CN108410329A - A kind of fire-retardant epoxy resin coating - Google Patents
A kind of fire-retardant epoxy resin coating Download PDFInfo
- Publication number
- CN108410329A CN108410329A CN201810237600.8A CN201810237600A CN108410329A CN 108410329 A CN108410329 A CN 108410329A CN 201810237600 A CN201810237600 A CN 201810237600A CN 108410329 A CN108410329 A CN 108410329A
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- parts
- fire
- epoxy resin
- resin coating
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses phenol-formaldehyde resin modified, organophosphorus ester, talcum powder, quartz sand, antifoaming agent, levelling agents obtained by a kind of fire-retardant epoxy resin coating, including the cyclic annular hydrocarbon compound of 2 or more unsaturated bonds, the compound condensation with phenolic hydroxyl group.By the above-mentioned means, the fire-retardant epoxy resin coating good weatherability of the present invention, substantially increases the flame retardant property of resin using the synergistic effect of phosphorus and other elements, and appropriate can reduce cost, has a wide range of prospect of the application.
Description
Technical field
The present invention relates to a kind of epoxy coatings, more particularly to a kind of fire-retardant epoxy resin coating.
Background technology
Epoxy resin has excellent electricity, mechanical property and resistance toization corrosivity and is obtained in terms of coating, building, electronics
To being widely applied, but limited its scope of application since epoxy resin hot property is poor, because a little, it is excellent to prepare hot property,
The high epoxy resin of flame retardant property becomes research emphasis.Can be by halogen come fire-retardant, but halogen can produce in combustion
Raw toxic gas, damages human body.
Invention content
The invention mainly solves the technical problem of providing a kind of fire-retardant epoxy resin coating, the coating good weatherability,
The flame retardant property of resin is substantially increased using the synergistic effect of phosphorus and other elements, and appropriate can reduce cost, is had
A wide range of prospect of the application.
In order to solve the above technical problems, one aspect of the present invention is：A kind of fire-retardant epoxy resin coating,
Including the cyclic annular hydrocarbon compounds of 2 or more unsaturated bonds, modified phenolic obtained by the compound condensation with phenolic hydroxyl group
Resin, organophosphorus ester, talcum powder, quartz sand, antifoaming agent, levelling agent, wherein the group of the epoxy coating is divided into：With matter
Measure part meter, cyclic annular hydrocarbon compound 10-15 parts, 8-12 parts of phenol-formaldehyde resin modified obtained by the compound condensation with phenolic hydroxyl group,
5.5-12.5 parts of organophosphorus ester, 1.5-8.5 parts of talcum powder, 2-6 parts of quartz sand, 0.5-1.5 parts of antifoaming agent, levelling agent 0.2-
1.5 part.
In a preferred embodiment of the present invention, the organophosphorus ester includes -4 methylol -2,6 of 1- oxos, and 7, trichlorine
Change phosphorus particle or alkyl chloride for oxygen phosphorus.
In a preferred embodiment of the present invention, a diameter of 10-50 nanometers of the phosphorus trichloride particle.
In a preferred embodiment of the present invention, the compound with phenolic hydroxyl group is oxybenzene compound or naphthols
Close one kind in object or two kinds.
In a preferred embodiment of the present invention, wherein the group of the epoxy coating is divided into：It is cyclic annular in terms of mass parts
8 parts of phenol-formaldehyde resin modified, 5.5 parts of organophosphorus ester obtained by 10 parts of hydrocarbon compound, the compound condensation with phenolic hydroxyl group are slided
1.5 parts of mountain flour, 2 parts of quartz sand, 0.55 part of antifoaming agent, 0.2 part of levelling agent.
In a preferred embodiment of the present invention, wherein the group of the epoxy coating is divided into：It is cyclic annular in terms of mass parts
12 parts of phenol-formaldehyde resin modified, 12.5 parts of organophosphorus ester obtained by 15 parts of hydrocarbon compound, the compound condensation with phenolic hydroxyl group,
8.5 parts of talcum powder, 6 parts of quartz sand, 1.5 parts of antifoaming agent, 1.5 parts of levelling agent
The beneficial effects of the invention are as follows：The fire-retardant epoxy resin coating good weatherability of the present invention utilizes phosphorus and other elements
Synergistic effect substantially increases the flame retardant property of resin, and appropriate can reduce cost, has a wide range of prospect of the application.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
All other embodiment that technical staff is obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment one：
A kind of fire-retardant epoxy resin coating, wherein the group of the epoxy coating is divided into：In terms of mass parts, cyclic hydrocarbon chemical combination
8 parts of phenol-formaldehyde resin modified, 5.5 parts of organophosphorus ester, talcum powder obtained by 10 parts of object, the compound condensation with phenolic hydroxyl group
1.5 parts, 2 parts of quartz sand, 0.55 part of antifoaming agent, 0.2 part of levelling agent, the organophosphorus ester includes -4 methylol -2 of 1- oxos,
6,7, phosphorus trichloride particle or alkyl chloride are for oxygen phosphorus.
Embodiment two：
A kind of fire-retardant epoxy resin coating, wherein the group of the epoxy coating is divided into：In terms of mass parts, cyclic hydrocarbon chemical combination
12 parts of phenol-formaldehyde resin modified, 12.5 parts of organophosphorus ester, talcum powder obtained by 15 parts of object, the compound condensation with phenolic hydroxyl group
8.5 parts, a diameter of 10 nanometers of 6 parts of quartz sand, 1.5 parts of antifoaming agent, the wherein described Zinc oxide particles of 1.5 parts of levelling agent.
Embodiment three：
A kind of fire-retardant epoxy resin coating, wherein the group of the epoxy coating is divided into：In terms of mass parts, cyclic hydrocarbon chemical combination
10 parts of phenol-formaldehyde resin modified, 6 parts of organophosphorus ester, talcum powder 2 obtained by 12 parts of object, the compound condensation with phenolic hydroxyl group
Part, 3 parts of quartz sand, 1 part of antifoaming agent, 0.5 part of levelling agent.
The beneficial effects of the invention are as follows：The fire-retardant epoxy resin coating good weatherability of the present invention, utilizes phosphorus and other members
The synergistic effect of element substantially increases the flame retardant property of resin, and appropriate can reduce cost, has a wide range of prospect of the application.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (6)
1. a kind of fire-retardant epoxy resin coating, which is characterized in that including：The cyclic annular hydrocarbon compound of 2 or more unsaturated bonds,
Phenol-formaldehyde resin modified, organophosphorus ester, talcum powder, quartz sand, antifoaming agent, stream obtained by compound condensation with phenolic hydroxyl group
Flat agent, wherein the group of the epoxy coating is divided into：In terms of mass parts, cyclic annular hydrocarbon compound 10-15 parts, have phenolic hydroxyl group
Compound condensation obtained by 8-12 parts of phenol-formaldehyde resin modified, 5.5-12.5 parts of organophosphorus ester, 1.5-8.5 parts of talcum powder, stone
2-6 parts of sand, 0.5-1.5 parts of antifoaming agent, 0.2-1.5 parts of levelling agent.
2. fire-retardant epoxy resin coating according to claim 1, which is characterized in that the organophosphorus ester includes 1- oxygen
- 4 methylols -2,6 of generation, 7, phosphorus trichloride particle or alkyl chloride are for oxygen phosphorus.
3. fire-retardant epoxy resin coating according to claim 2, which is characterized in that the diameter of the phosphorus trichloride particle
It is 10-50 nanometers.
4. fire-retardant epoxy resin coating according to claim 1, which is characterized in that the chemical combination with phenolic hydroxyl group
Object is oxybenzene compound or one kind in naphthol compound or two kinds.
5. fire-retardant epoxy resin coating according to claim 1, which is characterized in that the wherein described epoxy coating
Group is divided into：In terms of mass parts, phenol-formaldehyde resin modified obtained by 10 parts of cyclic annular hydrocarbon compound, the compound condensation with phenolic hydroxyl group
8 parts, 5.5 parts of organophosphorus ester, 1.5 parts of talcum powder, 2 parts of quartz sand, 0.55 part of antifoaming agent, 0.2 part of levelling agent.
6. fire-retardant epoxy resin coating according to claim 1, which is characterized in that the wherein described epoxy coating
Group is divided into：In terms of mass parts, phenol-formaldehyde resin modified obtained by 15 parts of cyclic annular hydrocarbon compound, the compound condensation with phenolic hydroxyl group
12 parts, 12.5 parts of organophosphorus ester, 8.5 parts of talcum powder, 6 parts of quartz sand, 1.5 parts of antifoaming agent, 1.5 parts of levelling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810237600.8A CN108410329A (en) | 2018-03-22 | 2018-03-22 | A kind of fire-retardant epoxy resin coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810237600.8A CN108410329A (en) | 2018-03-22 | 2018-03-22 | A kind of fire-retardant epoxy resin coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108410329A true CN108410329A (en) | 2018-08-17 |
Family
ID=63133237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810237600.8A Pending CN108410329A (en) | 2018-03-22 | 2018-03-22 | A kind of fire-retardant epoxy resin coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108410329A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093013A (en) * | 2019-05-07 | 2019-08-06 | 安徽美佳新材料股份有限公司 | A kind of fire-retardant epoxy resin |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629043A (en) * | 2009-06-24 | 2010-01-20 | 邵阳市创捷化工有限公司 | Ferrous metal surface fireproof flame resistance paint and production method thereof |
| CN103396704A (en) * | 2013-08-22 | 2013-11-20 | 吴江市冰心文教用品有限公司 | Unexpansive type fireproof pigment |
| CN103642323A (en) * | 2013-10-16 | 2014-03-19 | 苏州瑞邦塑胶有限公司 | Interior wall thermal-insulation flame-retardant nano-coating |
| CN105683285A (en) * | 2013-11-12 | 2016-06-15 | 杰富意化学株式会社 | Phenolic resin composition, epoxy resin composition, and cured epoxy resin |
-
2018
- 2018-03-22 CN CN201810237600.8A patent/CN108410329A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629043A (en) * | 2009-06-24 | 2010-01-20 | 邵阳市创捷化工有限公司 | Ferrous metal surface fireproof flame resistance paint and production method thereof |
| CN103396704A (en) * | 2013-08-22 | 2013-11-20 | 吴江市冰心文教用品有限公司 | Unexpansive type fireproof pigment |
| CN103642323A (en) * | 2013-10-16 | 2014-03-19 | 苏州瑞邦塑胶有限公司 | Interior wall thermal-insulation flame-retardant nano-coating |
| CN105683285A (en) * | 2013-11-12 | 2016-06-15 | 杰富意化学株式会社 | Phenolic resin composition, epoxy resin composition, and cured epoxy resin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093013A (en) * | 2019-05-07 | 2019-08-06 | 安徽美佳新材料股份有限公司 | A kind of fire-retardant epoxy resin |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180817 |