 2015-08-11 2015-11-11 大连华工创新科技股份有限公司 E-TPU (expanded thermoplastic polyurethane) tire and manufacturing method thereof
WO2017213500A1 (en) * 2016-06-07 2017-12-14 Hsv Moulded Foams Group N.V. Wheel
CN206690803U (en) * 2017-05-05 2017-12-01 张庆华 A kind of middle slow-moving vehicle multilayer solid tyre
CN107778521A (en) * 2017-09-12 2018-03-09 晋江创赢新材料科技有限公司 A kind of high-temperature resistant expanded bead tire, preparation method and expanded bead preparation method

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Application publication date: 20180904

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