CN108436037A - A method of inhibiting casting thermal fragmentation - Google Patents

A method of inhibiting casting thermal fragmentation Download PDF

Info

Publication number
CN108436037A
CN108436037A CN201810141851.6A CN201810141851A CN108436037A CN 108436037 A CN108436037 A CN 108436037A CN 201810141851 A CN201810141851 A CN 201810141851A CN 108436037 A CN108436037 A CN 108436037A
Authority
CN
China
Prior art keywords
shell
casting
thermal fragmentation
inhibiting
casting thermal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810141851.6A
Other languages
Chinese (zh)
Other versions
CN108436037B (en
Inventor
吕志刚
魏亚蒙
胡可辉
李欣怡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tsinghua University
Original Assignee
Tsinghua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tsinghua University filed Critical Tsinghua University
Priority to CN201810141851.6A priority Critical patent/CN108436037B/en
Publication of CN108436037A publication Critical patent/CN108436037A/en
Application granted granted Critical
Publication of CN108436037B publication Critical patent/CN108436037B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/12Treating moulds or cores, e.g. drying, hardening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns

Abstract

A method of inhibiting casting thermal fragmentation, the shell for casting is obtained using following steps:Prepare the aqueous solution containing alkaline hydrated oxide;Casting is susceptible to using the aqueous solution containing alkaline hydrated oxide at the corresponding shell in position of hot tearing and carries out local dipping;Shell is roasted, shell of the part containing basic anhydride is obtained.The present invention is easy to operate, flexible, highly reliable;By adjusting the solute component of maceration extract, concentration and dipping total amount, shell basic anhydride content is controlled, increases the generation of shell glass phase at high temperature, effectively improves the deformability of shell, it is suppressed that the generation of metal thermal fragmentation defect.

Description

A method of inhibiting casting thermal fragmentation
Technical field
The present invention relates to field of mechanical technique, and in particular to a method of inhibiting casting thermal fragmentation.
Background technology
Model casting be with it is waxed make the part cast wax-pattern, be then coated on wax-pattern mud formation mud mould, and Sprue gate is left when mud mould processed.After mud mould is dried, it is put into hot water and melts internal wax-pattern.The mud mould for having melted wax-pattern is taken out It is fired into Tao Mo again.Molten metal is poured into from sprue gate again to be cast.Casting thermal fragmentation is most common casting in model casting The titanium-aluminium alloy used in one of defect, especially aviation field, hot cracking tendency are fairly obvious.Hot tearing mainly by alloy property and Mold resisting stress causes, and is currently but these measures by improving casting structure, changing alloying component to inhibit the generation of hot tearing Limit the degree of freedom of casting structure design and composition design.And the structure and ingredient of some casting are stringent, such as part aviation Ti-Al alloy cast is very stringent to structural requirement and component requirements, cannot change easily.Therefore, thermal fragmentation defect is always to perplex The critical issue of practitioner.
Invention content
In order to solve above-mentioned technical problem, the purpose of the present invention is to provide a kind of sides inhibiting casting thermal fragmentation Method, to solve the problems, such as that model casting medium casting especially Ti-Al alloy cast is easy hot tearing, with operable simple, method Flexibly, the features such as reliability is high.
To reach the above technical purpose, the present invention adopts the following technical scheme that:
A method of inhibiting casting thermal fragmentation, the shell for casting is obtained using following steps:Preparation contains alkali The aqueous solution of property hydroxide;The position for being susceptible to hot tearing to casting using the aqueous solution containing alkaline hydrated oxide is corresponding Second shell position carries out local dipping;Roast shell so that contain basic anhydride in the second shell position.
Preferably, further comprising the steps of before preparing the aqueous solution containing alkaline hydrated oxide:Pore creating material is mixed into Sanding material;It is susceptible to the position corresponding first shell position of hot tearing in casting, uses the sanding material for being mixed with pore creating material Carry out stucco operation so that contain pore creating material in the first shell position;Roast shell so that the first shell position contains hole.
Preferably, the pore creating material includes starch or organic fiber, and additive amount is 0.01%-20% mass fractions.
Preferably, the alkaline hydrated oxide includes sodium hydroxide or potassium hydroxide, a concentration of 0.01%-20% mass point Number.
Preferably, the part dipping is brushed using syringe injection or hairbrush.
Preferably, in the dipping of part, the injection volume of syringe is that shell per cubic centimeter injects 0.01ml-1ml.
Preferably so that the calcination temperature for the shell that basic anhydride are contained at the second shell position is
120 DEG C -800 DEG C, roasting time is -24 hours 1 minute.
Preferably, it is susceptible to the backing layer at the corresponding shell in the first shell position of hot tearing in casting and carries out stucco behaviour Make.
Preferably, the first shell position and the second shell position are same area or different parts.
The present invention has the following advantages and the technique effect of high-lighting:
1) present invention adds pore creating material in sanding material, does not influence the stability of slurry, can arbitrarily be needed in shell Place uses;Shell microstructure is controlled by adjusting type, the quantity of pore creating material, avoids declining to a great extent for investment shell intensity; With the features such as easy to operate, method is flexible, and reliability is high;
2) by adjusting the type of basic anhydride solution, concentration, dip time controls containing for basic anhydride in shell Amount, to control the generation of shell glass phase, is precisely controlled shell softening temperature point and softening degree, to reach accurate Increase the purpose of shell deformability.
Description of the drawings
By the way that embodiment is described in conjunction with following accompanying drawings, features described above of the invention and technological merit will become More understands and be readily appreciated that.
Fig. 1 is the shell schematic diagram of the invention containing pore creating material;
Fig. 2 is the shell schematic diagram after present invention dipping hydroxide and low-temperature bake.
Wherein 1- sprue cups;2- shells;3- cavities;4- pore creating materials;5- basic anhydride;6- holes.
Specific implementation mode
Below with reference to the accompanying drawings come describe it is of the present invention inhibit casting thermal fragmentation method embodiment.This field it is general Logical technical staff will recognize, without departing from the spirit and scope of the present invention, can use a variety of different modes Or combinations thereof described embodiment is modified.Therefore, attached drawing and description are regarded as illustrative in nature, rather than are used for Limit scope of the claims.In addition, in the present specification, attached drawing is drawn not in scale, and identical reference numeral Indicate identical part.
A method of inhibiting casting thermal fragmentation, the shell for casting is obtained using following steps:
Prepare the aqueous solution containing alkaline hydrated oxide;
The position corresponding second shell portion of hot tearing is susceptible to casting using the aqueous solution containing alkaline hydrated oxide Position carries out local dipping;
Roast shell so that contain basic anhydride in the second shell position.
In one alternate embodiment, further comprising the steps of before preparing the aqueous solution containing alkaline hydrated oxide:
Pore creating material is mixed into sanding material;
The position corresponding first shell position of hot tearing is susceptible in casting, using be mixed with the sanding material of pore creating material into Row stucco operates so that contains pore creating material in the first shell position;
Roast shell so that the first shell position contains hole.
Wherein, the position containing hole and the position containing basic anhydride can be the different parts of shell.Namely It says, above-described first shell position and the second shell position can be the same area or different parts of shell.
In one alternate embodiment, the pore creating material includes starch or organic fiber, and additive amount is
0.01%-20% mass fractions.
In one alternate embodiment, the alkaline hydrated oxide includes sodium hydroxide or potassium hydroxide, a concentration of 0.01%-20% mass fractions.
In one alternate embodiment, part dipping is brushed using syringe injection or hairbrush.
In one alternate embodiment, in the dipping of part, the injection volume of syringe is injected for shell per cubic centimeter 0.01ml-1ml。
In one alternate embodiment, the calcination temperature of shell of the acquisition part containing basic anhydride is
120 DEG C -800 DEG C, roasting time is -24 hours 1 minute.
Fig. 1 is the shell schematic diagram of the invention containing pore creating material;Fig. 2 is after the present invention impregnates hydroxide and low-temperature bake Shell schematic diagram.Simultaneously using the method for pore creating material and infiltration alkaline hydrated oxide, and make the first shell position and second Shell position can obtain the better effect for preventing thermal fragmentation defect at the same position of shell, and below in conjunction with the accompanying drawings 1,2 Illustrate an example.
As shown in Figure 1, the shell 2 formed has the cavity 3 for being used to form casting, sprue cup 1 into cavity 3 for pouring Liquid metal.Specifically describe how to obtain this for selecting starch, alkaline hydrated oxide to select sodium hydroxide with pore creating material 4 below Shell 2.
1) it is mixed into the starch that mass fraction is 10% in sanding material, is uniformly mixed.
2) after the backing layer slashing operation of wax-pattern, the sanding material containing starch prepared is first easy cracking in casting The corresponding shell position in position carry out stucco operation, reuse not amyloid sanding material after the completion and carry out whole stucco Operation.Usually it is to carry out multiplicating starching, stucco on wax-pattern, to thicken shell.It obtains repeatedly as shown in Figure 1 Shell of the part containing pore creating material 4.Wherein, prepared by face layer carries out according to normal process, is generated to avoid to surface quality of continuous castings It influences.Wherein, face layer refers to that layer of wax-pattern close to model, and backing layer is wax-pattern close to that outmost layer of shell.
3) dewaxing baking operation is dried, obtains the shell that a large amount of holes are contained in part.
4) sodium hydrate aqueous solution containing 10% mass fraction is prepared.
5) syringe is used to inject the sodium hydrate aqueous solution configured in the shell position at corresponding casting position easy to crack, Injection volume is that shell per cubic centimeter injects 0.2 milliliter.
6) low-temperature bake is carried out to the shell for injecting sodium hydrate aqueous solution, calcination temperature is 500 DEG C, and roasting time is 6 hours, sodium hydroxide dehydration generated sodium oxide molybdena, i.e. basic anhydride 5, obtained part as shown in Figure 2 containing hole 6 and a large amount of The shell of basic anhydride 5.
Will be illustrated next the shell is how to avoid casting thermal fragmentation.By taking titanium-aluminium alloy pours as an example, in the shell The middle cast for carrying out titanium-aluminium alloy, the heating of casting process shell can be more than 1000 DEG C, be impregnated with the local shell life of sodium hydroxide At a large amount of glass phases.Glass when referring to mutually high temperature sintering each component and impurity generate shape after a series of physical, chemical reaction At a kind of amorphous substance.The intensity of glass phase is lower than crystalline phase, and a degree of softening can occur for shell in casting process, The part shell is porous structure simultaneously, is made a concession under the action of casting is shunk, avoids Ti-Al alloy cast and solidified Thermal fragmentation defect occurs in journey.
The present invention is easy to operate, flexible, highly reliable;It can be adjusted by adjusting the position of pore creating material, type and quantity Shell microstructure, so that shell adapts to the casting of a variety of materials and structure;By adjusting the solute component of maceration extract, concentration and Dip time controls shell basic anhydride content, increases the generation of shell glass phase at high temperature, effectively improves shell Deformability, it is suppressed that the generation of metal thermal fragmentation defect.
The foregoing is merely the preferred embodiment of the present invention, are not intended to restrict the invention, for those skilled in the art For member, the invention may be variously modified and varied.Any modification made by all within the spirits and principles of the present invention, Equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of method inhibiting casting thermal fragmentation, which is characterized in that obtain the shell for casting using following steps:
Prepare the aqueous solution containing alkaline hydrated oxide;
Casting is susceptible to using the aqueous solution containing alkaline hydrated oxide the position corresponding second shell position of hot tearing into Row part dipping;
Roast shell so that contain basic anhydride in the second shell position.
2. the method according to claim 1 for inhibiting casting thermal fragmentation, which is characterized in that contain alkaline hydrated oxide in preparation Aqueous solution before it is further comprising the steps of:
Pore creating material is mixed into sanding material;
It is susceptible to the position corresponding first shell position of hot tearing in casting, is spread using the sanding material for being mixed with pore creating material Sand operates so that contains pore creating material in the first shell position;
Roast shell so that the first shell position contains hole.
3. the method according to claim 2 for inhibiting casting thermal fragmentation, which is characterized in that the pore creating material includes starch or has Machine fiber, additive amount are 0.01%-20% mass fractions.
4. the method according to claim 1 for inhibiting casting thermal fragmentation, which is characterized in that the alkaline hydrated oxide includes hydrogen Sodium oxide molybdena or potassium hydroxide, a concentration of 0.01%-20% mass fractions.
5. the method according to claim 1 for inhibiting casting thermal fragmentation, which is characterized in that the part dipping uses syringe Injection or hairbrush are brushed.
6. the method according to claim 5 for inhibiting casting thermal fragmentation, which is characterized in that in the dipping of part, the note of syringe The amount of penetrating is that shell per cubic centimeter injects 0.01ml-1ml.
7. the method according to claim 1 for inhibiting casting thermal fragmentation, which is characterized in that so that alkali is contained at the second shell position Property oxide shell calcination temperature be 120 DEG C -800 DEG C, roasting time be -24 hours 1 minute.
8. the method according to claim 2 for inhibiting casting thermal fragmentation, which is characterized in that be susceptible to the of hot tearing in casting Backing layer at the corresponding shell in one shell position carries out stucco operation.
9. the method according to claim 2 for inhibiting casting thermal fragmentation, which is characterized in that the first shell position and the second shell Position is same area or different parts.
CN201810141851.6A 2018-02-11 2018-02-11 A method of inhibiting casting thermal fragmentation Active CN108436037B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810141851.6A CN108436037B (en) 2018-02-11 2018-02-11 A method of inhibiting casting thermal fragmentation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810141851.6A CN108436037B (en) 2018-02-11 2018-02-11 A method of inhibiting casting thermal fragmentation

Publications (2)

Publication Number Publication Date
CN108436037A true CN108436037A (en) 2018-08-24
CN108436037B CN108436037B (en) 2019-11-22

Family

ID=63192401

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810141851.6A Active CN108436037B (en) 2018-02-11 2018-02-11 A method of inhibiting casting thermal fragmentation

Country Status (1)

Country Link
CN (1) CN108436037B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4920025A (en) * 1972-06-15 1974-02-22
JPS5353519A (en) * 1976-10-26 1978-05-16 Honda Motor Co Ltd Method to manufacture casting mould
CN103231016A (en) * 2012-12-31 2013-08-07 湖北汽车工业学院 Casting method of magnesium alloy casting
CN104439081A (en) * 2014-11-25 2015-03-25 苏氏工业科学技术(北京)有限公司 Casting mold used in casting molding process of metal casting and casting
CN105198475A (en) * 2015-09-28 2015-12-30 西北工业大学 Method for producing complex-shaped porous silicon nitride ceramic product

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4920025A (en) * 1972-06-15 1974-02-22
JPS5353519A (en) * 1976-10-26 1978-05-16 Honda Motor Co Ltd Method to manufacture casting mould
CN103231016A (en) * 2012-12-31 2013-08-07 湖北汽车工业学院 Casting method of magnesium alloy casting
CN104439081A (en) * 2014-11-25 2015-03-25 苏氏工业科学技术(北京)有限公司 Casting mold used in casting molding process of metal casting and casting
CN105198475A (en) * 2015-09-28 2015-12-30 西北工业大学 Method for producing complex-shaped porous silicon nitride ceramic product

Also Published As

Publication number Publication date
CN108436037B (en) 2019-11-22

Similar Documents

Publication Publication Date Title
CN105458180B (en) A kind of shaping running channel and its preparation and method for blocking containing wax discharging port
CN104325081B (en) The preparation method of the combined type shell of insulation material is implanted in a kind of inside
CN101941053A (en) Preparation method of plate high-temperature alloy casting with high complexity
US9381565B2 (en) Monocrystalline casting mold
CN106734852A (en) A kind of anti-sticking tin liquid metal cools down the preparation method of directional solidification ceramic shell
AU2005240403A1 (en) Improvements in investment casting
CN108436037B (en) A method of inhibiting casting thermal fragmentation
CN109351951B (en) Process method for reducing loosening defect of single crystal blade platform
CN103894537A (en) Composite oxide shell for directional solidification technology as well as application thereof
CN109967714A (en) Composite centrifugal casting mold for annular titanium alloy part
CN109317613B (en) Shell preparation method for preventing bending deformation of directional test bar
CN107282857B (en) MgO-SrZrO3Composite shell, using and preparation method thereof
CN108246976B (en) Dewaxing method for ceramic shell
JP2022512205A (en) Improved casting slurry for shell mold manufacturing
CN205147225U (en) Accurate turbine wax matrix gate stick
CN109834249A (en) The construction method of filler material around a kind of middle water containing opening brick cup
CN110315033A (en) Ceramic shell mould and its manufacturing method for casting single crystal blade
CN103993188A (en) Method for reducing depth of nickel-based high-temperature alloy ingot shrinkage hole
TW453918B (en) A method of precise casting of shell
JP2013154352A (en) Filling pipe
EP2370376B1 (en) Method of impregnating crucibles and refractory articles
CN109475928B (en) Method for producing a shell mould
WO2016129006A1 (en) Process for the production of cores of silica for components of aeronautical and industrial turbines
SU657908A1 (en) Method of making casting moulds and cores
CN100522414C (en) Bronze ware thin wall hollow out long flow process casting technique

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant