CN108428748A - Film photovoltaic device with air-purifying function - Google Patents

Film photovoltaic device with air-purifying function Download PDF

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Publication number
CN108428748A
CN108428748A CN201810469026.9A CN201810469026A CN108428748A CN 108428748 A CN108428748 A CN 108428748A CN 201810469026 A CN201810469026 A CN 201810469026A CN 108428748 A CN108428748 A CN 108428748A
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China
Prior art keywords
layer
air
photovoltaic
film
purifying function
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CN201810469026.9A
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Chinese (zh)
Inventor
朱丽
王勤文
陈萨如拉
孙勇
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Tianjin University
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Tianjin University
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Priority to CN201810469026.9A priority Critical patent/CN108428748A/en
Publication of CN108428748A publication Critical patent/CN108428748A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/18Radiation
    • A61L9/20Ultraviolet radiation
    • A61L9/205Ultraviolet radiation using a photocatalyst or photosensitiser
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/16Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by purification, e.g. by filtering; by sterilisation; by ozonisation
    • F24F3/167Clean rooms, i.e. enclosed spaces in which a uniform flow of filtered air is distributed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/10Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering
    • F24F8/108Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by separation, e.g. by filtering using dry filter elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/20Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
    • F24F8/22Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using UV light
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/20Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
    • F24F8/24Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using sterilising media
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/036Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
    • H01L31/0392Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Catalysts (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a kind of film photovoltaic devices with air-purifying function, it is desirable to provide one kind can realize the film photovoltaic device of photovoltaic generation and air-purifying function.Including substrate layer, photovoltaic film layer and basal layer, the lower surface of substrate layer has transparent photocatalyst layer, photovoltaic film layer to be set to the upper surface of basal layer, the air duct of a side opening or both-side opening is provided between photocatalyst layer and photovoltaic film layer.The present invention by increasing photocatalysis layer and air duct, while realizing photovoltaic effect and air purification dual function on the basis of the functional layer of traditional films photovoltaic.

Description

Film photovoltaic device with air-purifying function
Technical field
The present invention relates to photovoltaic technology field, and more specifically, it relates to a kind of thin with air-purifying function Film photovoltaic device.
Background technology
The existence of people be unable to do without air, and the quality of air quality directly affects the health and lives safety of the mankind.Now, Environmental degradation and pollution aggravate, and the quality of air is worse and worse.So-called room air pollution refers to caused due to various reasons Harmful substance is exceeded in room air, and then influences the indoor environmental pollution behavior of health.Nuisance include bacterial virus, Pellet, volatile organic contaminant (VOCs), such as formaldehyde, benzene, ammonia, radioactivity oxygen.With the environmental protection meaning of people Know and improve, gradually there is high request, various air purification processing equipments to come into being the air quality of living environment.
The purification techniques of room air mainly has absorption, filtering, electrostatic separation, anion separation, film point by its mechanism point From and photocatalytic oxidation degradation etc..Wherein photocatalysis degradation technique is a new technology of rising in recent years, is that the world is each The hot spot of state's research.Photochemical catalyst is by using obtainable ambient light such as solar radiation or room light and outdoor optical, in room Various VOCs are given into photodissociation under the conditions of temperature, and can by bacteria inactivation rate, can effectively reduce certainly air pollutants to human body Harm, and have many advantages, such as less energy consumption, easy to operate, non-secondary pollution.But at the air purification with photo-catalysis function It is single to manage apparatus function.
With the aggravation of energy shortage, photovoltaic device is gradually widely used.One thin-film photovoltaic device Usually by manufacturing multiple material layer depositions on one substrate.From the point of view of simplified function view, these material layers can be with It is expressed as a kind of possible photovoltaic absorption layer coated by a buffer layer, the combination is by clamping between at least two conductive layers. Existing thin-film photovoltaic device is only capable of realizing single photovoltaic effect function.
Invention content
In view of the technical drawbacks of the prior art, it is an object of the present invention to provide one kind can realizing that photovoltaic is sent out Electricity, and the film photovoltaic device with air-purifying function.
The technical solution adopted to achieve the purpose of the present invention is:
A kind of film photovoltaic device with air-purifying function, including substrate layer, photovoltaic film layer and basal layer, It is characterized in that, the lower surface of the substrate layer is provided with transparent photocatalyst layer, the photovoltaic film layer is set to described The upper surface of basal layer is provided with the sky of a side opening or both-side opening between the photocatalyst layer and the photovoltaic film layer Gas channel.
The material of the substrate layer is glass, and the material of the basal layer is glass or porous ceramics.
The material of the photocatalyst layer is the photochemical catalyst of Ti bases or W bases.
The photochemical catalyst be titanium dioxide admire, the titanium oxide that adulterates or compound titanium oxide.
The photochemical catalyst is tungsten oxide, the tungsten oxide of doping or tungsten oxide composite material.
Compared with prior art, the beneficial effects of the invention are as follows:
1, the present invention is on the basis of the functional layer of traditional films photovoltaic, by increasing photocatalysis layer and air duct, Realize photovoltaic effect and air purification dual function simultaneously.
2, photocatalysis layer of the invention improves light transmittance using transparent, low-refraction, antireflective catalysis material, To improve entire film photovoltaic device with respect to electricity conversion.
3, the present invention selects porous ceramics as base layer material, is realized to the interception of air pollutants using microcellular structure Pretreatment, improves the purification efficiency of entire device.
Description of the drawings
Fig. 1 show the structural schematic diagram that the present invention has the film photovoltaic device of air-purifying function.
Specific implementation mode
Below in conjunction with the drawings and specific embodiments, the present invention is described in detail.
The present invention has the structural schematic diagram of the film photovoltaic device of air-purifying function as shown in Figure 1, including base Plate layer 1, photovoltaic film layer 4 and basal layer 5, in order to realize that air-purifying function, the lower surface of the substrate layer 1 are provided with Transparent photocatalyst layer 2, the photovoltaic film layer 4 are set to the upper surface of the basal layer 5, the photocatalyst layer 2 with The air duct 3 of a side opening or both-side opening is provided between the photovoltaic film layer 4.
In the present embodiment, the material of the basal layer is glass or porous ceramics.The preferred porous ceramics of material of basal layer, The microcellular structure of porous ceramics has certain interception function to the pollutant in air.
The material of the photocatalyst layer is the photochemical catalyst of Ti bases or W bases.The material of the photocatalysis coating is transparent Low-refraction, antireflective photocatalysis coating, photocatalysis coating described in light-transmissive simultaneously exposes to the photovoltaic film Light absorbing layer is to realize photovoltaic effect.The photocatalysis coating, can be by indoor air pollutants in the case where light irradiates Volatile organic matter carries out photocatalytic degradation and by bacteria inactivation rate.The material of the photocatalyst layer is being capable of responding to visible light , in the present embodiment, the photochemical catalyst can be Ti bases, such as titanium oxide or the composite titanium oxidation that titanium dioxide admires, adulterates Object etc..Alternatively, the photochemical catalyst is the material of W bases, such as tungsten oxide, the tungsten oxide of doping or tungsten oxide composite material Deng.Alternatively, photochemical catalyst can be in tungsten oxide, the tungsten oxide powder of doping or tungsten oxide composite powder extremely A kind of few combination with titanium dioxide, the titanium oxide of doping or at least one of compound titanium oxide material powder.
When using porous ceramic film material as basal layer, the side opening or both-side opening of air duct 3.Indoor pollution Air enters the microcellular structure of the porous ceramics as basal layer 5 from lower part, microcellular structure in air particulate matter and volatilization Property organic pollution has interception function, is pre-processed to air.Realize pretreated air, by photovoltaic film layer 4 into Enter in air duct 3, light irradiates the air in air duct through substrate layer 1 and photocatalysis layer 2, and photocatalytic degradation has occurred The reaction of volatile organic contaminant, makes air be purified.Purified air leaves from a side opening or both-side opening.
When using glass as basal layer, the both-side opening of air duct 3.Indoor pollution air is from the side of air duct Into light irradiates the air in air duct through substrate layer 1 and photocatalysis layer 2, and photocatalytic degradation volatility, which has occurred, to be had The reaction of machine pollutant, makes air be purified.Gas after being fully cleaned up leaves from another side opening.
The present invention is on the basis of the functional layer of traditional films photovoltaic, by increasing photocatalysis coating and air duct, Realize photovoltaic effect and air purification dual function simultaneously.
The above is only a preferred embodiment of the present invention, it is noted that for the common skill of the art For art personnel, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (5)

1. a kind of film photovoltaic device with air-purifying function, including substrate layer, photovoltaic film layer and basal layer, It is characterized in that, the lower surface of the substrate layer is provided with transparent photocatalyst layer, and the photovoltaic film layer is set to the base The upper surface of bottom is provided with the air of a side opening or both-side opening between the photocatalyst layer and the photovoltaic film layer Channel.
2. the film photovoltaic device according to claim 1 with air-purifying function, which is characterized in that the base The material of plate layer is glass, and the material of the basal layer is glass or porous ceramics.
3. the film photovoltaic device according to claim 1 or 2 with air-purifying function, which is characterized in that institute The material for stating photocatalyst layer is the photochemical catalyst of Ti bases or W bases.
4. the film photovoltaic device according to claim 3 with air-purifying function, which is characterized in that the light Catalyst be titanium dioxide admire, the titanium oxide that adulterates or compound titanium oxide.
5. the film photovoltaic device according to claim 3 with air-purifying function, which is characterized in that the light Catalyst is tungsten oxide, the tungsten oxide of doping or tungsten oxide composite material.
CN201810469026.9A 2018-05-16 2018-05-16 Film photovoltaic device with air-purifying function Withdrawn CN108428748A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115046284A (en) * 2022-06-27 2022-09-13 常州大学 Air step purifies heat production power supply type photoelectricity window

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010130965A1 (en) * 2009-05-14 2010-11-18 Kerting Air purification device
CN208157420U (en) * 2018-05-16 2018-11-27 天津大学 Film photovoltaic device with air-purifying function

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010130965A1 (en) * 2009-05-14 2010-11-18 Kerting Air purification device
CN208157420U (en) * 2018-05-16 2018-11-27 天津大学 Film photovoltaic device with air-purifying function

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BENDONG YU, QINGYANG JIANG, WEI HE等: "Performance study on a novel hybrid solar gradient utilization system for combined photocatalytic oxidation technology and photovoltaic/thermal technology", APPLIED ENERGY, vol. 215, pages 1 - 18 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115046284A (en) * 2022-06-27 2022-09-13 常州大学 Air step purifies heat production power supply type photoelectricity window
CN115046284B (en) * 2022-06-27 2024-03-08 常州大学 Air step purifies heat production power supply formula photoelectricity window

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Application publication date: 20180821

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