CN108440922A - A kind of PET composite material and preparation method thereof - Google Patents
A kind of PET composite material and preparation method thereof Download PDFInfo
- Publication number
- CN108440922A CN108440922A CN201810235341.5A CN201810235341A CN108440922A CN 108440922 A CN108440922 A CN 108440922A CN 201810235341 A CN201810235341 A CN 201810235341A CN 108440922 A CN108440922 A CN 108440922A
- Authority
- CN
- China
- Prior art keywords
- composite material
- temperature
- parts
- pet composite
- area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
It is composed of the following components by weight the present invention relates to a kind of PET composite material and preparation method thereof：PET is 80 parts 100 parts, and compounded mix is 16 parts 20 parts, and antiseptic is 4 parts 6 parts, and antioxidant is 0.1 part 0.5 part, and compatilizer is 0.1 part 0.3 part.Wollastonite surface is through Nano-meter SiO_22Its sharp keen corner angle becomes to be passivated after cladding, and smooth surface also becomes coarse, the problem of alleviating stress raisers in the composite material thereby resulted in.It is coated on the Nano-meter SiO_2 on wollastonite surface simultaneously2The interface interaction power between filler and PET matrix is also enhanced, to promote the mechanical property of PET composite material；The addition of antiseptic cerium/nano cuprous oxide improves the anti-microbial property of PET composite material.
Description
Technical field
The invention belongs to technical field of polymer materials, a kind of PET composite material and preparation method thereof is particularly related to.
Background technology
Polyethylene terephthalate (PET) have it is light, nontoxic, odorless, chemical stability is good, and insoluble at normal temperatures
In common solvent, the advantages that water imbibition is small.Although the comprehensive performance of PET is very excellent, the anti-microbial property of PET is general, this
Greatly limit the application range of PET composite material.
Meanwhile PET is in the preparation process of composite material, it is found that different fillers can lead to the mechanics of PET composite material
It is the decision of the performance and application range that determine PET composite material that performance, which has sizable variation, the filler in PET composite material,
One of factor, in order to improve the mechanical property and anti-microbial property of PET composite material simultaneously, researcher is carrying out always largely
Subject study, applicant propose to improve by a variety of work in terms of the mechanical property and antibiotic property to existing PET composite material
Technical solution.
Invention content
The object of the present invention is to provide a kind of PET composite material and preparation method thereof, by improving filler and antiseptic
Composition, solves the mechanical property and anti-microbial property of PET composite material in the prior art.
The present invention is achieved by the following technical solutions：
A kind of PET composite material, it is composed of the following components by weight：
The compounded mix is nano-silica/silicone lime stone compounded mix；
The antiseptic is cerium/nano cuprous oxide antiseptic.
The preparation method of the nano-silica/silicone lime stone compounded mix, includes the following steps：
(1) wollastonite is dried to 3-5h in 80-100 DEG C of baking oven；
(2) by sodium metasilicate, it is dry after wollastonite and polyethylene glycol be put into ethanol water, in temperature be 90-110
DEG C thermostat water bath in 8-10h；
(3) saturated ammonium chloride solution is slowly added dropwise under electric mixer stirring, centrifuge, filter after standing 2-4h, is dry,
It crushes, obtains Nano-meter SiO_22/ Wollastonite Composite Fillers.
Sodium metasilicate, wollastonite, polyethylene glycol and saturated ammonium chloride solution mass ratio be (30-50)：(100-160)：
(4-8)：(20-40).
The preparation method of cerium/nano cuprous oxide antiseptic, includes the following steps：
(1) a certain amount of nano cuprous oxide powder body, cerium chloride and deionized water are weighed；
(2) nano cuprous oxide powder body, cerium chloride, deionized water are put in three-necked flask, in 60-80 DEG C of tepidarium
Middle reaction 4-6h；
(3) pH value of a certain amount of hydrochloric acid conditioning solution is added to neutrality, then filtered, dried, grind to get to
Cerium/nano cuprous oxide antiseptic.
Nano cuprous oxide powder body, cerium chloride, deionized water mass ratio be (20-30)：(100-160)：(300-
420)。
The antioxidant is three (2,4- di-t-butyl) phenyl-phosphites, four [β-(3,5- di-tert-butyl-hydroxy phenyl)
Propionic acid] pentaerythritol ester or 1,3,5- trimethyls -2,4, one kind or several in 6- (3,5- di-t-butyl -4- hydroxyphenylmethyls) benzene
The mixing of kind.
The compatilizer is SEBS-g-MAH.
The preparation method of any of the above-described PET composite material, includes the following steps：
(1) 80 parts of -100 parts of PET, 16 parts of -20 parts of compounded mixs, 4 parts of -6 parts of antiseptics, 0.1 part of -0.5 part of antioxygen are weighed
Agent, 0.1 part of -0.3 part of SEBS-g-MAH are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material.
The step (2) is specially：The mixture obtained in step (1) is put into the hopper of double screw extruder and is squeezed
Go out to be granulated, wherein the double screw extruder includes six humidity provinces sequentially arranged, 240~260 DEG C of area's temperature, 2nd area
280~300 DEG C of temperature, three 280~300 DEG C of area's temperature, four 280~300 DEG C of area's temperature, five 280~300 DEG C of area's temperature, 6th area
280~300 DEG C of temperature, 280~300 DEG C of head temperature, 200~280r/min of screw speed.
The beneficial effects of the invention are as follows：
1, wollastonite surface is through Nano-meter SiO_22Its sharp keen corner angle becomes to be passivated after cladding, and smooth surface also becomes thick
It is rough, the problem of alleviating stress raisers in the composite material thereby resulted in.It is coated on the nanometer S on wollastonite surface simultaneously
iO2The interface interaction power between filler and PET matrix is also enhanced, to promote the mechanical property of PET composite material.
2, the addition of antiseptic cerium/nano cuprous oxide improves the anti-microbial property of PET composite material.
Specific implementation mode
Carry out the technical solution that the present invention will be described in detail by the following examples, embodiment below is merely exemplary, only
It can be used for explanation and illustration technical scheme of the present invention, and be not to be construed as the limitation to technical solution of the present invention.
The technical program is mainly used for improving the anti-microbial property and mechanical property of PET composite material, is not intended to protect
A kind of new PET composite material is protected, the technical program is mainly by the antiseptic and compounded mix of exploitation and existing PET materials
The combination of matter, the anti-microbial property and mechanical property for realizing PET composite material are improved, accordingly, with respect in the prior art
The amount ranges of the material of PET are not that this application claims focused protections.
Raw material used in various embodiments of the present invention is as follows：
PET (model 008L), Canadian Aclo；Sodium metasilicate, Shanghai jump reach Industrial Co., Ltd.；Wollastonite, Jiang Xihai
Source chemical industry；Polyethylene glycol, Hai'an petrochemical industry；Ammonium chloride, Zhuzhou Jianghai Environmental Protection Co., Ltd.；Nano cuprous oxide, north
Capital Deco Dao Jin Science and Technology Ltd.s；Cerium chloride, Shanghai Shu Can Industrial Co., Ltd.s；Hydrochloric acid, Chinese medicines group chemical reagent are limited
Company；Antioxidant (model Irganox168, Irganox1010, Irganox1330), Switzerland's Ciba；SEBS-g-MAH,
Suzhou Asia match plasticizing Co., Ltd.
Test equipment used in various embodiments of the present invention is as follows：
ZSK30 type double screw extruders, German W＆P companies；JL-1000 type tensile testing machines, the wide just experiment instrument in Guangzhou
Device company produces；HTL900-T-5B type injection (mo(u)lding) machines, the production of Hai Tai plastics machineries Co., Ltd；XCJ-500 type shock-testings
Machine, the production of Chengde testing machine factory；QT-1196 type tester for elongation, Dongguan City Gao Tai detecting instruments Co., Ltd；QD-GJS-
B12K type homogenizers, Beijing perseverance Order instrument and meter Co., Ltd.
The application provides a kind of PET composite material, composed of the following components by weight：
Compounded mix is nano-silica/silicone lime stone compounded mix；
Antiseptic is cerium/nano cuprous oxide antiseptic.
The preparation method of nano-silica/silicone lime stone compounded mix, includes the following steps：
(1) by wollastonite in 80-100 DEG C of baking oven dry 3-5h, fully remove the absorption water on wollastonite surface in case
With；
(2) by sodium metasilicate, it is dry after wollastonite and polyethylene glycol be put into ethanol water, in temperature be 90-110
DEG C thermostat water bath in 8-10h so that sodium metasilicate and wollastonite are completely dissolved；
(3) saturated ammonium chloride solution is slowly added dropwise under electric mixer stirring, centrifuge, filter after standing 2-4h, is dry,
It crushes, obtains Nano-meter SiO_22/ Wollastonite Composite Fillers.
Sodium metasilicate, wollastonite, polyethylene glycol and saturated ammonium chloride solution mass ratio be (30-50)：(100-160)：
(4-8)：(20-40).
The preparation method of cerium/nano cuprous oxide antiseptic, includes the following steps：
(1) a certain amount of nano cuprous oxide powder body, cerium chloride and deionized water are weighed；
(2) nano cuprous oxide powder body, cerium chloride, deionized water are put in three-necked flask, in 60-80 DEG C of tepidarium
Middle reaction 4-6h；
(3) pH value of a certain amount of hydrochloric acid conditioning solution is added to neutrality, then filtered, dried, grind to get to
Cerium/nano cuprous oxide antiseptic.
Nano cuprous oxide powder body, cerium chloride, deionized water mass ratio be (20-30)：(100-160)：(300-
420)。
Antioxidant be BASF AG three (2,4- di-t-butyls) phenyl-phosphites (referred to as
Irganox168), four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters (abbreviation
Irganox1010) or 1,3,5- trimethyls -2,4,6- (3,5- di-t-butyl -4- hydroxyphenylmethyls) benzene is (referred to as
One or more of) Irganox1330 mixing.
Compatilizer is SEBS-g-MAH.
Embodiment 1
(1) weigh 80 parts of PET, 16 parts of compounded mixs, 4 parts of ceriums/nano cuprous oxide antiseptic, 0.1 part
Irganox168,0.1 part of SEBS-g-MAH are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material P1.
Wherein each area's temperature of double screw extruder and screw speed are respectively：One 240 DEG C of area's temperature, two 280 DEG C of area's temperature,
Three 280 DEG C of area's temperature, four 280 DEG C of area's temperature, five 280 DEG C of area's temperature, six 280 DEG C of area's temperature, 280 DEG C of head temperature, screw rod turn
Fast 200r/min.
Embodiment 2
(1) weigh 100 parts of PET, 20 parts of compounded mixs, 6 parts of ceriums/nano cuprous oxide antiseptic, 0.1 part
Irganox168,0.2 part of Irganox1010,0.2 part of Irganox1330,0.3 part of SEBS-g-MAH are mixed and stirred for uniformly, obtaining
To mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material P2.
Wherein each area's temperature of double screw extruder and screw speed are respectively：One 260 DEG C of area's temperature, two 300 DEG C of area's temperature,
Three 300 DEG C of area's temperature, four 300 DEG C of area's temperature, five 300 DEG C of area's temperature, six 300 DEG C of area's temperature, 300 DEG C of head temperature, screw rod turn
Fast 280r/min.
Embodiment 3
(1) weigh 90 parts of PET, 18 parts of compounded mixs, 5 parts of ceriums/nano cuprous oxide antiseptic, 0.1 part
Irganox168,0.2 part of Irganox1010,0.2 part of SEBS-g-MAH are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material P3.
Wherein each area's temperature of double screw extruder and screw speed are respectively：One 250 DEG C of area's temperature, two 290 DEG C of area's temperature,
Three 290 DEG C of area's temperature, four 290 DEG C of area's temperature, five 290 DEG C of area's temperature, six 290 DEG C of area's temperature, 290 DEG C of head temperature, screw rod turn
Fast 240r/min.
Embodiment 4
(1) weigh 95 parts of PET, 19 parts of compounded mixs, 6 parts of ceriums/nano cuprous oxide antiseptic, 0.1 part
Irganox1010,0.2 part of Irganox1330,0.1 part of SEBS-g-MAH are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material P4.
Wherein each area's temperature of double screw extruder and screw speed are respectively：One 245 DEG C of area's temperature, two 285 DEG C of area's temperature,
Three 285 DEG C of area's temperature, four 285 DEG C of area's temperature, five 285 DEG C of area's temperature, six 285 DEG C of area's temperature, 285 DEG C of head temperature, screw rod turn
Fast 255r/min.
Embodiment 5
(1) weigh 100 parts of PET, 17 parts of compounded mixs, 5 parts of ceriums/nano cuprous oxide antiseptic, 0.2 part
Irganox1010,0.2 part of Irganox1330,0.1 part of SEBS-g-MAH are mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material P5.
Wherein each area's temperature of double screw extruder and screw speed are respectively：One 250 DEG C of area's temperature, two 295 DEG C of area's temperature,
Three 295 DEG C of area's temperature, four 295 DEG C of area's temperature, five 295 DEG C of area's temperature, six 295 DEG C of area's temperature, 295 DEG C of head temperature, screw rod turn
Fast 270r/min.
Comparative example 1
(1) 80 parts of PET, 16 parts of wollastonites, 0.1 part of Irganox1010,0.2 part of Irganox168,0.1 part of SEBS- are weighed
G-MAH is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material D1.
Wherein each area's temperature of double screw extruder and screw speed are respectively：One 255 DEG C of area's temperature, two 285 DEG C of area's temperature,
Three 285 DEG C of area's temperature, four 285 DEG C of area's temperature, five 285 DEG C of area's temperature, six 285 DEG C of area's temperature, 285 DEG C of head temperature, screw rod turn
Fast 245r/min.
Performance test：
Batten test is made with injection molding machine in PET composite material prepared by above-described embodiment 1-5 and comparative example 1, tests number
According to such as following table：
The antibiotic property and physical property of embodiment 1-5 will be better than comparative example 1 as can be seen from the above table.This is greatly extended
The application field of PET composite material, has very important significance.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And deformation, the scope of the present invention are extremely equally limited by appended claims.
Claims (9)
1. a kind of PET composite material, which is characterized in that composed of the following components by weight：
The compounded mix is nano-silica/silicone lime stone compounded mix；
The antiseptic is cerium/nano cuprous oxide antiseptic.
2. PET composite material according to claim 1, which is characterized in that the nano-silica/silicone lime stone is compound to be filled out
The preparation method of material, includes the following steps：
(1) wollastonite is dried to 3-5h in 80-100 DEG C of baking oven；
(2) by sodium metasilicate, it is dry after wollastonite and polyethylene glycol be put into ethanol water, in temperature be 90-110 DEG C
8-10h in thermostat water bath；
(3) saturated ammonium chloride solution is slowly added dropwise under electric mixer stirring, stands centrifugation, filtering, dry, powder after 2-4h
It is broken, obtain Nano-meter SiO_22/ Wollastonite Composite Fillers.
3. PET composite material according to claim 2, which is characterized in that sodium metasilicate, wollastonite, polyethylene glycol and full
Mass ratio with ammonium chloride solution is (30-50)：(100-160)：(4-8)：(20-40).
4. PET composite material according to claim 1, which is characterized in that the system of cerium/nano cuprous oxide antiseptic
Preparation Method includes the following steps：
(1) a certain amount of nano cuprous oxide powder body, cerium chloride and deionized water are weighed；
(2) nano cuprous oxide powder body, cerium chloride, deionized water are put in three-necked flask, it is anti-in 60-80 DEG C of tepidarium
Answer 4-6h；
(3) pH value of a certain amount of hydrochloric acid conditioning solution is added to neutrality, then filtered, dried, ground to get to rare earth
Cerium/nano cuprous oxide antiseptic.
5. PET composite material according to claim 4, which is characterized in that nano cuprous oxide powder body, cerium chloride, go from
The mass ratio of sub- water is (20-30)：(100-160)：(300-420).
6. PET composite material according to claim 1, which is characterized in that the antioxidant is three (2,4- di-t-butyls)
Phenyl-phosphite, four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters or 1,3,5- trimethyls -2,4,6-
The mixing of one or more of (3,5- di-t-butyl -4- hydroxyphenylmethyls) benzene.
7. PET composite material according to claim 1, which is characterized in that the compatilizer is SEBS-g-MAH.
8. the preparation method of any one of the claims 1 to 7 PET composite material, which is characterized in that include the following steps：
(1) weigh 80 parts of -100 parts of PET, 16 parts of -20 parts of compounded mixs, 4 parts of -6 parts of antiseptics, 0.1 part of -0.5 part of antioxidant,
0.1 part of -0.3 part of SEBS-g-MAH is mixed and stirred for uniformly, obtaining mixture；
(2) by the mixture extruding pelletization obtained in step (1) to get to PET composite material.
9. the preparation method of PET composite material according to any one of claims 8, which is characterized in that the step (2) is specially：It will step
Suddenly the mixture obtained in (1) puts into extruding pelletization in the hopper of double screw extruder, wherein the double screw extruder packet
Include six humidity provinces sequentially arranged, 240~260 DEG C of area's temperature, two 280~300 DEG C of area's temperature, three area's temperature 280~300
DEG C, four 280~300 DEG C of area's temperature, five 280~300 DEG C of area's temperature, six 280~300 DEG C of area's temperature, head temperature 280~300
DEG C, 200~280r/min of screw speed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810235341.5A CN108440922A (en) | 2018-03-21 | 2018-03-21 | A kind of PET composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810235341.5A CN108440922A (en) | 2018-03-21 | 2018-03-21 | A kind of PET composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108440922A true CN108440922A (en) | 2018-08-24 |
Family
ID=63196037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810235341.5A Pending CN108440922A (en) | 2018-03-21 | 2018-03-21 | A kind of PET composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108440922A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504045A (en) * | 2018-12-07 | 2019-03-22 | 安徽江淮汽车集团股份有限公司 | A kind of antibacterial PET composite material and preparation method |
| WO2023014333A1 (en) * | 2021-08-03 | 2023-02-09 | T.C. Erci̇yes Üni̇versi̇tesi̇ | Silica added pet bottle and production method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105837990A (en) * | 2016-05-17 | 2016-08-10 | 蚌埠市燕南塑料制品厂 | Anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe and preparation method thereof |
| CN106479139A (en) * | 2016-10-21 | 2017-03-08 | 安徽江淮汽车集团股份有限公司 | A kind of PBT composite and preparation method thereof |
| CN106977751A (en) * | 2017-05-11 | 2017-07-25 | 浙江银瑜新材料股份有限公司 | A kind of composite antibacterial deodorization functions master batch, the preparation method of fiber |
| CN107189249A (en) * | 2017-06-21 | 2017-09-22 | 安徽江淮汽车集团股份有限公司 | A kind of high-performance antibiosis PS composites and preparation method thereof |
| CN107216530A (en) * | 2017-07-21 | 2017-09-29 | 安徽江淮汽车集团股份有限公司 | A kind of PE composites and preparation method thereof |
-
2018
- 2018-03-21 CN CN201810235341.5A patent/CN108440922A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105837990A (en) * | 2016-05-17 | 2016-08-10 | 蚌埠市燕南塑料制品厂 | Anti-microbial superfine fully-vulcanized powdered rubber and polyvinyl chloride composite water pipe and preparation method thereof |
| CN106479139A (en) * | 2016-10-21 | 2017-03-08 | 安徽江淮汽车集团股份有限公司 | A kind of PBT composite and preparation method thereof |
| CN106977751A (en) * | 2017-05-11 | 2017-07-25 | 浙江银瑜新材料股份有限公司 | A kind of composite antibacterial deodorization functions master batch, the preparation method of fiber |
| CN107189249A (en) * | 2017-06-21 | 2017-09-22 | 安徽江淮汽车集团股份有限公司 | A kind of high-performance antibiosis PS composites and preparation method thereof |
| CN107216530A (en) * | 2017-07-21 | 2017-09-29 | 安徽江淮汽车集团股份有限公司 | A kind of PE composites and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张楠等: "含稀土铈载铜无机抗菌材料的制备与研究", 《硅酸盐通报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504045A (en) * | 2018-12-07 | 2019-03-22 | 安徽江淮汽车集团股份有限公司 | A kind of antibacterial PET composite material and preparation method |
| WO2023014333A1 (en) * | 2021-08-03 | 2023-02-09 | T.C. Erci̇yes Üni̇versi̇tesi̇ | Silica added pet bottle and production method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108794972B (en) | A kind of antibacterial antistatic ABS composite material and preparation method thereof | |
| CN107446336A (en) | A kind of low smell exempts to spray PC/ABS materials and preparation method thereof | |
| CN108440922A (en) | A kind of PET composite material and preparation method thereof | |
| CN106633383A (en) | High-performance high-transparency PP-PS composite material and preparation method thereof | |
| CN107573657A (en) | A kind of PET composite material and preparation method thereof | |
| CN107189249B (en) | A kind of high-performance antibiosis PS composite material and preparation method | |
| CN108912620A (en) | A kind of antibiotic conductive PET composite material and preparation method thereof | |
| CN107418050A (en) | A kind of high-performance antibiosis PP PA6 composites and preparation method thereof | |
| CN107216530A (en) | A kind of PE composites and preparation method thereof | |
| CN104292796A (en) | Application of zinc isoocatanoate in reduction on agglomeration of white carbon black, white carbon black dispersing agent containing zinc isoocatanoate and preparation method thereof | |
| CN109851821A (en) | A kind of eutectic solvent and its dissolving method that can effectively dissolve hyper-branched polyester | |
| CN106479072B (en) | A kind of PS composite material and preparation methods | |
| CN105331054A (en) | Composite conductive film | |
| CN106479137A (en) | A kind of high thermal conductivity PBT composite and preparation method thereof | |
| CN107746054A (en) | A kind of synthetic method of 3 aminopropyltriethoxywerene werene modified graphene oxide | |
| CN107759912A (en) | A kind of PS fulvene compounding materials and preparation method thereof | |
| CN107337924A (en) | A kind of antistatic high-performance PA66 composites and preparation method thereof | |
| CN103408949A (en) | Ultra-high-hardness mixed rubber and preparation method thereof | |
| CN109627578A (en) | A kind of weatherable master batch and preparation method thereof | |
| CN110804273A (en) | Scratch-resistant and fingerprint-resistant spraying-free POM composite material and preparation method thereof | |
| CN104277069B (en) | Synthesis and application of new nano hybrid | |
| CN105733231A (en) | Calcium sulfate whisker-modified polycarbonate alloy material and preparation method thereof | |
| CN108485231A (en) | A kind of epoxidation polyphenylene oxide conductive film and preparation method thereof | |
| CN108329648A (en) | A kind of weather-proof color masterbatch of ABS | |
| CN107163568B (en) | A kind of fire-retardant high-ductility PA6-ACS composite material and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180824 |