CN108424805A - A kind of refuse reclamation type compound bio fuel and preparation method thereof - Google Patents

A kind of refuse reclamation type compound bio fuel and preparation method thereof Download PDF

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Publication number
CN108424805A
CN108424805A CN201810179850.0A CN201810179850A CN108424805A CN 108424805 A CN108424805 A CN 108424805A CN 201810179850 A CN201810179850 A CN 201810179850A CN 108424805 A CN108424805 A CN 108424805A
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fuel
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weight
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车春玲
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Jiangxi Taid New Energy Co Ltd
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Jiangxi Taid New Energy Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/46—Solid fuels essentially based on materials of non-mineral origin on sewage, house, or town refuse
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/10—Treating solid fuels to improve their combustion by using additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00—Production of fats or fatty oils from raw materials
    • C11B1/02—Pretreatment
    • C11B1/04—Pretreatment of vegetable raw material
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00—Production of fats or fatty oils from raw materials
    • C11B1/10—Production of fats or fatty oils from raw materials by extracting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08—Inhibitors
    • C10L2230/088—Inhibitors for inhibiting or avoiding odor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/26—Composting, fermenting or anaerobic digestion fuel components or materials from which fuels are prepared
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention belongs to bio-fuel technical fields, and in particular to a kind of refuse reclamation type compound bio fuel and preparation method thereof includes the component of following parts by weight：40 50 parts of seaweed bio oil, 40 50 parts of kitchen rubbish biological fuel, 25 30 parts of methanol, 10 15 parts of C9,10 15 parts of additive.Each component cooperates in refuse reclamation type oleyl alcohol compound bio fuel of the present invention, combustion heat value is up to 39000kJ/kg, with preferable corrosion resistance, and the exhaust gas generated is less, has larger development potentiality and important economic benefit, social value as efficient, environmentally friendly alternative fuel.

Description

A kind of refuse reclamation type compound bio fuel and preparation method thereof
Technical field
The invention belongs to bio-fuel technical fields, and in particular to a kind of refuse reclamation type compound bio fuel and its system Preparation Method.
Background technology
Alcohol-based fuel is cheap, the environmentally friendly clean type fuel based on alcohols, mainly with liquid or solid form In the presence of, since alcohol radical itself is oxygen-containing, oxygen demand is few when burning, and can fully burn, have sanitation and hygiene, safety and environmental protection, The advantages that easy to use, cheap.Algae is with widely distributed, fat content is high, strong environmental adaptability, growth cycle is short, gives birth to Advantages, the algae such as production advantage of lower cost have attracted more and more concerns in biomass fuel development process.Kitchen garbage It is the sanitary waste that resident is formed during personal consumption, derives from a wealth of sources, is cheap, kitchen garbage main component includes There are starch, cellulose, protein, lipid and inorganic salts, content of organics abundant.It is converted into bio-fuel using kitchen garbage, The situation of energy shortage can either be alleviated, and the cost of biomass fuel can be substantially reduced.
Therefore, it studies a kind of by alcohol-based fuel, seaweed bio fuel and the compound new bio of kitchen garbage bio-fuel Fuel can not only solve the problem of environmental pollution that kitchen garbage is brought, but also can substantially reduce the cost of biomass fuel, alleviate The situation of energy shortage.
Technical solution
To solve the above-mentioned problems of the prior art, the present invention provides a kind of refuse reclamation type compound bio fuel, tools Body technique scheme is as follows：
A kind of refuse reclamation type compound bio fuel, includes the component of following parts by weight：40-50 parts of seaweed bio oil, kitchen rubbish 40-50 parts of rubbish bio-fuel, 25-30 parts of methanol, 10-15 parts of C9,10-15 parts of additive.
Preferably, the additive includes the raw material of following parts by weight：5-10 parts of ethyl alcohol, 3-5 parts of glyceryl triacetate, 5-10 parts of octanol, 10-15 parts of dimethoxym ethane, 4-7 parts of cation fluorine carbon surface active agent, 3-5 parts of diamyl iron, hydrocarbon compound 10- 15 parts, 10-15 parts of combustion adjuvant, 3-5 parts of stabilizer, 3-5 parts of anti-knock agent, 1-4 parts of deodorant, 1-5 parts of dispersant.
Preferably, the seaweed bio oil is prepared by following methods：
（1）Broken wall crushes：Cleaning removes the impurity such as silt for adulterating and the sea salt on surface in seaweed, be then added in seaweed with The distilled water of its equal weight, slurries are ground into wall-broken grinder, spare；
（2）Fermentation：Slurries are added in fermentation tank, the composite bacteria agent of slurry weight score 0.008-0.01% is added, mixing is equal It is even, it ferments 6-8 days under the conditions of 30-35 DEG C, obtains zymotic fluid, it is spare；
（3）Hydrothermal liquefaction：Zymotic fluid is added in autoclave, the distilled water of 3 times of weight of zymotic fluid, N is added2It is forced into 1.5 MPa are heated to 300 DEG C, are stirred reaction 1h with 150r/min, after being cooled to room temperature, release gas, it is mixed to pour out reaction Object is closed, it is spare；
（4）Extraction：Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get oily to the seaweed bio.
Preferably, the composite bacteria agent is by 3~5 parts of bacillus pumilus, 6~10 parts of saccharomyces cerevisiaes, 3~5 parts of lactic acid Enterococcus mixes.
Preferably, the kitchen garbage bio-fuel is prepared by following methods：
（1）Sterilization proposes oil processing：Will collect come kitchen garbage by sorting unit remove bulk materials after, into sterilizing chamber into Row sterilization, then after carrying oil and recycling grease therein to obtain oil removing solid refuse spare；
（2）Broken wall treatment：By oil removing solid refuse dry to water content be 20%-30%, be crushed to 100-200 mesh, then again into Row broken wall pulverization process；
（3）Fermentation process：The water of garbage weight score 40-50% is added in spray in rubbish after being pulverized, and garbage weight point is added The composite bacteria agent of number 0.009-0.013%, ferments 5-7 days under conditions of 35-40 DEG C；
（4）Hydrothermal liquefaction processing：Fermentate is added in autoclave, the distilled water of 3 times of weight of fermentate, N is added2Pressurization To 2.0 MPa, 300 DEG C are heated to, reaction 1h is stirred with 180r/min, after being cooled to room temperature, gas is released, pours out reaction Mixture, it is spare；Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get to oil removing solid refuse bio-fuel.
Preferably, it is 5~8 parts of bacillus pumilus, 5~10 parts of saccharomyces cerevisiaes that composite bacteria agent used, which is parts by weight, Bacterium, 2~4 parts of lactoenterococcus.
Preferably, it is 1 that the hydrocarbon compound, which includes weight ratio,:1.5 heptane and isooctane；The combustion adjuvant includes Weight ratio is 2:3:5 hexyl ether, methyl tertiary butyl ether(MTBE) and ethyl tert-butyl ether (ETBE).
Preferably, it is 3 that the stabilizer, which is weight ratio,:5 di-tert-butyl p-cresol and isobutyl amine；The anti-knock agent is Methyl cyclic diolefine manganese tricarbonyl；The deodorant is essence；The dispersant is polymethacrylates.
The invention also discloses the preparation methods of above-mentioned refuse reclamation type oleyl alcohol compound bio fuel, and concrete scheme is such as Under.
The preparation method of refuse reclamation type oleyl alcohol compound bio fuel, includes the following steps：
（1）Prepare additive：Under normal temperature and pressure conditions, ethyl alcohol, hydrocarbon compound, octanol, dimethoxym ethane are added in configurator It is uniformly mixed, glyceryl triacetate, cation fluorine carbon surface active agent, diamyl iron, combustion adjuvant, stabilizer, antiknock is then added Agent, deodorant, dispersant are uniform, and above-mentioned mixed raw material is then mixed 1h by explosion-proof centrifugal pump circulation, then quiet 2h is set to get to additive, it is spare；
（2）Under normal temperature and pressure conditions, kitchen garbage bio-fuel, seaweed bio oil, C9 are added in configurator and are uniformly mixed, Then additive is added to be uniformly mixed, adds methanol and is uniformly mixed, then pump above-mentioned mixed raw material by explosion-proof centrifugal Cycle mixing 1h, is then allowed to stand 2h to get to the refuse reclamation type oleyl alcohol compound bio fuel.
Advantageous effect
（1）Each component cooperates in refuse reclamation type oleyl alcohol compound bio fuel of the present invention, and combustion heat value is up to 39000kJ/kg has preferable corrosion resistance, and the exhaust gas generated is less, has as efficient, environmentally friendly alternative fuel Larger development potentiality and important economic benefit, social value.Seaweed bio oil, kitchen rubbish biological fuel and methanol is selected to make Based on fire ingredient, methanol can improve the oxygen content of fuel, fuel energy is made fully to burn, and kitchen rubbish biological fuel belongs to waste again Using type fuel, can not only solve the problem of environmental pollution that kitchen garbage is brought, but can substantially reduce biomass fuel at This, seaweed bio oil belongs to inexpensive recyclable organism oil, has higher combustion heat value；C9, can be with as calorific value enhancer Significantly improve the combustion heat value of fuel.
（2）It is added to efficient additive in refuse reclamation type oleyl alcohol compound bio fuel of the present invention, is added Ethyl alcohol can promote to burn in agent；Octanol, dimethoxym ethane are added as cosolvent, each component can be made to dissolve each other；Ferrocene is for energy saving Antismoke agent and cation fluorine carbon surface active agent are made into calorific value enhancer；Glyceryl triacetate in addition to can with other material combinations, Outside the flash-point for improving fuel, additionally it is possible to protective film is formed in metallic surface, contact of the corrosive deposit with metal surface has been isolated, It prevents burning to corrosion of metal so as to play, enhances the corrosion resistance of fuel；Hydrocarbon compound can carry significantly The calorific value of high fuel；The addition of combustion adjuvant can greatly improve the calorific value of fuel；Stabilizer can guarantee fuel in use Stable quality, anti-knock agent can greatly improve the safety of fuel, and dispersant makes insoluble substance keep dispersion outstanding in fuel Floating state, so as not to engine key position row at lacquer deposit, while also can guarantee that combustibility is good, reduce exhaust Amount reduces pollution.
（3）In the preparation method of seaweed bio oil of the present invention, seaweed is subjected to broken wall treatment, seaweed can be crushed Cell wall, so that the active principle in seaweed is released, can effective component extracting to greatest extent, improve the exploitation value of seaweed Value, but also fermentation time can be shortened；Slurries after broken wall treatment are subjected to fermentation process, can make slurry reaction generation can The fuel of burning, is greatly improved yield；Zymotic fluid is subjected to hydrothermal liquefaction, zymotic fluid can be made further to react, be converted to Fuel oil.By the above method, the yield of gained seaweed bio oil may be up to 32.3%.
（4）In the preparation method of kitchen garbage bio-fuel of the present invention, raw material is carried out putting forward oil processing step Sterilization processing can prevent harmful bacteria from growing, and prevent from adversely affecting subsequent reactions, can also make raw material convenient for protecting It deposits；Raw material after crushing is subjected to broken wall treatment, the cell wall of raw material can be crushed, the active principle in raw material is made to be released Put, can effective component extracting to greatest extent, improve utility value, but also fermentation time can be shortened；Fermentation process is carried out, Raw material reaction can be made to generate to combustible fuel, be greatly improved yield；Tunning is subjected to hydrothermal liquefaction, hair can be made Ferment product further reacts, and is converted to fuel.By the above method, the yield of gained fuel may be up to 57.3%.
Specific implementation mode
Embodiment 1
A kind of refuse reclamation type oleyl alcohol compound bio fuel, includes the component of following parts by weight：Seaweed bio oil 40 parts, kitchen rubbish 50 parts of rubbish bio-fuel, 25 parts of methanol, 10 parts of C9,10 parts of additive.
The additive includes the raw material of following parts by weight：5 parts of ethyl alcohol, 5 parts of glyceryl triacetate, 5 parts of octanol, dimethoxym ethane 10 parts, it is 4 parts of cation fluorine carbon surface active agent, 3 parts of diamyl iron, 10 parts of hydrocarbon compound, 15 parts of combustion adjuvant, 3 parts of stabilizer, anti- 3 parts of detonator, 1 part of deodorant, 5 parts of dispersant.
The seaweed bio oil is prepared by following methods：
（1）Broken wall crushes：Cleaning removes the impurity such as silt for adulterating and the sea salt on surface in seaweed, be then added in seaweed with The distilled water of its equal weight, slurries are ground into wall-broken grinder, spare；
（2）Fermentation：Slurries are added in fermentation tank, the composite bacteria agent of slurry weight score 0.008% is added, are uniformly mixed, It ferments 8 days under the conditions of 30 DEG C, obtains zymotic fluid, it is spare；
（3）Hydrothermal liquefaction：Zymotic fluid is added in autoclave, the distilled water of 3 times of weight of zymotic fluid, N is added2It is forced into 1.5 MPa are heated to 300 DEG C, are stirred reaction 1h with 150r/min, after being cooled to room temperature, release gas, it is mixed to pour out reaction Object is closed, it is spare；
（4）Extraction：Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get oily to the seaweed bio.
The composite bacteria agent is mixed by 3 parts of bacillus pumilus, 6 parts of saccharomyces cerevisiaes, 3 parts of lactoenterococcus.
The kitchen garbage bio-fuel is prepared by following methods：
（1）Sterilization proposes oil processing：Will collect come kitchen garbage by sorting unit remove bulk materials after, into sterilizing chamber into Row sterilization, then after carrying oil and recycling grease therein to obtain oil removing solid refuse spare；
（2）Broken wall treatment：It is 20% that oil removing solid refuse, which is dried to water content, is crushed to 100 mesh, then carries out wall cell disruption powder again Broken processing；
（3）Fermentation process：The water of garbage weight score 40% is added in spray in rubbish after being pulverized, and garbage weight score is added 0.013% composite bacteria agent ferments 5 days under conditions of 40 DEG C, and composite bacteria agent used is that parts by weight are 5 parts short and small gemma bar Bacterium, 10 parts of S. cervisiaes, 2 parts of lactoenterococcus；
（4）Hydrothermal liquefaction processing：Fermentate is added in autoclave, the distilled water of 3 times of weight of fermentate, N is added2Pressurization To 2.0 MPa, 300 DEG C are heated to, reaction 1h is stirred with 180r/min, after being cooled to room temperature, gas is released, pours out reaction Mixture, it is spare；Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get to oil removing solid refuse bio-fuel.
The hydrocarbon compound includes that weight ratio is 1:1.5 heptane and isooctane；The combustion adjuvant includes that weight ratio is 2:3:5 hexyl ether, methyl tertiary butyl ether(MTBE) and ethyl tert-butyl ether (ETBE).
The stabilizer is that weight ratio is 3:5 di-tert-butyl p-cresol and isobutyl amine；The anti-knock agent is methyl ring two Alkene manganese tricarbonyl；The deodorant is essence；The dispersant is polymethacrylates.
The preparation method of above-mentioned refuse reclamation type oleyl alcohol compound bio fuel, includes the following steps：
（1）Prepare additive：Under normal temperature and pressure conditions, ethyl alcohol, hydrocarbon compound, octanol, dimethoxym ethane are added in configurator It is uniformly mixed, glyceryl triacetate, cation fluorine carbon surface active agent, diamyl iron, combustion adjuvant, stabilizer, antiknock is then added Agent, deodorant, dispersant are uniform, and above-mentioned mixed raw material is then mixed 1h by explosion-proof centrifugal pump circulation, then quiet 2h is set to get to additive, it is spare；
（2）Under normal temperature and pressure conditions, kitchen garbage bio-fuel, seaweed bio oil, C9 are added in configurator and are uniformly mixed, Then additive is added to be uniformly mixed, adds methanol and is uniformly mixed, then pump above-mentioned mixed raw material by explosion-proof centrifugal Cycle mixing 1h, is then allowed to stand 2h to get to the refuse reclamation type oleyl alcohol compound bio fuel.
Embodiment 2
A kind of refuse reclamation type oleyl alcohol compound bio fuel, includes the component of following parts by weight：Seaweed bio oil 50 parts, kitchen rubbish 40 parts of rubbish bio-fuel, 30 parts of methanol, 15 parts of C9,10 parts of additive.
Preferably, the additive includes the raw material of following parts by weight：10 parts of ethyl alcohol, 5 parts of glyceryl triacetate, octanol 10 parts, 15 parts of dimethoxym ethane, 7 parts of cation fluorine carbon surface active agent, 5 parts of diamyl iron, 15 parts of hydrocarbon compound, 10 parts of combustion adjuvant, 5 parts of stabilizer, 5 parts of anti-knock agent, 4 parts of deodorant, 5 parts of dispersant.
Preferably, the seaweed bio oil is prepared by following methods：
（1）Broken wall crushes：Cleaning removes the impurity such as silt for adulterating and the sea salt on surface in seaweed, be then added in seaweed with The distilled water of its equal weight, slurries are ground into wall-broken grinder, spare；
（2）Fermentation：Slurries are added in fermentation tank, the composite bacteria agent of slurry weight score 0.01% is added, are uniformly mixed, It ferments 6 days under the conditions of 35 DEG C, obtains zymotic fluid, it is spare；
（3）Hydrothermal liquefaction：Zymotic fluid is added in autoclave, the distilled water of 3 times of weight of zymotic fluid, N is added2It is forced into 1.5 MPa are heated to 300 DEG C, are stirred reaction 1h with 150r/min, after being cooled to room temperature, release gas, it is mixed to pour out reaction Object is closed, it is spare；
（4）Extraction：Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get oily to the seaweed bio.
Preferably, the composite bacteria agent is mixed by 5 parts of bacillus pumilus, 6 parts of saccharomyces cerevisiaes, 5 parts of lactoenterococcus It forms.
Preferably, the kitchen garbage bio-fuel is prepared by following methods：
（1）Sterilization proposes oil processing：Will collect come kitchen garbage by sorting unit remove bulk materials after, into sterilizing chamber into Row sterilization, then after carrying oil and recycling grease therein to obtain oil removing solid refuse spare；
（2）Broken wall treatment：It is 30% that oil removing solid refuse, which is dried to water content, is crushed to 200 mesh, then carries out wall cell disruption powder again Broken processing；
（3）Fermentation process：The water of garbage weight score 50% is added in spray in rubbish after being pulverized, and garbage weight score is added 0.013% composite bacteria agent ferments 5 days under conditions of 35 DEG C；
（4）Hydrothermal liquefaction processing：Fermentate is added in autoclave, the distilled water of 3 times of weight of fermentate, N is added2Pressurization To 2.0 MPa, 300 DEG C are heated to, reaction 1h is stirred with 180r/min, after being cooled to room temperature, gas is released, pours out reaction Mixture, it is spare；Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get to oil removing solid refuse bio-fuel.
Preferably, it is 8 parts of bacillus pumilus, 5 parts of S. cervisiaes, 2 parts of breasts that composite bacteria agent used, which is parts by weight, Sour enterococcus.
Preferably, it is 1 that the hydrocarbon compound, which includes weight ratio,:1.5 heptane and isooctane；The combustion adjuvant includes Weight ratio is 2:3:5 hexyl ether, methyl tertiary butyl ether(MTBE) and ethyl tert-butyl ether (ETBE).
Preferably, it is 3 that the stabilizer, which is weight ratio,:5 di-tert-butyl p-cresol and isobutyl amine；The anti-knock agent is Methyl cyclic diolefine manganese tricarbonyl；The deodorant is essence；The dispersant is polymethacrylates.
The preparation method of above-mentioned refuse reclamation type oleyl alcohol compound bio fuel, includes the following steps：
（1）Prepare additive：Under normal temperature and pressure conditions, ethyl alcohol, hydrocarbon compound, octanol, dimethoxym ethane are added in configurator It is uniformly mixed, glyceryl triacetate, cation fluorine carbon surface active agent, diamyl iron, combustion adjuvant, stabilizer, antiknock is then added Agent, deodorant, dispersant are uniform, and above-mentioned mixed raw material is then mixed 1h by explosion-proof centrifugal pump circulation, then quiet 2h is set to get to additive, it is spare；
（2）Under normal temperature and pressure conditions, kitchen garbage bio-fuel, seaweed bio oil, C9 are added in configurator and are uniformly mixed, Then additive is added to be uniformly mixed, adds methanol and is uniformly mixed, then pump above-mentioned mixed raw material by explosion-proof centrifugal Cycle mixing 1h, is then allowed to stand 2h to get to the refuse reclamation type oleyl alcohol compound bio fuel.
Embodiment 3
A kind of refuse reclamation type oleyl alcohol compound bio fuel, includes the component of following parts by weight：Seaweed bio oil 45 parts, kitchen rubbish 45 parts of rubbish bio-fuel, 28 parts of methanol, 11 parts of C9,13 parts of additive.
The additive includes the raw material of following parts by weight：8 parts of ethyl alcohol, 4 parts of glyceryl triacetate, 8 parts of octanol, dimethoxym ethane 12 parts, it is 5 parts of cation fluorine carbon surface active agent, 4 parts of diamyl iron, 13 parts of hydrocarbon compound, 11 parts of combustion adjuvant, 4 parts of stabilizer, anti- 4 parts of detonator, 2 parts of deodorant, 2 parts of dispersant.
The seaweed bio oil is prepared by following methods：
（1）Broken wall crushes：Cleaning removes the impurity such as silt for adulterating and the sea salt on surface in seaweed, be then added in seaweed with The distilled water of its equal weight, slurries are ground into wall-broken grinder, spare；
（2）Fermentation：Slurries are added in fermentation tank, the composite bacteria agent of slurry weight score 0.009% is added, are uniformly mixed, It ferments 8 days under the conditions of 35 DEG C, obtains zymotic fluid, it is spare；
（3）Hydrothermal liquefaction：Zymotic fluid is added in autoclave, the distilled water of 3 times of weight of zymotic fluid, N is added2It is forced into 1.5 MPa are heated to 300 DEG C, are stirred reaction 1h with 150r/min, after being cooled to room temperature, release gas, it is mixed to pour out reaction Object is closed, it is spare；
（4）Extraction：Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get oily to the seaweed bio.
Preferably, the composite bacteria agent is mixed by 4 parts of bacillus pumilus, 8 parts of saccharomyces cerevisiaes, 4 parts of lactoenterococcus It forms.
Preferably, the kitchen garbage bio-fuel is prepared by following methods：
（1）Sterilization proposes oil processing：Will collect come kitchen garbage by sorting unit remove bulk materials after, into sterilizing chamber into Row sterilization, then after carrying oil and recycling grease therein to obtain oil removing solid refuse spare；
（2）Broken wall treatment：It is 24% that oil removing solid refuse, which is dried to water content, is crushed to 100 mesh, then carries out wall cell disruption powder again Broken processing；
（3）Fermentation process：The water of garbage weight score 45% is added in spray in rubbish after being pulverized, and garbage weight score is added 0.012% composite bacteria agent ferments 7 days under conditions of 35 DEG C；
（4）Hydrothermal liquefaction processing：Fermentate is added in autoclave, the distilled water of 3 times of weight of fermentate, N is added2Pressurization To 2.0 MPa, 300 DEG C are heated to, reaction 1h is stirred with 180r/min, after being cooled to room temperature, gas is released, pours out reaction Mixture, it is spare；Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get to oil removing solid refuse bio-fuel.
Composite bacteria agent used is that parts by weight are 6 parts of bacillus pumilus, 6 parts of S. cervisiaes, 3 parts of lactoenterococcus.
The hydrocarbon compound includes that weight ratio is 1:1.5 heptane and isooctane；The combustion adjuvant includes that weight ratio is 2:3:5 hexyl ether, methyl tertiary butyl ether(MTBE) and ethyl tert-butyl ether (ETBE).
The stabilizer is that weight ratio is 3:5 di-tert-butyl p-cresol and isobutyl amine；The anti-knock agent is methyl ring two Alkene manganese tricarbonyl；The deodorant is essence；The dispersant is polymethacrylates.
The preparation method of above-mentioned refuse reclamation type oleyl alcohol compound bio fuel, includes the following steps：
（1）Prepare additive：Under normal temperature and pressure conditions, ethyl alcohol, hydrocarbon compound, octanol, dimethoxym ethane are added in configurator It is uniformly mixed, glyceryl triacetate, cation fluorine carbon surface active agent, diamyl iron, combustion adjuvant, stabilizer, antiknock is then added Agent, deodorant, dispersant are uniform, and above-mentioned mixed raw material is then mixed 1h by explosion-proof centrifugal pump circulation, then quiet 2h is set to get to additive, it is spare；
（2）Under normal temperature and pressure conditions, kitchen garbage bio-fuel, seaweed bio oil, C9 are added in configurator and are uniformly mixed, Then additive is added to be uniformly mixed, adds methanol and is uniformly mixed, then pump above-mentioned mixed raw material by explosion-proof centrifugal Cycle mixing 1h, is then allowed to stand 2h to get to the refuse reclamation type oleyl alcohol compound bio fuel.

Claims (9)

1. a kind of refuse reclamation type compound bio fuel, which is characterized in that include the component of following parts by weight：Seaweed bio oil 40-50 parts, 40-50 parts of kitchen rubbish biological fuel, 25-30 parts of methanol, 10-15 parts of C9,10-15 parts of additive.
2. refuse reclamation type compound bio fuel according to claim 1, which is characterized in that the additive include with The raw material of lower parts by weight：5-10 parts of ethyl alcohol, 3-5 parts of glyceryl triacetate, 5-10 parts of octanol, 10-15 parts of dimethoxym ethane, cation fluorine 4-7 parts of carbon surface active agent, 10-15 parts of hydrocarbon compound, 10-15 parts of combustion adjuvant, 3-5 parts of stabilizer, resists 3-5 parts of diamyl iron 3-5 parts of detonator, 1-4 parts of deodorant, 1-5 parts of dispersant.
3. refuse reclamation type compound bio fuel according to claim 1, which is characterized in that the seaweed bio oil by It is prepared by following methods：
Broken wall crushes：Cleaning removes the impurity such as silt for adulterating and the sea salt on surface in seaweed, be then added in seaweed and its Deng the distilled water of weight, slurries are ground into wall-broken grinder, it is spare；
Fermentation：Slurries are added in fermentation tank, the composite bacteria agent of slurry weight score 0.008-0.01% is added, are uniformly mixed, It ferments 6-8 days under the conditions of 30-35 DEG C, obtains zymotic fluid, it is spare；
Hydrothermal liquefaction：Zymotic fluid is added in autoclave, the distilled water of 3 times of weight of zymotic fluid, N is added2It is forced into 1.5 MPa is heated to 300 DEG C, is stirred reaction 1h with 150r/min, after being cooled to room temperature, releases gas, pours out reaction mixing Object, it is spare；
（4）Extraction：Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get oily to the seaweed bio.
4. refuse reclamation type oleyl alcohol compound bio fuel according to claim 3, which is characterized in that the composite bacteria agent It is mixed by 3~5 parts of bacillus pumilus, 6~10 parts of saccharomyces cerevisiaes, 3~5 parts of lactoenterococcus.
5. refuse reclamation type compound bio fuel according to claim 1, which is characterized in that the kitchen garbage biology Fuel is prepared by following methods：
（1）Sterilization proposes oil processing：Will collect come kitchen garbage by sorting unit remove bulk materials after, into sterilizing chamber into Row sterilization, then after carrying oil and recycling grease therein to obtain oil removing solid refuse spare；
（2）Broken wall treatment：By oil removing solid refuse dry to water content be 20%-30%, be crushed to 100-200 mesh, then again into Row broken wall pulverization process；
（3）Fermentation process：The water of garbage weight score 40-50% is added in spray in rubbish after being pulverized, and garbage weight point is added The composite bacteria agent of number 0.009-0.013%, ferments 5-7 days under conditions of 35-40 DEG C；
（4）Hydrothermal liquefaction processing：Fermentate is added in autoclave, the distilled water of 3 times of weight of fermentate, N is added2Pressurization To 2.0 MPa, 300 DEG C are heated to, reaction 1h is stirred with 180r/min, after being cooled to room temperature, gas is released, pours out reaction Mixture, it is spare；Use CH2Cl2Reaction mixture is extracted, residue, CH are then filtered to isolate2Cl2Mutually rotated under the conditions of 40 DEG C Evaporation removes CH2Cl2To get to oil removing solid refuse bio-fuel.
6. refuse reclamation type compound bio fuel according to claim 5, which is characterized in that composite bacteria agent used is attached most importance to Amount number is 5~8 parts of bacillus pumilus, 5~10 parts of S. cervisiaes, 2~4 parts of lactoenterococcus.
7. refuse reclamation type compound bio fuel according to claim 2, which is characterized in that the hydrocarbon compound packet It is 1 to include weight ratio:1.5 heptane and isooctane；The combustion adjuvant includes that weight ratio is 2:3:5 hexyl ether, methyl tertiary butyl ether(MTBE) And ethyl tert-butyl ether (ETBE).
8. refuse reclamation type compound bio fuel according to claim 2, which is characterized in that the stabilizer is weight Than being 3:5 di-tert-butyl p-cresol and isobutyl amine；The anti-knock agent is methyl cyclic diolefine manganese tricarbonyl；The deodorant is perfume Essence；The dispersant is polymethacrylates.
9. the preparation method of any refuse reclamation type compound bio fuel of claim 1-8, which is characterized in that including Following steps：
（1）Prepare additive：Under normal temperature and pressure conditions, ethyl alcohol, hydrocarbon compound, octanol, dimethoxym ethane are added in configurator It is uniformly mixed, glyceryl triacetate, cation fluorine carbon surface active agent, diamyl iron, combustion adjuvant, stabilizer, antiknock is then added Agent, deodorant, dispersant are uniform, and above-mentioned mixed raw material is then mixed 1h by explosion-proof centrifugal pump circulation, then quiet 2h is set to get to additive, it is spare；
（2）Under normal temperature and pressure conditions, kitchen garbage bio-fuel, seaweed bio oil, C9 are added in configurator and are uniformly mixed, Then additive is added to be uniformly mixed, adds methanol and is uniformly mixed, then pump above-mentioned mixed raw material by explosion-proof centrifugal Cycle mixing 1h, is then allowed to stand 2h to get to the refuse reclamation type oleyl alcohol compound bio fuel.
CN201810179850.0A 2018-03-05 2018-03-05 A kind of refuse reclamation type compound bio fuel and preparation method thereof Withdrawn CN108424805A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202200004886A1 (en) * 2022-03-14 2023-09-14 Thermolysys S R L PROCESS AND APPARATUS FOR THE PRODUCTION OF BIO-OIL FROM LIGNOCELLULOSE BIOMASS

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202200004886A1 (en) * 2022-03-14 2023-09-14 Thermolysys S R L PROCESS AND APPARATUS FOR THE PRODUCTION OF BIO-OIL FROM LIGNOCELLULOSE BIOMASS
WO2023175493A1 (en) * 2022-03-14 2023-09-21 Thermolysys S.R.L. Process and apparatus for the production of bio-oil from lignocellulosic biomass

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