CN108410385A - A kind of environment-friendly type decoration surface lining and preparation method thereof - Google Patents

A kind of environment-friendly type decoration surface lining and preparation method thereof Download PDF

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Publication number
CN108410385A
CN108410385A CN201810219295.XA CN201810219295A CN108410385A CN 108410385 A CN108410385 A CN 108410385A CN 201810219295 A CN201810219295 A CN 201810219295A CN 108410385 A CN108410385 A CN 108410385A
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layer
environment
adhesive
friendly type
pvc
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谭志恒
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Foshan Lifeng Daily Necessities Co Ltd
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Foshan Lifeng Daily Necessities Co Ltd
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Priority to CN201810219295.XA priority Critical patent/CN108410385A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/06—Embossing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
    • C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
    • C08B30/18—Dextrin, e.g. yellow canari, white dextrin, amylodextrin or maltodextrin; Methods of depolymerisation, e.g. by irradiation or mechanically
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B31/00—Preparation of derivatives of starch
    • C08B31/003—Crosslinking of starch
    • C08B31/006—Crosslinking of derivatives of starch
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/123—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/04—Starch derivatives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C23/00—Making patterns or designs on fabrics
    • D06C23/04—Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B2038/0052—Other operations not otherwise provided for
    • B32B2038/0084—Foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/24—Presence of a foam
    • C09J2400/243—Presence of a foam in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/26—Presence of textile or fabric
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2403/00—Presence of starch
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2427/00—Presence of halogenated polymer
    • C09J2427/005—Presence of halogenated polymer in the release coating
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/20—Protein-derived artificial fibres
    • D10B2211/26—Globulin, e.g. groundnut protein
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]

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  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Textile Engineering (AREA)
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  • General Chemical & Material Sciences (AREA)
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  • Mechanical Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of environment-friendly type decoration surface linings, include bottom adhesive layer, PVC foam layer, the faces PVC layer, intermediate adhesive layer, fibrous layer successively；The bottom adhesive layer and intermediate adhesive layer are the Environment-friendlyadhesive adhesive layer being made of Environment-friendlyadhesive adhesive, and the PVC foam layer thickness is 2 3mm, and the PVC surface thicknesses are 0.8 1mm, and the fibrous layer is mixed fiber layer.Environment-friendly type decoration surface lining in the present invention is simple in structure, and binding force is strong between layers, and metope attachment ornament materials, furniture attachment ornament materials etc. can be used as to be used.It is environment-friendly type starch adhesive that adhesive in the present invention, which uses, which, to the equal fanout free region of human body, meets environmental requirement without poisonous and harmful substance volatilization, preparation process and using process.

Description

A kind of environment-friendly type decoration surface lining and preparation method thereof
Technical field
The invention belongs to the invention belongs to high molecular material application fields, and in particular to a kind of decorative paste plane materiel of environment-friendly type Material and preparation method thereof.
Background technology
Finishing field in traditional house decoration or office space, many places need to use a large amount of papery decoration As attachment material, such as woodgrained paper, water wave paper, these traditional ornament materials need to utilize a large amount of timber and patch material The glue of dress, it is very big to timber resources consumption, simultaneously because needing to use a large amount of glue, on the one hand improve decoration On the other hand the cost of material entirety often contains a large amount of volatile materials, in processing manufacturing process in glue product Greater risk is formd to the health of human body of producer, while security risk is also constituted to user in use.Closely Nian Lai, consumer is to the remaining volatile gas of ornament materials（Formaldehyde etc.）Attention rate is higher and higher, do not meet environmental requirement, The ornament materials for giving out the volatile materials unfavorable to human body is gradually abandoned by market.
With the continuous promotion that consumer requires ornament materials, the product characteristic of ornament materials require to focus primarily upon with Under several aspects：
1, the feature of environmental protection of material, the material as decoration must directly or indirectly not injure user；
2, the applicability of material and the decorative aesthetic requirement that need to meet consumer；
3, the process of material need to adapt to industrialized production.
Starch is a kind of reproducible natural biomass high-molecular compound, and raw material sources are abundant and cheap, are one The biodegradable regenerated resources of kind.The adhesive product produced as raw material by starch have it is non-toxic and tasteless, without residual The characteristics of remaining chemical gas release, especially reduced increasingly in crude resources it is present, using petrochemicals as raw material Macromolecular adhesive is of high cost and not environmentally, can not only economize on resources using starch as the adhesive of raw material, but also meet environmentally protective Requirement.In decoration material field, how starch adhesive to be matched with existing ornament materials structure be one be worth into The project of row further investigation.
Invention content
In order to solve the deficiencies in the prior art, the present invention provides a kind of decorative faced comprising Environment-friendlyadhesive adhesive Material, the surface lining raw material is environmentally protective, and preparation method is simple, not will produce releasing for bad VOC in use It puts.
Institute of the invention technique effect to be achieved is realized by following scheme：
A kind of environment-friendly type decoration surface lining provided in the present invention successively include bottom adhesive layer, PVC foam layer, the faces PVC layer, Intermediate adhesive layer, fibrous layer；The bottom adhesive layer and intermediate adhesive layer are the environment-friendly type glue being made of Environment-friendlyadhesive adhesive Adhensive layer, the PVC foam layer thickness are 2-3mm, and the PVC surface thicknesses are 0.8-1mm, and the fibrous layer is composite fibre Layer.
Starch is formed by connecting by many dehydrated glucose units, is respectively had on C2, C3 and C5 of each glucose unit As soon as hydroxyl, thus have thousands of a activity hydroxies on a starch chain high-polymer molecular, and each starch granules It is to be interwoven in the form of crystal region and unsetting area by unnumbered amylose and branched amylopectin molecules chain again, therefore, The number of hydroxyl is to be calculated with the larger order of magnitude, and the cohesive force of starch adhesive is exactly source in starch adhesive The Hydrogen bonding forces caused by hydroxyl.In the prior art, also there are many starch adhesive is applied on ornament materials Technical solution, but totally apparently, starch adhesive dry strength in the prior art tends to meet the requirements, but is carrying out Unqualified when the test of water proof bonding strength, in general, existing starch adhesive impregnates in 60 DEG C or so of hot water 2h can limit the use of starch adhesive in this way there is a situation where coming unglued later.
In technical scheme of the present invention, the defect of existing starch adhesive is improved from the following：1, by starch Adhesive is applied in decorative overlay material, and not as the binder of main board material；2, improvement connects with starch adhesive Material, by being changed to macromolecule PVC material to the sensitive paper material of humiture or wood materials；3, improve the knot of surface lining Structure enables starch adhesive to carry out complete wetting to surface lining, while being arranged rational especially with the setting of foaming layer Thickness is adapted therewith；4, fibrous layer is set in the outer surface of surface lining, not only there is good appearance, but also have The effect of moisture-barrier reduces influence of the variation to surface lining of ambient humidity.
Further, the composition and mass fraction of the Environment-friendlyadhesive adhesive are：
Modified starch starches 90-100 parts
20-30 parts of water
1-1.2 parts of borax
0.2-0.5 parts of propyl alcohol
3-4 parts of polyvinyl alcohol
0.3-0.5 parts of gaultherolin
0.1-0.2 parts of organic silicon defoamer
Wherein, the preparation method of the modified starch slurry is：Sodium trimetaphosphate, poly first are added after starch is mixed with water successively Aldehyde, epoxychloropropane stirring, wherein starch, water, sodium trimetaphosphate, paraformaldehyde, epoxychloropropane mass ratio be 1:（2.4- 2.6）：（0.01-0.03）：（0.07-0.09）：（0.05-0.07）；Sodium carbonate is added after stirring evenly adjusts pH value in 10- In 10.2 ranges, it is heated to 58-62 DEG C, the continuation of saturation solution of sodium bisulfite is added dropwise into reaction system instead after reacting 1.5-2h Should be 7 to pH value, it is 25-30% then to add water to be adjusted to solids level concentration in reaction system, then adjusts the temperature to 38-40 DEG C Continue to be stirred to react 6-8h, obtains required modified starch slurry.
Starch is modified first in the present invention, so that the alcoholic extract hydroxyl group of starch is generated two with reactant using sodium trimetaphosphate Ehter bond or diester linkage, to make two or more starch molecules preliminary " bridge formation " together, while add paraformaldehyde into One step promotes ether cross-linking reaction, accelerates reaction speed and promotes reaction process.Epoxychloropropane can make the above-mentioned gelatinization of starch Reaction is more thorough, and can effectively promote the viscosity of starch slurry.Reactant is initially under alkaline environment and crosslinks, so Reach highly cross-linked by the way that the reaction was continued after sodium hydrogensulfite adjusting pH value afterwards, the starch slurry viscosity after reacting 6-8 hours It is basicly stable with property, without reprocessing.
Further, in the present invention, the starch in the modified starch slurry preparation method is that cornstarch or glutinous rice form sediment Powder；The preparation method of the Environment-friendlyadhesive adhesive is：Modified starch slurry is dispersed in water, with 2-3 DEG C/min in whipping process Heating speed be heated to 75-78 DEG C, then sequentially add borax, propyl alcohol, polyvinyl alcohol, gaultherolin and organosilicon Antifoaming agent stirs 3-5min after the addition of each raw material, and cooled to room temperature obtains required adhesive after stirring.This hair The feature of environmental protection adhesive boiling water heating being prepared in bright is not gelatinized, and 5h or more is impregnated in 60 DEG C or so of hot water and is not come unglued.
Further, the heretofore described faces PVC layer is handled by cremate, and the technique of the activation process is：By the faces PVC Layer irradiates 3-5min using ultraviolet lamp, and ultraviolet lamp wavelength of light is 200-280nm, irradiation power 20-30W.Ultraviolet light Processing can be promoted the faces PVC layer surface energy, make the faces PVC layer have better adhesive property.
Further, heretofore described fibrous layer is blend fibre layer, is fine by ptt fiber, cotton fiber, soybean protein Dimension, polypropylene fibre carry out blended obtained lamellar fibre material, wherein ptt fiber, cotton fiber, soybean fiber, poly- Mass ratio is in tacryl blended weave（35-40）：（3-5）：（12-17）：（35-40）.Blend fibre close structure, waterproof Excellent performance.
Preferably, a diameter of 3-8 μm of the ptt fiber, cotton fiber, soybean fiber, polypropylene fibre, length is less than 1mm.Selection diameter and the small fiber of length can further increase the tightness degree of blend fibre, while provide surface lining A kind of smooth appearance makes surface lining surface touch smooth comfortable, meets the actual use demand of decorative overlay material.
Preferably, the fiber layer thickness is 0.1-0.3mm.
A kind of method preparing above-mentioned environment-friendly type decoration surface lining is also provided in the present invention, steps are as follows：
S01：Bottom adhesive layer is brushed on separation cloth, is then laid with PVC foam layer, is then laid with the faces PVC layer, is foamed, Embossed is carried out using Embosser under blowing temperature while foaming terminates, makes the faces PVC layer that there is the decorative pattern of setting；
S02：After embossed, intermediate adhesive layer is brushed immediately, is then laid with fibrous layer；
S03：Fibrous layer embosses fibrous layer using the Embosser in S01 after being laid with, and pressure is embossed in the step It is 0.7-0.8 times of embossing step in S01, the embossing time is 6-8h；
S04：10-30min is dried to matte layer using 30-40 DEG C of dry warm wind after embossing, it will system after dry The decorative overlay material obtained is sprawled, and room temperature is naturally cooling to.
Further, in S01, the separation cloth is teflon cloth.
Further, in S03, embossing pressure is 0.8 times of embossing step in S01, and the embossing time is 6h.
Surface lining secure bond is made together using twice grained method in the preparation process of the present invention, due to this hair Using short fiber blending raw material in bright, it is possible to using slightly lower embossing pressure emboss to promote veneer for a long time The intensity and integraty of material entirety.
The present invention has the following advantages：
1, the environment-friendly type decoration surface lining in the present invention is simple in structure, and binding force is strong between layers, metope can be used as to paste Dress ornament materials, furniture attachment ornament materials etc. are used.
2, it is environment-friendly type starch adhesive that the adhesive in the present invention, which uses, which waves without poisonous and harmful substance Hair, preparation process and use process meet environmental requirement to the equal fanout free region of human body.
3, the outer layer of the environment-friendly type decoration surface lining in the present invention is mixed using shorter macromolecular fibre and fabric fibre Woven material is made, and hardness is higher than existing imitative down material, not easily to fall off, and is unlikely to deform during molding, during use It is long to be not easy to fall ash discoloration, service life.
3, preparation method is simple for environment-friendly type decorative overlay material in the present invention, is suitble to industrialized large-scale production Technique.
Specific implementation mode
With reference to embodiment, the present invention will be described in detail.
Embodiment 1
The preparation of modified starch slurry 1.：
Added successively after cornstarch is mixed with water sodium trimetaphosphate, paraformaldehyde, epoxychloropropane stirring, wherein starch, Water, sodium trimetaphosphate, paraformaldehyde, epoxychloropropane mass ratio be 1:2.4：0.01：0.07：0.05；Add after stirring evenly Add sodium carbonate to adjust pH value within the scope of 10-10.2, be heated to 60 DEG C, saturation sulfurous is added dropwise into reaction system after reacting 1.5h Sour hydrogen sodium solution the reaction was continued to pH value be 7, then plus water to be adjusted in reaction system solids level concentration be 25%, then adjust Temperature continues to be stirred to react 6h to 38 DEG C, obtains required modified starch slurry 1..
The preparation of modified starch slurry 2.：
Added successively after cornstarch is mixed with water sodium trimetaphosphate, paraformaldehyde, epoxychloropropane stirring, wherein starch, Water, sodium trimetaphosphate, paraformaldehyde, epoxychloropropane mass ratio be 1:2.5：0.03：0.07：0.07；Add after stirring evenly Add sodium carbonate to adjust pH value within the scope of 10-10.2, be heated to 62 DEG C, saturation sulfurous acid is added dropwise into reaction system after reacting 2h Hydrogen sodium solution the reaction was continued to pH value be 7, then plus water to be adjusted in reaction system solids level concentration be 25%, then adjust temperature It spends to 40 DEG C and continues to be stirred to react 6h, obtain required modified starch slurry 2..
The preparation of modified starch slurry 3.：
Added successively after glutinous rice starch is mixed with water sodium trimetaphosphate, paraformaldehyde, epoxychloropropane stirring, wherein starch, Water, sodium trimetaphosphate, paraformaldehyde, epoxychloropropane mass ratio be 1:2.6：0.03：0.09：0.05；Add after stirring evenly Add sodium carbonate to adjust pH value within the scope of 10-10.2, be heated to 60 DEG C, saturation sulfurous is added dropwise into reaction system after reacting 1.5h Sour hydrogen sodium solution the reaction was continued to pH value be 7, then plus water to be adjusted in reaction system solids level concentration be 30%, then adjust Temperature continues to be stirred to react 6h to 40 DEG C, obtains required modified starch slurry 3..
The preparation of modified starch slurry 4.：
Added successively after glutinous rice starch is mixed with water sodium trimetaphosphate, paraformaldehyde, epoxychloropropane stirring, wherein starch, Water, sodium trimetaphosphate, paraformaldehyde, epoxychloropropane mass ratio be 1:2.5：0.02：0.09：0.07；Add after stirring evenly Add sodium carbonate to adjust pH value within the scope of 10-10.2, be heated to 60 DEG C, saturation sulfurous acid is added dropwise into reaction system after reacting 2h Hydrogen sodium solution the reaction was continued to pH value be 7, then plus water to be adjusted in reaction system solids level concentration be 28%, then adjust temperature It spends to 40 DEG C and continues to be stirred to react 6h, obtain required modified starch slurry 4..
The preparation of modified starch slurry 5.：
Added successively after glutinous rice starch is mixed with water sodium trimetaphosphate, paraformaldehyde, epoxychloropropane stirring, wherein starch, Water, sodium trimetaphosphate, paraformaldehyde, epoxychloropropane mass ratio be 1:2.6：0.03：0.09：0.07；Add after stirring evenly Add sodium carbonate to adjust pH value within the scope of 10-10.2, be heated to 61 DEG C, saturation sulfurous is added dropwise into reaction system after reacting 1.8h Sour hydrogen sodium solution the reaction was continued to pH value be 7, then plus water to be adjusted in reaction system solids level concentration be 30%, then adjust Temperature continues to be stirred to react 6h to 38 DEG C, obtains required modified starch slurry 5..
Above-mentioned modified starch slurry slurry viscosity and property are basicly stable, use modified starch slurry in the following embodiments 3. Do raw material.
Embodiment 2
The preparation of Environment-friendlyadhesive adhesive 1.：
The composition and mass fraction of Environment-friendlyadhesive adhesive raw material be：
Modified starch starches 90 parts
22 parts of water
1.1 parts of borax
0.4 part of propyl alcohol
3 parts of polyvinyl alcohol
0.3 part of gaultherolin
0.1 part of organic silicon defoamer
Preparation method is：Modified starch slurry is dispersed in water, is heated to the heating speed of 2 DEG C/min in whipping process 75 DEG C, borax, propyl alcohol, polyvinyl alcohol, gaultherolin and organic silicon defoamer are then sequentially added, is stirred after the addition of each raw material 3min is mixed, after stirring 1. cooled to room temperature obtains required adhesive.
The preparation of Environment-friendlyadhesive adhesive 2.：
The composition and mass fraction of Environment-friendlyadhesive adhesive raw material be：
Modified starch starches 100 parts
25 parts of water
1.1 parts of borax
0.5 part of propyl alcohol
4 parts of polyvinyl alcohol
0.5 part of gaultherolin
0.1 part of organic silicon defoamer
Preparation method is：Modified starch slurry is dispersed in water, is heated with the heating speed of 2.4 DEG C/min in whipping process To 78 DEG C, borax, propyl alcohol, polyvinyl alcohol, gaultherolin and organic silicon defoamer are then sequentially added, after the addition of each raw material 3min is stirred, after stirring 2. cooled to room temperature obtains required adhesive.
The preparation of Environment-friendlyadhesive adhesive 3.：
The composition and mass fraction of Environment-friendlyadhesive adhesive raw material be：
Modified starch starches 95 parts
30 parts of water
1.2 parts of borax
0.5 part of propyl alcohol
4 parts of polyvinyl alcohol
0.5 part of gaultherolin
0.2 part of organic silicon defoamer
Preparation method is：Modified starch slurry is dispersed in water, is heated to the heating speed of 3 DEG C/min in whipping process 78 DEG C, borax, propyl alcohol, polyvinyl alcohol, gaultherolin and organic silicon defoamer are then sequentially added, is stirred after the addition of each raw material 5min is mixed, after stirring 3. cooled to room temperature obtains required adhesive.
The preparation of Environment-friendlyadhesive adhesive 4.：
The composition and mass fraction of Environment-friendlyadhesive adhesive raw material be：
Modified starch starches 100 parts
30 parts of water
1.2 parts of borax
0.5 part of propyl alcohol
4 parts of polyvinyl alcohol
0.3 part of gaultherolin
0.2 part of organic silicon defoamer
Preparation method is：Modified starch slurry is dispersed in water, is heated to the heating speed of 2 DEG C/min in whipping process 78 DEG C, borax, propyl alcohol, polyvinyl alcohol, gaultherolin and organic silicon defoamer are then sequentially added, is stirred after the addition of each raw material 5min is mixed, after stirring 4. cooled to room temperature obtains required adhesive.
The preparation of Environment-friendlyadhesive adhesive 5.：
The composition and mass fraction of Environment-friendlyadhesive adhesive raw material be：
Modified starch starches 98 parts
30 parts of water
1.2 parts of borax
0.2 part of propyl alcohol
3.2 parts of polyvinyl alcohol
0.3 part of gaultherolin
0.2 part of organic silicon defoamer
Preparation method is：Modified starch slurry is dispersed in water, is heated with the heating speed of 2.1 DEG C/min in whipping process To 77 DEG C, borax, propyl alcohol, polyvinyl alcohol, gaultherolin and organic silicon defoamer are then sequentially added, after the addition of each raw material 4min is stirred, after stirring 5. cooled to room temperature obtains required adhesive.
Embodiment Environment-friendlyadhesive adhesive 1. -5. in the feature of environmental protection adhesive that is prepared give up to heat in boiling water and be not gelatinized, 5h or more is impregnated in 60 DEG C or so of hot water not come unglued.1. it is used as raw material into luggage using above-mentioned Environment-friendlyadhesive adhesive in embodiment Adorn the preparation of surface lining.
Embodiment 3
The preparation of fibrous layer：
Material in the prior art for veneer often all employs the raw material of animality, such as wool, this kind of raw material although Feel is relatively good, but cannot be otherwise easily deformed by excessively high outer force effect in process, meanwhile, including animal Property raw material matte layer color it is not lasting, it is general with the binding force of Environment-friendlyadhesive adhesive in the present invention, be easy during use de- It falls.
It is used in the present embodiment and ptt fiber, cotton fiber, soybean fiber, polypropylene fibre is subjected to blended institute Matte material obtained.Ptt fiber, cotton fiber, soybean fiber, polypropylene fibre stock diameter are 5 μm, and length is in 0.5- Within the scope of 1mm.
Fibrous material is 1.：Mass ratio is in ptt fiber, cotton fiber, soybean fiber, polypropylene fibre blended weave 35：3：16：35.
Fibrous material is 2.：Mass ratio is in ptt fiber, cotton fiber, soybean fiber, polypropylene fibre blended weave 40：4：15：37.
Fibrous material is 3.：Mass ratio is in ptt fiber, cotton fiber, soybean fiber, polypropylene fibre blended weave 37：5：13：37.
Fibrous material is 4.：Mass ratio is in ptt fiber, cotton fiber, soybean fiber, polypropylene fibre blended weave 38：5：13：39.
Fibrous material is 5.：Mass ratio is in ptt fiber, cotton fiber, soybean fiber, polypropylene fibre blended weave 40：4：15：40.
Above-mentioned matte material is compared, ptt fiber and polypropylene fibre total content are higher, and fibrous material feel is harder, and cotton is fine Peacekeeping soybean fiber total content is higher, and feel is softer, is not easy to spring back after pressing.Comprehensive feel, appearance and resist processing, choosing Fibrous material is selected 2. to process raw material as subsequent.
Embodiment 4
The preparation of decorative overlay material：
S01：Bottom adhesive layer is brushed on polytetrafluoroethylene (PTFE) separation cloth, is then laid with PVC foam layer, is then laid with activated The faces PVC layer, foams, and carries out embossed using Embosser under blowing temperature while foaming terminates, makes the faces PVC Layer has the decorative pattern of setting；PVC foam layer thickness after embossed is 2mm, and surface average pore size is 50 μm, the faces PVC layer Thickness is 0.8mm.
The faces PVC layer activation process technique be：The faces PVC layer is irradiated into 5min, ultraviolet lamp light wave using ultraviolet lamp A length of 205nm, irradiation power 22W.
S02：After embossed, intermediate adhesive layer is brushed immediately, and then laying depth is the fibrous layer of 0.1mm.
S03：Fibrous layer embosses fibrous layer using the Embosser in S01 after being laid with, and is embossed in the step Pressure is 0.7 times of embossing step in S01, and the embossing time is 6h.
S04：15min is dried to matte layer using 35 DEG C of dry warm winds after embossing, will be made after dry Decorative overlay material sprawled, be naturally cooling to room temperature.
Embodiment 5
Preparation process technique is same as Example 4 in the present embodiment, the difference is that：
In S03, embossing pressure is 0.8 times of embossing step in S01, and the embossing time is 6h.
Embodiment 6
Preparation process technique is same as Example 4 in the present embodiment, the difference is that：
PVC foam layer thickness is 2mm, and surface average pore size is 40 μm, and PVC surface thicknesses are 1mm.
Embodiment 7
Preparation process technique is same as Example 4 in the present embodiment, the difference is that：
PVC foam layer thickness is 3mm, and surface average pore size is 30 μm, and PVC surface thicknesses are 1mm.
Embodiment 8
Preparation process technique is same as Example 4 in the present embodiment, the difference is that：
PVC foam layer thickness is 3mm, and surface average pore size is 30 μm, and PVC surface thicknesses are 0.9mm.
Embodiment 9
Preparation process technique is same as Example 4 in the present embodiment, the difference is that：
Fiber layer thickness is 0.2mm.
Embodiment 10
Preparation process technique is same as Example 4 in the present embodiment, the difference is that：
Fiber layer thickness is 0.3mm.
In above-described embodiment, the technique of brushing adhesive and brushing macromolecule in vellum finish material is prepared in the prior art Adhesive is identical, for the purpose of adjacent two layers to be glued together.In an embodiment of the present invention, the embossing in S01 and S03 is utilized Environment-friendlyadhesive adhesive is depressed into foaming layer with fibrous layer, keeps overall structure cohesive force strong by step.According to actual process situation, In view of the requirement of drying process and use environment, the adjustment of adaptability can be carried out to the usage amount of adhesive.This hair embodiment Middle face decoration material is simple in structure, and binding force is strong between layers, can be used as metope attachment ornament materials, furniture attachment dress Exterior material etc. is used.In use, the attachment of ornament materials can be carried out by removing separation cloth, simple and easy to do.
Face decoration material in the present invention it can be seen from embodiment is volatilized using raw material without poisonous and harmful substance, Preparation process and use process meet environmental requirement to the equal fanout free region of human body.Face decoration material surface in the present invention uses Shorter macromolecular fibre is made with fabric fibre blended material, and hardness is higher than existing imitative down material, not easily to fall off, and is being molded During be unlikely to deform, it is long to be not easy to fall ash discoloration, service life during use.Meanwhile the present invention in PVC base matte Preparation method is simple for ornament materials, is suitble to industrialized large-scale production process.
Finally, it should be noted that above example be only to illustrate the embodiment of the present invention technical solution rather than to its into Row limitation, although the embodiment of the present invention is described in detail with reference to preferred embodiment, those skilled in the art It should be understood that the technical solution of the embodiment of the present invention can be still modified or replaced equivalently, and these are changed or wait The range of modified technical solution disengaging technical solution of the embodiment of the present invention cannot also be made with replacement.

Claims (10)

1. a kind of environment-friendly type decoration surface lining, it is characterised in that：
The material includes bottom adhesive layer, PVC foam layer, the faces PVC layer, intermediate adhesive layer, fibrous layer successively；The bottom glue Glutinous layer and intermediate adhesive layer are the Environment-friendlyadhesive adhesive layer being made of Environment-friendlyadhesive adhesive, and the PVC foam layer thickness is 2- 3mm, the PVC surface thicknesses are 0.8-1mm, and the fibrous layer is mixed fiber layer.
2. environment-friendly type decoration surface lining as described in claim 1, it is characterised in that：The composition and matter of the Environment-friendlyadhesive adhesive Measuring number is：
Modified starch starches 90-100 parts
20-30 parts of water
1-1.2 parts of borax
0.2-0.5 parts of propyl alcohol
3-4 parts of polyvinyl alcohol
0.3-0.5 parts of gaultherolin
0.1-0.2 parts of organic silicon defoamer
Wherein, the preparation method of the modified starch slurry is：Sodium trimetaphosphate, poly first are added after starch is mixed with water successively Aldehyde, epoxychloropropane stirring, wherein starch, water, sodium trimetaphosphate, paraformaldehyde, epoxychloropropane mass ratio be 1:（2.4- 2.6）：（0.01-0.03）：（0.07-0.09）：（0.05-0.07）；Sodium carbonate is added after stirring evenly adjusts pH value in 10- In 10.2 ranges, it is heated to 58-62 DEG C, the continuation of saturation solution of sodium bisulfite is added dropwise into reaction system instead after reacting 1.5-2h Should be 7 to pH value, it is 25-30% then to add water to be adjusted to solids level concentration in reaction system, then adjusts the temperature to 38-40 DEG C Continue to be stirred to react 6-8h, obtains required modified starch slurry.
3. environment-friendly type decoration surface lining as claimed in claim 2, it is characterised in that：In the modified starch slurry preparation method Starch is cornstarch or glutinous rice starch；The preparation method of the Environment-friendlyadhesive adhesive is：Modified starch slurry is dispersed to water In, it is heated to 75-78 DEG C with the heating speed of 2-3 DEG C/min in whipping process, borax is then sequentially added, propyl alcohol, gathers Vinyl alcohol, gaultherolin and organic silicon defoamer stir 3-5min after the addition of each raw material, are naturally cooled to after stirring Room temperature obtains required adhesive.
4. environment-friendly type decoration surface lining as described in claim 1, it is characterised in that：The faces the PVC layer is handled by cremate, institute The technique for stating activation process is：The faces PVC layer is irradiated into 3-5min using ultraviolet lamp, ultraviolet lamp wavelength of light is 200- 280nm, irradiation power 20-30W.
5. environment-friendly type decoration surface lining as described in claim 1, it is characterised in that：The fibrous layer is blend fibre layer, is Blended obtained fibrous material is carried out by ptt fiber, cotton fiber, soybean fiber, polypropylene fibre, wherein ptt fiber, Mass ratio is in cotton fiber, soybean fiber, polypropylene fibre blended weave（35-40）：（3-5）：（12-17）：（35- 40）.
6. environment-friendly type decoration surface lining as claimed in claim 5, it is characterised in that：The ptt fiber, cotton fiber, soybean egg A diameter of 3-8 μm of white fiber, polypropylene fibre, length are less than 1mm.
7. environment-friendly type decoration surface lining as described in claim 1, it is characterised in that：The fiber layer thickness is 0.1-0.3mm.
8. a kind of method preparing the environment-friendly type decoration surface lining as described in claim 1-7 is any, it is characterised in that with including Following steps：
S01：Bottom adhesive layer is brushed on separation cloth, is then laid with PVC foam layer, is then laid with the faces PVC layer, is foamed, Embossed is carried out using Embosser under blowing temperature while foaming terminates, makes the faces PVC layer that there is the decorative pattern of setting；
S02：After embossed, intermediate adhesive layer is brushed immediately, is then laid with fibrous layer；
S03：Fibrous layer embosses fibrous layer using the Embosser in S01 after being laid with, and pressure is embossed in the step It is 0.7-0.8 times of embossing step in S01, the embossing time is 6-8h；
S04：10-30min is dried to matte layer using 30-40 DEG C of dry warm wind after embossing, it will system after dry The decorative overlay material obtained is sprawled, and room temperature is naturally cooling to.
9. the preparation method of vellum finish material as described in right 8, it is characterised in that：In S01, the separation cloth is polytetrafluoroethyl-ne Alkene cloth.
10. the preparation method of vellum finish material as described in right 8, it is characterised in that：In S03, embossing pressure is embossed in S01 0.8 times of step, embossing time are 6h.
CN201810219295.XA 2018-03-16 2018-03-16 A kind of environment-friendly type decoration surface lining and preparation method thereof Pending CN108410385A (en)

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Application publication date: 20180817