CN108435172A - A kind of ultraviolet optical drive nano-composite catalyst - Google Patents
A kind of ultraviolet optical drive nano-composite catalyst Download PDFInfo
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- CN108435172A CN108435172A CN201810353716.8A CN201810353716A CN108435172A CN 108435172 A CN108435172 A CN 108435172A CN 201810353716 A CN201810353716 A CN 201810353716A CN 108435172 A CN108435172 A CN 108435172A
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- silver
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- wolframic acid
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- 239000003054 catalyst Substances 0.000 title claims abstract description 36
- 230000003287 optical effect Effects 0.000 title claims abstract description 10
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 61
- 239000002253 acid Substances 0.000 claims abstract description 39
- 229910052709 silver Inorganic materials 0.000 claims abstract description 35
- 239000004332 silver Substances 0.000 claims abstract description 35
- 239000002131 composite material Substances 0.000 claims abstract description 16
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims description 9
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- 239000011941 photocatalyst Substances 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 230000007613 environmental effect Effects 0.000 abstract description 8
- 230000003197 catalytic effect Effects 0.000 abstract description 7
- 230000015556 catabolic process Effects 0.000 abstract description 4
- 238000006731 degradation reaction Methods 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000005416 organic matter Substances 0.000 abstract 1
- 239000010865 sewage Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 20
- 238000000520 microinjection Methods 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 206010034960 Photophobia Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- PLKATZNSTYDYJW-UHFFFAOYSA-N azane silver Chemical compound N.[Ag] PLKATZNSTYDYJW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 208000013469 light sensitivity Diseases 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6527—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
- B01J37/343—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of ultrasonic wave energy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/804—UV light
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F2101/34—Organic compounds containing oxygen
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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Abstract
The invention belongs to Environmental Chemistry technical fields, and in particular to a kind of ultraviolet optical drive nano-composite catalyst, preparation method and its application in environmental area.By the present invention in that generating Nano silver grain in wolframic acid silver surface with the method for ultraviolet source irradiation, utilize the plasma resonance effect of metal Nano silver grain, nano silver/wolframic acid silver composite highly effective visible light catalyst has been prepared, can realize the fast degradation of organic matter in sewage system.Due to small-size effect and plasma resonance effect, not only so that the catalytic effect of the nano-photocatalyst is obviously improved, but also the usage amount of catalyst is substantially reduced, effectively saves use cost of the photochemical catalyst in field of environmental improvement.
Description
Technical field
The invention belongs to Environmental Chemistry technical fields, and in particular to a kind of ultraviolet optical drive nano silver/wolframic acid silver is compound is urged
Agent, preparation method and its application in environmental area.
Background technology
The moment such as water pollution, air pollution in life are all threatening people's health.How pollution, protection ring are reduced
Border becomes the problem of countries in the world are paid close attention to jointly.Therefore, how efficient process harmful organic substance becomes the heat that environmental area is studied
Point.At present most study, the use of most wide photochemical catalyst is anatase titanium dioxide nano-powder, it is cheap because its is safe and non-toxic
Price and photocatalysis performance outstanding and by numerous concerns.Anatase titanium dioxide is disadvantageous in that, energy gap
It is wider, the ultraviolet excitation (λ with specific wavelength is needed when in use<387nm), and the energy of ultraviolet region is less than too in sunlight
The 5% of sunlight gross energy, if using the direct catalytic degradation organic pollution of sunlight, the effect is unsatisfactory.In order to solve this
One problem, it is seen that photochemical catalyst becomes the hot spot of photocatalysis field research.Although wolframic acid silver photochemical catalyst is that one kind is had excellent performance
Visible light catalyst, but seldom about wolframic acid silver photochemical catalyst report at present, the catalytic effect of the Ag tungstate catalyst of acquisition
Need to further increase, hinder such material field of environmental improvement practical application process.
It is well known that the specific surface area for improving catalyst is the most common means for promoting catalyst effect, and this
Invention is directed to the existing dissatisfactory deficiency of Ag tungstate catalyst catalytic effect, creatively proposes a kind of nano silver/wolframic acid
The preparation method of silver-colored composite catalyst generates the side of nano silver and micro-injection reactant by using wolframic acid silver photodecomposition
Method has prepared nano silver/wolframic acid silver composite photo-catalyst.The ingenious plasma resonance that nano silver particles are utilized of this method
Effect significantly improves degradation efficiency of the wolframic acid silver photochemical catalyst to organic pollution.
Invention content
It is an object of the invention to propose a kind of preparation side of new ultra-violet optical drive nano silver/wolframic acid silver composite catalyst
Method, acquisition catalytic performance is superior, the novel nano photochemical catalyst of stable structure, solves existing pure titinium dioxide or load dioxy
The visible light utilization efficiency of Ag tungstate catalyst that the catalyst visible light catalytic effect of change titanium is undesirable and common is low, is catalyzed
The problems such as journey is slow, while the usage amount of wolframic acid silver when degradation unit volume is catalyzed object is effectively reduced, improve catalyst
Service efficiency reduces the use cost of catalyst, help to realize Ag tungstate catalyst field of environmental improvement quantum jump.
The present invention proposes a kind of preparation method of ultraviolet optical drive nano silver/wolframic acid silver composite catalyst, specific to prepare
Step is：1) silver nitrate solution and ammonium hydroxide is used to prepare silver ammino solution；2) prepared sodium tungstate solution is put into beaker, is added
Enter proper amount of surfactant；3) sodium tungstate solution is placed in ultrasonic disperser, is added silver ammino solution using micro syringe
Enter into sodium tungstate solution；4) precipitation of generation is centrifuged, it is dry after washing, then be placed under ultraviolet light and irradiate 1~3 point
Clock generates Nano silver grain in wolframic acid silver surface, collects product, obtain nano silver/wolframic acid silver composite catalyst.
The specific preparation condition of nano silver/wolframic acid silver composite catalyst is in the present invention：1) the addition matter of surfactant
Amount：The 0.5~10% of silver-colored source and sodium tungstate quality summation；2) template used in is polyethylene glycols or triton x-100
Or one kind of Tween 80 or Sodium Polyacrylate or neopelex.3) light source used in is ultraviolet light.
The invention has the advantages that：
1, it has been put forward for the first time a kind of method preparing nano silver/wolframic acid silver composite photo-catalyst using light sensitivity principles.
2. since the nano silver prepared by this method has plasma resonance effect, urging for wolframic acid silver can be obviously improved
Change activity.Compared with single wolframic acid silver photochemical catalyst, nano silver/wolframic acid silver composite photo-catalyst is in the same amount of Luo Dan that degrades
When bright B, catalytic efficiency is 10 times of existing Ag tungstate catalyst or more.
3. the present invention prepares nano silver/wolframic acid silver composite photocatalyst under the conditions of ultraviolet light by micro-injection for the first time
Agent, and new pattern can be generated by changing the type of surfactant, to realize for different-shape nano silver/wolframic acid
The compound controlledly synthesis of silver.It is compared compared with method, not only product catalyst performance is good, but also realizes that the artificial of morphology and size can
Control, meets different application demands.
Specific implementation mode
Below by specific embodiment, the present invention is further illustrated.
Embodiment 1：
It measures 10mL 0.5mol/L wolframic acid sodium water solutions to be placed in clean beaker, beaker is placed in ultrasonic dispersers, is added
1mL 0.14g/L polyglycol solutions, after surfactant is completely dissolved, by 10mL 1.0mol/L silver ammino solutions with micro
Injection is added in beaker, after complete reaction, is filtered, and spontaneously dries obtain wolframic acid aluminium powder at room temperature, then be in wavelength
It is irradiated 3 minutes under the ultraviolet lamp that 265nm power is 8 watts, obtains nano silver/wolframic acid silver composite photo-catalyst.
Embodiment 2
It measures 10mL 0.05mol/L wolframic acid sodium water solutions to be placed in clean beaker, beaker is placed in ultrasonic dispersers, is added
Enter 1mL 0.14g/L triton x-100 solution, after surfactant is completely dissolved, by 10mL 0.15mol/L silver ammino solutions
It is added in beaker with micro-injection agent, after complete reaction, is filtered, spontaneously dried obtain wolframic acid aluminium powder at room temperature, then
Wavelength is to be irradiated 2 minutes under the ultraviolet lamp that 265nm power is 10 watts, obtains nano silver/wolframic acid silver composite photo-catalyst.
Embodiment 3
It measures 10mL 0.05mol/L wolframic acid sodium water solutions to be placed in clean beaker, beaker is placed in ultrasonic dispersers, is added
Enter 1mL 0.14g/L polyacrylamide solutions, after surfactant is completely dissolved, 10mL 0.15mol/L silver ammino solutions are used
Micro-injection agent is added in beaker, after complete reaction, is filtered, and spontaneously dries obtain wolframic acid aluminium powder at room temperature, then in wave
It is irradiated 2 minutes under the ultraviolet lamp that a length of 265nm power is 15 watts, obtains nano silver/wolframic acid silver composite photo-catalyst.
Embodiment 4
It measures 10mL 0.05mol/L wolframic acid sodium water solutions to be placed in clean beaker, beaker is placed in ultrasonic dispersers, is added
Enter 1mL 2.8g/L Tween 80 solution, after surfactant is completely dissolved, by 10mL 0.15mol/L silver ammino solutions with micro
Injection is added in beaker, after complete reaction, is filtered, and spontaneously dries obtain wolframic acid aluminium powder at room temperature, then be in wavelength
It is irradiated 2 minutes under the ultraviolet lamp that 265nm power is 8 watts, obtains nano silver/wolframic acid silver composite photo-catalyst.
Embodiment 5
It measures 10mL 0.05mol/L wolframic acid sodium water solutions to be placed in clean beaker, beaker is placed in ultrasonic dispersers, is added
Enter 1mL 2.8g/L neopelex solution, after surfactant is completely dissolved, by 10mL 0.15mol/L silver ammonia
Solution is added to micro-injection agent in beaker, after complete reaction, is filtered, and spontaneously dries obtain wolframic acid aluminium powder at room temperature,
It is irradiated 1 minute in the case where wavelength is the ultraviolet lamp that 265nm power is 15 watts again, obtains nano silver/wolframic acid silver composite photo-catalyst.
Claims (4)
1. a kind of ultraviolet optical drive nano-composite catalyst, the nano-composite catalyst is by nano silver and wolframic acid money part group
At specific preparation process is：1) silver nitrate solution and ammonium hydroxide is used to prepare silver ammino solution；2) prepared sodium tungstate solution is put
Enter in beaker, proper amount of surfactant is added；3) sodium tungstate solution is placed in ultrasonic disperser, will using micro syringe
Silver ammino solution is added in sodium tungstate solution；4) precipitation of generation is centrifuged, it is dry after washing, then be placed under ultraviolet light
Irradiation 1~3 minute makes wolframic acid silver surface generate nano silver particles, collects product, obtains nano silver/wolframic acid silver composite catalyst.
2. a kind of ultraviolet optical drive nano-composite catalyst according to claim 1, it is characterised in that the surface of addition
Activating agent quality is the 0.5~10% of silver-colored source and sodium tungstate quality summation.
3. a kind of ultraviolet optical drive nano-composite catalyst according to claim 1, it is characterised in that live on the surface
Property agent be polyethylene glycols or triton x-100 or Tween 80 or Sodium Polyacrylate or neopelex one kind.
4. a kind of ultraviolet optical drive nano-composite catalyst according to claim 1, it is characterised in that used light source
For ultraviolet lamp, power is 8~15 watts.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111167451A (en) * | 2020-03-16 | 2020-05-19 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of silver tungstate microcrystal ball cluster photocatalyst, product and application thereof |
| CN113509903A (en) * | 2020-04-09 | 2021-10-19 | 石河子大学 | Photostimulation response type material and preparation method and application thereof |
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Patent Citations (1)
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|---|---|---|---|---|
| CN106268805A (en) * | 2016-08-17 | 2017-01-04 | 哈尔滨理工大学 | A kind of silver wolframic acid nano silver wire and preparation method thereof |
Non-Patent Citations (1)
| Title |
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Cited By (3)
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| CN111167451A (en) * | 2020-03-16 | 2020-05-19 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of silver tungstate microcrystal ball cluster photocatalyst, product and application thereof |
| CN113509903A (en) * | 2020-04-09 | 2021-10-19 | 石河子大学 | Photostimulation response type material and preparation method and application thereof |
| CN113509903B (en) * | 2020-04-09 | 2022-06-28 | 石河子大学 | Photostimulation response type material and preparation method and application thereof |
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