CN108440005A - Light thermal-shield refractory castable - Google Patents

Light thermal-shield refractory castable Download PDF

Info

Publication number
CN108440005A
CN108440005A CN201810640009.7A CN201810640009A CN108440005A CN 108440005 A CN108440005 A CN 108440005A CN 201810640009 A CN201810640009 A CN 201810640009A CN 108440005 A CN108440005 A CN 108440005A
Authority
CN
China
Prior art keywords
parts
flyash
magnesium carbonate
mullite
hollow ball
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810640009.7A
Other languages
Chinese (zh)
Inventor
丁左宏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Tianzige New Material Technology Co Ltd
Original Assignee
Jiangsu Tianzige New Material Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Tianzige New Material Technology Co Ltd filed Critical Jiangsu Tianzige New Material Technology Co Ltd
Priority to CN201810640009.7A priority Critical patent/CN108440005A/en
Publication of CN108440005A publication Critical patent/CN108440005A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206Magnesium oxides or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/528Spheres

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Ceramic Products (AREA)

Abstract

A kind of light thermal-shield refractory castable, is made of following raw material:Flyash, mullite, alumina hollow ball, alumina powder, magnesium carbonate;The parts by weight of above-mentioned raw materials are:10~20 parts of flyash, 20~30 parts of mullite, 10~20 parts of alumina hollow ball, 30~40 parts of alumina powder, 20~30 parts of magnesium carbonate.Mullite, alumina hollow ball are aggregate, and flyash, alumina powder, magnesium carbonate are matrix.

Description

Light thermal-shield refractory castable
Technical field
The invention belongs to technical field of refractory materials more particularly to a kind of light thermal-shield refractory castables.
Background technology
Compared with qualitative refractory product, short with technological process as the unshape refractory of representative using castable refractory, Energy consumption and the advantages such as at low cost, easy to use, applied widely, globality and using effect are good, thus in world wide It is inside rapidly developed, shared proportion is higher and higher in entire refractory material.It is advanced in some refractory technologies Country in, the yield of unshape refractory is already close to the yield for being even more than setting product.For example, current Japan is not The ratio that amorphous refractory yield accounts for entire refractory material has reached 60% or so;The U.S. is 50% or so;English, moral, method Equal states are 40%~50%.Nowadays, castable refractory has been widely used in the industry neck such as metallurgy, building materials, electric power, chemical industry In the high-temperature service in domain, the castable refractory of various materials has been widely applied.
Light thermal-shield refractory castable refers to low thermal conductivity and the castable refractory of low heat capacity, and also referred to as thermal insulation fire-resistant pours Material feeding.Insulating refractory casting material obtains lower thermal conductivity, the in general stomata of material mainly by way of introducing stomata Rate is higher, and its thermal conductivity is lower, and also lower heat insulation is better for the thermal conductivity of the smaller material in aperture of stomata.Fireclay insulating refractory There is extensive purposes reducing the energy consumption of high-temperature service, meeting in high temperature special process requirement.Existing method prepares light The problem of matter insulating refractory casting material is:First, the porosity is not high, the main source of stomata is aglite in castable refractory, Preparing the porosity of lightening casting material generally can all be less than the porosity of aglite, thus cannot achieve lightening casting material High porosity;Second is that the porosity of castable is higher but aperture is larger, and for porous material, the smaller lightweight of bore dia The intensity of material is high, and thermal conductivity is low, this is because the quantity of stomata is just more in the small material of bore dia, contributes to subtract at high temperature Few convection of heat and radiation are to reduce the thermal conductivity of castable.
Invention content
In view of this, in view of the deficiencies of the prior art, a kind of bulk density of present invention offer is small, thermal conductivity is low, thermal insulation It can light thermal-shield refractory castable good, after liner body molding without maintenance.
A kind of light thermal-shield refractory castable, is made of following raw material:Flyash, mullite, alumina hollow ball, oxidation Aluminium micro mist, magnesium carbonate;The parts by weight of above-mentioned raw materials are:10~20 parts of flyash, 20~30 parts of mullite, alumina hollow ball 10~20 parts, 30~40 parts of alumina powder, 20~30 parts of magnesium carbonate.Mullite, alumina hollow ball be aggregate, flyash, Alumina powder, magnesium carbonate are matrix.
In conclusion compared with prior art, the present invention the alumina hollow ball in aggregate has special surface texture And boring, surface irregularity, increase contact specific surface area so that aggregate and alumina powder, magnesium carbonate, powder in matrix Coal ash is firmly combined with, and not only improves fire resistance, but also increases the intensity and heat insulation effect of material, under magnesium carbonate hot environment It decomposes and generates carbon dioxide, magnesia, carbon dioxide can increase the porosity of light thermal-shield refractory castable, and aluminium oxide is micro- The thermal shock resistance that magnesium aluminate spinel ensures light thermal-shield refractory castable is generated under powder, magnesia hot environment.
Specific implementation mode
With reference to embodiment, invention is further described in detail.This specific embodiment is only the solution to the present invention It releases, is not the limitation to invention, those skilled in the art can be as needed to this implementation after reading this specification Example makes any modification, but as long as all being protected by Patent Law in scope of the presently claimed invention.
Embodiment 1
A kind of light thermal-shield refractory castable, is made of following raw material:Flyash, mullite, alumina hollow ball, oxidation Aluminium micro mist, magnesium carbonate;The parts by weight of above-mentioned raw materials are:10 parts of flyash, 30 parts of mullite, 10 parts of alumina hollow ball, oxygen Change 40 parts of aluminium micro mist, 20 parts of magnesium carbonate.Mullite, alumina hollow ball are aggregate, and flyash, alumina powder, magnesium carbonate are Matrix.
Embodiment 2
A kind of light thermal-shield refractory castable, is made of following raw material:Flyash, mullite, alumina hollow ball, oxidation Aluminium micro mist, magnesium carbonate;The parts by weight of above-mentioned raw materials are:20 parts of flyash, 20 parts of mullite, 20 parts of alumina hollow ball, oxygen Change 30 parts of aluminium micro mist, 30 parts of magnesium carbonate.Mullite, alumina hollow ball are aggregate, and flyash, alumina powder, magnesium carbonate are Matrix.
Alumina hollow ball in the aggregate of above-mentioned thermal insulation fire-resistant pouring material has special surface texture and boring, Surface irregularity increases contact specific surface area so that aggregate is combined jail with alumina powder, magnesium carbonate, flyash in matrix Gu not only improving fire resistance, but also the intensity and heat insulation effect of material are increased, is decomposed under magnesium carbonate hot environment and generate two Carbonoxide, magnesia, carbon dioxide can increase the porosity of light thermal-shield refractory castable, and alumina powder, magnesia are high The thermal shock resistance that magnesium aluminate spinel ensures light thermal-shield refractory castable is generated under warm environment.

Claims (3)

1. a kind of light thermal-shield refractory castable, it is characterised in that:It is made of following raw material:Flyash, mullite, aluminium oxide are empty Bulbus cordis, alumina powder, magnesium carbonate;The parts by weight of above-mentioned raw materials are:10~20 parts of flyash, 20~30 parts of mullite, oxygen Change 10~20 parts of aluminium hollow ball, 30~40 parts of alumina powder, 20~30 parts of magnesium carbonate;Mullite, alumina hollow ball are bone Material, flyash, alumina powder, magnesium carbonate are matrix.
2. light thermal-shield refractory castable according to claim 1, it is characterised in that:The parts by weight of above-mentioned raw materials are: 10 parts of flyash, 30 parts of mullite, 10 parts of alumina hollow ball, 40 parts of alumina powder, 20 parts of magnesium carbonate.
3. light thermal-shield refractory castable according to claim 1, it is characterised in that:The parts by weight of above-mentioned raw materials are: 20 parts of flyash, 20 parts of mullite, 20 parts of alumina hollow ball, 30 parts of alumina powder, 30 parts of magnesium carbonate.
CN201810640009.7A 2018-06-21 2018-06-21 Light thermal-shield refractory castable Withdrawn CN108440005A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810640009.7A CN108440005A (en) 2018-06-21 2018-06-21 Light thermal-shield refractory castable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810640009.7A CN108440005A (en) 2018-06-21 2018-06-21 Light thermal-shield refractory castable

Publications (1)

Publication Number Publication Date
CN108440005A true CN108440005A (en) 2018-08-24

Family

ID=63206577

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810640009.7A Withdrawn CN108440005A (en) 2018-06-21 2018-06-21 Light thermal-shield refractory castable

Country Status (1)

Country Link
CN (1) CN108440005A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113213963A (en) * 2021-06-26 2021-08-06 江西陶瓷工艺美术职业技术学院 Light refractory material prepared from construction waste and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113213963A (en) * 2021-06-26 2021-08-06 江西陶瓷工艺美术职业技术学院 Light refractory material prepared from construction waste and preparation method thereof

Similar Documents

Publication Publication Date Title
CN102815951B (en) Flame-resistant corrosion-resistant coating
CN102795870B (en) Light-weight magnesia brick and preparation method thereof
CN101734937A (en) Lightweight spinel refractory bricks and preparation method thereof
CN102718514A (en) Micropore high-strength corundum-calcium hexaluminate composite refractory raw material and preparation method thereof
CN103408297A (en) Calcium hexaluminate-mullite composite material and preparation method thereof
CN105801133A (en) Light-weight and heat-insulation brick
CN101638315B (en) Ceramic plate composite and preparation method thereof
CN108558376A (en) A kind of low heat conduction high-strength fireproof pour material
CN105801064A (en) Production technology of light-weight and heat-insulation brick
CN105503216B (en) A kind of preparation method of high-strength light alumina hollow ball product
CN104860687A (en) Corundum slag-aluminum profile plant industrial sludge refractory castable
CN105481375A (en) Energy-saving and fire-resistant material
CN108440005A (en) Light thermal-shield refractory castable
CN106336227B (en) A kind of mineral products waste refractory material and its preparation process
CN104446524B (en) Heat barrier and heat radiation complex function based aluminum oxide pouring material for saving energy in high-temperature environment
CN103408312B (en) Aluminum-silicon-based lightweight castable and preparation method thereof
CN109809803A (en) A kind of fish torpedo ladle permanent layer coating
CN105418095B (en) A kind of lightweight refractory for glass smelting kiln of low heat conduction
CN105565828A (en) Lightweight high-strength thermal-insulation fireproof casting material
CN108002851A (en) Refractory brick containing mullite and preparation method thereof
CN102589292B (en) Magnesium-titanium three-layer composite brick and production method thereof
CN101838150A (en) Siliceous mullite brick
CN104291845B (en) Insulating refractory casting material containing magnesium carbonate
CN108395262A (en) A kind of olivine combination magnesium aluminate spinel hollow ball castable and preparation method
CN207197264U (en) A kind of electrical kiln refractory brick of light thermal-insulation

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20180824