CN108456006A - The recyclability restorative procedure of Nixing pottery hallrcuts - Google Patents
The recyclability restorative procedure of Nixing pottery hallrcuts Download PDFInfo
- Publication number
- CN108456006A CN108456006A CN201810525280.6A CN201810525280A CN108456006A CN 108456006 A CN108456006 A CN 108456006A CN 201810525280 A CN201810525280 A CN 201810525280A CN 108456006 A CN108456006 A CN 108456006A
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- CN
- China
- Prior art keywords
- nixing pottery
- mixed serum
- slight crack
- hallrcuts
- recyclability
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/87—Ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5024—Silicates
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention provides the recyclability restorative procedures of Nixing pottery hallrcuts, include the following steps：1) by flyash and SmCl3Grinding, adds water to stir evenly, obtains mixed serum；2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；Continue to dip at mixed serum smearing slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled；3) green body is smoothed out, 15~30min, natural cooling are fired at 1000~1100 DEG C.The present invention at powerful mullite network structure and slight crack by carrying out cross-fixing, to play the role of repairing slight crack, thin but also more mullite network structure intensity is larger not only, can hinder the sliding of crystal boundary, the extension that can prevent crackle, to effectively prevent secondary cracking.
Description
Technical field
The present invention relates to the manufacture crafts of Nixing pottery, and in particular to the recyclability restorative procedure of Nixing pottery hallrcuts.
Background technology
The technique of Nixing pottery includes mainly following steps：1) blank is prepared：Blank, which is selected, crosses admiring for Qiezhou urban district
The soil of Jiang Yidong, being commonly called as eastern mud, (for mild-clay, color is yellow-white, contains micro quartz sand, in the production technology of Nixing pottery
In serve adjustment plasticity with associativity), and by the emperor himself to the west of river region soil, be commonly called as western mud (containing a small amount of K2O、NaO、
CaO、MgO、Fe203、TiO2、MnO2, it is a kind of higher purple mudstone of iron-holder, color is aubergine, and superficial layer has a small amount of irony
Dip dyeing is hard paste, and plasticity and associativity are poor), the weight percent by eastern mud 40~60%, western mud 40~60% is mixed
It closes, blank is made in the series of process such as ground, dehydration；The moisture content of blank is 24~25%；2) blank forming：Using plastic
The green body of various types is made in blank by method or slip casting method；3) green body is modified：Green body is modified to reach design requirement；4) it does
It is dry：Green body is dried using aeration drying, green body moisture is made to exclude；5) drawing engraving：It picture and is carried out in green body writing of submitting a written statement to a higher authority
Engraving；6)：Body drying；7) green body is fired：Dry green body loading of kiln to be fired, firing temperature is controlled at 1100~1200 DEG C,
Firing time is 10h, kiln discharge after cooling；8) polishing grinding：By green body polishing polish to get.
The defect of Nixing pottery is exactly that brittleness is big, the polycrystalline structure that Nixing pottery is made of ionic bond or covalent bond, these changes
The atom for learning key arranges closely unlike metallic bond, is difficult to cause the movement of dislocation there are many hole.Covalent bond is directional,
Keep crystal structure complicated, and the ability with higher anti-distortion and obstruction displacement movement, lacks the cunning that material can be promoted to deform
Shifting system.Nixing pottery is once by applied load, along with ceramic process it is difficult to which being constituted in material surface for avoiding is micro- scarce
Sunken presence, they all constitute formation of crack, and stress will be concentrated at the tip of these crackles.Nixing pottery can disappear either with or without other
The system for consuming extraneous energy, is only exchanged with new free energy.So-called new free energy is exactly the extension shape of crack tip
At the energy that is absorbed of new surface.Such result results in the Quick Extended of crackle and shows as so-called brittleness and break
It splits.
Invention content
Technical problem to be solved by the invention is to provide the recyclability restorative procedure of Nixing pottery hallrcuts, the technique is thorough
The slight crack of green body is repaired in bottom, moreover it is possible to effectively prevent secondary cracking after firing.
In order to solve the above technical problems, the technical solution adopted by the present invention is the recyclability reparation side of Nixing pottery hallrcuts
Method includes the following steps：
1) by flyash and SmCl3Grinding, adds water to stir evenly, obtains mixed serum；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；After
The continuous mixed serum that dips is smeared at slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled out
Until full；
3) green body is smoothed out, 15~30min, natural cooling are fired at 1000~1100 DEG C.
Al in flyash2O3、Fe2O3, MgO be eutectic oxide, liquid phase can be formed at 1000~1100 DEG C, promote
Into the synthesis of mullite, Cl-Presence can reduce the viscosity of liquid phase, the atom in liquid phase is more prone to spread, under the conditions of this
The initial stage that mullite is precipitated, there is high nucleation rate, atoms permeating easy to perform to accelerate the growth of bar-like grains, therefore shape
At more mullite bar-like grains.Sm3+Rodlike mullite grains size can be refined, particle is completely embedded, intergranular to have
It imitates migration area and contact area increases, more but also thin mullite bar-like grains form huge network structure not only for these, penetrate into
To slight crack depths, crossover network is formed with slight crack, to play the role of repairing slight crack.Not only due to not only thin but also more mullite net
Network structural strength is larger, can hinder the sliding of crystal boundary, can prevent the extension of crackle, to effectively prevent secondary cracking.
Although rare earth oxide can also play the role of crystal grain thinning, the quantity of crystal grain can not be increased, crystal grain is thin
But it is few, good repairing effect can not be played, secondary cracking is extremely easy tod produce.
Low congruent melting oxide altogether in flyash is between sintering cooling stage remnants liquid phases are filled in rodlike mullite grains
Gap and play bonding effect, avoid mullite growth caused by short texture, further improve repairing effect.
The moisture content of mixed serum is 30~50%.
Flyash is ground to 200~400 mesh.
SmCl3Weight be flyash 0.01~0.05%.
15~20min is fired at 1000~1050 DEG C.
Compared with prior art, the present invention is by carrying out cross-fixing at powerful mullite network structure and slight crack, from
And play the role of repairing slight crack, thin but also more mullite network structure intensity is larger not only, can hinder the sliding of crystal boundary, can be to prevent
The extension of crack arrest line, to effectively prevent secondary cracking.
Specific implementation mode
The essentiality content further illustrated the present invention below with embodiment, but the present invention is not limited with this.
It is that identical size, same process, the same batch of same recipe are made to test Nixing pottery green body used below
Nixing pottery vessel, adopt and carry out Crack handling in a like fashion, crack size is same, and (length 3cm, depth are
0.5mm)。
Embodiment 1
1) by flyash and SmCl3200 mesh are ground to, water is added to stir evenly, obtain the mixed serum that moisture content is 30%；
SmCl3Weight be flyash 0.01%；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；After
The continuous mixed serum that dips is smeared at slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled out
Until full；
3) green body is smoothed out, 15min, natural cooling are fired at 1000 DEG C.
Flexural strength test, intensity 104MPa are carried out to slight crack repair place.
Reference examples 1
1) by flyash and Sm2O3200 mesh are ground to, water is added to stir evenly, obtain the mixed serum that moisture content is 30%；
Sm2O3Weight be flyash 0.01%；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；After
The continuous mixed serum that dips is smeared at slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled out
Until full；
3) green body is smoothed out, 15min, natural cooling are fired at 1000 DEG C.
Flexural strength test, intensity 49MPa are carried out to slight crack repair place.
Reference examples 2
1) flyash is ground to 200 mesh, water is added to stir evenly, obtain the mixed serum that moisture content is 30%；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；After
The continuous mixed serum that dips is smeared at slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled out
Until full；
3) green body is smoothed out, 15min, natural cooling are fired at 1000 DEG C.
Flexural strength test, intensity 31MPa are carried out to slight crack repair place.
Reference examples 3
1) with brush dip Nixing pottery blank slurries (moisture content 30%) uniformly smear Nixing pottery green body slight crack at until
Complete wetting spontaneously dries；Continue to dip at slurries smearing slight crack until complete wetting, natural drying so repeat, up to dry
Until the crack of dry green body is filled；
3) green body is smoothed out, 15min, natural cooling are fired at 1000 DEG C.
Flexural strength test, intensity 15MPa are carried out to slight crack repair place.
Embodiment 2
1) by flyash and SmCl3400 mesh are ground to, water is added to stir evenly, obtain the mixed serum that moisture content is 50%；
SmCl3Weight be flyash 0.05%；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；After
The continuous mixed serum that dips is smeared at slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled out
Until full；
3) green body is smoothed out, 30min, natural cooling are fired at 1100 DEG C.
Flexural strength test, intensity 99MPa are carried out to slight crack repair place.
Embodiment 3
1) by flyash and SmCl3300 mesh are ground to, water is added to stir evenly, obtain the mixed serum that moisture content is 40%；
SmCl3Weight be flyash 0.03%；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；After
The continuous mixed serum that dips is smeared at slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled out
Until full；
3) green body is smoothed out, 18min, natural cooling are fired at 1020 DEG C.
Flexural strength test, intensity 110MPa are carried out to slight crack repair place.
Embodiment 4
1) by flyash and SmCl32000 mesh are ground to, water is added to stir evenly, obtain the mixing slurry that moisture content is 50%
Liquid；SmCl3Weight be flyash 0.01%；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；After
The continuous mixed serum that dips is smeared at slight crack until complete wetting, natural drying so repeat, until the crack of dry base substrate is filled out
Until full；
3) green body is smoothed out, 15min, natural cooling are fired at 1100 DEG C.
Flexural strength test, intensity 96MPa are carried out to slight crack repair place.
Claims (5)
1. the recyclability restorative procedure of Nixing pottery hallrcuts, it is characterised in that：Include the following steps：
1) by flyash and SmCl3Grinding, adds water to stir evenly, obtains mixed serum；
2) mixed serum is dipped with brush uniformly to smear at Nixing pottery green body slight crack until complete wetting, spontaneously dries；Continue to dip in
Take mixed serum to smear at slight crack until complete wetting, spontaneously dry, so repeat, until the crack of dry base substrate be filled for
Only；
3) green body is smoothed out, 15~30min, natural cooling are fired at 1000~1100 DEG C.
2. the recyclability restorative procedure of Nixing pottery hallrcuts according to claim 1, it is characterised in that：Mixed serum
Moisture content is 30~50%.
3. the recyclability restorative procedure of Nixing pottery hallrcuts according to claim 1, it is characterised in that：Flyash is ground
It is milled to 200~400 mesh.
4. the recyclability restorative procedure of Nixing pottery hallrcuts according to claim 1, it is characterised in that：SmCl3Weight
It is the 0.01~0.05% of flyash.
5. the recyclability restorative procedure of Nixing pottery hallrcuts according to claim 4, it is characterised in that：1000~
15~20min is fired at 1050 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810525280.6A CN108456006A (en) | 2018-05-28 | 2018-05-28 | The recyclability restorative procedure of Nixing pottery hallrcuts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810525280.6A CN108456006A (en) | 2018-05-28 | 2018-05-28 | The recyclability restorative procedure of Nixing pottery hallrcuts |
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| Publication Number | Publication Date |
|---|---|
| CN108456006A true CN108456006A (en) | 2018-08-28 |
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| CN201810525280.6A Pending CN108456006A (en) | 2018-05-28 | 2018-05-28 | The recyclability restorative procedure of Nixing pottery hallrcuts |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101462219A (en) * | 2009-01-16 | 2009-06-24 | 南开大学 | Method for repairing general-purpose crackle forming based on graphene |
| CN103771902A (en) * | 2014-01-03 | 2014-05-07 | 惠达卫浴股份有限公司 | Repair material and repair method for sanitary ceramics |
| US20140216653A1 (en) * | 2013-02-05 | 2014-08-07 | Promat Research and Technology Centre NV | Fire protection mortar |
| CN107915499A (en) * | 2017-12-01 | 2018-04-17 | 苏州宏久航空防热材料科技有限公司 | A kind of restorative procedure of C/SiC ceramic matric composites |
-
2018
- 2018-05-28 CN CN201810525280.6A patent/CN108456006A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101462219A (en) * | 2009-01-16 | 2009-06-24 | 南开大学 | Method for repairing general-purpose crackle forming based on graphene |
| US20140216653A1 (en) * | 2013-02-05 | 2014-08-07 | Promat Research and Technology Centre NV | Fire protection mortar |
| CN103771902A (en) * | 2014-01-03 | 2014-05-07 | 惠达卫浴股份有限公司 | Repair material and repair method for sanitary ceramics |
| CN107915499A (en) * | 2017-12-01 | 2018-04-17 | 苏州宏久航空防热材料科技有限公司 | A kind of restorative procedure of C/SiC ceramic matric composites |
Non-Patent Citations (2)
| Title |
|---|
| 林彬荫等: "《蓝晶石 红柱石 硅线石》", 31 March 2011, 冶金工业出版社 * |
| 陈群玉等: "利用机械力化学活化粉煤灰制备莫来石", 《中国科技论文》 * |
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Application publication date: 20180828 |