CN108472238A - Hair styling compositions containing nonionic and amphoteric polymers - Google Patents
Hair styling compositions containing nonionic and amphoteric polymers Download PDFInfo
- Publication number
- CN108472238A CN108472238A CN201780006413.2A CN201780006413A CN108472238A CN 108472238 A CN108472238 A CN 108472238A CN 201780006413 A CN201780006413 A CN 201780006413A CN 108472238 A CN108472238 A CN 108472238A
- Authority
- CN
- China
- Prior art keywords
- composition
- acrylate
- range
- methacrylate
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The present invention is in the field of cosmetics and relates to a hair styling composition comprising a vinylcaprolactam/VP/dimethylaminoethyl methacrylate copolymer and an amphoteric copolymer. The compositions exhibit synergistic improvement in styling performance when applied to human hair.
Description
Technical field
The invention belongs to cosmetic fields, and are related to a kind of including caprolactam/VP/ dimethylaminoethyl acrylate methyl bases
The hair setting composition of amino-ethyl ester copolymer and ampholyte copolymer.The composition for meeting the present invention is being administered to human tau
Outstanding shaping performance is provided after hair.
Background technology
Beautiful and attractive appearance is many Man's Demands.Therefore, the daily personal nursing of people is essential
Part focus on hair.In general, using shampoo to clean hair first.It is then possible to provide the tune of hair using hair conditioner
Reason.Therefore, hair conditioner can be formulated into be administered to hair and then the rinse-off products that are rinsed with water or application after be retained in
Conservative product in dry hair or wet hair.After conditioning, hair can be shaped using fixed creams, gel or spray.Or
Person can fix hair style or enhancing curling using hair mousse.
All products listed above have in common that, for a variety of different beneficial reasons, their formula is logical
Often all contain polymer.For example, polymer can be used for thickening or the purpose that forms a film, and for providing nursing or in cosmetic composition
It is middle to help out as dispersion enhancing agent.Hair setting composition preferably contains polymer as setting agent, wherein institute
State the rigidity that polymer improves hair.In addition, the hair style that the polymer as setting agent can improve hair keeps or determines again
Type performance.Further, it is desirable to which the polymer as setting agent does not make hair feel dry after application.Especially for application
To have if hair feels moistening and/or humidity while sizing to for the aqueous or alcohol gel spray of dry hair
Benefit.
However, the polymer used in hair setting composition is usually customized to only show in one or more
The benefit that face discusses.Therefore, the composition usually contains many different polymer, and it is fixed to provide satisfactory hair with covering
Benefiting needed for type.Therefore, the merging of different polymer may be problematic, because in the composition may hair
Biochemical reaction.These chemical reactions may cause the undesired reuniting effect of the composition.In addition, containing there are many polymerizations
The preparation of the hair setting composition of object may be expensive.Therefore it provides the polymer of a variety of benefits can be provided simultaneously
Combination, is still desirable.
2008/052886 A2 of WO describe hair setting composition, provide thickening and film-forming quality and high
Conservation degree, without abandoning flexible and good humidity resistance.The hair setting composition include at least one copolymer and
At least one film forming and/or solid film amphoteric polymer.Wherein, according to 2008/052886 A2 of WO, can select acrylate/
Lauryl acrylate/octadecyl acrylate/amine oxides methacrylate copolymer, which is used as, is included in the formula
In ampholyte copolymer.However, 2008/052886 A2 of WO are not mentioned using acrylate/lauryl acrylate/acrylic acid
Stearyl/amine oxides methacrylate copolymer and caprolactam/VP/ dimethylaminoethyl acrylate methyl base ammonia
The combination of base ethyl ester copolymer.
2011/048179 A1 of WO disclose the cosmetic composition for keratin fiber moulding.According to WO 2011/
In addition the description of 048179 A1, the composition can contain at least one film forming and/or solid membrane polymer.This polymer
Anion, both sexes, nonionic, permanent cation and temporary cationic polymer can be selected from.Listed above each is gathered
It is other to close species, discloses the extensive list of possible polymer.Wherein, as amphoteric polymer, acrylate/propylene is listed
The polymer of sour lauryl/octadecyl acrylate/amine oxides methacrylate copolymer type.As temporary sun
An example in ionomer classification can find caprolactam/VP/ dimethylamine ethyls
Ester copolymer.However, there is no disclosure introduction by such as both sexes of the polymer of certain classifications in 2011/048179 A1 of WO and
It will be beneficial that temporary cationic polymer, which is combined,.In addition, also no disclosure is built in 2011/048179 A1 of WO
The combination of the present invention is discussed to provide the effect in front, collaboration on the shaping performance of hair.
2013/087315 A2 of WO disclose a kind of powder cosmetic combination for the temporary moulding containing keratin fiber
Object, according to description can contain selected from nonionic, anion, both sexes and cationic polymer at least one polymer.Together
Sample, for each polymer classes, provide the extensive list of possible polymer.Therefore, in non-ionic polymers group
Caprolactam/VP/ dimethylamine ethyl ester copolymers can be found.In description amphoteric polymer
In chapters and sections, the amphoteric polymer with similar structure in the present invention is also listed.However, 2013/087315 A2 of WO are not old
State by selected polymer group be combined whether the beneficial fact.Therefore, in view of 2013/087315 A2 of WO, to hair fixing
It is non-obvious that composition adds both both sexes and non-ionic polymers simultaneously.In addition, in the nonionic stated and two
Property polymer group in select the present invention copolymer specific combination with to the shaping performance of hair provide front, collaboration effect
Fruit, it is even more non-obvious.
Other documents for containing the component of at least one present invention for being dedicated to hair fixing are such as DE
102011089578 2006/044193 A2 and 1997/004796 A1 of WO of A1, WO.The document of the reference is all without open
Any guidance to the present invention.
Summary of the invention
The present invention is to provide for the combination with the polymer of improved human hair's shaping performance.Surprisingly
It was found that including caprolactam/VP/ dimethylamine ethyl ester copolymers and hereinafter defined one kind
Or the hair setting composition of a variety of ampholyte copolymers, outstanding shaping performance is shown after being administered to human hair.Specifically
For, it was unexpectedly determined that the combination of polymers of the present invention shows that the collaboration of shaping performance changes when being administered to human hair
It is kind.
Therefore, the first object of the present invention is a kind of hair setting composition for human hair, and it includes vinyl
Caprolactam/VP/ dimethylamine ethyl ester copolymers and one or more ampholyte copolymers, the both sexes are poly-
Close object polymerization certainly：
At least one monomer (MO1) is selected from acrylic acid, methacrylic acid, alkyl acrylate and methacrylic acid
Arrcostab, and
At least one monomer (MO2) is selected from the monomer of formula (I)
Wherein R1It is hydrogen or CH3Group, n are the integers in 1 to 4 range, and p is the integer in 1 to 10 range, and q is 1
Integer to 10 ranges,
With the monomer of formula (II)
Wherein R2It is hydrogen or CH3Group, r are the integers in 1 to 4 range, and s is the integer in 1 to 10 range, and t is 1 to 10
Integer in range, and u is the integer in 1 to 4 range.
Another object of the present invention is the purposes of the composition of the present invention, is used for the interim moulding of human hair.
The hair setting composition of the present invention includes caprolactam/VP/ dimethylamine ethyls
Ester copolymer.Caprolactam/VP/ dimethylamine ethyl ester copolymers are by monomer N- ethylene pyrroles
The nonionic that alkanone (VP), n- vinyl caprolactams and methacrylic acid 2- (dimethylamino) ethyl ester (DMAEMA) are formed is poly-
Close object.
In the present compositions, caprolactam/VP/ dimethylamine ethyl ester copolymers
Total concentration relative to total composition by weight 0.1% to 10%, preferably 0.5% to 5%, most preferably 1% to 4%
In the range of.
In general, caprolactam/VP/ dimethylamine ethyl ester copolymers are in alcohol and/or water
It is supplied in property solution.Caprolactam/VP/ dimethylamine ethyl ester copolymers can be suspended and/
Or it is dissolved in the solution.
The hair setting composition of the present invention to composition addition preferably by being used as alcohol and/or aqueous suspension
The caprolactam/VP/ dimethylamine ethyl ester copolymers prepare, wherein solid content
Total weight relative to the alcohol suspension is about 10% to 50%, preferably 28% to 40% by weight.
Alcohol suspension containing caprolactam/VP/ dimethylamine ethyl ester copolymers can be with
From Fa.Ashland with trade name GaffixTMCommercially available from VC-713 polymer.Contain caprolactam/VP/ methacrylic acids
The aqueous solution of dimethyl aminoethyl ester copolymer can be from Fa.Ashland with trade name Advantage S solution polymers
Purchase.
The hair setting composition of the present invention includes one or more ampholyte copolymers, and the ampholyte copolymer polymerization is free
From at least one monomer (MO1) of acrylic acid, methacrylic acid, alkyl acrylate and alkyl methacrylate and selected from formula
(I) and at least one monomer of the monomer of formula (II) (MO2).
The alkyl of alkyl acrylate and alkyl methacrylate can contain at most 24 carbon atoms.
According to the present invention, the alkyl acrylate can be preferably chosen from methyl acrylate, ethyl acrylate, acrylic acid
Propyl ester, isopropyl acrylate, butyl acrylate, isobutyl acrylate, Hexyl 2-propenoate, 2-ethyl hexyl acrylate, decyl acrylate, third
Olefin(e) acid lauryl, acrylic acid tetradecane base ester, aliphatic acrylate and/or octadecyl acrylate.
In addition, the alkyl methacrylate can be preferably chosen from methyl methacrylate, ethyl methacrylate,
Propyl methacrylate, isopropyl methacrylate, butyl methacrylate, Isobutyl methacrylate, methacrylic acid oneself
Ester, 2-Propenoic acid, 2-methyl-, octyl ester, decyl-octyl methacrylate, lauryl methacrylate, methacrylic acid tetradecane base ester, methyl-prop
Olefin(e) acid cetyl ester and/or octadecyl methacrylate.
In the hair setting composition of the present invention, the total concentration of one or more ampholyte copolymers is relative to total
Composition by weight preferably 0.1% to 10%, more preferably 0.5% to 5%, most preferably 0.75% to 3% range
It is interior.
In addition, in an embodiment of the invention, one or more ampholyte copolymers and vinyl acyl in oneself
The ratio of amine/VP/ dimethylamine ethyl ester copolymers is by weight 2:1 to 1:3, preferably by weight
1:1.8 to 1:2.2.It has been surprisingly discovered that especially by weight 1:1.8 to 1:Under 2.2 ratio, it was found that two
Kind of polymer dried in room conditions about hair damp, the hair after application at once after rigidity and hair style keep and
The synergistic effect of the shaping performance again of 4 hours hairs after application.
In a preferred embodiment of the present invention, the hair setting composition contains only a kind of amphoteric polymer,
The wherein described amphiprotic copolymer poly closes certainly：
At least two monomers (MO1), wherein one of described monomer be selected from acrylic acid, methyl acrylate, ethyl acrylate,
Propyl acrylate, isopropyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate and methyl-prop
Isopropyl gadoleate, and second of monomer is selected from octadecyl acrylate and octadecyl methacrylate, and
The monomer (MO2) of following structures
Wherein R1It is CH3Group, n are the integers in 1 to 4 range, and p is the integer in 1 to 2 range, and q is 1 to 2 model
Enclose interior integer.
The preferred ampholyte copolymer for meeting above-mentioned requirements is acrylate/octadecyl acrylate/amine oxides
Methacrylate copolymer.This copolymer can be with trade name Diaformer Z-632 and Diaformer Z-772 quotient
Purchase.Two kinds of products can be bought from Fa.Mitsubishi Chemical.
In another preferred embodiment of the present invention, the hair setting composition contains only a kind of both sexes copolymerization
Object, wherein the amphiprotic copolymer poly closes certainly：
At least two monomers (MO1), wherein the monomer is selected from acrylic acid, methyl acrylate, ethyl acrylate, propylene
Propyl propionate, isopropyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate and methacrylic acid
Isopropyl ester, and
The monomer (MO2) of following structures
Wherein R2It is CH3Group, r are the integers in 1 to 4 range, and s is the integer in 1 to 2 range, and t is in 1 to 2 range
Integer, and u be equal to 1.
The preferred ampholyte copolymer for meeting above-mentioned requirements is Methacryloyl ethyl betaine/acrylic ester copolymer
Object, can be with trade name Yukaformer commercially available from.The copolymer of Yukaformer types can be from Fa.Mitsubishi
Chemical is bought.
In the more preferable embodiment of the present invention, the hair setting composition contains only a kind of amphoteric polymer,
Described in ampholyte copolymer polymerization from：
At least three kinds of monomers (MO1), wherein one of described monomer be selected from acrylic acid, methyl acrylate, ethyl acrylate,
Propyl acrylate, isopropyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate and methyl-prop
Isopropyl gadoleate, second of monomer are selected from octadecyl acrylate and octadecyl methacrylate, the choosing of the third monomer
From lauryl acrylate and lauryl methacrylate, and
The monomer (MO2) of following structures
Wherein R1It is CH3Group, n are the integers in 1 to 4 range, and p is the integer in 1 to 2 range, and q is 1 to 2 model
Enclose interior integer.
The preferred amphoteric polymer for meeting above-mentioned requirements is acrylate/lauryl acrylate/octadecyl base
Ester/amine oxides methacrylate copolymer.This polymer can with trade name Diaformer Z-631 and
Commercially available from Diaformer Z-651.Two kinds of products can be bought from Fa.Mitsubishi Chemical.
In general, acrylate/lauryl acrylate/octadecyl acrylate/amine oxides methacrylate is total
Polymers is supplied in aqueous and/or alcohol solution.Acrylate/lauryl acrylate/octadecyl acrylate/ethamine oxidation
Object methacrylate copolymer can be suspended and/or be dissolved in this solution.
Preferably, to composition addition as the aqueous acrylate/lauryl acrylate with alcohol solution/
Octadecyl acrylate/amine oxides methacrylate copolymer, wherein described aqueous and alcohol solution preferably contains
Have：
20% to 40% acrylate/lauryl acrylate/octadecyl acrylate/ethamine oxidation by weight
Object methacrylate copolymer,
50% to 70% ethyl alcohol by weight,
1% to 20% water by weight,
More preferably contain
28% to 32% acrylate/lauryl acrylate/octadecyl acrylate/ethamine oxidation by weight
Object methacrylate copolymer,
61% to 65% ethyl alcohol by weight,
5% to 9% water by weight,
The amount is calculated relative to described aqueous and alcohol solution total weight.
It is described to contain acrylate/lauryl acrylate/octadecyl acrylate/ethamine oxygen in the case of furthermore it is preferred that
Compound methacrylate copolymer, second alcohol and water aqueous and alcohol solution be characterized in that described aqueous and alcohol solution tool
Have when being measured at a temperature of 20 DEG C, 600mPas to 1300mPas, preferably 800mPas to 1100mPas, more
Viscosity within the scope of preferably 900mPas to 1000mPas.It has been found, surprisingly, that by with as described above viscous
The aqueous and alcohol solution of degree prepares the composition of the present invention, finds the hair fixing performance of the hair setting composition of the present invention
It is improved.It is this to contain acrylate/lauryl acrylate/octadecyl acrylate/amine oxides methacrylic acid
Ester copolymer, second alcohol and water aqueous and alcohol solution can be from Fa.Mitsubishi Chemical with trade name
Commercially available from Diaformer Z-631.Using measurement method described below, the viscosity of Diaformer Z-631 is according to surveying and determination at 20 DEG C
It is 930mPas down.
It may include two kinds in the hair setting composition of the present invention in another preferred embodiment of the present invention
Or more ampholyte copolymer, wherein these ampholyte copolymers be selected from acrylate/lauryl acrylate/octadecyl base
Ester/amine oxides methacrylate copolymer, Methacryloyl ethyl betaine/acrylate copolymer and acrylic acid
Ester/octadecyl acrylate/amine oxides methacrylate copolymer.By combining two or more these copolymerization
Object, composition of the invention provide outstanding shaping performance for human hair.
In addition, in an embodiment of the invention, hair setting composition of the invention preferably includes water.It is preferred that
Ground, in the present compositions the concentration of water relative to the total weight of the composition by weight more than 80%, more preferably
Ground is by weight more than 90%.
In yet another embodiment of the present invention, hair setting composition of the invention preferably includes ethyl alcohol.It is preferred that
Ground, in the present compositions the concentration of ethyl alcohol relative to the total weight of the composition by weight more than 80%, it is more excellent
Selection of land is by weight more than 90%.
The hair setting composition of the present invention preferably contains one or more water-soluble solvents.Preferred water-soluble solvent
It is glycerine, ethylene glycol and propylene glycol.The concentration of one or more water-soluble solvents amount to relative to total composition with weight
In the range of gauge preferably 0.1% to 5%, more preferably 0.25% to 3%, most preferably 0.5% to 2%.
The hair setting composition of the present invention can also include at least one vitamin, provitamin or derivatives thereof, with
Additional nursing is provided for hair and/or skin.This vitamin, provitamin or derivatives thereof, which can be selected from, is assigned to dimension life
The all substances of the group of plain A, vitamin B, vitamin C, vitamin E, vitaminF and biotin.Preferably it is assigned to B
Vitamin, provitamin and its derivative of family vitamin.It may be embodied in the preferred dimension life in the composition of the present invention
Element is panthenol and/or niacinamide.
The vitamin, provitamin and its derivative preferably with relative to total composition by weight 0.05% to
1% total concentration uses.
In a preferred embodiment of the invention, only in the composition comprising panthenol and/or niacinamide as the present invention
Vitamin, provitamin and its derivative.
The hair setting composition of the present invention preferably includes one or more emulsifying agents.These emulsifiers can be selected from the moon
Ion, cation, both sexes and nonionic emulsifier.Most preferably nonionic emulsifier.
Nonionic emulsifier can be preferably chosen from the fatty glyceride containing 4 to 500 polyalkylene units or partially
The polyalkylene glycol ethers of drier oil fat.Their suitable but non-limiting examples are PEG-30 rilanit specials, PEG-35 hydrogenations
Castor oil, Cremophor RH40, PEG-45 rilanit specials, PEG-50 rilanit specials, PEG-55 rilanit specials,
PEG-60 rilanit specials, PEG-65 rilanit specials, PEG-70 rilanit specials, PEG-75 rilanit specials, PEG-80 hydrogen
Change castor oil, PEG-100 rilanit specials, PEG-150 rilanit specials, PEG-200 rilanit specials.
In addition, the polyalkylene glycol ethers of fatty glyceride or inclined drier oil fat are preferably defined by following formula (III)s：
Wherein R3、R4And R5Linear chain or branched chain independently selected from hydrogen or comprising 6 to 22 carbon atoms, saturation and/or insatiable hunger
The acyl group free radical of sum, and wherein v, w and x are the integers in 0 to 500 range, and the wherein summation of integer v, w and x must wait
In 3 or bigger.Suitable example is PEG-6 caprylic/caprics glyceride, PEG-8 caprylic/caprics glyceride, PEG-6 capric acid glycerine
Ester, PEG-3 cocounut oil acid glyceride, PEG-7 cocounut oil acid glyceride, PEG-30 cocounut oil acid glyceride, PEG-40 cocounut oil acid glyceride,
PEG-80 cocounut oil acid glyceride, bis- glyceryl isostearates of PEG-15, bis- glyceryl isostearates of PEG-30, PEG-12 distearyls
Acid glyceride, PEG-8 glyceryl laurate esters, PEG-20 glyceryl laurate esters, PEG-20 tristerins and PEG-30 are stearic
Acid glyceride.
Most preferred nonionic emulsifier is Cremophor RH40, PEG-6 caprylic/caprics glyceride and its mixing
Object.
In the hair setting composition of the present invention, the total concentration of one or more nonionic emulsifiers is preferably opposite
In the range of total composition by weight 0.05% to 5%, more preferably 0.1% to 0.5%.
In a preferred embodiment of the invention, include only Cremophor RH40 and PEG-6 caprylic/capric glyceride
As nonionic emulsifier, wherein in the present compositions the total concentration of two kinds of emulsifiers relative to total composition with weight
In the range of gauge 0.1% to 0.5%.
The hair setting composition of the present invention can also include one or more preservatives.Preservative is to prevent cosmetics group
Close the substance that object is decomposed due to microorganism growth or undesired chemical change.
The preferred preservative for including in the present compositions is Phenoxyethanol, Sensiva SC50, para hydroxybenzene first
Sour methyl esters, ethyl-para-hydroxybenzoate, butyl p-hydroxybenzoate, methylisothiazolinone, chlormethylisothiazo,ine ketone
(chlormethylisothiazolinone), DMDM- glycolylureas (bis- (the methylol) -5,5- Dimethyl Hydan of 1,3-) and/or its
Mixture.
The total concentration of one or more preservatives described in the hair setting composition of the present invention is relative to total combination
Object is by weight in the range of 0.1% to 3%, preferably 0.2% to 0.8%.
The hair setting composition of the present invention can also contain one or more other film forming or hair strengthens polymer,
It can be selected from anionic polymer, cationic polymer, non-ionic polymers and/or amphoteric polymer.
Film forming polymer be understood to be ought by weight 0.01% to 20% concentration in aqueous, alcohol or aqueous -ol
Property composition in use, can on hair deposited polymer membrane polymer, wherein the concentration is relative to total combination
Object calculates.
Hair strengthens the polymer that polymer is understood to be for moulding and fixes hair.Retain examination in common curling
All polymer for improving hair intensity when middle measurement are tested, is all understood to be hair and strengthens polymer.Curling retains mensuration
Description can for example be found in US 5089253A.
However, since the hair setting composition of the present invention provides surprising good shaping performance by oneself, preferably
Ground, composition of the invention strengthen polymer without other film forming or hair.
In the sense of the present invention, film forming or hair is not taken as clearly to strengthen polymer containing silicone polymer.Therefore,
The hair setting composition of the present invention can also contain silicone species containing one or more, to provide effective hair conditioning.This
A little substances can be silicone oil or silicon-containing polymer such as silicone Quaternium-18 or other polymerizations for containing quaternary ammonium group and silicon
Object.
However, since silicone compounds usually cause hair sagging, it is therefore preferred to the hair setting compositions of the present invention
Without containing silicone polymer.
The another kind of conditioner that can be optionally added to the hair setting composition of the present invention is protein and polyprotein
Hydrolysate, such as hydrolysis fibroin, hydrolyzed wheat protein and/or Hydrolyzed Collagen.
The present invention hair setting composition can also include pearlescent pigment, mica and/or effect pigment, with prepare regarding
Attractive composition in feel.
The hair setting composition for meeting the present invention can also include following substance, such as ultraviolet protective agent, dyestuff, ubiquinone
Such as Co-Q10, plant extracts, antioxidant such as oryzanol and fragrance.
The hair setting composition for meeting the present invention preferably can be hair mousse, aerosol hair spray agent, non-aerosol
Gel spray, gel and/or wax.
The most preferably non-aerosol gel spray with 0.2 to 200mPas viscosity at a temperature of 20 DEG C,
And it is comprised in pump spray.
The composition of the present invention and the viscosity of raw material use Brookfield RVT (Brookfield
Engineering it) measures.The measurement carries out at a temperature of 20 DEG C.Agitating device for the measurement is that RV-4 turns
Son.Rotary speed is set to 20min-1。
In the sense of the present invention, term " ... after at once " mean at most 1 minute period, term " being free of " meaning
The total concentration that taste the substance being previously mentioned in the hair setting composition of the present invention does not surpass by weight relative to total composition
0.1% is crossed, and term " indoor conditions " is defined as 20 DEG C and 1013mbar.
Embodiment
The following examples will illustrate the hair setting composition of the present invention, but is not intending to and limits the invention to these implementations
Example.Numerical value in embodiment is with the weight percent of the total weight of composition.The composition is by existing each component
It is mixed in water to prepare.
Embodiment 1-4：Aqueous hair spray
Inv=meets the invention example of the present invention
1Come from the Gaffix of AshlandTMVC-713 polymer, active component content are 37 weight %
2Come from the DIAFORMER Z-631 of Mitsubishi Chemical, active component content is 30 weight %
3Come from the DIAFORMER Z-632 of Mitsubishi Chemical, active component content is 30 weight %
Embodiment 5-8：Aqueous hair spray
Inv=meets the invention example of the present invention
1Come from the Gaffix of AshlandTMVC-713 polymer, active component content are 37 weight %
2Come from the DIAFORMER Z-631 of Mitsubishi Chemical, active component content is 30 weight %
3Come from the DIAFORMER Z-632 of Mitsubishi Chemical, active component content is 30 weight %
4Come from the YUKAFORMER SM of Mitsubishi Chemical, active component content is 30 weight %
Embodiment 9-13：Aqueous solution
Following experiments have been carried out, to show by using the composition of the present invention, have provided the solution of problem described above
Certainly scheme.The experiment of the progress is hai roll experiment (hair tresses test).Assessment by well-trained hairdresser into
Row.Asia dark hair (each testing 10g) is tested shown in this article.
Following compositions are had evaluated in hai roll experiment：
Com=does not meet the comparative example of the present invention
Inv=meets the invention example of the present invention
1Come from the Gaffix of AshlandTMVC-713 polymer, active component content are 37 weight %
2Come from the DIAFORMER Z-631 of Mitsubishi Chemical, active component content is 30 weight %
The sizing of human hair depends on multiple parameters.According to the present invention, determine to be applied to the composition of human hair
Type performance corresponds to the damp of hair at once after application, the rigidity for the hair assessed after dry hair in room conditions and
Hair style is kept, and 4 hours hairs with water wetting (per 10g hair 0.5g water) after the application hair setting composition
Again shaping performance.In order to evaluate the shaping performance of composition, all parameters described below are assessed by stylist：It sends out at once after application
The damp of volume, hai roll dry in room conditions after rigidity and hair style keep, and 4 hours hairs are again after application
Shaping performance.
Detailed test procedure is as follows：
The hai roll is cleaned using the shampoo composite without any conditioner.For this purpose, by the hai roll warm water
Wetting, then shampoo is applied and be dispersed on entire hair 10 seconds.For each sample, apply same amount of shampoo.
Then the shampoo composite is washed off from hair with warm water, until being remained without shampoo.Applying embodiment to be tested
Before composition, the hai roll is dried.
In order to assess shaping performance, 2.2g Hairstyling compositions are sprayed on dry hai roll.Then stylist with hand by being spread
Entire hai roll is opened up to assess the damp of hair.Then, it places it under indoor conditions until hair is completely dried.In order to assess
The rigidity of hair, stylist analyze the power applied required for digital flexion hai roll.In this stage, exist also by analysis hai roll
Holding after touched keeps to assess hair style.Analyze shaping performance again within 4 hours after applying said compositions.Mesh thus
, 0.5g water is sprayed on hair and is molded hair again with hand.Again the shaping performance is according to whether may be again
The fact that shaping hair, is evaluated.
Each parameter is evaluated using the score value between 1 to 7, wherein 1 mean it is bad, 7 correspond to it is good.It answers herein
This is pointed out, for damp, 7 score value means that hair feel is moist after the application hair spray.Rigidity is come
It says, 7 score value means that hair is stiffening.For hair style holding, 7 score value means that hair style keeps good after application.
For after 4 hours again for sizing, 7 score value means after applying said compositions 4 hours can shaping hair again.
Since all parameters listed all contribute the shaping performance of composition, by dividing for the gain of parameter
Value is added, to evaluate the overall shaping performance of the composition.
All results are presented in the following table：
In the upper table for showing test result, composition embodiment 9 and embodiment 13 are determined and arrive worst sizing
Performance, these compositions only contain required one of the substance of the present invention, therefore do not meet the present invention.For the group of all present invention
It closes for object, that is, embodiment 10, embodiment 11 and embodiment 12, shows the improved shaping performance compared with non-present invention sample.
Since the total concentration of the polymer in the composition of all experiments is 3%, it is thus determined that the collaboration of the composition of the present invention
Effect.
Claims (28)
1. for the hair setting composition of human hair, it includes caprolactam/VP/ dimethylaminoethyl acrylate methyl base ammonia
Base ethyl ester copolymer and one or more ampholyte copolymers, the ampholyte copolymer polymerization is certainly：
At least one monomer (MO1) is selected from acrylic acid, methacrylic acid, alkyl acrylate and methacrylate
Ester, and
At least one monomer (MO2) is selected from the monomer of formula (I)
Wherein R1It is hydrogen or CH3Group, n are the integers in 1 to 4 range, and p is the integer in 1 to 10 range, and q is 1 to 10
Integer in range,
With the monomer of formula (II)
Wherein R2It is hydrogen or CH3Group, r are the integers in 1 to 4 range, and s is the integer in 1 to 10 range, and t is 1 to 10 range
Interior integer, and u is the integer in 1 to 4 range.
2. composition according to claim 1, it is characterised in that caprolactam/VP/ dimethylamines
The concentration of ethyl ester copolymer relative to total composition by weight 0.1% to 10% in the range of.
3. composition according to claim 2, it is characterised in that caprolactam/VP/ dimethylamines
The concentration of ethyl ester copolymer relative to total composition by weight 0.5% to 5% in the range of.
4. composition according to claim 3, it is characterised in that caprolactam/VP/ dimethylamines
The concentration of ethyl ester copolymer relative to total composition by weight 1% to 4% in the range of.
5. according to the composition of any one of Claims 1-4, it is characterised in that the concentration of one or more ampholyte copolymers
Relative to total composition by weight 0.1% to 10% in the range of.
6. composition according to claim 5, it is characterised in that the concentration of one or more ampholyte copolymers relative to
Total composition is by weight in the range of 0.5% to 5%.
7. composition according to claim 6, it is characterised in that the concentration of one or more ampholyte copolymers relative to
Total composition is by weight in the range of 0.75% to 3%.
8. composition according to any one of claims 1 to 7, it is characterised in that one or more ampholyte copolymers and ethylene
The ratio of base caprolactam/VP/ dimethylamine ethyl ester copolymers is 2 by weight:1 to 1:3.
9. composition according to claim 8, it is characterised in that one or more ampholyte copolymers and vinyl acyl in oneself
The ratio of amine/VP/ dimethylamine ethyl ester copolymers is 1 by weight:1.8 to 1:2.2.
10. according to the composition of any one of claim 1 to 9, it is characterised in that contain only a kind of both sexes in the composition
Polymer, and the wherein described amphiprotic copolymer poly closes certainly：
At least two monomers (MO1), wherein one of described monomer is selected from acrylic acid, methyl acrylate, ethyl acrylate, propylene
Propyl propionate, isopropyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate and methacrylic acid
Isopropyl ester, and second of monomer is selected from octadecyl acrylate and octadecyl methacrylate and following structures
Monomer (MO2)
Wherein R1It is CH3Group, n are the integers in 1 to 4 range, and p is the integer in 1 to 2 range, and q is in 1 to 2 range
Integer.
11. composition according to claim 10, it is characterised in that contain acrylate/octadecyl acrylate/ethamine oxygen
Compound methacrylate copolymer is as amphoteric polymer.
12. according to the composition of any one of claim 1 to 9, it is characterised in that the hair setting composition contains only one kind
Ampholyte copolymer, wherein the amphiprotic copolymer poly closes certainly：
At least two monomers (MO1), wherein the monomer is selected from acrylic acid, methyl acrylate, ethyl acrylate, acrylic acid third
Ester, isopropyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate and methacrylic acid isopropyl
Ester, and
The monomer (MO2) of following structures
Wherein R2It is CH3Group, r are the integers in 1 to 4 range, and s is the integer in 1 to 2 range, and t is whole in 1 to 2 range
Number, and u is equal to 1.
13. composition according to claim 12, it is characterised in that total containing Methacryloyl ethyl betaine/acrylate
Polymers is as amphoteric polymer.
14. according to the composition of any one of claim 1 to 9, it is characterised in that the hair setting composition contains only one kind
Amphoteric polymer, wherein the amphiprotic copolymer poly closes certainly：
At least three kinds of monomers (MO1), wherein one of described monomer is selected from acrylic acid, methyl acrylate, ethyl acrylate, propylene
Propyl propionate, isopropyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate and methacrylic acid
Isopropyl ester, second of monomer are selected from octadecyl acrylate and octadecyl methacrylate, the third monomer is selected from third
Olefin(e) acid lauryl and lauryl methacrylate, and
The monomer (MO2) of following structures
Wherein R1It is CH3Group, n are the integers in 1 to 4 range, and p is the integer in 1 to 2 range, and q is in 1 to 2 range
Integer.
15. composition according to claim 14, it is characterised in that contain acrylate/lauryl acrylate/acrylic acid 18
Arrcostab/amine oxides methacrylate copolymer is as amphoteric polymer.
16. according to the composition of any one of claim 1 to 9, it is characterised in that can in the hair setting composition of the present invention
To include two or more ampholyte copolymers, wherein these ampholyte copolymers are selected from acrylate/lauryl acrylate/propylene
Sour stearyl/amine oxides methacrylate copolymer, Methacryloyl ethyl betaine/acrylic ester copolymer
Object and acrylate/octadecyl acrylate/amine oxides methacrylate copolymer.
17. according to the composition of any one of claim 1 to 16, it is characterised in that the composition includes also water, and in institute
The concentration of water in composition is stated relative to total composition by weight more than 80%.
18. according to the composition of any one of claim 1 to 16, it is characterised in that the composition also includes alcohol, preferably second
Alcohol, and in the composition the concentration of ethyl alcohol relative to total composition by weight more than 80%.
19. according to the composition of any one of claim 1 to 18, it is characterised in that the composition includes selected from glycerine, second two
The total concentration of one or more water-soluble solvents of alcohol and propylene glycol, the solvent is by weight relative to total composition
0.1% to 5%.
20. according to the composition of any one of claim 1 to 19, it is characterised in that the composition include selected from panthenol and/or
One or more vitamins of niacinamide, provitamin or derivatives thereof, total concentration is by weight relative to total composition
0.05% to 1%.
21. according to the composition of any one of claim 1 to 20, it is characterised in that the composition includes one or more emulsifications
Agent.
22. composition according to claim 21, it is characterised in that the composition includes Cremophor RH40, PEG-6
Caprylic/capric glyceride and its mixture as emulsifier, total concentration relative to total composition be by weight 0.05% to
5%.
23. according to the composition of any one of claim 1 to 22, it is characterised in that the composition includes one or more anti-corrosions
Agent, the preservative be selected from Phenoxyethanol, Sensiva SC50, methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, to hydroxyl
Yl benzoic acid butyl ester, methylisothiazolinone, chlormethylisothiazo,ine ketone, DMDM- glycolylureas (bis- (the methylol) -5,5- of 1,3- two
Methyl hydantoin) and/or its mixture, total concentration is 0.1% to 3% by weight relative to total composition.
24. according to the composition of any one of claim 1 to 23, it is characterised in that the composition is free of film forming polymer or head
Hair strengthens polymer.
25. according to the composition of any one of claim 1 to 24, it is characterised in that the composition, which is free of, contains silicone polymer.
26. according to the composition of any one of claim 1 to 25, it is characterised in that the composition has at a temperature of 20 DEG C
0.2 to 200mPas viscosity, and be accommodated in pump spray.
27. the method for preparing claim 1 to 26 any one of them composition, wherein each component is mixed in water
It closes.
28. being used for the purposes of the interim moulding of human hair according to the composition of any one of claim 1 to 26.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNPCT/CN2016/076670 | 2016-03-18 | ||
| PCT/CN2016/076670 WO2017156756A1 (en) | 2016-03-18 | 2016-03-18 | Hair styling composition containing non-ionic polymer and amphoteric polymer |
| PCT/EP2017/055963 WO2017157921A1 (en) | 2016-03-18 | 2017-03-14 | Hair styling composition containing a non-ionic and an amphoteric polymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108472238A true CN108472238A (en) | 2018-08-31 |
Family
ID=58314196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780006413.2A Pending CN108472238A (en) | 2016-03-18 | 2017-03-14 | Hair styling compositions containing nonionic and amphoteric polymers |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN108472238A (en) |
| WO (2) | WO2017156756A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102017217455A1 (en) | 2017-09-29 | 2019-04-04 | Henkel Ag & Co. Kgaa | Means and methods for temporary deformation of keratinous fibers |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6506372B1 (en) * | 1999-06-25 | 2003-01-14 | L'oreal S.A. | Cosmetic compositions containing an amphoteric polymer and a fixing/conditioner polymer, and their uses |
| CN101433504A (en) * | 2008-12-08 | 2009-05-20 | 广东名臣有限公司 | Composition for protecting hair and shaping hair |
| US20100028272A1 (en) * | 2006-10-30 | 2010-02-04 | Henkel Ag & Co. Kgaa | Cosmetic composition |
| US20100189678A1 (en) * | 2007-10-04 | 2010-07-29 | Henkel Ag & Co. Kgaa | Hair Preparation Containing Two Copolymers |
| US20120201774A1 (en) * | 2009-10-22 | 2012-08-09 | Matthias Schweinsberg | Composition for Shaping Keratin Fibres Containing Starches Modified with Propylene Oxide |
| WO2013087315A3 (en) * | 2011-12-16 | 2014-11-20 | Henkel Ag & Co. Kgaa | Powdery cosmetics |
| US20150030554A1 (en) * | 2011-11-28 | 2015-01-29 | Henkek AG & Co. KGaA | Shine-producing hair treatment agent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020085988A1 (en) * | 1996-11-04 | 2002-07-04 | Takanori Nambu | Hair styling composition |
| WO2003024414A1 (en) * | 2001-09-13 | 2003-03-27 | Mitsubishi Chemical Corporation | Resin compositions for cosmetics and cosmetics |
| US9408785B2 (en) * | 2012-10-15 | 2016-08-09 | L'oreal | Hair styling compositions containing aqueous wax dispersions |
-
2016
- 2016-03-18 WO PCT/CN2016/076670 patent/WO2017156756A1/en active Application Filing
-
2017
- 2017-03-14 CN CN201780006413.2A patent/CN108472238A/en active Pending
- 2017-03-14 WO PCT/EP2017/055963 patent/WO2017157921A1/en active Application Filing
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6506372B1 (en) * | 1999-06-25 | 2003-01-14 | L'oreal S.A. | Cosmetic compositions containing an amphoteric polymer and a fixing/conditioner polymer, and their uses |
| US20100028272A1 (en) * | 2006-10-30 | 2010-02-04 | Henkel Ag & Co. Kgaa | Cosmetic composition |
| US20100189678A1 (en) * | 2007-10-04 | 2010-07-29 | Henkel Ag & Co. Kgaa | Hair Preparation Containing Two Copolymers |
| CN101433504A (en) * | 2008-12-08 | 2009-05-20 | 广东名臣有限公司 | Composition for protecting hair and shaping hair |
| US20120201774A1 (en) * | 2009-10-22 | 2012-08-09 | Matthias Schweinsberg | Composition for Shaping Keratin Fibres Containing Starches Modified with Propylene Oxide |
| US20150030554A1 (en) * | 2011-11-28 | 2015-01-29 | Henkek AG & Co. KGaA | Shine-producing hair treatment agent |
| WO2013087315A3 (en) * | 2011-12-16 | 2014-11-20 | Henkel Ag & Co. Kgaa | Powdery cosmetics |
| US20140345640A1 (en) * | 2011-12-16 | 2014-11-27 | Henkel Ag & Co. Kgaa | Powdery Hair Cosmetics |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017156756A1 (en) | 2017-09-21 |
| WO2017157921A1 (en) | 2017-09-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5049377A (en) | Hair-care composition and methods of treating hair | |
| AU2017232524B2 (en) | Personal care composition for a keratin substrate comprising conditioning, color protecting and styling polymer | |
| EP1719500B1 (en) | Polymer mixture for cosmetic compositions. | |
| CZ2003133A3 (en) | Branched block copolymers for treating keratin substrates | |
| US10166179B2 (en) | Fixative polymers and hair styling compositions thereof | |
| KR20130026526A (en) | Acrylic polymer | |
| EP1878423A2 (en) | Hair styling preparations with special protein hydrolysates | |
| CA3094844C (en) | Hair styling compositions comprising polygalactomanans, and method for using the same | |
| DE102005017463A1 (en) | Polymer combination for cosmetic preparations | |
| US5869032A (en) | Quaternized copolymers suitable as active ingredients in cosmetic formulations, such as hair styling compositions | |
| CN102892799B (en) | Cation/cationogen comb copolymer compositions and containing their personal care product | |
| JP3253023B2 (en) | Hair styling | |
| KR20160063396A (en) | Bodycare compositions | |
| CN108472238A (en) | Hair styling compositions containing nonionic and amphoteric polymers | |
| JP2001508456A (en) | Aqueous composition and use thereof | |
| EP2606934A2 (en) | Use of octanohydroxamic acid in hair styling formulations | |
| JP2002523532A (en) | Cationic polymers and their use | |
| EP1568352A1 (en) | Polymer combination for styling compositions | |
| JP3865031B2 (en) | Hairdresser | |
| CN113382778A (en) | Hair styling composition | |
| KR101127948B1 (en) | Hair Roll Maker Compositions | |
| KR20000051877A (en) | Novel hair styling composition | |
| DE102005051867A1 (en) | Cosmetic hair styling preparation, useful as hair spray, comprises fixing polymers, preferably amphoteric or nonionic polymers and 1,2-alkanediol |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180831 |
|
| WD01 | Invention patent application deemed withdrawn after publication |