CN108452764A - The adsorbent of halide ion in a kind of removal waste water - Google Patents
The adsorbent of halide ion in a kind of removal waste water Download PDFInfo
- Publication number
- CN108452764A CN108452764A CN201710603887.7A CN201710603887A CN108452764A CN 108452764 A CN108452764 A CN 108452764A CN 201710603887 A CN201710603887 A CN 201710603887A CN 108452764 A CN108452764 A CN 108452764A
- Authority
- CN
- China
- Prior art keywords
- waste water
- adsorbent
- ion
- halide ion
- amount
- Prior art date
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- 239000002351 wastewater Substances 0.000 title claims abstract description 28
- 239000003463 adsorbent Substances 0.000 title claims abstract description 25
- -1 halide ion Chemical class 0.000 claims abstract description 36
- 239000000243 solution Substances 0.000 claims abstract description 22
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 11
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 11
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims abstract 3
- 229940006460 bromide ion Drugs 0.000 claims abstract 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims abstract 3
- 229940006461 iodide ion Drugs 0.000 claims abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052742 iron Inorganic materials 0.000 claims abstract 3
- 241000370738 Chlorion Species 0.000 claims abstract 2
- 238000000975 co-precipitation Methods 0.000 claims abstract 2
- 238000010521 absorption reaction Methods 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 238000013019 agitation Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000011701 zinc Substances 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000003957 anion exchange resin Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 238000003911 water pollution Methods 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- VTEIFHQUZWABDE-UHFFFAOYSA-N 2-(2,5-dimethoxy-4-methylphenyl)-2-methoxyethanamine Chemical compound COC(CN)C1=CC(OC)=C(C)C=C1OC VTEIFHQUZWABDE-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The sorbing material of halide ion in the removal waste water that the present invention provides a kind of based on zinc-iron binary hydrotalcite.It is (5 33) mg/g that it, which adsorbs the amount of fluorine ion, and the amount of chlorion is (40 106) mg/g, and the amount of bromide ion is (60 158) mg/g, and the amount of iodide ion is (150 269) mg/g.Zinc-iron ratio is (1 4) in zinc-iron binary hydrotalcite:1, the specific method of the halide ion in waste water solution is adsorbed as adsorbent is：Zinc-iron binary hydrotalcite is prepared using the method for co-precipitation；Mass ratio by contained halide ion in adsorbent and waste water is (0.2 7)：The adsorbent is added in waste water solution, magnetic agitation by 1 ratio, and reaction stirring (0.5 2) h, filters out adsorbent at a temperature of 25 DEG C, detects the amount of remaining halide ion in waste water；This method is suitable for the waste water aqueous solution of a concentration of (0.1 1) M of halide ion.
Description
Technical field
The present invention relates to water-treatment technology fields, and in particular to removes zinc-iron binary neatly masonry adsorbent in waste water
The application of halide ion.
Background technology
With China's expanding economy, China's water pollution situation is increasingly severe.In such water environment, people
Higher and higher to the degree of concern of water pollution treatment technology, the removal technology of the pollutants such as COD, BOD, nitrogen, phosphorus, heavy metal obtains
Great development.At present other than fluoride has corresponding limited value of discharge standard, there is no arrange for other common halogen ions
Limitation is put, inadequate to its attention rate, corresponding removal technology is relatively fewer.But halide ion is difficult by micro- life in industrial wastewater
Object is utilized, and high concentration waste water containing halogen is such as not added with improvement and is directly discharged into rivers, can be destroyed the balance of nature of water body, be made water
Matter deteriorates, and does great damage to aquaculture, freshwater resources, even can polluted underground water and drinking water source when serious.Therefore
The removal technology for studying halide ion is all meaningful to ecological and environmental protection.
The method for removing halide ion in water removal at present mainly has:Solvent extraction technology, anion-exchange resin method, compound wadding
The methods of solidifying agent flocculation treatment.Solvent extraction technology mainly utilizes compound molten in the solvent of two kinds immiscible (or slightly soluble)
The difference of solution degree or distribution coefficient makes compound be transferred in another solvent from a kind of solvent.Pass through repeated multiple times extraction
It taking, the compound of the overwhelming majority can be extracted, the halide ion cost removed in waste water in this way is relatively high,
It is economically not cost-effective.Anion-exchange resin method, composite flocculation agent coagulating/flocculating method for processing essence are removed by way of absorption
Fall the halide anion in waste water, research emphasis is in the efficiency-cost ratio for improving sorbing material at present.
Stratiform hydrotalcite (LDH) nano material be by positively charged main layer board (metal hydroxides) and interlayer the moon from
Made of interaction assembling of the son by non-covalent bond.The layer structure feature of hydrotalcite make its interlayer anion can with it is various
Anion swaps.At present document report is had no with the application of halide ion in zinc-iron hydrotalcite Adsorption waste water.
Invention content
The purpose of the present invention is to provide a kind of to remove halide ion in waste water based on zinc-iron binary hydrotalcite (LDH)
Efficient remover.
The purpose of the present invention is achieved through the following technical solutions：A. adsorption reaction：By institute's phosphoric acid in adsorbent and waste water
The mass ratio of root is (0.2-7)：The adsorbent is added in waste water solution, magnetic agitation by 1 ratio, at a temperature of 25 DEG C
Reaction stirring (0.5-2) h, filters out adsorbent, detects the amount of remaining halide ion in waste water；This method is suitable for halide ion
A concentration of (0.1-1) M waste water aqueous solution.(whether also having b technical solutions)
Preferably, the zinc-iron ratio in the waste water of a concentration of (0.1-0.5) M of halide ion, added is 1:1 binary water
Talcum can reach the maximal absorptive capacity of the absorption halide ion of adsorbent.
The method that the present invention is combined by physics with chemical action is realized most by adjusting the ratio of zinc and ferro element
Halide ion in the Adsorption waste water of big degree.
Specific implementation mode
Embodiment 1
Prepare Zn1The absorption property of Fe-LDH and halide ion is tested
The ferric nitrate of the zinc nitrate of 23.81g and 32.32g is dissolved into the water of 300mL, solution A is named as.By the carbon of 40.1g
The sodium hydroxide of sour sodium and 30g are dissolved into the water of 300mL, are named as solution B.By solution A and solution B with 20mL/min's
Speed is added drop-wise in the deionized water of carbon dioxide removal simultaneously, forms reaction solution, by the dropwise addition speed for adjusting solution A and solution B
Degree, remains at (6 ± 0.3) by the pH of deionized water, drips crystallization 6h at ambient temperature, centrifugal drying obtains powder
The Zn of last shape1Fe-LDH。
By a certain amount of Zn1Fe-LDH is distributed in the 200mL deionized waters of certain content of halide ions, is mixed
Uniformly, 0.5h is stirred, adsorbent is filtered out, the amount of remaining halide ion is surveyed with inductively-coupled plasma spectrometer, by changing
It calculates, calculates the amount of adsorbent absorption halide ion.Specific experiment parameter and measurement result are shown in Table 1.
1 Zn of table1Fe-LDH as adsorbent adsorb waste water in halide ion when specific experiment parameter and absorption halogen from
The amount of son.
Embodiment 2
Prepare Zn4The absorption property of Fe-LDH and phosphate radical is tested
The ferric nitrate of the nickel nitrate of 95.25g and 32.32g is dissolved into the water of 300mL, solution A is named as.By the carbon of 40.1g
The sodium hydroxide of sour sodium and 30g are dissolved into the water of 300mL, are named as solution B.By solution A and solution B with 20mL/min's
Speed is added drop-wise in the deionized water of carbon dioxide removal simultaneously, forms reaction solution, by the dropwise addition speed for adjusting solution A and solution B
Degree, remains at (6 ± 0.3) by the pH of deionized water, drips crystallization 6h at ambient temperature, centrifugal drying obtains powder
The Zn of last shape4Fe-LDH。
By a certain amount of Zn4Fe-LDH is distributed in the 200mL deionized waters of certain content of halide ions, is mixed
Uniformly, certain time is stirred, adsorbent is filtered out, the amount of remaining halide ion is surveyed with inductively-coupled plasma spectrometer, is led to
Conversion is crossed, the amount of adsorbent absorption halide ion is calculated.Specific experiment parameter and measurement result are shown in Table 2.
2 Zn of table4Fe-LDH as adsorbent adsorb waste water in halide ion when specific experiment parameter and absorption halogen from
The amount of son.
Claims (4)
1. the adsorbent of halide ion in a kind of removal waste water, it is characterised in that：Halide ion be common fluorine ion, chlorine from
Son, bromide ion, iodide ion, adsorbent are zinc-iron binary hydrotalcite.
2. the amount of the adsorbent of halide ion according to claim 1, absorption fluorine ion is (5-33) mg/g, chlorion
Amount be (40-106) mg/g, the amount of bromide ion is (60-158) mg/g, and the amount of iodide ion is (150-269) mg/g.
3. zinc-iron binary hydrotalcite adsorbent according to claim 1, wherein zinc-iron ratio are (1-4):1.
4. the purposes of zinc-iron binary hydrotalcite adsorbent according to claim 1, it is characterized in that being inhaled as adsorbent
The specific method of halide ion in attached waste water solution is：Zinc-iron binary hydrotalcite is prepared using the method for co-precipitation；By absorption
The mass ratio of agent and contained halide ion in waste water is (0.2-7)：The adsorbent is added in waste water solution, magnetic by 1 ratio
Power stirs, and reaction stirring (0.5-2) h, filters out adsorbent at a temperature of 25 DEG C, detects the amount of remaining halide ion in waste water；
This method is suitable for the waste water aqueous solution of a concentration of (0.1-1) M of halide ion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710603887.7A CN108452764B (en) | 2017-07-21 | 2017-07-21 | Adsorbent for removing halogen ions in wastewater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710603887.7A CN108452764B (en) | 2017-07-21 | 2017-07-21 | Adsorbent for removing halogen ions in wastewater |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108452764A true CN108452764A (en) | 2018-08-28 |
| CN108452764B CN108452764B (en) | 2020-09-15 |
Family
ID=63220996
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710603887.7A Expired - Fee Related CN108452764B (en) | 2017-07-21 | 2017-07-21 | Adsorbent for removing halogen ions in wastewater |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108452764B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109847703A (en) * | 2019-01-14 | 2019-06-07 | 中国环境科学研究院 | A kind of sodium secondary alkyl sulfonate modified hydrotalcite adsorbent and its preparation method and application |
| CN115106053A (en) * | 2021-03-17 | 2022-09-27 | 中国疾病预防控制中心辐射防护与核安全医学所(国家卫生健康委核事故医学应急中心) | Composite adsorption material and preparation method and application thereof |
| CN115140779A (en) * | 2022-05-05 | 2022-10-04 | 中南大学 | Hexagonal chlorine intercalation cobalt-aluminum hydrotalcite-like defluorination material and preparation and application thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109847703A (en) * | 2019-01-14 | 2019-06-07 | 中国环境科学研究院 | A kind of sodium secondary alkyl sulfonate modified hydrotalcite adsorbent and its preparation method and application |
| CN115106053A (en) * | 2021-03-17 | 2022-09-27 | 中国疾病预防控制中心辐射防护与核安全医学所(国家卫生健康委核事故医学应急中心) | Composite adsorption material and preparation method and application thereof |
| CN115106053B (en) * | 2021-03-17 | 2024-04-09 | 中国疾病预防控制中心辐射防护与核安全医学所(国家卫生健康委核事故医学应急中心) | Composite adsorption material and preparation method and application thereof |
| CN115140779A (en) * | 2022-05-05 | 2022-10-04 | 中南大学 | Hexagonal chlorine intercalation cobalt-aluminum hydrotalcite-like defluorination material and preparation and application thereof |
| CN115140779B (en) * | 2022-05-05 | 2023-09-08 | 中南大学 | Hexagonal chlorine intercalation cobalt-aluminum hydrotalcite defluorination material and preparation and application thereof |
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| Publication number | Publication date |
|---|---|
| CN108452764B (en) | 2020-09-15 |
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