CN108410408A - A kind of high tenacity cloud stone glue and preparation method thereof - Google Patents
A kind of high tenacity cloud stone glue and preparation method thereof Download PDFInfo
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- CN108410408A CN108410408A CN201810223931.6A CN201810223931A CN108410408A CN 108410408 A CN108410408 A CN 108410408A CN 201810223931 A CN201810223931 A CN 201810223931A CN 108410408 A CN108410408 A CN 108410408A
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- high tenacity
- polyester resin
- cloud stone
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of high tenacity cloud stone glue, which is characterized in that includes the component of following parts by weight：Unsaturated polyester resin：20 ~ 35 parts；Polyether acrylate：3 ~ 6.5 parts；Nano core shell rubber particle：0.01 ~ 0.1 part；Methylolethane triacrylate：2 ~ 4.5 parts；Unsaturated polyester resin initiator：0.2 ~ 0.5 part；Thixotropic agent：0.5 ~ 3 part；Inorganic filler：35 ~ 55 parts.The high tenacity cloud stone glue has high bond strength, ageing resistance is strong, and weather resistance is stablized, its toughness and retractility are stronger simultaneously, it can prevent from deforming because of vibrations or under wind-force, the effect of expanding with heat and contract with cold after plate adhesion, distort so that the phenomenon that falling off, and preparation method is simple for process, is easy to construct.
Description
Technical field
The present invention relates to a kind of cloud stone glues and preparation method thereof, and in particular to a kind of high tenacity cloud stone glue and its preparation side
Method.
Background technology
Cloud stone glue, that is, unsaturated-resin glue, the country are also referred to as cloud stone glue.Cloud stone glue is suitable for viscous between all kinds of stone materials
Crack and the mark of break for connecing or repairing stone surface, be usually used in the repairings of all types of paver engineerings and all kinds of stone materials, cemented in place and
Joint filling.It is used for the stone material property filled up bonding, and also referred to as unstructuredness is bonded.Unstructuredness bonding is relative to structural one kind connect
Using organic chemistry adhesive to the defect of stone material, such as crackle, hole, sand holes, product defect, finishing positioning repaired,
Filling, enhancing, a kind of fixed technique.Being widely used for cloud stone glue is general, and the current country has many producers to develop a variety of systems
The cloud stone glue product of row.
Existing cloud stone glue is generally made of unsaturated multi-polyester, filler and a small amount of thixotropic agent rilanit special, is passed through
The viscosity of unsaturated multi-polyester resin bonds marble, granite and stone material.But cloud stone glue itself does not have toughness, by force
Degree is little, and since the ratio great disparity of unsaturated polyester resin and fixed hardener formula (is typically 100:3), when artificial construction
Bad control may result in colloid and become fragile once ratio is more than 3%, reduce adhesive property, final to shorten the service life, lead to danger
Occur, filler oil factor used in cloud stone glue is high in addition, and wetability is poor, causes cloud stone glue adhesive strength low, easy dusting cracking, simultaneously
Long-time storage in the environment of temperature is higher than 25 DEG C, also will appear the separation because of resin and filler due to surface resin is caused to ooze
Go out, bottom glue due to amount of resin is reduced and the phenomenon that be hardened, not only influence the appearance of product, also result in the shakiness of its mechanical property
It is qualitative.
In summary, it would be highly desirable to find a kind of cloud stone glue with excellent mechanical property.
Invention content
Above-mentioned to solve the problems, such as, the purpose of the present invention is to provide a kind of high tenacity cloud stone glue and its preparation sides
Method.The high tenacity cloud stone glue has high bond strength, and ageing resistance is strong, and weather resistance is stablized, while its toughness and stretching
Contracting is stronger, can prevent from deforming because of vibrations after plate adhesion or under wind-force, the effect of expanding with heat and contract with cold, distort so that fall off
Phenomenon, and preparation method is simple for process, is easy to construct.
In order to achieve the above objectives, the technical scheme is that：
A kind of high tenacity cloud stone glue, includes the component of following parts by weight：Unsaturated polyester resin：20~35 parts；Polyethers
Acrylate：3~6.5 parts；Nano core shell rubber particle：0.01~0.1 part；Methylolethane triacrylate：2~4.5
Part；Unsaturated polyester resin initiator：0.2~0.5 part；Thixotropic agent：0.5~3 part；Inorganic filler：35~55 parts.
Further, include the component of following parts by weight：Unsaturated polyester resin：22~30 parts；Polyether acrylate：
4.5~6.5 parts；Nano core shell rubber particle：0.01~0.06 part；Methylolethane triacrylate：3~4.5 parts；Insatiable hunger
With polyester resin initiator：0.2~0.4 part；Thixotropic agent：1~2 part；Inorganic filler：40~50 parts.
Further, include the component of following parts by weight：Unsaturated polyester resin：26 parts；Polyether acrylate：5 parts；
Nano core shell rubber particle：0.03 part；Methylolethane triacrylate：3.3 part；Unsaturated polyester resin initiator：0.3
Part；Thixotropic agent：1.5 part；Inorganic filler：47 parts.Polyether acrylate is added in the cloud stone glue, participates in unsaturated polyester resin
Curing reaction is participated in a manner of covalent bond in curing network, plays toughening effect；Meanwhile also by nanometer in solidification process
Core-shell rubber particles are wrapped up into curing network, and are uniformly distributed therein, and further function as toughening effect, therefore can prevent plank
It deforms, distort so that the phenomenon that falling off because of vibrations or under wind-force, the effect of expanding with heat and contract with cold after bonding；In addition high tenacity marble
Glue has high bond strength, and ageing resistance is strong, and weather resistance is stablized.
Further, the grain size of the nano core shell rubber particle is 80~200nm, and core is butadiene-styrene rubber, and shell is poly-
Methyl methacrylate.Nano core shell rubber particle diameter is small, and uniform particle sizes, stabilization, is easy to improve toughness and easy to process
Molding.
Further, the unsaturated polyester resin initiator is benzoyl peroxide or lauroyl peroxide or azo two
Any one of isobutyronitrile or hydrogen peroxide.
Further, the thixotropic agent is any in rilanit special or aerosil or low molecular weight polyethylene
Kind.
Further, the inorganic filler be silicon powder or powdered whiting or any one of bentonite or barium sulfate or
Combination.
A kind of preparation method of high tenacity cloud stone glue, includes the following steps：By unsaturated polyester resin, polyoxyalkylene acrylate
Ester, nano core shell rubber particle, methylolethane triacrylate, thixotropic agent and inorganic filler, are sufficiently mixed, and stirring 10~
20min adds unsaturated polyester resin initiator, is heated to 35~45 DEG C, continues to stir evenly 30~60min, then quiet
It sets cooling and obtains high tenacity cloud stone glue.The preparation method is simple for process, is easy to construct.
The beneficial effects of the present invention are：
A kind of high tenacity cloud stone glue of the present invention has high bond strength, and ageing resistance is strong, and weather resistance is steady
It is fixed, while its toughness and retractility are stronger, are changed after capable of preventing plate adhesion because shaking or being issued in wind-force, the effect of expanding with heat and contract with cold
Shape, distortion are so that the phenomenon that falling off, and preparation method is simple for process, is easy to construct.
Specific implementation mode
Embodiment 1
A kind of high tenacity cloud stone glue, includes the component of following parts by weight：Unsaturated polyester resin：20 parts；Polyethers propylene
Acid esters：3 parts；Nano core shell rubber particle：0.02 part；Methylolethane triacrylate：2.7 part；Benzoyl peroxide：
0.3 part；Aerosil：0.5 part；Silicon powder：35 parts.
A kind of preparation method of high tenacity cloud stone glue, includes the following steps：By unsaturated polyester resin, polyoxyalkylene acrylate
Ester, nano core shell rubber particle, methylolethane triacrylate, aerosil and silicon powder, are sufficiently mixed, stirring
15min adds benzoyl peroxide, is heated to 45 DEG C, continues to stir evenly 30min, is then allowed to stand cooling and obtains high tenacity
Cloud stone glue.
Embodiment 2
A kind of high tenacity cloud stone glue, includes the component of following parts by weight：Unsaturated polyester resin：29 parts；Polyethers propylene
Acid esters：4.5 part；Nano core shell rubber particle：0.01 part；Methylolethane triacrylate：4.5 part；Lauroyl peroxide：
0.2 part；Rilanit special：0.5 part；Bentonite：41 parts.
A kind of preparation method of high tenacity cloud stone glue, includes the following steps：By unsaturated polyester resin, polyoxyalkylene acrylate
Ester, nano core shell rubber particle, methylolethane triacrylate, rilanit special and bentonite, are sufficiently mixed, stirring
10min adds lauroyl peroxide, is heated to 35 DEG C, continues to stir evenly 50min, is then allowed to stand cooling and obtains high tenacity
Cloud stone glue.
Embodiment 3
A kind of high tenacity cloud stone glue, includes the component of following parts by weight：Unsaturated polyester resin：26 parts；Polyethers propylene
Acid esters：5 parts；Nano core shell rubber particle：0.03 part；Methylolethane triacrylate：3.3 part；Benzoyl peroxide：
0.3 part；Low molecular weight polyethylene：1.5 part；Barium sulfate：47 parts.
A kind of preparation method of high tenacity cloud stone glue, includes the following steps：By unsaturated polyester resin, polyoxyalkylene acrylate
Ester, nano core shell rubber particle, methylolethane triacrylate, low molecular weight polyethylene and barium sulfate, are sufficiently mixed, stir
15min is mixed, benzoyl peroxide is added, is heated to 40 DEG C, continues to stir evenly 40min, cooling is then allowed to stand and obtains high-ductility
Property cloud stone glue.
Embodiment 4
A kind of high tenacity cloud stone glue, includes the component of following parts by weight：Unsaturated polyester resin：35 parts；Polyethers propylene
Acid esters：6.5 part；Nano core shell rubber particle：0.1 part；Methylolethane triacrylate：2 parts；Azodiisobutyronitrile：0.5
Part；Aerosil：2.5 part；Powdered whiting：55 parts.
A kind of preparation method of high tenacity cloud stone glue, includes the following steps：By unsaturated polyester resin, polyoxyalkylene acrylate
Ester, nano core shell rubber particle, methylolethane triacrylate, aerosil and powdered whiting, are sufficiently mixed,
20min is stirred, azodiisobutyronitrile is added, is heated to 40 DEG C, continue to stir evenly 60min, cooling is then allowed to stand and obtains height
Toughness cloud stone glue.
Embodiment 5
A kind of high tenacity cloud stone glue, includes the component of following parts by weight：Unsaturated polyester resin：30 parts；Polyethers propylene
Acid esters：5.8 part；Nano core shell rubber particle：0.07 part；Methylolethane triacrylate：2.5 part；Lauroyl peroxide：
0.4 part；Rilanit special：3 parts；Barium sulfate：42 parts.
A kind of preparation method of high tenacity cloud stone glue, includes the following steps：By unsaturated polyester resin, polyoxyalkylene acrylate
Ester, nano core shell rubber particle, methylolethane triacrylate, rilanit special and barium sulfate, are sufficiently mixed, stirring
10min adds lauroyl peroxide, is heated to 35 DEG C, continues to stir evenly 45min, is then allowed to stand cooling and obtains high tenacity
Cloud stone glue.
The performance for the high tenacity cloud stone glue that Examples 1 to 5 is prepared is tested, and the results are shown in Table 1.
Table 1
Wherein, the comparative example 1 be embodiment 1 in do not add polyether acrylate, nano core shell rubber particle is prepared into
The cloud stone glue arrived.Can obtain obtained high tenacity cloud stone glue by data in table has high bond strength, and ageing resistance is strong,
And weather resistance is stablized, while its toughness and retractility are stronger, can prevent after plate adhesion because of vibrations or in wind-force, expand with heat and contract with cold
It deforms, distort under effect so that the phenomenon that falling off.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although with reference to compared with
Good embodiment describes the invention in detail, it will be understood by those of ordinary skill in the art that, it can be to the technology of invention
Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all cover the power in the present invention
In sharp claimed range.
Claims (8)
1. a kind of high tenacity cloud stone glue, which is characterized in that include the component of following parts by weight：Unsaturated polyester resin：20~35
Part；Polyether acrylate：3 ~ 6.5 parts；Nano core shell rubber particle：0.01 ~ 0.1 part；Methylolethane triacrylate：2~
4.5 part；Unsaturated polyester resin initiator：0.2 ~ 0.5 part；Thixotropic agent：0.5 ~ 3 part；Inorganic filler：35 ~ 55 parts.
2. high tenacity cloud stone glue according to claim 1, which is characterized in that include the component of following parts by weight：Insatiable hunger
And polyester resin：22 ~ 30 parts；Polyether acrylate：4.5 ~ 6.5 parts；Nano core shell rubber particle：0.01 ~ 0.06 part；Three hydroxyl first
Base ethane triacrylate：3 ~ 4.5 parts；Unsaturated polyester resin initiator：0.2 ~ 0.4 part；Thixotropic agent：1 ~ 2 part；It is inorganic to fill out
Material：40 ~ 50 parts.
3. high tenacity cloud stone glue according to claim 1, which is characterized in that include the component of following parts by weight：Insatiable hunger
And polyester resin：26 parts；Polyether acrylate：5 parts；Nano core shell rubber particle：0.03 part；Trimethylolethane trimethacrylate acrylic acid
Ester：3.3 part；Unsaturated polyester resin initiator：0.3 part；Thixotropic agent：1.5 part；Inorganic filler：47 parts.
4. high tenacity cloud stone glue according to claim 1, which is characterized in that the grain size of the nano core shell rubber particle is
80 ~ 200nm, core are butadiene-styrene rubber, and shell is polymethyl methacrylate.
5. high tenacity cloud stone glue according to claim 1, which is characterized in that the unsaturated polyester resin initiator was
Benzoyl Oxide or lauroyl peroxide or any one of azodiisobutyronitrile or hydrogen peroxide.
6. high tenacity cloud stone glue according to claim 1, which is characterized in that the thixotropic agent is rilanit special or gas phase
Any one of silica or low molecular weight polyethylene.
7. high tenacity cloud stone glue according to claim 1, which is characterized in that the inorganic filler is silicon powder or heavy carbon
Sour calcium or any one of bentonite or barium sulfate or combination.
8. a kind of preparation method of high tenacity cloud stone glue as described in claim 1, which is characterized in that include the following steps：It will
Unsaturated polyester resin, polyether acrylate, nano core shell rubber particle, methylolethane triacrylate, thixotropic agent and
Inorganic filler is sufficiently mixed, and is stirred 10 ~ 20min, is added unsaturated polyester resin initiator, is heated to 35 ~ 45 DEG C, is continued
30 ~ 60min is stirred evenly, cooling is then allowed to stand and obtains high tenacity cloud stone glue.
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| CN201810223931.6A CN108410408B (en) | 2018-03-19 | 2018-03-19 | High-toughness marble adhesive and preparation method thereof |
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| CN201810223931.6A CN108410408B (en) | 2018-03-19 | 2018-03-19 | High-toughness marble adhesive and preparation method thereof |
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| CN108410408B CN108410408B (en) | 2021-01-15 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113897164A (en) * | 2021-10-26 | 2022-01-07 | 江苏大力士投资有限公司 | Marble adhesive with high adhesion and high toughness and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113897164A (en) * | 2021-10-26 | 2022-01-07 | 江苏大力士投资有限公司 | Marble adhesive with high adhesion and high toughness and preparation method thereof |
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| CN108410408B (en) | 2021-01-15 |
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