CN108437587A - A kind of novel organic film material of heat-insulating sound-insulating - Google Patents

A kind of novel organic film material of heat-insulating sound-insulating Download PDF

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Publication number
CN108437587A
CN108437587A CN201810073676.1A CN201810073676A CN108437587A CN 108437587 A CN108437587 A CN 108437587A CN 201810073676 A CN201810073676 A CN 201810073676A CN 108437587 A CN108437587 A CN 108437587A
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China
Prior art keywords
film layer
butyl rubber
insulating
film
layer
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CN201810073676.1A
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Chinese (zh)
Inventor
马义才
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Fuhua Novel Material Co Ltd Of Section In Hefei
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Fuhua Novel Material Co Ltd Of Section In Hefei
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Priority to CN201810073676.1A priority Critical patent/CN108437587A/en
Publication of CN108437587A publication Critical patent/CN108437587A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/045—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/18—Layered products comprising a layer of natural or synthetic rubber comprising butyl or halobutyl rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066—Use of inorganic compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/20—Metallic material, boron or silicon on organic substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24—Vacuum evaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0207—Materials belonging to B32B25/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/10—Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08J2323/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08J2323/22—Copolymers of isobutene; butyl rubber

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of novel organic film materials of heat-insulating sound-insulating, are related to new material technology field.Including polyester film；Two surfaces of polyester film are coated with the first metallic diaphragm and the second metallic diaphragm respectively；One surface recombination of the first metallic diaphragm has one first polyimide film layer, a surface recombination of the second metallic diaphragm to have one second polyimide film layer；One surface recombination of the first polyimide film layer has one first butyl rubber film layer, a surface recombination of the second polyimide film layer to have one second butyl rubber film layer；Each film layer is by being compounded to form an overall structure.The novel organic film material of the heat-insulating sound-insulating of the present invention has superior sound-absorbing property, anti-flammability, heat-insulating properties and heat resistance；By the way that each film layer is combined into an overall structure so that organic film material of the invention has good structural.

Description

A kind of novel organic film material of heat-insulating sound-insulating
Technical field
The invention belongs to new material technology fields, more particularly to a kind of novel organic film material of heat-insulating sound-insulating.
Background technology
Noise, the unwanted side effect of industrial development cause more and more to damage.Therefore, there has been provided various sides Method prevents noise.As this mode for preventing noise, carried out in many ways for research and develop can postpone, absorb or every The research of new sound-absorbing acoustic material from sound.
It is required that the representative industrial department of sound-absorbing acoustic material includes electric appliance such as air-conditioning, refrigerator, washing machine, grass trimmer Deng, means of transport such as vehicle, ship, aircraft etc., construction material such as wall material, flooring material etc. is such.Other are a variety of Industrial circle also requires sound-absorbing acoustic material.In general, other than good sound-absorbing property, according to their application, Seeking the sound-absorbing acoustic material for industry has the weight mitigated, anti-flammability, heat-resisting and heat-insulating properties.Especially, for being used for The sound-absorbing acoustic material of 200 DEG C or the engine at higher temperature, exhaust system etc. is maintained, possible further requirement is fire-retardant Property and heat resistance.Currently, about the sound-absorbing acoustic material with excellent heat resistance, increasingly attract attention.
Invention content
The purpose of the present invention is to provide a kind of novel organic film materials of heat-insulating sound-insulating, have superior sound absorption properties Matter, anti-flammability, heat-insulating properties and heat resistance；By the way that each film layer is combined into an overall structure so that organic film of the invention Material has good structural.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions：
The present invention is a kind of novel organic film material of heat-insulating sound-insulating, including polyester film；The two of the polyester film Surface is coated with the first metallic diaphragm and the second metallic diaphragm respectively；
One surface recombination of first metallic diaphragm has one first polyimide film layer, second metallic diaphragm One surface recombination has one second polyimide film layer；
One surface recombination of first polyimide film layer has one first butyl rubber film layer, second polyamides sub- One surface recombination of amine film layer has one second butyl rubber film layer；
The polyester film, the first metallic diaphragm, the second metallic diaphragm, the first polyimide film layer, the second polyamides are sub- Amine film layer, the first butyl rubber film layer and the second butyl rubber film layer are by being compounded to form an overall structure.
Further, the thickness of the polyester film is 30-100um；The polyester film is by the poly- terephthaldehydes of 95-99% Sheet is made through melt blending, using extrusion molding in the fire-retardant particles of sour glycol ester and 1-5%, then through made of biaxial tension Polyester film.
Further, first metallic diaphragm is layer gold or silver layer, and thickness is 10-50um；
Wherein, first metallic diaphragm is by using polyester film as substrate, using gold or silver particles as thin-film material, making Technique includes：
S01 is first placed in by substrate and containing golden or silver particles evaporation source in vacuum tank, and is vacuumized；
After S02 is evacuated to vacuum, in vacuum tank, gold or silver particles are sent out by air source, gold or silver particles fly towards substrate It goes and is attached on a surface of substrate and form a metallic diaphragm.
Further, second metallic diaphragm and the first metallic diaphragm composition, structure and its preparation process all same.
Further, the thickness of first polyimide film layer and the second polyimide film layer is 20-80um.
Further, structure, composition and the preparation process of the first butyl rubber film layer and the second butyl rubber film layer All same；The thickness of the first butyl rubber film layer and the second butyl rubber film layer is 50-150um.
Further, the first butyl rubber film layer includes following component in parts by weight：
100 parts by weight of butyl rubber, plasticizer 3-5 parts by weight, vulcanizing agent 3-8 parts by weight, accelerating agent 2-5 parts by weight, reinforcement Agent 30-70 parts by weight, foaming agent 0.5-2 parts by weight, activating agent 5-10 parts by weight and fire-retardant particles 2-5 parts by weight；
Wherein, the preparation process of the first butyl rubber film layer comprises the following processes；
A, accurate to weigh the upper each raw material of formula；
B, the butyl rubber accurately weighed, plasticizer, reinforcing agent, foaming agent and activating agent are put into be kneaded in mixer and is heated up To 100-120 DEG C, pressure 0.45-0.50MPa；
C, input accurately weigh fire-retardant particles continue be kneaded be warming up to 160-170 DEG C, blanking slice obtains rubber compound glue Piece, pressure 0.25-0.30MPa；
D, rubber compound film is placed 8-12 hours cooling under conditions of environment temperature is 15-20 DEG C；
E, the mixed sheet cooled down is put into mixer and carries out initial refining, the blanking temperature of refining is 140-150 DEG C, pressure 0.45-0.50MPa；By slice after refining obtain refining film place environment temperature be 15-20 DEG C under conditions of it is cold But 8-12 hours；
F, the refining film cooled down, vulcanizing agent, accelerating agent are put into mixer and be kneaded together, blanking temperature is 100-110 DEG C, pressure 0.45-0.50MPa；Slice obtains butyl rubber film；
G, the butyl rubber film that thickness is 50-150um is made in butyl rubber film.
Further, the reinforcing agent selects black black wood charcoal or white carbon or black wood charcoal is black and white carbon.
Further, the slice thickness in the process C, process E and process F is 6-8mm.
Further, the first butyl rubber film layer further includes having blowing promotor, dispersant, anti-scorch in parts by weight It is one or more in agent, anti-aging agent, antiozonant, antistatic agent, ultraviolet screener and aromatic.
The invention has the advantages that：
The novel organic film material of the heat-insulating sound-insulating of the present invention has superior sound-absorbing property, anti-flammability, heat-insulating properties And heat resistance；By the way that each film layer is combined into an overall structure so that organic film material of the invention has good structure Property；The present invention is used as the outer layer of organic film by two butyl glue-lines, utilizes the characteristic of butyl rubber so that the present invention has good While the sound-insulating and heat-insulating effect got well, the service life of product of the present invention is improved.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, will be described below to embodiment required Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for ability For the those of ordinary skill of domain, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is organic film material structural schematic diagram of the present invention；
In attached drawing, parts list represented by the reference numerals are as follows：
1- polyester films, the first polyimide film layers of 2-, the second polyimide film layers of 3-, the first metal films of 101- Layer, the second metallic diaphragms of 102-, 201- the first butyl rubber film layers, 202- the second butyl rubber film layers.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained all other without creative efforts Embodiment shall fall within the protection scope of the present invention.
Embodiment one
Refering to Figure 1, it is a kind of novel organic film material of heat-insulating sound-insulating, including polyester that the present invention, which is the present invention, Two surfaces of film layer 1, polyester film 1 are coated with the first metallic diaphragm 101 and the second metallic diaphragm 102 respectively；
One surface recombination of the first metallic diaphragm 101 has one first polyimide film layer 2, the second metallic diaphragm 102 One surface recombination has one second polyimide film layer 3；
One surface recombination of the first polyimide film layer 2 has one first butyl rubber film layer 201, the second polyimides thin One surface recombination of film layer 3 has one second butyl rubber film layer 301；
Polyester film 1, the first metallic diaphragm 101, the second metallic diaphragm 102, the first polyimide film layer 2, second are poly- Imide membrane layer 3, the first butyl rubber film layer 201 and the second butyl rubber film layer 301 pass through the integral knot of complex Structure.
Preferably, the thickness of polyester film 1 is 50um；Polyester film 1 by 97.5% polyethylene terephthalate and Sheet is made through melt blending, using extrusion molding in 2.5% fire-retardant particles, then through polyester film made of biaxial tension.
Preferably, the first metallic diaphragm 101 is layer gold or silver layer, and thickness is 25um；
Wherein, the first metallic diaphragm 101 is by being substrate with polyester film 1, using gold or silver particles as thin-film material, makes Technique includes：S01 gold or the evaporation source of silver particles are placed in vacuum tank, and are vacuumized；After S02 is evacuated to vacuum, hold in vacuum In device, gold or silver particles are sent out by air source, gold or silver particles are flown towards substrate and are attached on a surface of substrate and form one Metallic diaphragm.
Preferably, the second metallic diaphragm 102 and the first metallic diaphragm 101 composition, structure and its preparation process all same.
Preferably, the thickness of the first polyimide film layer 2 and the second polyimide film layer 3 is 50um.
Preferably, structure, composition and the preparation process of the first butyl rubber film layer 201 and the second butyl rubber film layer 301 All same；The thickness of first butyl rubber film layer 201 and the second butyl rubber film layer 301 is 100um.
Preferably, the first butyl rubber film layer 201 includes following component in parts by weight：
100 parts by weight of butyl rubber, 4 parts by weight of plasticizer, 6 parts by weight of vulcanizing agent, 4 parts by weight of accelerating agent, 55 weight of reinforcing agent Measure part, 1 parts by weight of foaming agent, 4 parts by weight of 8 parts by weight of activating agent and fire-retardant particles；
Wherein, the preparation process of the first butyl rubber film layer 201 comprises the following processes；
A, accurate to weigh the upper each raw material of formula；
B, the butyl rubber accurately weighed, plasticizer, reinforcing agent, foaming agent and activating agent are put into be kneaded in mixer and is heated up To 100-120 DEG C, pressure 0.45-0.50MPa；
C, input accurately weigh fire-retardant particles continue be kneaded be warming up to 160-170 DEG C, blanking slice obtains rubber compound glue Piece, pressure 0.25-0.30MPa；
D, rubber compound film is placed 8 hours cooling under conditions of environment temperature is 15-20 DEG C；
E, the mixed sheet cooled down is put into mixer and carries out initial refining, the blanking temperature of refining is 140-150 DEG C, pressure 0.45-0.50MPa；By slice after refining obtain refining film place environment temperature be 15-20 DEG C under conditions of it is cold But 8 hours；
F, the refining film cooled down, vulcanizing agent, accelerating agent are put into mixer and be kneaded together, blanking temperature is 100-110 DEG C, pressure 0.45-0.50MPa；Slice obtains butyl rubber film；
G, the butyl rubber film that thickness is 100um is made in butyl rubber film.
Preferably, reinforcing agent selects that black wood charcoal is black or white carbon or black wood charcoal is black and white carbon.
Preferably, the slice thickness in process C, process E and process F is 6-8mm.
Preferably, the first butyl rubber film layer 201 further includes having blowing promotor, dispersant, antiscorching agent, preventing in parts by weight Old agent, antiozonant.
Embodiment two
Refering to Figure 1, it is a kind of novel organic film material of heat-insulating sound-insulating, including polyester that the present invention, which is the present invention, Two surfaces of film layer 1, polyester film 1 are coated with the first metallic diaphragm 101 and the second metallic diaphragm 102 respectively；
One surface recombination of the first metallic diaphragm 101 has one first polyimide film layer 2, the second metallic diaphragm 102 One surface recombination has one second polyimide film layer 3；
One surface recombination of the first polyimide film layer 2 has one first butyl rubber film layer 201, the second polyimides thin One surface recombination of film layer 3 has one second butyl rubber film layer 301；
Polyester film 1, the first metallic diaphragm 101, the second metallic diaphragm 102, the first polyimide film layer 2, second are poly- Imide membrane layer 3, the first butyl rubber film layer 201 and the second butyl rubber film layer 301 pass through the integral knot of complex Structure.
Preferably, the thickness of polyester film 1 is 90um；Polyester film 1 is by 99% polyethylene terephthalate and 1% Fire-retardant particles through melt blending, sheet is made using extrusion molding, then through polyester film made of biaxial tension.
Preferably, the first metallic diaphragm 101 is layer gold or silver layer, and thickness is 15um；
Wherein, the first metallic diaphragm 101 is by being substrate with polyester film 1, using gold or silver particles as thin-film material, makes Technique includes：S01 gold or the evaporation source of silver particles are placed in vacuum tank, and are vacuumized；After S02 is evacuated to vacuum, hold in vacuum In device, gold or silver particles are sent out by air source, gold or silver particles are flown towards substrate and are attached on a surface of substrate and form one Metallic diaphragm.
Preferably, the second metallic diaphragm 102 and the first metallic diaphragm 101 composition, structure and its preparation process all same.
Preferably, the thickness of the first polyimide film layer 2 and the second polyimide film layer 3 is 75um.
Preferably, structure, composition and the preparation process of the first butyl rubber film layer 201 and the second butyl rubber film layer 301 All same；The thickness of first butyl rubber film layer 201 and the second butyl rubber film layer 301 is 145um.
Preferably, the first butyl rubber film layer 201 includes following component in parts by weight：
100 parts by weight of butyl rubber, 5 parts by weight of plasticizer, 8 parts by weight of vulcanizing agent, 5 parts by weight of accelerating agent, 65 weight of reinforcing agent Measure part, 2 parts by weight of foaming agent, 5 parts by weight of 9 parts by weight of activating agent and fire-retardant particles；
Wherein, the preparation process of the first butyl rubber film layer 201 comprises the following processes；
A, accurate to weigh the upper each raw material of formula；
B, the butyl rubber accurately weighed, plasticizer, reinforcing agent, foaming agent and activating agent are put into be kneaded in mixer and is heated up To 100-120 DEG C, pressure 0.45-0.50MPa；
C, input accurately weigh fire-retardant particles continue be kneaded be warming up to 160-170 DEG C, blanking slice obtains rubber compound glue Piece, pressure 0.25-0.30MPa；
D, rubber compound film is placed 10 hours cooling under conditions of environment temperature is 15-20 DEG C；
E, the mixed sheet cooled down is put into mixer and carries out initial refining, the blanking temperature of refining is 140-150 DEG C, pressure 0.45-0.50MPa；By slice after refining obtain refining film place environment temperature be 15-20 DEG C under conditions of it is cold But 10 hours；
F, the refining film cooled down, vulcanizing agent, accelerating agent are put into mixer and be kneaded together, blanking temperature is 100-110 DEG C, pressure 0.45-0.50MPa；Slice obtains butyl rubber film；
G, the butyl rubber film that thickness is 150um is made in butyl rubber film.
Preferably, reinforcing agent selects that black wood charcoal is black or white carbon or black wood charcoal is black and white carbon.
Preferably, the slice thickness in process C, process E and process F is 6-8mm.
Preferably, the first butyl rubber film layer 201 further includes having dispersant, antiscorching agent, anti-aging agent, anti-quiet in parts by weight Electric agent, ultraviolet screener.
Embodiment three
Refering to Figure 1, it is a kind of novel organic film material of heat-insulating sound-insulating, including polyester that the present invention, which is the present invention, Two surfaces of film layer 1, polyester film 1 are coated with the first metallic diaphragm 101 and the second metallic diaphragm 102 respectively；
One surface recombination of the first metallic diaphragm 101 has one first polyimide film layer 2, the second metallic diaphragm 102 One surface recombination has one second polyimide film layer 3；
One surface recombination of the first polyimide film layer 2 has one first butyl rubber film layer 201, the second polyimides thin One surface recombination of film layer 3 has one second butyl rubber film layer 301；
Polyester film 1, the first metallic diaphragm 101, the second metallic diaphragm 102, the first polyimide film layer 2, second are poly- Imide membrane layer 3, the first butyl rubber film layer 201 and the second butyl rubber film layer 301 pass through the integral knot of complex Structure.
Preferably, the thickness of polyester film 1 is 30um；Polyester film 1 is by 95% polyethylene terephthalate and 5% Fire-retardant particles through melt blending, sheet is made using extrusion molding, then through polyester film made of biaxial tension.
Preferably, the first metallic diaphragm 101 is layer gold or silver layer, and thickness is 15um；
Wherein, the first metallic diaphragm 101 is by being substrate with polyester film 1, using gold or silver particles as thin-film material, makes Technique includes：S01 gold or the evaporation source of silver particles are placed in vacuum tank, and are vacuumized；After S02 is evacuated to vacuum, hold in vacuum In device, gold or silver particles are sent out by air source, gold or silver particles are flown towards substrate and are attached on a surface of substrate and form one Metallic diaphragm.
Preferably, the second metallic diaphragm 102 and the first metallic diaphragm 101 composition, structure and its preparation process all same.
Preferably, the thickness of the first polyimide film layer 2 and the second polyimide film layer 3 is 25um.
Preferably, structure, composition and the preparation process of the first butyl rubber film layer 201 and the second butyl rubber film layer 301 All same；The thickness of first butyl rubber film layer 201 and the second butyl rubber film layer 301 is 50um.
Preferably, the first butyl rubber film layer 201 includes following component in parts by weight：
100 parts by weight of butyl rubber, 3 parts by weight of plasticizer, 3 parts by weight of vulcanizing agent, 2 parts by weight of accelerating agent, 40 weight of reinforcing agent Measure part, 0.5 parts by weight of foaming agent, 2 parts by weight of 5 parts by weight of activating agent and fire-retardant particles；
Wherein, the preparation process of the first butyl rubber film layer 201 comprises the following processes；
A, accurate to weigh the upper each raw material of formula；
B, the butyl rubber accurately weighed, plasticizer, reinforcing agent, foaming agent and activating agent are put into be kneaded in mixer and is heated up To 100-120 DEG C, pressure 0.45-0.50MPa；
C, input accurately weigh fire-retardant particles continue be kneaded be warming up to 160-170 DEG C, blanking slice obtains rubber compound glue Piece, pressure 0.25-0.30MPa；
D, rubber compound film is placed 12 hours cooling under conditions of environment temperature is 15-20 DEG C；
E, the mixed sheet cooled down is put into mixer and carries out initial refining, the blanking temperature of refining is 140-150 DEG C, pressure 0.45-0.50MPa；By slice after refining obtain refining film place environment temperature be 15-20 DEG C under conditions of it is cold But 12 hours；
F, the refining film cooled down, vulcanizing agent, accelerating agent are put into mixer and be kneaded together, blanking temperature is 100-110 DEG C, pressure 0.45-0.50MPa；Slice obtains butyl rubber film；
G, the butyl rubber film that thickness is 50um is made in butyl rubber film.
Preferably, reinforcing agent selects that black wood charcoal is black or white carbon or black wood charcoal is black and white carbon.
Preferably, the slice thickness in process C, process E and process F is 6-8mm.
Preferably, the first butyl rubber film layer 201 further includes having anti-aging agent in parts by weight.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the present invention In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example. Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to preferably explain the present invention Principle and practical application, to enable skilled artisan to be best understood by and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (10)

1. a kind of novel organic film material of heat-insulating sound-insulating, including polyester film (1), it is characterised in that：The polyester film (1) two surfaces are coated with the first metallic diaphragm (101) and the second metallic diaphragm (102) respectively；
One surface recombination of first metallic diaphragm (101) has one first polyimide film layer (2), second metal film One surface recombination of layer (102) has one second polyimide film layer (3)；
One surface recombination of first polyimide film layer (2) has one first butyl rubber film layer (201), and described second is poly- One surface recombination of imide membrane layer (3) has one second butyl rubber film layer (301)；
The polyester film (1), the first metallic diaphragm (101), the second metallic diaphragm (102), the first polyimide film layer (2), the second polyimide film layer (3), the first butyl rubber film layer (201) and the second butyl rubber film layer (301) pass through It is compounded to form an overall structure.
2. a kind of novel organic film material of heat-insulating sound-insulating according to claim 1, which is characterized in that the polyester film The thickness of layer (1) is 30-100um；The polyester film (1) by 95-99% polyethylene terephthalates and 1-5% resistance Agent particle is fired through melt blending, sheet is made using extrusion molding, then through polyester film made of biaxial tension.
3. a kind of novel organic film material of heat-insulating sound-insulating according to claim 1, which is characterized in that first gold medal It is layer gold or silver layer to belong to film layer (101), and thickness is 10-50um；
Wherein, first metallic diaphragm (101) by with polyester film (1) be substrate, using gold or silver particles as thin-film material, Manufacture craft includes：
S01 is first placed in by substrate and containing golden or silver particles evaporation source in vacuum tank, and is vacuumized；
After S02 is evacuated to vacuum, in vacuum tank, gold or silver particles are sent out by air source, gold or silver particles are flown simultaneously towards substrate It is attached on a surface of substrate and forms a metallic diaphragm.
4. a kind of novel organic film material of heat-insulating sound-insulating according to claim 1, which is characterized in that second gold medal Belong to film layer (102) and the first metallic diaphragm (101) composition, structure and its preparation process all same.
5. a kind of novel organic film material of heat-insulating sound-insulating according to claim 1, which is characterized in that described first is poly- Imide membrane layer (2) and the thickness of the second polyimide film layer (3) are 20-80um.
6. a kind of novel organic film material of heat-insulating sound-insulating according to claim 1, which is characterized in that first fourth Structure, composition and the preparation process all same of base rubber film layer (201) and the second butyl rubber film layer (301)；First fourth The thickness of base rubber film layer (201) and the second butyl rubber film layer (301) is 50-150um.
7. a kind of novel organic film material of heat-insulating sound-insulating according to claim 1 or 6, which is characterized in that described Monobutyl glue film layer (201) includes following component in parts by weight：
100 parts by weight of butyl rubber, plasticizer 3-5 parts by weight, vulcanizing agent 3-8 parts by weight, accelerating agent 2-5 parts by weight, reinforcing agent 30- 70 parts by weight, foaming agent 0.5-2 parts by weight, activating agent 5-10 parts by weight and fire-retardant particles 2-5 parts by weight；
Wherein, the preparation process of the first butyl rubber film layer (201) comprises the following processes；
A, accurate to weigh the upper each raw material of formula；
B, the butyl rubber accurately weighed, plasticizer, reinforcing agent, foaming agent and activating agent are put into mixer to be kneaded and is warming up to 100-120 DEG C, pressure 0.45-0.50MPa；
C, input accurately weigh fire-retardant particles continue be kneaded be warming up to 160-170 DEG C, blanking slice obtains rubber compound film, pressure Power is 0.25-0.30MPa；
D, rubber compound film is placed 8-12 hours cooling under conditions of environment temperature is 15-20 DEG C；
E, the mixed sheet cooled down is put into mixer and carries out initial refining, the blanking temperature of refining is 140-150 DEG C, pressure Power is 0.45-0.50MPa；Slice after refining is obtained into refining film and places cooling 8- under conditions of environment temperature is 15-20 DEG C 12 hours；
F, the refining film cooled down, vulcanizing agent, accelerating agent are put into mixer and be kneaded together, blanking temperature 100- 110 DEG C, pressure 0.45-0.50MPa；Slice obtains butyl rubber film；
G, the butyl rubber film that thickness is 50-150um is made in butyl rubber film.
8. a kind of novel organic film material of heat-insulating sound-insulating according to claim 7, which is characterized in that the reinforcing agent Select that black wood charcoal is black or white carbon or black wood charcoal is black and white carbon.
9. a kind of novel organic film material of heat-insulating sound-insulating according to claim 7, which is characterized in that the process C, Slice thickness in process E and process F is 6-8mm.
10. a kind of novel organic film material of heat-insulating sound-insulating according to claim 7, which is characterized in that described first Butyl rubber film layer (201) further includes having blowing promotor, dispersant, antiscorching agent, anti-aging agent, antiozonant, preventing in parts by weight It is one or more in electrostatic agent, ultraviolet screener and aromatic.
CN201810073676.1A 2018-01-25 2018-01-25 A kind of novel organic film material of heat-insulating sound-insulating Pending CN108437587A (en)

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CN110562590A (en) * 2019-09-22 2019-12-13 浙江横浦科技有限公司 Novel active packaging material

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CN1586884A (en) * 2004-09-24 2005-03-02 东华大学 Heat insulation soft thin composite fabric, preparing method and its use
CN2847455Y (en) * 2005-12-20 2006-12-13 中国重型汽车集团有限公司 Composite acoustic material
CN201900756U (en) * 2010-11-19 2011-07-20 浙江吉利汽车研究院有限公司 Novel sound-insulation and heat-insulation pad for automobile engine cabin
CN203344406U (en) * 2013-05-21 2013-12-18 常州博光薄膜科技有限公司 Heat-insulating sticking film
CN103709537A (en) * 2013-12-13 2014-04-09 李巍巍 Composite foam sound insulation material and preparation method thereof
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CN85106548A (en) * 1985-08-22 1987-02-18 中国科学院上海硅酸盐研究所 Multilayer heat insulation
CN1586884A (en) * 2004-09-24 2005-03-02 东华大学 Heat insulation soft thin composite fabric, preparing method and its use
CN2847455Y (en) * 2005-12-20 2006-12-13 中国重型汽车集团有限公司 Composite acoustic material
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CN110562590B (en) * 2019-09-22 2021-06-04 扬州科信包装印刷有限公司 Novel active packaging material

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Application publication date: 20180824