CN108474168B - Laundry care appliance with a material container - Google Patents
Laundry care appliance with a material container Download PDFInfo
- Publication number
- CN108474168B CN108474168B CN201680079462.4A CN201680079462A CN108474168B CN 108474168 B CN108474168 B CN 108474168B CN 201680079462 A CN201680079462 A CN 201680079462A CN 108474168 B CN108474168 B CN 108474168B
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- container
- laundry care
- care appliance
- washing liquid
- lye
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
- D06F35/003—Washing machines, apparatus, or methods not otherwise provided for using electrochemical cells
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Detail Structures Of Washing Machines And Dryers (AREA)
- Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
The invention relates to a laundry care appliance (100) having a lye container (105), a washing drum (107) arranged in the lye container (105) and a substance container (117) for receiving a polyoxometalate catalyst (129), wherein the substance container (117) is connected to a supply line (119) for supplying washing liquid into the substance container (117), and the substance container (117) is connected to a discharge line (121) for discharging washing liquid onto the lye container (105). The polyoxometalate catalyst (129) is configured to produce hydrogen peroxide by chemical reaction with the wash liquor to obtain a wash liquor containing hydrogen peroxide. The discharge line (121) has a valve (123) which is designed to disconnect the lye container (105) from the substance container (117) in a first position and to connect the substance container (117) to the lye container (105) in a second position in order to supply the washing liquor containing hydrogen peroxide to the lye container (105) and to effect bleaching of the laundry in the washing drum (107).
Description
Technical Field
The invention relates to a laundry care appliance having a material container.
Background
In conventional laundry care appliances, chemically active bleaching agents (in particular chemical bleaching agents) are added in order to treat certain contaminants of the laundry to be treated. For this purpose, for example, a bleach-containing laundry care substance (in particular a bleach-containing all-purpose powder detergent) is manually supplied by the user of the laundry care appliance into the rinsing-in housing of the laundry care appliance.
DE 102011083572 a1 discloses a water-conducting household appliance having a container for receiving items to be cleaned, wherein the container comprises an inner surface which contains a catalytically acting substance.
DE 102013205302 a1 discloses a water-conducting household appliance which contains at least one catalytically active substance in the surface.
Disclosure of Invention
The object of the invention is, inter alia, to provide a laundry care appliance which enables an automatic addition of chemical bleaching agent.
According to one aspect of the invention, this object is achieved by a laundry care appliance having: a lye container for receiving the wash liquor; a washing drum arranged in the lye container for receiving the laundry; and a substance container for receiving a polyoxometalate catalyst (polyoxometalate-katalyzer), wherein the substance container is fluidically connected to the supply line for supplying washing liquid into the substance container, wherein the substance container is fluidically connected to the discharge line for discharging washing liquid onto the lye container, wherein the polyoxometalate catalyst is designed to: producing hydrogen peroxide by chemical reaction with the washing liquid to obtain a washing liquid containing hydrogen peroxide, and wherein the delivery line has a valve configured to: in the first position, the lye container is fluidically separated from the substance container, and in the second position, the substance container is fluidically connected to the lye container for supplying the washing liquor containing hydrogen peroxide to the lye container and for enabling bleaching of the laundry in the washing drum.
This achieves the technical advantage that: by using a polyoxometalate catalyst, a washing liquid containing hydrogen peroxide can be produced in the substance container, which washing liquid can be supplied to the lye container in a valve-controlled manner. This ensures an effective dosage of the bleaching action of the washing liquor containing hydrogen peroxide on the laundry.
In conventional laundry care appliances, a chemical bleaching dye, for example a chlorine bleach, is usually provided manually by the user of the laundry care appliance into the wash-in housing in order to achieve a bleaching action of the laundry during the laundry care process. Thus, in the event that the chemical bleaching agent is improperly added by the user to the flush-in housing, an unpleasant and potentially health-damaging odor may result.
The polyoxometalate catalyst received in the substance container according to the invention catalyzes a chemical reaction for the production of hydrogen peroxide.
Here, the polyoxometalate catalyst oxidizes molecular oxygen (molekularen Sauerstoff) to the superoxide anion (Hyperoxidanien). The generated superoxide anion can chemically react with water to produce hydrogen peroxide. The hydrogen peroxide produced can be used as a bleaching agent for bleaching laundry. Polyoxometallate catalysts are inorganic metal-oxygen clusters (metal-Sauerstoff-Cluster) which generally comprise polyatomic anions which are built up in particular from transition metal oxyanions, in particular tungstates, molybdates, vanadates, niobates and/or tantalates, and are bridged by oxygen atoms. Polyoxometallate catalysts including tungstates may include [ SiV3W9O40]7-The anion can alternatively be titanium modified (Titan-modifizer).
The polyoxometallate acts as a catalyst and is not consumed in the scope of the catalytic cycle (Katalyse-zyklus), so that hydrogen peroxide can be constantly produced. Thus, there is a constant availability of the effective bleaching action of the laundry care appliance. Thus, the user of the laundry care appliance does not have to purchase bleach again, or the manual refilling of bleach into the rinsing-in housing by the user can be dispensed with. Furthermore, in the case of polyoxometalate catalysts, no by-products harmful to the environment or unpleasant odours are produced, which occur, for example, in the case of chlorine bleaches. Furthermore, the constant availability of such a washing liquid containing hydrogen peroxide can be utilized in order to keep the laundry care appliance free of microorganisms and free of biofilms.
By a laundry care appliance is understood an appliance for laundry care (for example a washing machine or a laundry dryer). Such laundry care appliances are understood to be, in particular, household laundry care appliances. Namely, such laundry care appliances: the laundry care appliance is used in the household sector and, with the aid of the laundry care appliance, treats household-relevant quantities of laundry.
In an advantageous embodiment of the laundry care appliance, the supply line and the discharge line are each fluidically connected to the lye container, and the supply line is connected to a pump which is designed to: the washing liquid is pumped out of the lye container via the supply line and the pumped-out washing liquid is resupplied to the lye container via the substance container and via the discharge line.
This achieves the technical advantage that: an effective circulating pumping system (Umpumpsystem) is achieved in which the substance container with the polyoxometalate catalyst is arranged by the supply line and the discharge line being fluidically connected to the lye container. Thus, effective bleaching of the laundry can be achieved by activating the pump, whereby the washing liquor is pumped out of the lye container, the pumped-out washing liquor is admixed with hydrogen peroxide in the substance container, and the washing liquor containing hydrogen peroxide is subsequently resupplied to the lye container.
In a further advantageous embodiment of the laundry care appliance, the lye container is fluidically connected to the discharge line of the laundry care appliance for discharging washing liquor from the laundry care appliance, wherein the supply line is fluidically connected to the discharge line, wherein the substance container is designed as a washing liquor reservoir for receiving washing liquor, wherein the discharge line is fluidically connected to the lye container, wherein the discharge line is connected to a liquid pump, which is designed to: the washing liquid is pumped from the substance container via a discharge line into the lye container.
This achieves the technical advantage that: the washing liquid to be drained off from the lye container via the drain line can be led via the supply line to the washing liquid reservoir and stored there, for example for further washing processes. Since the washing liquid accumulator is also designed as a material container for receiving the polyoxometalate catalyst, the supplied washing liquid is admixed with hydrogen peroxide in the material container and can be stored in the material container (or washing liquid accumulator) as a washing lye containing hydrogen peroxide. If bleaching of the laundry is desired, the washing lye containing hydrogen peroxide can be supplied from the washing liquor reservoir to the lye container via the discharge line.
In a further advantageous embodiment of the laundry care appliance, the outlet line has an outlet container for receiving the washing liquid guided through the outlet line, wherein the supply line is fluidically connected to the outlet container of the outlet line for supplying the washing liquid from the outlet container to the product container through the supply line.
This achieves the technical advantage that: an intermediate reservoir for receiving the washing liquid discharged via the discharge line is realized by the discharge container. Thus, the cleaning liquid can be efficiently supplied from the discharge container to the material container through the supply line.
In a further advantageous embodiment of the laundry care appliance, the supply line is fluidically connected to a water supply (Wasserzufuhr) of the laundry care appliance for supplying water from the water supply to the product container via the supply line.
This achieves the technical advantage that: by means of a direct fluid-technical connection between the substance container and the water supply of the laundry care appliance, water can be supplied directly from the water supply to the substance container. Thus, a washing liquid containing hydrogen peroxide (especially water containing hydrogen peroxide) can be obtained by the polyoxometalate catalyst. What can be avoided, in particular by attaching the substance container directly to the water supply, is: the laundry care substance (e.g. detergent) injected into the rinsing housing reaches the substance container, so that damage or deactivation of the laundry care substance by the hydrogen peroxide produced is avoided.
In a further advantageous embodiment of the laundry care appliance, the laundry care appliance has a flushing-in housing for supplying the washing liquid, wherein the flushing-in housing is fluidically connected to the lye container via a housing line (schalenleitsung) for conveying the washing liquid from the flushing-in housing to the lye container via the housing line.
This achieves the technical advantage that: by injecting the laundry care substance into the wash-in housing, a functional amount of washing liquid (in particular washing lye) can be provided, which can be supplied to the lye container via the housing line. The housing part line is not connected to the supply line or the discharge line, in particular in terms of flow technology, so that the supply of the washing liquid from the flushing-in housing part into the lye container and the supply of the washing liquid containing hydrogen peroxide from the substance container into the lye container can be effected with different liquid paths.
In a further advantageous embodiment of the laundry care appliance, the polyoxometalate catalyst is received in the substance container as polyoxometalate-coated particles (polyoxometalate-beschthyttes Granulat).
This achieves the technical advantage that: by introducing the polyoxometalate-coated particles into the material container, the polyoxometalate catalyst can be made to react chemically particularly efficiently with the washing liquid for the production of hydrogen peroxide. The polyoxometalate-coated particles here have a particularly large surface which can be used for chemical reactions with the washing liquid, whereby the effectiveness of the catalytic reaction can be improved.
In a further advantageous embodiment of the laundry care appliance, the polyoxometalate catalyst is connected in a material-locking manner to the container wall of the product container, wherein the container wall is coated in particular with the polyoxometalate catalyst.
This achieves the technical advantage that: the polyoxometalate catalyst can be fixed particularly effectively to the vessel wall by a cohesive connection between the polyoxometalate catalyst and the vessel wall of the material vessel. The container walls may in particular be coated with a polyoxometalate catalyst in order to obtain a reactive (reaktionstictive) surface on the container walls.
In a further advantageous embodiment of the laundry care appliance, the supply line has a further valve which is configured to: in the first position, the supply line is fluidically separated from the substance container, and in the second position, the supply line is fluidically connected to the substance container in order to enable a supply of washing liquid into the substance container.
This achieves the technical advantage that: by means of such a further valve arranged in the supply line, it is possible to effectively control: whether or not the washing liquid should be supplied to the material container. This makes it possible to control the generation of hydrogen peroxide by the polyoxometalate catalyst.
In a further advantageous embodiment of the laundry care appliance, the laundry care appliance comprises a selection device for selecting a plurality of laundry care programs, wherein the laundry care appliance comprises a control device, and wherein the control device is configured to: controlling the valve or the further valve in accordance with the selected laundry care program.
This achieves the technical advantage that: by controlling the valve (or the further valve) in accordance with the selected laundry care program, the supply of washing liquid containing hydrogen peroxide to the lye container can be effectively regulated. Depending on the selected laundry care program, the bleaching action can therefore be adapted to the degree of soiling of the laundry, the amount of laundry and/or the type of laundry.
In a further advantageous embodiment of the laundry care appliance, the lye container is fluidically connected to the discharge line of the laundry care appliance, wherein the discharge line is connected to a lye pump, wherein the lye pump is designed to: the washing liquid is pumped out of the laundry care appliance via the outlet line.
This achieves the technical advantage that: the lye pump can pump washing liquid out of the lye container through the discharge line and effectively out of the laundry care appliance.
In a further advantageous embodiment of the laundry care appliance, a tumbling element is arranged in the substance containerWherein the tumbling element is configured to: make the washing liquidTumbling in substance containers
This achieves the technical advantage that: the tumbling element comprises a means for moving the washing liquid in the material container, by which the washing liquid can be effectively tumbled (or agitated) in the material container, thereby enabling a constant continuous chemical reaction of the polyoxometalate catalyst with the washing liquid.
In a further advantageous embodiment of the laundry care appliance, an air inlet element is arranged in the product container, wherein the air inlet element is designed to: air is introduced into the washing liquid in the substance container.
This achieves the technical advantage that: the air introduction element comprises a means for introducing air into the cleaning solution in the substance container, by means of which a sufficient amount of oxygen can be provided in the substance container for use in order to be able to efficiently generate hydrogen peroxide by means of the polyoxometalate catalyst.
In a further advantageous embodiment of the laundry care appliance, the polyoxometalate catalyst comprises a tungstate, wherein the tungstate comprises in particular vanadium.
This achieves the technical advantage that: particularly effective polyoxometallate catalysts can be obtained by tungstates, in particular by tungstates containing vanadium.
In a further advantageous embodiment of the laundry care appliance, the tungstate may comprise [ SiV ]3W9O40]7-The anion may alternatively be titanium modified.
This achieves the technical advantage that: [ SiV ]3W9O40]7-Anionic and/or titanium modified tungstates achieve particularly effective polyoxometallate catalysts.
Drawings
Further embodiments are explained with reference to the figures. The figures show:
FIG. 1: a schematic view of a laundry care appliance;
FIG. 2: a schematic view of a substance container arranged in a circulation pumping system of a laundry care appliance;
FIG. 3: a schematic view of a substance container fluidically connected to a water supply; and
FIG. 4: a schematic illustration of a material container which is fluidically connected to the discharge line of the lye container.
Detailed Description
Fig. 1 shows a schematic view of a generic laundry care appliance 100, for example a washing machine. The laundry care appliance 100 comprises a wash-in housing 101, into which a detergent or other liquid substance can be injected. The laundry care appliance 100 comprises a door 103 for loading the laundry care appliance 100 with laundry.
Fig. 2 shows a schematic view of a substance container arranged in a circulation pumping system of a laundry care appliance. The laundry care appliance 100 comprises a lye container 105 for receiving washing liquid and a washing drum 107 arranged in the lye container 105 for receiving the laundry. The laundry care appliance 100 comprises an immersion housing 101, the immersion housing 101 being fluidically connected to a water supply 109 of the laundry care appliance 100 for supplying fresh water from the water supply 109 to the immersion housing 101. The washing liquid produced by mixing the laundry care substance located in the rinsing housing 101 with water is supplied from the rinsing housing 101 to the lye container 105 via a housing line 111 which is fluidically connected to the lye container 105.
Furthermore, the lye container 105 is fluidically connected to the discharge line 113 of the laundry care appliance 100. The discharge line 113 is connected to a lye pump 115, the lye pump 115 being configured for: the washing liquid is pumped out of the laundry care appliance 100 through the discharge line 113.
Furthermore, the laundry care appliance 100 has a substance container 117, which substance container 117 is fluidically connected to a supply line 119 for supplying washing liquid into the substance container 117, wherein the supply line 119 is also fluidically connected to the lye container 105. Furthermore, the substance container 117 is fluidically connected to the lye container 105 via a discharge line 121 for discharging the washing liquid from the substance container 117.
The discharge line 121 has a valve 123, the valve 123 being configured to: in the first position, the lye container 105 is fluidically separated from the substance container 117, and in the second position, the substance container 117 is fluidically connected to the lye container 105. Thus, by the position of the valve 123 it is possible to control: whether washing liquid is supplied from the substance container 117 to the lye container 105.
The substance container 117 is part of a circulation pumping system 125 of the laundry care appliance 100, wherein the circulation pumping system 125 has a pump 127. The pump 127 is configured to: the washing liquid is pumped out of the lye container 105 through the supply line 119 and the pumped-out washing liquid is resupplied to the lye container 105 through the substance container 117 and through the lead-out line 121.
In the substance container 117, a polyoxometalate catalyst 129 is received, which polyoxometalate catalyst 129 comprises, in particular, polyoxometalate-coated particles or is, in particular, connected in a material-locking manner to a container wall 131 of the substance container 117.
The polyoxometalate catalyst 129 is an oxidation catalyst (oxidationkatalyzer) that oxidizes molecular oxygen to a superoxide anion. The generated superoxide anion can chemically react with water to produce hydrogen peroxide. The hydrogen peroxide produced here is an oxidizing agent which can be used as a bleaching agent for bleaching laundry. Polyoxometalate catalysts are inorganic metal-oxygen clusters which generally comprise polyatomic anions which are built up in particular from transition metal oxyanions (in particular tungstates, molybdates, vanadates, niobates and/or tantalates) and are bridged by oxygen atoms. Polyoxometallate catalysts 129 including tungstate may include, inter alia, [ SiV3W9O40]7-The anion may alternatively be titanium modified.
When the washing liquid is supplied to the substance container 117 through the supply line 119, the polyoxometallate catalyst 129 received in the substance container 117 reacts with the water of the washing liquid, wherein hydrogen peroxide is produced, and the washing liquid containing hydrogen peroxide is obtained. From the substance container 117, the washing liquid containing hydrogen peroxide can be supplied via the discharge line 121 to the lye container 105 for bleaching the laundry received in the washing drum 107 of the laundry care appliance 100.
Here, the supply of the washing liquid containing hydrogen peroxide into the lye container 105 can be controlled by means of the valve 123. If no washing liquid containing hydrogen peroxide is supplied to the lye container 105, the valve 123 is in the first position and the lye container 105 is fluidically separated from the substance container 117. If the valve 123 is pivoted into the second position, the substance container 117 is fluidically connected to the lye container 105 and the washing liquor containing hydrogen peroxide can be supplied from the substance container 117 to the lye container 105, and thus an effective bleaching of the laundry in the washing drum 107 can be achieved.
Thus, the supply of the washing liquid containing hydrogen peroxide, and thus the degree of bleaching of the laundry, can be regulated by the valve 123.
Fig. 3 shows a schematic view of a substance container which is fluidically connected to a water supply. In the lye container 105 of the laundry care appliance 100, a washing drum 107 is arranged for receiving laundry. The laundry care appliance 100 comprises a wash-in housing 101, wherein water is supplied from a water supply 109 to the wash-in housing 101 and wash liquor supplied by the wash-in housing 101 is supplied to the lye container 105 via a housing line 111. Furthermore, the laundry care appliance 100 has a discharge line 113, which discharge line 113 is connected to a lye pump 115, wherein the lye pump 115 is configured to: the washing liquid is pumped out of the laundry care appliance 100 through the discharge line 113.
Furthermore, the laundry care appliance 100 has a substance container 117, which substance container 117 is fluidically connected to a supply line 119 for supplying washing liquid into the substance container 117. The supply line 119 is connected to the water supply 109 of the laundry care appliance 100 for supplying water (in particular fresh water) from the water supply 109 to the substance container 117 via the supply line 119. The supply line 119 may have a further valve 133, the further valve 133 being configured to: the supply of water to the substance container 117 is controlled.
Furthermore, the substance container 117 is fluidically connected to the lye container 105 via a discharge line 121 for discharging the washing liquid from the substance container 117. The discharge line 121 has a valve 123, the valve 123 being configured to: in the first position, the lye container 105 is fluidically separated from the substance container 117, and in the second position, the substance container 117 is fluidically connected to the lye container 105. Thus, by the position of the valve 123 it is possible to control: whether washing liquid is supplied from the substance container 117 to the lye container 105.
A polyoxometallate catalyst 129 is received in the substance container 117 as explained with respect to fig. 2. In the case where the polyoxometalate catalyst 129 is contacted with the washing liquid, hydrogen peroxide is produced by a chemical reaction with water, whereby a washing liquid containing hydrogen peroxide is obtained. The supply of the washing liquid containing hydrogen peroxide into the lye container 105 can be controlled by means of the valve 123. If no washing liquid containing hydrogen peroxide is supplied to the lye container 105, the valve 123 is in the first position and the lye container 105 is fluidically separated from the substance container 117. If the valve 123 is pivoted into the second position, the substance container 117 is fluidically connected to the lye container 105 and the washing liquor containing hydrogen peroxide can be supplied to the lye container 105 and thus an effective bleaching of the laundry in the washing drum 107 can be achieved.
Fig. 4 shows a schematic view of a material container which is fluidically connected to the discharge line of the lye container. In the lye container 105 of the laundry care appliance 100, a washing drum 107 is arranged for receiving laundry. The laundry care appliance 100 comprises a wash-in housing 101, wherein water is supplied from a water supply 109 to the wash-in housing 101 and the resulting washing liquid is supplied to the lye container 105 via a housing line 111. Furthermore, the laundry care appliance 100 has a discharge line 113, which discharge line 113 is connected to a lye pump 115, wherein the lye pump 115 is configured to: the washing liquid is pumped out of the laundry care appliance 100 through the discharge line 113.
Furthermore, the laundry care appliance 100 has a substance container 117, which substance container 117 is fluidically connected to a supply line 119 for supplying washing liquid into the substance container 117. The supply line 119 is fluidically connected to the outlet line 113 (in particular the outlet container 135 of the outlet line 113). The washing liquid can thus be supplied from the discharge line 113 (or the discharge container 135) via the supply line 119 to the substance container 117. The substance container 117 is in particular designed as a washing liquid reservoir for receiving washing liquid. Furthermore, the substance container 117 is fluidically connected to the lye container 105 via a discharge line 121. The washing liquid can be pumped from the substance container 117 into the lye container 105 via the discharge line 121 by means of the liquid pump 137.
The discharge line 121 has a valve 123, the valve 123 being configured to: in the first position, the lye container 105 is fluidically separated from the substance container 117, and in the second position, the substance container 117 is fluidically connected to the lye container 105. Thus, by the position of the valve 123 it is possible to control: whether washing liquid is supplied from the substance container 117 to the lye container 105.
A polyoxometallate catalyst 129 is received in the substance container 117 as explained with reference to fig. 2 and 3. In the case where the polyoxometalate catalyst 129 is contacted with the washing liquid, hydrogen peroxide is produced by a chemical reaction with water, whereby a washing liquid containing hydrogen peroxide is obtained. The supply of the washing liquid containing hydrogen peroxide into the lye container 105 can be controlled by means of the valve 123. If no washing liquid containing hydrogen peroxide is supplied to the lye container 105, the valve 123 is in the first position and the lye container 105 is fluidically separated from the substance container 117. If the valve 123 is pivoted into the second position, the substance container 117 is fluidically connected to the lye container 105. Thereby, the washing liquid containing hydrogen peroxide can be supplied from the substance container 117 to the lye container 105, and thereby an effective bleaching of the laundry in the washing drum 107 can be achieved.
One of the many advantages of such a material container 117, along with the polyoxometalate catalyst 129 received therein, is that: without the addition of additives (e.g., detergents), a washing liquid (in particular a bleaching agent) containing hydrogen peroxide can be generated in the laundry care appliance 100. Thus enabling the laundry care appliance 100 to generate and add bleach in an automatically controlled manner. Thereby it is ensured that: depending on the specific laundry care situation (for example depending on the specific laundry care program), an optimally dosed amount of washing liquor (in particular bleaching agent) containing hydrogen peroxide can be used. This allows effective bleaching of the laundry without excessive dosing of the washing liquid containing hydrogen peroxide.
Furthermore, the polyoxometalate catalyst 129 is not consumed, so that the user of the laundry care appliance 100 does not have to purchase bleach, and there is always an effective bleaching action of the laundry care appliance 100 for use. Furthermore, no by-products harmful to the environment are produced and no unpleasant or possibly health-damaging odor is perceived by the user, which may occur, for example, when chlorine bleach is used. The continuous availability of such a washing liquid containing hydrogen peroxide, in particular a bleaching agent, can also be utilized in order to permanently keep the laundry care appliance 100 free of microorganisms and biofilm.
All features explained and illustrated in connection with a single embodiment of the invention can be provided in different combinations in the subject-matter according to the invention to achieve its advantageous effects at the same time.
The scope of protection of the invention is provided by the claims and is not limited by the features explained in the description or shown in the drawings.
List of reference numerals
100 washing nursing device
101 punch-in housing
103 door
105 lye container
107 washing drum
109 water supply part
111 shell pipeline
113 discharge line
115 lye pump
117 material container
119 supply line
121 lead-out pipeline
123 valve
125 cycle pumping system
127 pump
129 polyoxometallate catalysts
131 container wall
133 additional valve
135 discharge container
137 liquid pump
Claims (17)
1. A laundry care appliance (100) having
-a lye container (105) for receiving washing liquor,
-a washing drum (107) for receiving laundry, the washing drum being arranged in the lye container (105), and
-a substance container (117) for receiving a polyoxometalate catalyst (129),
wherein the substance container (117) is fluidically connected to a feed line (119) for feeding a washing liquid into the substance container (117),
wherein the substance container (117) is fluidically connected to a discharge line (121) for discharging the washing liquid to the lye container (105),
it is characterized in that the preparation method is characterized in that,
the polyoxometalate catalyst (129) is configured to: by chemical reaction with the washing liquid, thereby producing hydrogen peroxide to obtain a washing liquid containing hydrogen peroxide, and
the discharge line (121) has a valve (123) which is designed to: in a first position, the lye container (105) is fluidically separated from the substance container (117), and, in a second position, the substance container (117) is fluidically connected to the lye container (105) for supplying a washing liquor containing hydrogen peroxide to the lye container (105) and for effecting bleaching of the laundry in the washing drum (107),
wherein the laundry care appliance (100) has a wash-in housing (101) for supplying washing liquid,
wherein the flushing housing part (101) is fluidically connected to the lye container (105) via a housing part line (111) for conveying the washing liquid from the flushing housing part (101) via the housing part line (111) into the lye container (105),
wherein the housing part line (111) is fluidically unconnected to the feed line (119) or the discharge line (121), so that the feed of washing liquid from the flushing-in housing part (101) into the lye container (105) and the feed of washing liquid containing hydrogen peroxide from the substance container (117) into the lye container can be effected in different liquid paths.
2. Laundry care appliance (100) according to claim 1,
it is characterized in that the preparation method is characterized in that,
the supply line (119) and the discharge line (121) are each fluidically connected to the lye container (105), and
the supply line (119) is connected to a pump (127) which is designed to: washing liquid is pumped out of the lye container (105) through the supply line (119), and the pumped-out washing liquid is supplied back to the lye container (105) through the substance container (117) and through the discharge line (121).
3. Laundry care appliance (100) according to claim 1,
it is characterized in that the preparation method is characterized in that,
the lye container (105) is fluidically connected to the discharge line (113) of the laundry care appliance (100) for discharging washing liquor from the laundry care appliance (100),
the supply line (119) is fluidically connected to the discharge line (113),
the substance container (117) is designed as a washing liquid reservoir for receiving washing liquid, and
the discharge line (121) is fluidically connected to the lye container (105),
wherein the outlet line (121) is connected to a liquid pump (137) which is designed to: the washing liquid is pumped from the substance container (117) through the discharge line (121) into the lye container (105).
4. Laundry care appliance (100) according to claim 3,
it is characterized in that the preparation method is characterized in that,
the discharge line (113) having a discharge container (135) for receiving the washing liquid guided through the discharge line (113),
wherein the supply line (119) is fluidically connected to a discharge container (135) of the discharge line (113) for supplying washing liquid from the discharge container (135) via the supply line (119) to the substance container (117).
5. Laundry care appliance (100) according to claim 1,
it is characterized in that the preparation method is characterized in that,
the supply line (119) is fluidically connected to a water supply (109) of the laundry care appliance (100) in order to supply water from the water supply (109) via the supply line (119) to the product container (117).
6. The laundry care appliance (100) according to any of the preceding claims,
it is characterized in that the preparation method is characterized in that,
the polyoxometalate catalyst (129) is received in the material container (117) as polyoxometalate-coated particles.
7. The laundry care appliance (100) according to any of claims 1-5,
it is characterized in that the preparation method is characterized in that,
the polyoxometalate catalyst (129) is connected in a material-locking manner to a wall (131) of the substance container (117).
8. The laundry care appliance (100) according to any of claims 1-5,
it is characterized in that the preparation method is characterized in that,
the supply line (119) has a further valve (133) which is designed to: in a first position, the supply line (119) is fluidically separated from the substance container (117), and in a second position, the supply line (119) is fluidically connected to the substance container (117) in order to be able to supply washing liquid into the substance container (117).
9. The laundry care appliance (100) according to any of claims 1-5,
it is characterized in that the preparation method is characterized in that,
the laundry care appliance (100) comprises a selection device for selecting a plurality of laundry care programs, and
the laundry care appliance (100) comprises a control device, wherein the control device is configured to: -controlling said valve (123) according to the selected laundry care program.
10. Laundry care appliance (100) according to claim 8,
it is characterized in that the preparation method is characterized in that,
the laundry care appliance (100) comprises a control device, wherein the control device is configured to: -controlling the further valve (133) according to the selected laundry care program.
11. Laundry care appliance (100) according to any of claims 1-5, 10,
it is characterized in that the preparation method is characterized in that,
the lye container (105) is fluidically connected to the discharge line (113) of the laundry care appliance (100),
wherein the discharge pipeline (113) is connected with an alkaline liquid pump (115),
wherein the lye pump (115) is configured for: pumping washing liquid out of the laundry care appliance (100) through the discharge line (113).
12. Laundry care appliance (100) according to any of claims 1-5, 10,
it is characterized in that the preparation method is characterized in that,
a tumbling element is arranged in the substance container (117), wherein the tumbling element is configured for: the washing liquid is tumbled in the substance container (117).
13. Laundry care appliance (100) according to any of claims 1-5, 10,
it is characterized in that the preparation method is characterized in that,
an air inlet element is arranged in the product container (117), wherein the air inlet element is designed to: air is introduced into the washing liquid in the substance container (117).
14. Laundry care appliance (100) according to any of claims 1-5, 10,
it is characterized in that the preparation method is characterized in that,
the polyoxometalate catalyst (129) includes a tungstate.
15. Laundry care appliance (100) according to claim 14,
it is characterized in that the preparation method is characterized in that,
the tungstate comprises [ SiV3W9O40]7-The anion is either a titanium modified tungstate.
16. Laundry care appliance (100) according to claim 7,
it is characterized in that the preparation method is characterized in that,
the vessel wall (131) is coated with the polyoxometalate catalyst (129).
17. Laundry care appliance (100) according to claim 14,
it is characterized in that the preparation method is characterized in that,
the tungstate salt comprises vanadium.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016200602.9A DE102016200602A1 (en) | 2016-01-19 | 2016-01-19 | Laundry care device with a substance container |
DE102016200602.9 | 2016-01-19 | ||
PCT/EP2016/074860 WO2017125171A1 (en) | 2016-01-19 | 2016-10-17 | Laundry care device with a substance container |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108474168A CN108474168A (en) | 2018-08-31 |
CN108474168B true CN108474168B (en) | 2021-01-29 |
Family
ID=57218860
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201680079462.4A Active CN108474168B (en) | 2016-01-19 | 2016-10-17 | Laundry care appliance with a material container |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3405609B1 (en) |
CN (1) | CN108474168B (en) |
DE (1) | DE102016200602A1 (en) |
PL (1) | PL3405609T3 (en) |
WO (1) | WO2017125171A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019216696A1 (en) * | 2019-10-30 | 2021-05-06 | BSH Hausgeräte GmbH | Laundry care device with a filter element |
DE102020213968B3 (en) * | 2020-11-06 | 2022-02-17 | E.G.O. Elektro-Gerätebau GmbH | Washing machine and method for operating such a washing machine |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4319973A (en) * | 1977-12-06 | 1982-03-16 | Battelle Memorial Institute | Method and machine for washing and bleaching textiles |
US6074437A (en) * | 1998-12-23 | 2000-06-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Bleaching with polyoxometalates and air or molecular oxygen |
US6513180B2 (en) * | 2001-05-10 | 2003-02-04 | Maytag Corporation | Washing machine incorporating a bleach activator |
KR100480726B1 (en) * | 2002-11-26 | 2005-04-07 | 엘지전자 주식회사 | Washing machine and of the same method |
EP1739207A3 (en) * | 2005-06-27 | 2007-10-03 | Unilever N.V. | Peroxide generating device and method |
GB2437079A (en) * | 2006-04-11 | 2007-10-17 | Dyson Technology Ltd | Hydrogen peroxide production apparatus |
CN102444005B (en) * | 2011-09-23 | 2013-09-04 | 南京乐金熊猫电器有限公司 | Device and method for preventing liquid detergents from being fed by mistake |
DE102011083578B4 (en) * | 2011-09-28 | 2019-10-24 | BSH Hausgeräte GmbH | Process for softening laundry in a washing machine and washing machine suitable for this purpose |
DE102011083572A1 (en) | 2011-09-28 | 2013-03-28 | BSH Bosch und Siemens Hausgeräte GmbH | Water-conducting household appliance with a catalytically active internal surface and method for its operation |
DE102013205302A1 (en) | 2013-03-26 | 2014-10-16 | BSH Bosch und Siemens Hausgeräte GmbH | Domestic appliance with a catalytically active surface and method for its operation |
-
2016
- 2016-01-19 DE DE102016200602.9A patent/DE102016200602A1/en not_active Withdrawn
- 2016-10-17 WO PCT/EP2016/074860 patent/WO2017125171A1/en active Application Filing
- 2016-10-17 CN CN201680079462.4A patent/CN108474168B/en active Active
- 2016-10-17 PL PL16788647T patent/PL3405609T3/en unknown
- 2016-10-17 EP EP16788647.2A patent/EP3405609B1/en active Active
Also Published As
Publication number | Publication date |
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DE102016200602A1 (en) | 2017-07-20 |
WO2017125171A1 (en) | 2017-07-27 |
PL3405609T3 (en) | 2020-07-27 |
CN108474168A (en) | 2018-08-31 |
EP3405609B1 (en) | 2020-02-05 |
EP3405609A1 (en) | 2018-11-28 |
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