CN108456375A - Wire and cable protection pipe material and preparation method thereof - Google Patents
Wire and cable protection pipe material and preparation method thereof Download PDFInfo
- Publication number
- CN108456375A CN108456375A CN201810158729.XA CN201810158729A CN108456375A CN 108456375 A CN108456375 A CN 108456375A CN 201810158729 A CN201810158729 A CN 201810158729A CN 108456375 A CN108456375 A CN 108456375A
- Authority
- CN
- China
- Prior art keywords
- parts
- added
- agent
- butadiene
- tube material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 229920001971 elastomer Polymers 0.000 claims abstract description 17
- 239000005060 rubber Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 11
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004203 carnauba wax Substances 0.000 claims abstract description 8
- 239000004014 plasticizer Substances 0.000 claims abstract description 6
- 238000004073 vulcanization Methods 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 39
- 244000043261 Hevea brasiliensis Species 0.000 claims description 28
- 229920003052 natural elastomer Polymers 0.000 claims description 28
- 229920001194 natural rubber Polymers 0.000 claims description 28
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 27
- 230000001376 precipitating effect Effects 0.000 claims description 21
- CUJPJTIBYGTKKC-UHFFFAOYSA-N cyclohexanol;diphenylmethanone Chemical compound OC1CCCCC1.C=1C=CC=CC=1C(=O)C1=CC=CC=C1 CUJPJTIBYGTKKC-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 claims description 14
- 239000003153 chemical reaction reagent Substances 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000005864 Sulphur Substances 0.000 claims description 5
- 239000012778 molding material Substances 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 4
- USFRYJRPHFMVBZ-UHFFFAOYSA-M benzyl(triphenyl)phosphanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)CC1=CC=CC=C1 USFRYJRPHFMVBZ-UHFFFAOYSA-M 0.000 claims description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 4
- AXWJKQDGIVWVEW-UHFFFAOYSA-N 2-(dimethylamino)butanedioic acid Chemical compound CN(C)C(C(O)=O)CC(O)=O AXWJKQDGIVWVEW-UHFFFAOYSA-N 0.000 claims description 3
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 claims description 3
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims description 3
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims 2
- PHZDLMOVTNOUBV-UHFFFAOYSA-N CCl.[O] Chemical group CCl.[O] PHZDLMOVTNOUBV-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 150000004040 pyrrolidinones Chemical class 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- 230000006835 compression Effects 0.000 abstract description 6
- 238000007906 compression Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- JEWHCPOELGJVCB-UHFFFAOYSA-N aluminum;calcium;oxido-[oxido(oxo)silyl]oxy-oxosilane;potassium;sodium;tridecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.[Na].[Al].[K].[Ca].[O-][Si](=O)O[Si]([O-])=O JEWHCPOELGJVCB-UHFFFAOYSA-N 0.000 abstract 1
- NRCSJPUCBTUPDG-UHFFFAOYSA-N benzyl-chloro-triphenyl-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(Cl)(C=1C=CC=CC=1)CC1=CC=CC=C1 NRCSJPUCBTUPDG-UHFFFAOYSA-N 0.000 abstract 1
- 235000013869 carnauba wax Nutrition 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 229910001743 phillipsite Inorganic materials 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- CCYXLFPXYGBISJ-UHFFFAOYSA-N [Cl+].C(C1=CC=CC=C1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound [Cl+].C(C1=CC=CC=C1)[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 CCYXLFPXYGBISJ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- GGBJHURWWWLEQH-UHFFFAOYSA-N butylcyclohexane Chemical compound CCCCC1CCCCC1 GGBJHURWWWLEQH-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- 229940073769 methyl oleate Drugs 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a wire and cable protection tube material and a preparation method thereof, relating to the technical field of wire and cable protection materials, wherein the material comprises the following raw materials: PVC with high polymerization degree, NR-SBR composite rubber, fumed silica, carnauba wax, phillipsite powder, antimony trioxide, benzyl triphenyl phosphorus chloride, N-hydroxymethyl acrylamide, a plasticizer, an anti-aging agent, a promoter and a vulcanizing agent. The preparation method is prepared by banburying, roll milling and vulcanization of raw materials. The protective tube material disclosed by the invention is simple to prepare, has excellent high and low temperature resistance, insulativity, water resistance, corrosion resistance, impact toughness, compression resistance, tensile resistance and weather resistance, ensures that the sheath material has a longer service life in outdoor severe environments such as high and low temperature, much rainwater and the like, ensures the stability, reliability and safety of cables and wires in the protective tube in the process of transmitting power signals, and has a wide market prospect.
Description
Technical field
The present invention relates to electric wire protection materials technical fields, and in particular to a kind of electric wire protection tube material and its
Preparation method.
Background technology
With the development of the society, the environmental consciousness of people is also strengthened, advanced country in the world oneself forbid the electricity of leaded cadmium
Line cable protection pipe lists, and the non-toxic electric wire cable protection pipe without lead cadmium has become a kind of new trend.Electric wire is protected simultaneously
Pillar should also meet that compression strength is high, flexible curved performance is good, compression strength is high, shock resistance is good, tensile strength is high, heat-resisting
The features such as temperature height and flame retardant property are good, formability is good.Therefore, be badly in need of providing a kind of nontoxic, forming is easy, heat resisting temperature is high,
Impact resistance is good, compression strength is high, good flame resistance, and the excellent electric wire of various performances protects tube material, prepares system
It makes at low cost, can be bent, the spiral winding pipe being easily installed.
Invention content
For problems of the prior art, the present invention provides a kind of electric wire protection tube material and its preparation sides
Method, this kind of protection pipe material preparation is simple, has excellent resistant of high or low temperature, insulating properties, waterproof anti-corrosion, shock resistance tough
Property, resistance to compression pull resistance and weatherability.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of electric wire protection tube material, including following raw material by weight：40-50 parts of high DP PVC,
55-65 parts of NR-SBR compounded rubbers, 10-12 parts of gas-phase silica, 6-10 parts of Brazil wax, 4-8 parts of phillipsine mountain flour, three
Aoxidize 3-5 parts of two antimony, 0.6-0.8 parts of benzyltriphenylphosphonium chloride, 0.7-1.0 parts of N hydroxymethyl acrylamide, plasticizer 1-2
Part, 1-3 parts of anti-aging agent, 1-2 parts of accelerating agent and 1-2 parts of vulcanizing agent；
Above-mentioned NR-SBR compounded rubbers pass through made from following steps：
Step 1：Take following composition by weight：30-35 parts of natural rubber, 25-30 parts of butadiene-styrene rubber, 1- ethylene
1-1.5 parts of base -2.5-3 parts of 2-Pyrrolidone, 2-3.5 parts of n-isopropyl acrylamide and hydroxycyclohexan benzophenone；
Step 2：Natural rubber is dissolved in toluene, a concentration of 20-22g/L natural rubbers solution is configured to；By butylbenzene rubber
Peptization is configured to a concentration of 22-24g/L butadiene-styrene rubber solution in toluene；
Step 3：L-vinyl-2-pyrrolidone is added into natural rubber solution, under conditions of temperature is 50-60 DEG C
It is stirred to react 2-3h, obtains mixed liquor A；N-isopropyl acrylamide is added into butadiene-styrene rubber solution, is 55-65 DEG C in temperature
Under the conditions of be stirred to react 3-4h, obtain mixed liquid B；
Step 4：Mixed liquor A and mixed liquid B are mixed, and hydroxycyclohexan benzophenone is added and is heated in a nitrogen atmosphere
60-70 DEG C of reaction 4-6h, obtains mixed liquor C；Precipitating reagent finally is added in mixed liquor C and carries out precipitating, and uses Soxhlet extractor pair
Precipitating object is stripped, and extracting finishes to obtain the final product.
Further, above-mentioned protection tube material includes following raw material by weight：45 parts of high DP PVC,
60 parts of NR-SBR compounded rubbers, 11 parts of gas-phase silica, 8 parts of Brazil wax, 6 parts of phillipsine mountain flour, antimony oxide 4
Part, 0.7 part of benzyltriphenylphosphonium chloride, 0.85 part of N hydroxymethyl acrylamide, 1.5 parts of plasticizer, 2 parts of anti-aging agent, accelerating agent
1.5 parts and 1.5 parts of vulcanizing agent.
Further, above-mentioned NR-SBR compounded rubbers pass through made from following steps：
Step 1：Take following composition by weight：32 parts of natural rubber, 26 parts of butadiene-styrene rubber, 1- vinyl -2- pyrroles
1.25 parts of 3 parts of pyrrolidone, 2.5 parts of n-isopropyl acrylamide and hydroxycyclohexan benzophenone；
Step 2：Natural rubber is dissolved in toluene, a concentration of 21g/L natural rubbers solution is configured to；Butadiene-styrene rubber is molten
In toluene, it is configured to a concentration of 23g/L butadiene-styrene rubber solution；
Step 3：L-vinyl-2-pyrrolidone is added into natural rubber solution, is stirred under conditions of temperature is 55 DEG C
Reaction 2.5h is mixed, mixed liquor A is obtained；N-isopropyl acrylamide is added into butadiene-styrene rubber solution, the condition for being 60 DEG C in temperature
Under be stirred to react 3.5h, obtain mixed liquid B；
Step 4：Mixed liquor A and mixed liquid B are mixed, and hydroxycyclohexan benzophenone is added and is heated to 65 in a nitrogen atmosphere
DEG C reaction 5h, obtain mixed liquor C；Precipitating reagent finally is added in mixed liquor C and carries out precipitating, and using Soxhlet extractor to precipitating object into
Row extracting, extracting finish to obtain the final product.
Preferably, above-mentioned plasticizer uses chloromethane epoxide methyl oleate or dioctyl phthalate.
Preferably, above-mentioned anti-aging agent is using any one of antioxidant 4010NA, antioxidant 4020 or anti-aging agent RD.
Preferably, above-mentioned accelerating agent is using any one of altax, Vulcanization accelerator TMTD or Urotropinum.
Preferably, above-mentioned vulcanizing agent is using cumyl peroxide, 1,1- bis(t-butylperoxy)s -3,3,5- front threes
Any one of butylcyclohexane or bis- (tert-butylperoxyiso-propyl) benzene.
A kind of preparation method of above-mentioned electric wire protection tube material, follows the steps below：
(1) raw material is weighed by the weight；
(2) by other all feedstock transportations to mixer of sulphur removal agent, mixing handles 2-3h, and before mixing terminates
60-70s when, vulcanizing agent is added, mixing terminates to obtain mixing materials；
(3) mixing materials are delivered in open mill, mill molding are carried out under the conditions of temperature is 64-68 DEG C, after molding
Material be delivered in vulcanizing press, pressure be 175-185kgf/cm2, temperature be 140-150 DEG C under conditions of, vulcanization
Processing 8-10min obtains the electric wire protection tube material of the present invention.
The present invention has following advantageous effect：The electric wire protection pipe material preparation of the present invention is simple, raw material sources
Extensively, convenient material drawing, it is of low cost, zero-emission in production process, it is pollution-free, do not generate any harmful, penetrating odor, green
Environmental protection, compatibility performance is good between raw material, and plasticity is strong, and density is small, transport and install convenient, suitable for scale of mass production；By right
Raw materials for production and its technique improve and optimizate, and are especially added to NR-SBR compounded rubbers, cooperate with the addition of auxiliary material and auxiliary agent
And its effect so that protection pipe material structure realizes compactness improvement, has reached vertical net formula molecular structure, and then improve into
The various aspects of performance of product electric wire protection pipe has excellent resistant of high or low temperature, insulating properties, waterproof anti-corrosion, shock resistance
It is longer to ensure that protective cover material has under the adverse circumstances such as outdoor high/low temperature, rainy water for toughness, resistance to compression pull resistance and weatherability
Service life has ensured stability, reliability and safety of the cable and wire in protection pipe in the signal process that transmits electric power,
Have a vast market foreground.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of electric wire protection tube material, weighs following raw material：High DP PVC 40kg, NR-SBR compounded rubber
55kg, gas-phase silica 10kg, Brazil wax 6kg, phillipsine mountain flour 4kg, antimony oxide 3kg, benzyltriphenyl phosphonium chlorine
Change phosphorus 0.6kg, N hydroxymethyl acrylamide 0.7kg, chloromethane epoxide methyl oleate 1kg, antioxidant 4020 1kg, Urotropinum 1kg
With 1,1- bis(t-butylperoxy)s -3,3,5- trimethyl-cyclohexanes 1kg；
The preparation of NR-SBR compounded rubbers：
Step 1：Weigh following composition：Natural rubber 30kg, butadiene-styrene rubber 25kg, l-vinyl-2-pyrrolidone
2.5kg, n-isopropyl acrylamide 2kg and hydroxycyclohexan benzophenone 1kg；
Step 2：Natural rubber is dissolved in toluene, a concentration of 20g/L natural rubbers solution is configured to；Butadiene-styrene rubber is molten
In toluene, it is configured to a concentration of 22g/L butadiene-styrene rubber solution；
Step 3：L-vinyl-2-pyrrolidone is added into natural rubber solution, is stirred under conditions of temperature is 50 DEG C
Reaction 2h is mixed, mixed liquor A is obtained；N-isopropyl acrylamide is added into butadiene-styrene rubber solution, under conditions of temperature is 55 DEG C
It is stirred to react 3h, obtains mixed liquid B；
Step 4：Mixed liquor A and mixed liquid B are mixed, and hydroxycyclohexan benzophenone is added and is heated to 60 in a nitrogen atmosphere
DEG C reaction 4h, obtain mixed liquor C；Precipitating reagent finally is added in mixed liquor C and carries out precipitating, and using Soxhlet extractor to precipitating object into
Row extracting, extracting finish to obtain the final product.
A kind of preparation method of above-mentioned electric wire protection tube material, follows the steps below：
(1) first by other all feedstock transportations to mixer of sulphur removal agent, mixing handles 2h, and before mixing terminates
60s when, vulcanizing agent is added, mixing terminates to obtain mixing materials；
(2) mixing materials are delivered in open mill again, mill molding is carried out under the conditions of temperature is 64 DEG C, it finally will molding
Material afterwards is delivered in vulcanizing press, is 175kgf/cm in pressure2, temperature be 140 DEG C under conditions of, vulcanizing treatment
8min obtains the electric wire protection tube material of the present invention.
Embodiment 2
A kind of electric wire protection tube material, weighs following raw material：High DP PVC 45kg, NR-SBR compounded rubber
60kg, gas-phase silica 11kg, Brazil wax 8kg, phillipsine mountain flour 6kg, antimony oxide 4kg, benzyltriphenyl phosphonium chlorine
Change phosphorus 0.7kg, N hydroxymethyl acrylamide 0.85kg, dioctyl phthalate 1.5kg, antioxidant 4010NA 2kg, promote
Agent DM 1.5kg and cumyl peroxide 1.5kg；
Above-mentioned NR-SBR compounded rubbers pass through made from following steps：
Step 1：Step 1：Take following composition by weight：Natural rubber 32kg, butadiene-styrene rubber 26kg, 1- ethylene
Base -2-Pyrrolidone 3kg, n-isopropyl acrylamide 2.5kg and hydroxycyclohexan benzophenone 1.25kg；
Step 2：Natural rubber is dissolved in toluene, a concentration of 21g/L natural rubbers solution is configured to；Butadiene-styrene rubber is molten
In toluene, it is configured to a concentration of 23g/L butadiene-styrene rubber solution；
Step 3：L-vinyl-2-pyrrolidone is added into natural rubber solution, is stirred under conditions of temperature is 55 DEG C
Reaction 2.5h is mixed, mixed liquor A is obtained；N-isopropyl acrylamide is added into butadiene-styrene rubber solution, the condition for being 60 DEG C in temperature
Under be stirred to react 3.5h, obtain mixed liquid B；
Step 4：Mixed liquor A and mixed liquid B are mixed, and hydroxycyclohexan benzophenone is added and is heated to 65 in a nitrogen atmosphere
DEG C reaction 5h, obtain mixed liquor C；Precipitating reagent finally is added in mixed liquor C and carries out precipitating, and using Soxhlet extractor to precipitating object into
Row extracting, extracting finish to obtain the final product.
A kind of preparation method of above-mentioned electric wire protection tube material, follows the steps below：
(1) first by other all feedstock transportations to mixer of sulphur removal agent, mixing handles 2.5h, and terminates in mixing
When preceding 65s, vulcanizing agent is added, mixing terminates to obtain mixing materials；
(2) mixing materials are delivered in open mill again, mill molding is carried out under the conditions of temperature is 66 DEG C, it finally will molding
Material afterwards is delivered in vulcanizing press, is 180kgf/cm in pressure2, temperature be 145 DEG C under conditions of, vulcanizing treatment
9min obtains the electric wire protection tube material of the present invention.
Embodiment 3
A kind of electric wire protection tube material, weighs following raw material：High DP PVC 50kg, NR-SBR compounded rubber
65kg, gas-phase silica 12kg, Brazil wax 10kg, phillipsine mountain flour 8kg, antimony oxide 5kg, benzyltriphenyl phosphonium chlorine
Change phosphorus 0.8kg, N hydroxymethyl acrylamide 1.0kg, dioctyl phthalate 2kg, anti-aging agent RD 3kg, Vulcanization accelerator TMTD
2kg and bis- (tert-butylperoxyiso-propyl) benzene 2kg；
The preparation of NR-SBR compounded rubbers：
Step 1：Weigh following composition：Natural rubber 35kg, butadiene-styrene rubber 30kg, l-vinyl-2-pyrrolidone 3kg,
N-isopropyl acrylamide 3.5kg and hydroxycyclohexan benzophenone 1.5kg；
Step 2：Natural rubber is dissolved in toluene, a concentration of 22g/L natural rubbers solution is configured to；Butadiene-styrene rubber is molten
In toluene, it is configured to a concentration of 24g/L butadiene-styrene rubber solution；
Step 3：L-vinyl-2-pyrrolidone is added into natural rubber solution, is stirred under conditions of temperature is 60 DEG C
Reaction 3h is mixed, mixed liquor A is obtained；N-isopropyl acrylamide is added into butadiene-styrene rubber solution, under conditions of temperature is 65 DEG C
It is stirred to react 4h, obtains mixed liquid B；
Step 4：Mixed liquor A and mixed liquid B are mixed, and hydroxycyclohexan benzophenone is added and is heated to 70 in a nitrogen atmosphere
DEG C reaction 6h, obtain mixed liquor C；Precipitating reagent finally is added in mixed liquor C and carries out precipitating, and using Soxhlet extractor to precipitating object into
Row extracting, extracting finish to obtain the final product.
A kind of preparation method of above-mentioned electric wire protection tube material, follows the steps below：
(1) first by other all feedstock transportations to mixer of sulphur removal agent, mixing handles 3h, and before mixing terminates
70s when, vulcanizing agent is added, mixing terminates to obtain mixing materials；
(2) mixing materials are delivered in open mill again, mill molding is carried out under the conditions of temperature is 68 DEG C, it finally will molding
Material afterwards is delivered in vulcanizing press, is 185kgf/cm in pressure2, temperature be 150 DEG C under conditions of, vulcanizing treatment
10min obtains the electric wire protection tube material of the present invention.
Protection pipe performance detection
It is that 1.6mm electric wire protection pipes carry out performance detection, inspection that thickness, which is made, in material made from above-described embodiment 1-3
Result is surveyed to see the table below shown in 1；
Table 1
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of electric wire protects tube material, which is characterized in that including following raw material by weight：High DP PVC
40-50 parts, 55-65 parts of NR-SBR compounded rubbers, 10-12 parts of gas-phase silica, 6-10 parts of Brazil wax, phillipsine mountain flour
4-8 parts, 3-5 parts of antimony oxide, 0.6-0.8 parts of benzyltriphenylphosphonium chloride, 0.7-1.0 parts of N hydroxymethyl acrylamide, increase
Mould 1-2 parts of 1-2 parts of agent, 1-3 parts of anti-aging agent, 1-2 parts of accelerating agent and vulcanizing agent；
The NR-SBR compounded rubbers pass through made from following steps：
Step 1：Take following composition by weight：30-35 parts of natural rubber, 25-30 parts of butadiene-styrene rubber, 1- vinyl -2-
1-1.5 parts of 2.5-3 parts of pyrrolidones, 2-3.5 parts of n-isopropyl acrylamide and hydroxycyclohexan benzophenone；
Step 2：Natural rubber is dissolved in toluene, a concentration of 20-22g/L natural rubbers solution is configured to；Butadiene-styrene rubber is molten
In toluene, it is configured to a concentration of 22-24g/L butadiene-styrene rubber solution；
Step 3：L-vinyl-2-pyrrolidone is added into natural rubber solution, is stirred under conditions of temperature is 50-60 DEG C
2-3h is reacted, mixed liquor A is obtained；N-isopropyl acrylamide is added into butadiene-styrene rubber solution, the condition for being 55-65 DEG C in temperature
Under be stirred to react 3-4h, obtain mixed liquid B；
Step 4：Mixed liquor A and mixed liquid B are mixed, and hydroxycyclohexan benzophenone is added and is heated to 60-70 in a nitrogen atmosphere
DEG C reaction 4-6h, obtain mixed liquor C；Precipitating reagent finally is added in mixed liquor C and carries out precipitating, and using Soxhlet extractor to precipitating object
It is stripped, extracting finishes to obtain the final product.
2. a kind of electric wire according to claim 1 protects tube material, which is characterized in that including it is following by weight
Raw material：45 parts of high DP PVC, 60 parts of NR-SBR compounded rubbers, 11 parts of gas-phase silica, 8 parts of Brazil wax, calcium ten
6 parts of word zeolite powder, 4 parts of antimony oxide, 0.7 part of benzyltriphenylphosphonium chloride, 0.85 part of N hydroxymethyl acrylamide, plasticizer
1.5 parts of 1.5 parts, 2 parts of anti-aging agent, 1.5 parts of accelerating agent and vulcanizing agent.
3. a kind of electric wire according to claim 1 protects tube material, which is characterized in that the NR-SBR compounded rubbers
Made from following steps：
Step 1：Take following composition by weight：32 parts of natural rubber, 26 parts of butadiene-styrene rubber, 1- vinyl -2- pyrrolidines
1.25 parts of 3 parts of ketone, 2.5 parts of n-isopropyl acrylamide and hydroxycyclohexan benzophenone；
Step 2：Natural rubber is dissolved in toluene, a concentration of 21g/L natural rubbers solution is configured to；Butadiene-styrene rubber is dissolved in first
In benzene, it is configured to a concentration of 23g/L butadiene-styrene rubber solution；
Step 3：L-vinyl-2-pyrrolidone is added into natural rubber solution, stirring is anti-under conditions of temperature is 55 DEG C
2.5h is answered, mixed liquor A is obtained；N-isopropyl acrylamide is added into butadiene-styrene rubber solution, is stirred under conditions of temperature is 60 DEG C
Reaction 3.5h is mixed, mixed liquid B is obtained；
Step 4：Mixed liquor A and mixed liquid B are mixed, and hydroxycyclohexan benzophenone is added and is heated to 65 DEG C in a nitrogen atmosphere instead
5h is answered, mixed liquor C is obtained；Precipitating reagent finally is added in mixed liquor C and carries out precipitating, and precipitating object is taken out using Soxhlet extractor
It carries, extracting finishes to obtain the final product.
4. a kind of electric wire according to claim 1 protects tube material, which is characterized in that the plasticizer is chloromethane oxygen
Based oleic acid methyl esters or dioctyl phthalate.
5. a kind of electric wire according to claim 1 protects tube material, which is characterized in that the anti-aging agent is anti-aging agent
Any one of 4010NA, antioxidant 4020 or anti-aging agent RD.
6. a kind of electric wire according to claim 1 protects tube material, which is characterized in that the accelerating agent is accelerating agent
Any one of DM, Vulcanization accelerator TMTD or Urotropinum.
7. a kind of electric wire according to claim 1 protects tube material, which is characterized in that the vulcanizing agent is peroxidating
In diisopropylbenzene (DIPB), 1,1- bis(t-butylperoxy)s -3,3,5- trimethyl-cyclohexanes or bis- (tert-butylperoxyiso-propyl) benzene
It is any.
8. a kind of preparation method for protecting tube material such as claim 1-7 any one of them electric wires, which is characterized in that packet
Include following steps：
(1) raw material is weighed by the weight；
(2) by other all feedstock transportations to mixer of sulphur removal agent, mixing handles 2-3h, and before mixing terminates
When 60-70s, vulcanizing agent is added, mixing terminates to obtain mixing materials；
(3) mixing materials are delivered in open mill, mill molding are carried out under the conditions of temperature is 64-68 DEG C, by object after molding
Material is delivered in vulcanizing press, is 175-185kgf/cm in pressure2, temperature be 140-150 DEG C under conditions of, vulcanizing treatment
8-10min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810158729.XA CN108456375A (en) | 2018-02-26 | 2018-02-26 | Wire and cable protection pipe material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810158729.XA CN108456375A (en) | 2018-02-26 | 2018-02-26 | Wire and cable protection pipe material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108456375A true CN108456375A (en) | 2018-08-28 |
Family
ID=63216523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810158729.XA Withdrawn CN108456375A (en) | 2018-02-26 | 2018-02-26 | Wire and cable protection pipe material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108456375A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231484A (en) * | 2014-09-25 | 2014-12-24 | 重庆顾地塑胶电器有限公司 | Cable protection pipe material and cable protection pipe made of material |
| CN105860371A (en) * | 2016-04-29 | 2016-08-17 | 安徽华宇电缆集团有限公司 | Waterproof building-out cable |
| CN107383691A (en) * | 2017-08-17 | 2017-11-24 | 安徽卓越电力设备有限公司 | A kind of Heavy-duty cables protective cover material |
-
2018
- 2018-02-26 CN CN201810158729.XA patent/CN108456375A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231484A (en) * | 2014-09-25 | 2014-12-24 | 重庆顾地塑胶电器有限公司 | Cable protection pipe material and cable protection pipe made of material |
| CN105860371A (en) * | 2016-04-29 | 2016-08-17 | 安徽华宇电缆集团有限公司 | Waterproof building-out cable |
| CN107383691A (en) * | 2017-08-17 | 2017-11-24 | 安徽卓越电力设备有限公司 | A kind of Heavy-duty cables protective cover material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102746587B (en) | Insulation rubber for longitudinal water-tight demagnetization cable used for ship, and manufacture method for insulation rubber | |
| CN102702624A (en) | Ternary ethylenepropylene insulating sizing material for 35KV high-voltage cable accessory and preparation method for ternary ethylenepropylene insulating sizing material | |
| CN103059352A (en) | Sheath rubber for rubber sheath flexible cables | |
| CN116199961B (en) | High-temperature-resistant corrosion-resistant wire harness material and preparation method thereof | |
| US20180258264A1 (en) | Method of preparing bio-based elastomer composite comprising silica and poly dibutyl itaconate-ter-isoprene-ter-glycidyl methacrylate | |
| CN114350098A (en) | Heat-resistant environment-friendly cable material and preparation method thereof | |
| CN103289415B (en) | A kind of cable jacket material containing modified methyl vinylsiloxane rubber and preparation method thereof | |
| CN115960424A (en) | Flexible fire-resistant robot cable | |
| CN112552609A (en) | Insulating flame-retardant ethylene propylene diene monomer rubber material | |
| CN117384441A (en) | PE pipe and preparation method thereof | |
| CN108003444A (en) | A kind of low smoke halogen-free fire retardant polyolefin cable material and preparation method thereof | |
| CN111154204A (en) | Weather-resistant wire and cable material and production process thereof | |
| CN104151746A (en) | environment-friendly fire-retardant insulation material and application thereof in electric cables | |
| CN101955601B (en) | Chloroprene rubber improved by ionomer | |
| KR101624589B1 (en) | The preparing method of silica-polybutadiene composite material and the silica-polybutadiene composite material thereby | |
| CN108456375A (en) | Wire and cable protection pipe material and preparation method thereof | |
| CN113789042B (en) | Flame-retardant environment-friendly PC-ABS composite plastic master batch and preparation method thereof | |
| CN101735592B (en) | Flame-resistant polyphenylether composition and method for preparing same | |
| CN111607165B (en) | High-expansion insulating ethylene-propylene rubber cold-contraction material, and preparation method and application thereof | |
| CN108299783B (en) | High-strength flame-retardant cable material and preparation method thereof | |
| CN103172948A (en) | PVC (polyvinyl chloride) plastic plate for flame-retardant door and preparation method thereof | |
| CN112111143A (en) | Environment-friendly cable material and preparation method thereof | |
| CN112552616A (en) | Flame-retardant PVC cable material and preparation method and application thereof | |
| CN105802242A (en) | Stretch-proof shielding cable material formula and preparation method of stretch-proof shielding cable material | |
| CN110483921A (en) | A kind of low smoke and zero halogen photovoltaic irradiation cable material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180828 |