CN108440937A - A kind of preparation method of New Antistatic Materials - Google Patents

A kind of preparation method of New Antistatic Materials Download PDF

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Publication number
CN108440937A
CN108440937A CN201810252792.XA CN201810252792A CN108440937A CN 108440937 A CN108440937 A CN 108440937A CN 201810252792 A CN201810252792 A CN 201810252792A CN 108440937 A CN108440937 A CN 108440937A
Authority
CN
China
Prior art keywords
parts
product
glass fibre
spare
antistatic materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810252792.XA
Other languages
Chinese (zh)
Inventor
刘光耀
赖兆庭
陈子豪
刘亚龙
程护伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongshan Lixin Technology Industrial Co Ltd
Original Assignee
Zhongshan Lixin Technology Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongshan Lixin Technology Industrial Co Ltd filed Critical Zhongshan Lixin Technology Industrial Co Ltd
Priority to CN201810252792.XA priority Critical patent/CN108440937A/en
Publication of CN108440937A publication Critical patent/CN108440937A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12Polyphenylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of preparation methods of New Antistatic Materials, anti-static material proposed by the present invention substitutes some Imported material with domestic raw material, product cost is greatly lowered, and be modified by activeness and quietness, properties of product increase on existing anti-static material.Its formula is:20 parts~30 parts of polyphenylene oxide, 620 parts~30 parts of nylon, 0~5 part of toughener, 0~5 part of compatilizer, 10 parts~30 parts of glass fibre, 10 parts~20 parts of carbon nanotube master batch, 0~0.5 part of antioxidant, 0~0.5 part of lubricant.It weighs up that each component is spare according to formula constituent, by other raw materials in addition to glass fibre, puts into blender together, after being dried under the conditions of 140 DEG C, stirring 2~3H, it is spare to be discharged to turnover box;Production equipment temperature is set at 260~290 DEG C, the raw material being stirred is through double screw extruder melt blending, extrusion, check rod, pelletizing up to product.

Description

A kind of preparation method of New Antistatic Materials
Technical field
The present invention relates to anti-static material technical field, more particularly to a kind of preparation method of New Antistatic Materials.
Background technology
Existing anti-static material cost is excessively high, and supply falls short of demand for raw material, leads to market unsettled of supplying;Production technology Cumbersome, low production efficiency, environmental pollution is big.
Invention content
The technical problem to be solved in the present invention is to provide a kind of preparation methods of New Antistatic Materials, overcome above existing The defect of technology has many advantages, such as that production cost is low, efficient, energy conservation and environmental protection.
In order to solve the above-mentioned technical problem, the technical scheme is that:
A kind of preparation method of New Antistatic Materials:
Anti-static material proposed by the present invention substitutes some Imported material with domestic raw material, product cost is greatly lowered, And be modified by activeness and quietness, properties of product increase on existing anti-static material.Its formula is:Polyphenylene oxide 20 parts~30 Part, 620 parts~30 parts of nylon, 0~5 part of toughener, 0~5 part of compatilizer, 10 parts~30 parts of glass fibre, carbon nanotube master batch 10 parts~20 parts, 0~0.5 part of antioxidant, 0~0.5 part of lubricant.
It weighs up that each component is spare according to formula constituent, by other raw materials in addition to glass fibre, puts into blender together, It is dried under the conditions of 140 DEG C, after 2~3H of stirring, it is spare to be discharged to turnover box;Be arranged production equipment temperature at 260~290 DEG C, The raw material being stirred is through double screw extruder melt blending, extrusion, check rod, pelletizing up to product.
The beneficial effects of the invention are as follows:
This formula and the made anti-static material of technological process, production cost is low, product strength height (tensile strength > 80MPa, bending strength > 130MPa), good toughness (notch impact strength > 2Kj/m2), low (the < 2*10-5/ of coefficient of thermal expansion DEG C), heat distortion temperature height (200 DEG C of 1.82MPa, HDT >), processing performance is good.Production efficiency can be improved in this method, reduces environment Pollution.
It can guarantee the stabilization of raw material supply;
The use ratio of high cost polyphenylene oxide is greatly lowered, and has high price advantage;
The physical property of product compares current material raising, and cost performance is high;
In production process, volatile organic matter (VOC) is greatly lowered, high environment friendly;
Secondary recovery is convenient, and antistatic property conservation rate is high when recycling is processed;
Improve production efficiency.
Description of the drawings
Fig. 1 is that a kind of New Antistatic Materials of the present invention fill Cost comparisons' figure of anti-static material with conventional carbon black.
Fig. 2 is that a kind of New Antistatic Materials of the present invention fill the intensity contrast figure of anti-static material with conventional carbon black.
Fig. 3 is that a kind of New Antistatic Materials of the present invention fill the high temperature resistant comparison of anti-static material with conventional carbon black Figure.
Specific implementation mode
The specific implementation mode of the present invention is described further below in conjunction with the accompanying drawings.It should be noted that for The explanation of these embodiments is used to help understand the present invention, but does not constitute limitation of the invention.In addition, disclosed below The each embodiment of the present invention in involved technical characteristic can be combined with each other as long as they do not conflict with each other.
A kind of preparation method of New Antistatic Materials:
Anti-static material proposed by the present invention substitutes some Imported material with domestic raw material, product cost is greatly lowered, And be modified by activeness and quietness, properties of product increase on existing anti-static material.Its formula is:Polyphenylene oxide 20 parts~30 Part, 620 parts~30 parts of nylon, 0~5 part of toughener, 0~5 part of compatilizer, 10 parts~30 parts of glass fibre, carbon nanotube master batch 10 parts~20 parts, 0~0.5 part of antioxidant, 0~0.5 part of lubricant.
It weighs up that each component is spare according to formula constituent, by other raw materials in addition to glass fibre, puts into blender together, It is dried under the conditions of 140 DEG C, after 2~3H of stirring, it is spare to be discharged to turnover box;Be arranged production equipment temperature at 260~290 DEG C, The raw material being stirred is through double screw extruder melt blending, extrusion, check rod, pelletizing up to product.
As shown in Figure 1-Figure 3, the performance comparison figure of New Antistatic Materials and conventional carbon black filling anti-static material;
Compatilizer, the selection of toughener and dosage are conducive to improve the physical property of product;
The dosage of nylon 6, glass fibre utilizes raising cost performance;
Carbon nanotube replaces conductive black energy conservation and environmental protection.
Embodiments of the present invention are explained in detail above in association with attached drawing, but the present invention is not limited to described implementations Mode.For a person skilled in the art, in the case where not departing from the principle of the invention and spirit, to these embodiments A variety of change, modification, replacement and modification are carried out, are still fallen in protection scope of the present invention.

Claims (1)

1. a kind of preparation method of New Antistatic Materials, includes the following steps:
The formula proportion of the New Antistatic Materials is:
It weighs up that each component is spare according to formula constituent, by other raw materials in addition to glass fibre, puts into blender together, It is dried under the conditions of 140 DEG C, after 2~3H of stirring, it is spare to be discharged to turnover box;
Production equipment temperature is set at 260~290 DEG C, the raw material that has been stirred through double screw extruder melt blending, squeeze out, lead Item, pelletizing are up to product.
CN201810252792.XA 2018-03-26 2018-03-26 A kind of preparation method of New Antistatic Materials Pending CN108440937A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810252792.XA CN108440937A (en) 2018-03-26 2018-03-26 A kind of preparation method of New Antistatic Materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810252792.XA CN108440937A (en) 2018-03-26 2018-03-26 A kind of preparation method of New Antistatic Materials

Publications (1)

Publication Number Publication Date
CN108440937A true CN108440937A (en) 2018-08-24

Family

ID=63197087

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810252792.XA Pending CN108440937A (en) 2018-03-26 2018-03-26 A kind of preparation method of New Antistatic Materials

Country Status (1)

Country Link
CN (1) CN108440937A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503969A (en) * 2018-03-26 2018-09-07 中山礼信科技实业有限公司 A kind of preparation method of novel elastomer material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1434712A (en) * 1973-06-27 1976-05-05 Sumitomo Electric Industries Preparation of lubricatn-containing synthetic resin composi tions
CN102382453A (en) * 2011-09-28 2012-03-21 深圳市科聚新材料有限公司 Antistatic nylon material and preparation method thereof
CN102898810A (en) * 2012-10-29 2013-01-30 虞海香 PPO/PA66 plastic and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1434712A (en) * 1973-06-27 1976-05-05 Sumitomo Electric Industries Preparation of lubricatn-containing synthetic resin composi tions
CN102382453A (en) * 2011-09-28 2012-03-21 深圳市科聚新材料有限公司 Antistatic nylon material and preparation method thereof
CN102898810A (en) * 2012-10-29 2013-01-30 虞海香 PPO/PA66 plastic and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108503969A (en) * 2018-03-26 2018-09-07 中山礼信科技实业有限公司 A kind of preparation method of novel elastomer material

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Application publication date: 20180824