CN108414297B - A kind of collection device of Gaseous Detonation method nano materials - Google Patents
A kind of collection device of Gaseous Detonation method nano materials Download PDFInfo
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- 238000005474 detonation Methods 0.000 title claims abstract description 66
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 18
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 10
- 230000015572 biosynthetic process Effects 0.000 abstract description 9
- 239000002245 particle Substances 0.000 abstract description 9
- 238000004458 analytical method Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000012876 topography Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 239000002105 nanoparticle Substances 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
- 238000004200 deflagration Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000004880 explosion Methods 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 239000002041 carbon nanotube Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000010892 electric spark Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000002114 nanocomposite Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910003910 SiCl4 Inorganic materials 0.000 description 1
- 229910020442 SiO2—TiO2 Inorganic materials 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- 229910003082 TiO2-SiO2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- QNZRVYCYEMYQMD-UHFFFAOYSA-N copper;pentane-2,4-dione Chemical compound [Cu].CC(=O)CC(C)=O QNZRVYCYEMYQMD-UHFFFAOYSA-N 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/22—Devices for withdrawing samples in the gaseous state
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
- G01N23/22—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material
- G01N23/2202—Preparing specimens therefor
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Biomedical Technology (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The present invention provides a kind of collection devices of Gaseous Detonation method nano materials, belong to nano material synthesis technical field.By equal length and the collecting platform shiftable haulage line with fixed device is nominally fixed with shape, obtains the fixed frame of nano material collecting device.Collecting platform is fixed on the fixed frame of collection device, the collection device of nano material is made.The device is built in Gaseous Detonation pipe, and is tested by Gaseous Detonation nano materials, particle size is had collected and is less than the sample that detonation inside pipe wall is collected into.Usefulness of the present invention has: 1) collection device stable structure, material physico-chemical property are stablized, and collect the nano material of different location.2) the nano material partial size on collection device is respectively less than detonation inside pipe wall particle size, facilitates the theory analysis for disclosing Gaseous Detonation nano materials.3) according to the sample topography feature of different location, a kind of collection specific morphology, the method for sized nanostructures material are provided.
Description
Technical field
The present invention relates to a kind of collection devices of Gaseous Detonation method nano materials, more particularly, it relates to
A kind of device of position-movable collection detonation reaction zone product, belongs to nano material synthesis technical field.The production being collected into
Object can be used to disclose the growth mechanism of Gaseous Detonation method nano materials.
Background technique
Gaseous Detonation method is a kind of to operate the nano material system that convenient, reaction rate is fast, equipment requirement is low, product purity is high
(the quick-fried temperature of Yan Honghao, Wu Linsong, Li Xiaojie, Zhao Tiejun synthesizes nano-TiO to Gaseous Detonation to Preparation Method2The influence of structure and performance
[J] " Journal of Inorganic Materials " .2017,03:275-280).Gaseous Detonation method generally uses imflammable gas (such as H2, hydrocarbonization
Close object etc.) and O2Or the mixed gas of the oxidizing gas such as air is ignited in closed space by electric spark as quick-fried source
The gas generates the detonation of high temperature or detonation Means of Pyrolyzed Precursor prepares nano material.TiCl4Heated easily gasification, it is quick-fried frequently as gas phase
Hong method prepares nano-TiO2Presoma, research finds the factors such as quick-fried source, explosion velocity, initial pressure, initial temperature, precursor concentration
It can be to nano-TiO2Object phase and pattern generate different degrees of influence, or even cause change (the Ou Yangxin of its photocatalytic activity
Gas deflagration and Detonation Process prepare the titanium dioxide nanoparticle research Dalian [D]: Dalian University of Technology's doctoral thesis, and 2009).
Nano SnO2With Nano-meter SiO_22Respectively SnCl can be decomposed by Gaseous Detonation method4With SiCl4Preparation, and their appearance and size is same
Sample is influenced (change of Yan Honghao, Wu Linsong, Li Xiaojie, Wang little Hong, Wang Shengjie the presoma with respect to the amount of substance by above-mentioned factor
Change prepares Nano-meter SiO_2 to hydrogen-oxygen gas deflagration2Influence [J] " explosion and impact " .2012,06:581-584. Yan Hong of particle
Great, Wang Shengjie, Li Xiaojie, Wu Linsong initial pressure prepare nano SnO to Gaseous Detonation2Influence [J] " functional material "
.2013,20:3016-3019).It can get TiO by adjusting presoma type2-SnO2、TiO2-SiO2、TiO2-Fe2O3Etc. receiving
Nano composite material, and the purer TiO of its photocatalytic activity2Nano particle have significantly promotion (L.S.Wu, H.H.Yan,
J.L.Xiao,X.J.Li,X.H.Wang.Characterization and photocatalytic properties of
SiO2-TiO2nanocomposites prepared through gaseous detonation method[J].
《Ceramics International》.2017,43(12):9377-9381.L.S.Wu,H.H.Yan,X.J.Li,
X.H.Wang.Characterization and photocatalytic properties of SnO2-
TiO2nanocomposites prepared through gaseous detonation method[J].《Ceramics
International".2017,43(1):1517-1521.).In addition to oxide, the carbon-clad metal of Gaseous Detonation method preparation is received
Rice material, carbon nanomaterial and carbon nanotube etc. have good appearance structure and stability.Make presoma with ferrocene, it can
Prepare carbon-coated iron/carbonization iron nano-particle (H.Yan, T.Zhao, X.Li, C.Hun.Hydrogen and air detonation
(deflagration)synthesis of carbon-encapsulated iron nanoparticles[J],
"Combustion,Explosion and Shockwaves".2015,51(4):495-501.)；Make forerunner with acetylacetone copper
Body can synthesize carbon copper-clad nano particle (Yan Honghao, Zhang Xiaofei, Zhao Bibo, Zhao Tiejun, Li Xiaojie gas phase/condensed explosive detonation
Carbon copper-clad nanoparticle features [J] " light laser and the particle beams " .2017,08:74-78. of synthesis)；Ignite benzene-oxygen gas mixture
Body, can be synthesized under the conditions of negative oxygen onion-like fullerene nano material (N.Luo, H.W.Jing, Z.G.Ma,
R.H.Chen.Gaseous detonation chemical synthesis of onion-like carbons[J].
"Mendeleev Communications".2017,27(2):195-197.)；By adjusting imflammable gas in mixed gas
Ratio, using ferrocene as catalyst can obtain carbon nano-tube material (T.J.Zhao, X.J.Li, J.H.S.Lee,
H.H.Yan.The effects of hydrogen proportion on the synthesis of carbon
nanomaterials with gaseous detonation(deflagration)method[J].《Materials
Research Express " .2018,5 (2): 025024. Yang Rui, Li Xiaojie, Yan Honghao Gaseous Detonation method synthesis iron content multi wall
Carbon nanotube [J] " Chinese Journal Of High Pressure Physics " .2017,03:209-214.).
Gaseous Detonation nano materials reaction rate is very fast, reaction process and its complexity, the life for nano particle
Long mechanism mainly explains (Chen Tianwu, Luo Ning, Yan Honghao, Liu Kaixin gas phase explosion with the Kruis growth model of aerosol
TiO in flow field2Numerical analysis pre-test [J] " Chinese Journal Of High Pressure Physics " .2014,06:729-735. Yan Hong of nanoparticle growth
It is great, Wu Linsong, Li Xiaojie, application [J] " rare gold of the Wang Shengjie particle growth model in Gaseous Detonation nano materials
Belong to material and engineering " .2015,05:1144-1148).It is calculated by numerical value, finds an important factor for influencing particle size, and pre-
A possibility that surveying nano material size tunable.However, generally requiring product precipitating 10 in Gaseous Detonation nano materials
Or so minute goes to collect again, so the growth phenomenon of nano particle can not be verified in an experiment.Therefore, it is necessary to a kind of special
Sample collection device, nanoparticle growth machine during Gaseous Detonation is disclosed with product when obtaining Gaseous Detonation reaction
System.
Summary of the invention
The purpose of the present invention is inventing a kind of collection device of Gaseous Detonation method nano materials, to obtain Gaseous Detonation
Nanometer product when reaction.
Technical principle of the invention:
One, Gaseous Detonation process can generate the high temperature of nearly 3000K, and generate relatively large impact force, so, collect dress
Certain heat-resisting quantity, reliable structural stability, physicochemical stability should be met by setting.
Two, collection device cannot significantly affect the propagation of detonation wave, need to have good detonation wave permeability.
Technical solution of the present invention:
A kind of collection device of Gaseous Detonation method nano materials, the collection device are placed in Gaseous Detonation experimental provision
It is interior, including fixed frame and collecting platform two parts；
The fixed frame further comprises shape nominal 6 and collecting platform shiftable haulage line 7, and shape nominal 6, which is located at, to be received
The both ends of acquisition means form fixed frame for fixing collecting platform shiftable haulage line 7；
The collecting platform further comprises collecting platform 8 and fixed device 9, and it is solid that collecting platform 8 passes through fixed device 9
It is scheduled on collecting platform shiftable haulage line 7, and is slided on collecting platform shiftable haulage line 7.
The shape nominal 6 is the polygons, round or ellipse such as triangle, quadrangle.
The nominal 6 quantity more than two of the shape, for fixing collecting platform shiftable haulage line 7.
The composing quantity of the collecting platform shiftable haulage line is 1 or more.
The collecting platform 8 is the porous flake of the high porosity of stainless steel mesh sheet or hole greater than 0.8mm of 10 mesh
Material, shape are round, ellipse or polygon.
The collection device is the corrosion-resistant, high temperature resistants, oxidation resistant material such as stainless steel, copper, titanium.
The collection nano material is TiO2、SnO2、SiO2, carbon-coated iron, carbon copper-clad, carbon packet cobalt, carbon nanotube, nanometer
The nano material of the Gaseous Detonations method such as carbon synthesis.
Beneficial effects of the present invention: 1) collection device stable structure, material physico-chemical property are stablized, and collect different location
Nano material.2) the nano material partial size on collection device is respectively less than detonation inside pipe wall particle size, and it is quick-fried to facilitate announcement gas phase
The theory analysis of Hong nano materials.3) according to the sample topography feature of different location, a kind of collection specific morphology, ruler are provided
The method of very little nano material.
Detailed description of the invention
Fig. 1 is the Detonation Tube schematic device that Gaseous Detonation experiment is used used in the present invention.
Fig. 2 is the schematic diagram of nano material collecting device.
Fig. 3 is that Gaseous Detonation prepares TiO2Transmission electron microscope (TEM) picture.
Fig. 4 is sample in the TEM picture for collecting position 1 (at Detonation Tube tail end 160mm).
Fig. 5 is sample in the TEM picture for collecting position 2 (at Detonation Tube tail end 320mm).
Fig. 6 is sample in the TEM picture for collecting position 3 (at Detonation Tube tail end 640mm).
In figure: 1 electric spark；2 vacuum pumping valves and presoma injection valve；3 vacuum meters；4 temperature control systems；5 sealing flanges；6
Shape is nominal；7 collecting platform shiftable haulage lines；8 collecting platforms；9 fixed devices.
Specific embodiment
A specific embodiment of the invention is further illustrated below in conjunction with attached drawing and technical solution.
Embodiment 1
By taking Fig. 2 is to design a model as an example.Making material diameter is 6mm, and outer diameter is that the annulus of 95mm is nominal as shape.It cuts
It takes the screw thread silk steel that 3 equal length diameters are 6mm and has fixed device, as collecting platform shiftable haulage line.Finally, screw thread silk
Steel both ends according to etc. angular separation fixed with annulus, complete collection device frame.The stainless steel mesh sheet of 10 mesh is cut into directly
Diameter is then the disk of 95mm is fixed in the fixed frame of collection device as the collecting platform of nano material with nut
On, the production of nano material collecting device can be completed.Material therefor is 304 type stainless steels.It is received with the synthesis of Gaseous Detonation method
Rice TiO2It is illustrated for collection.
Gaseous Detonation pipe is cleaned up and keeps the drying of tank interior.Nano material is thoroughly cleaned with ethyl alcohol collects dress
The fixed frame set simultaneously is dried, in case impurity generates pollution to sample.After being washed and dried with EtOH Sonicate ripple
Collecting platform is fixed on frame according to away from Detonation Tube tail portion 160mm distance, is then placed in the nano material collecting device
It in Gaseous Detonation pipe, is aligned one end with Detonation Tube tail portion, Gaseous Detonation is avoided to impact the damage to tube wall.Then blanket gas
Phase Detonation Tube, vacuumizes, and after being heated to 130 DEG C, injects the TiCl of 2ml4, and be that 2:1 is filled with H according to volume ratio2With O2To 1
Atmospheric pressure.Temperature uses 20J electric spark to ignite mixed gas after keeping 5min.Gaseous Detonation pipe is opened after 5min, takes out nanometer material
Expect collection device, the nano-powder on collecting platform.Finally, the sample being collected into is characterized and is analyzed.
As shown in figure 4, spherical in shape away from the sample on collecting platform at the 160mm of Detonation Tube tail portion, partial size 20mm range with
It is interior.The TiO that detonation inside pipe wall is collected when no collection device2Particle (as shown in Figure 3), it is flat that partial size is significantly greater than nano material collection
The TiO obtained on platform2。
Embodiment 2
According to the experimental method of embodiment 1, sample collection position is adjusted to away from Gaseous Detonation pipe tail portion 320mm, remaining
Step is same as Example 1.There are obvious corner angle in the sample being collected into, and partial size slightly increases, and sees the TEM of Fig. 5 sample
Figure.
Embodiment 3
According to the experimental method of embodiment 1, sample collection position is adjusted to away from Gaseous Detonation pipe tail portion 640mm, remaining
Step is same as Example 1.The sample being collected into has apparent corner angle, and partial size between 20-30nm, but is less than in significantly increasing
The Product size that detonation inside pipe wall is collected is shown in the TEM figure of Fig. 6 sample.
In conclusion the nanometer that the present invention can obtain when Gaseous Detonation reacts by this nano material collecting device produces
Object provides the experimental observation foundation of Gaseous Detonation nano materials particles collision growth, this helps to disclose Gaseous Detonation
The growth mechanism and theoretical calculation of nano materials.
The parameter and scheme that the present invention is not limited to the above embodiment are not limited to Gaseous Detonation method synthesis TiO2Receipts
Collection, all any modification, improvement and equivalent replacements made within spirit and principle of the invention, should be included in of the invention
Within protection scope.
Claims (8)
1. a kind of collection device of Gaseous Detonation method nano materials, which is characterized in that the collection device is placed in Gaseous Detonation
In experimental provision, including fixed frame and collection part two parts；
The fixed frame further comprises shape nominal (6) and collecting platform shiftable haulage line (7), and shape nominal (6) is located at
The both ends of collection device form fixed frame for fixing collecting platform shiftable haulage line (7)；
The collection part further comprises collecting platform (8) and fixes device (9), and collecting platform (8) passes through fixed device
(9) it is removably fixed on collecting platform shiftable haulage line (7), and is slided on collecting platform shiftable haulage line (7).
2. collection device according to claim 1, which is characterized in that the collection device is corrosion-resistant, high temperature resistant, resistance to
Oxidation material is made.
3. collection device according to claim 1 or 2, which is characterized in that the shape nominal (6) is polygon, circle
Shape or ellipse, quantity more than two.
4. collection device according to claim 1 or 2, which is characterized in that the group of the collecting platform shiftable haulage line (7)
It is 1 or more at quantity.
5. collection device according to claim 3, which is characterized in that the composition of the collecting platform shiftable haulage line (7)
Quantity is 1 or more.
6. according to claim 1, collection device described in 2 or 5, which is characterized in that the collecting platform (8) be 10 purposes not
The porous sheet material of the high porosity of rust steel mesh piece or hole greater than 0.8mm, shape are round, ellipse or polygon.
7. collection device according to claim 3, which is characterized in that the collecting platform (8) is the stainless steel of 10 mesh
The porous sheet material of the high porosity of mesh sheet or hole greater than 0.8mm, shape are round, ellipse or polygon.
8. collection device according to claim 4, which is characterized in that the collecting platform (8) is the stainless steel of 10 mesh
The porous sheet material of the high porosity of mesh sheet or hole greater than 0.8mm, shape are round, ellipse or polygon.
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| JP6110116B2 (en) * | 2012-11-28 | 2017-04-05 | 日本写真印刷株式会社 | Gas component adsorption tube, gas component collection device, and gas component collection method. |
| CN204359560U (en) * | 2014-04-10 | 2015-05-27 | 齐齐哈尔大学 | Multifunction atmospheric depositing dust automatic sampler |
| CN105836729B (en) * | 2016-04-11 | 2017-12-05 | 大连理工大学 | The method that Gaseous Detonation method synthesizes iron content CNT |
| CN107305168B (en) * | 2016-04-22 | 2020-05-22 | 中国石油化工股份有限公司 | Gaseous mercury catches mercury device |
| CN206161388U (en) * | 2016-11-03 | 2017-05-10 | 内蒙古包钢钢联股份有限公司 | Raw coke oven gas composition detects sample and takes integrated equipment |
| CN206710154U (en) * | 2017-05-09 | 2017-12-05 | 湖北省公信检测服务有限公司 | A kind of environmental project detects sampler with water quality |
| CN206740458U (en) * | 2017-05-10 | 2017-12-12 | 广西壮族自治区环境保护科学研究院 | A kind of eight grades of abiotic stepwise sampler rain insensitive devices |
| CN208171688U (en) * | 2018-05-03 | 2018-11-30 | 大连理工大学 | A kind of collection device of Gaseous Detonation method nano materials |
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2018
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