CN108410263A - A kind of polywood paper water-based gloss oil and preparation method thereof - Google Patents
A kind of polywood paper water-based gloss oil and preparation method thereof Download PDFInfo
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- CN108410263A CN108410263A CN201810271473.3A CN201810271473A CN108410263A CN 108410263 A CN108410263 A CN 108410263A CN 201810271473 A CN201810271473 A CN 201810271473A CN 108410263 A CN108410263 A CN 108410263A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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Abstract
A kind of polywood paper water-based gloss oil and preparation method thereof, the polywood paper water-based gloss oil is composed of the following raw materials in parts by weight：50 68 parts of silicone acrylic emulsion, 58 parts of wax assistant, 0.5 2 parts of hand feeling agent, 0.05 0.15 parts of wetting agent, 10 17 parts of low mass molecule alcohol, 15.9 22.95 parts of deionized water；The present invention selects the homemade film-forming resin for having the silicone acrylic emulsion of " the siliceous shell of interior crosslinking core " unique texture as water-based gloss oil, and the resin pollution resistance is good, and water resistance is good, ensure that water-fast, the oil resistance of water-based gloss oil product of the present invention；Organosilicon acrylic resin and wax assistant are used cooperatively, and are conducive to the film compactness on enhancing gloss oil surface, are ensured the adhesive force and resistance to marring of film；The fissility of resistance to adhesive tape of product of the present invention is substantially better than commercially available oiliness gloss oil product；Used by the collocation of each auxiliary agent, ensure water-based gloss oil product of the present invention storage stability and it is good resist it is adhesive.
Description
(1) technical field
The present invention relates to water-based gloss oils and preparation method thereof, and in particular to a kind of water can apply to polywood paper printing surface
Property gloss oil and preparation method thereof.
(2) background technology
Polywood paper is to belong to one kind of furniture paper body paper ornament made of printing in 30-50 grams, can be direct
By decoration, protective effect machine is bonded or manual assembly is in furniture plate surface.Decoration function is mainly by the oil on polywood paper
Layer of ink provides, and protective effect then leans on the light oil reservoir on ink layer to provide.Traditional polywood paper ink and gloss oil be all it is solvent type,
In view of the Environmental Protection Situation of current sternness, polywood paper ink, gloss oil Water-borne modification process be increasingly urgent to.
(3) invention content
The purpose of the present invention is to provide a kind of polywood paper water-based gloss oils and preparation method thereof.
Technical scheme is as follows：
A kind of polywood paper water-based gloss oil, is composed of the following raw materials in parts by weight：
50-68 parts of silicone acrylic emulsion, 5-8 parts of wax assistant, 0.5-2 parts of hand feeling agent, 0.05-0.15 parts of wetting agent, low mass molecule alcohol
10-17 parts, 15.9-22.95 parts of deionized water.
The preparation method of the polywood paper water-based gloss oil is：
(1) 0.5-2 parts of hand feeling agents, 0.05-0.15 parts of wetting agents, 10-17 parts of low mass molecule alcohols, 8-10 parts of deionized waters are added
Into dispersion sand mill, 0.5-1h is stirred with the rate of 2000-3000rpm, obtains dispersion liquid, it is spare；
(2) 50-68 parts of silicone acrylic emulsions, 5-8 parts of wax assistants, 7.9-12.95 parts of deionized waters are added in dispersion sand mill,
It is uniformly mixed with the rate of 300-500rpm, then adds dispersion liquid obtained by step (1), rotating speed is kept to continue to stir
0.5-1h, filtering and discharging is to get the polywood paper water-based gloss oil.
In the present invention, the wax assistant is that one or more of oxypolymer wax, modified poly ester type wax are arbitrary
The mixture of ratio；The oxypolymer wax such as VISCOCER 1017 (CERONAS companies), VISCOCER 2016
(CERONAS companies), MD-2042 (KEIM companies)；(CERONAS is public by the modified poly ester type wax such as ADDIMER 696
Department), ADDIMER 697 (CERONAS companies), particularly preferred MD-2042 (KEIM companies).
The hand feeling agent be organic silicon hand feeling agent, specially SF-337 (Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.),
One in SF-337 (Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.), DL-203 (road silicon material technology (Shanghai) Co., Ltd.)
The mixture of kind or two or more arbitrary proportions, particularly preferred SF-337 (Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.).
The wetting agent be (modification) poly- alcoxyl alkane wetting agent, specially Levaslip W-461 (ELEMENTIS companies),
One or both of Levelol W-469 (ELEMENTIS companies), DW-390 (road silicon material technology (Shanghai) Co., Ltd.)
The mixture of any of the above ratio, particularly preferred Levaslip W-461 (ELEMENTIS companies).
The low mass molecule alcohol is the mixture of ethyl alcohol, a kind of or both arbitrary proportion in isopropanol, preferably isopropanol.
The silicone acrylic emulsion is the homemade silicone acrylic emulsion with " the siliceous shell of interior crosslinking core-" unique texture, by as follows
The raw material of parts by weight forms：
2~4 parts of response type anion emulsifier, 1.8~3.1 parts of response type nonionic emulsifier, pH buffer 0.2~
0.4 part, 1.5~2.3 parts of inorganic peroxy class initiator, 0.6~0.8 part of oxidizing initiators, reduction 0.55~0.6 part of initiator,
7~10 parts of methyl methacrylate monomer, 68~72 parts of n-butyl acrylate monomer, 20~25 parts of organosiloxane monomer, C1-
1.2~1.5 parts of C3 alcohol, 0.06~0.08 part of tert-butyl hydroperoxide, 0.06~0.08 part of rongalite, deionized water 126~
130 parts.
The response type anion emulsifier is selected from appointing in SE-10N (ADEKA companies), SE-1025A (ADEKA companies)
One or both of anticipating is with the mixture of arbitrary proportion, preferably SE-1025A (ADEKA companies).
The response type nonionic emulsifier is selected from ER-10 (ADEKA companies), ER-20 (ADEKA companies), ER-30
(ADEKA is public by (ADEKA companies), ER-40 (ADEKA companies), NE-10 (ADEKA companies), NE-20 (ADEKA companies), NE-30
Department) in any one or two or more arbitrary proportions mixture, preferably NE-10 (ADEKA companies).
Any one of the pH buffer in sodium bicarbonate, sodium carbonate, preferably sodium bicarbonate.
Any one of the inorganic peroxy class initiator in ammonium persulfate, potassium peroxydisulfate, sodium peroxydisulfate, preferably mistake
Sodium sulphate.
The oxidizing initiators are selected from hydroperoxide kind initiator, dialkyl class initiator, diacyl peroxides
Any one in class initiator, the hydroperoxide kind initiator such as hydrogen peroxide, isopropyl benzene hydroperoxide, the peroxide
Change dioxane base class initiator such as two different phenylpropyl alcohol of peroxidating, the peroxidating two acyl base class initiator such as diphenyl peroxide first
Acyl, particularly preferred isopropyl benzene hydroperoxide.
The reduction initiator is in tertiary amines initiator, thio-alcohol initiator, organo-metallic compound class initiator
Any one, the tertiary amines initiator such as N, N- dimethyl toluidines, the thio-alcohol initiator such as methyl mercaptan, second
Mercaptan, organo-metallic compound class the initiator such as triethyl aluminum, boron triethyl, particularly preferred N, N- dimethyl toluene
Amine.
The organosiloxane monomer is particularly preferably vinyl silane triisopropoxide (AC-76).
The mixing of any one or two or more arbitrary proportion of the C1-C3 alcohol in methanol, ethyl alcohol, isopropanol
Object, preferably isopropanol.
The preparation method of the silicone acrylic emulsion is：
(1) by 5 parts by weight of acrylic acid N-butyl monomers, 20~25 parts by weight organosiloxane monomers, 7~10 parts by weight first
Base methacrylate monomer, 0.6~0.8 parts by weight oxidizing initiators, 0.55~0.6 parts by weight reduction initiator, 1~2 weight
Part response type nonionic emulsifier mixing, and in the stirring and dissolving under stirring speed of 200~250rpm, obtain shell monomers and phase is added dropwise；
(2) by 2~4 parts by weight response type anion emulsifiers, 0.8~1.1 parts by weight response type nonionic emulsifier, 5
Parts by weight of acrylic acid N-butyl monomer is added in 102~106 parts by weight of deionized water, 400~750rpm stir speed under stir
And 86~88 DEG C are warming up to, reduction stirs speed to 150~250rpm, and 4.3 parts by weight of inorganic peroxide initiator solutions are added,
After apparent blue light occurs in reaction system, while 58~62 parts by weight of acrylic acid N-butyl monomers and 11.2~12 parts by weight are added dropwise
Inorganic peroxy class initiator solution, the two drip off simultaneously, and temperature of reaction system is down to 63 by time for adding later in 5~7h
~68 DEG C, be added 1.2~1.5 parts by weight C1-C3 alcohol, then simultaneously a dropping step (1) prepare shell monomers be added dropwise mutually and
The time for adding of phase is added dropwise in 2~3h, the pH buffer in 6.2~6.4 parts by weight pH buffer aqueous solutions, the shell monomers
The rate of addition of aqueous solution, which is subject to, maintains pH value of reaction system to be adjusted 5.5~7.5, the pH value of reaction system every
20min is surveyed once, and after shell monomers are added dropwise mutually and pH buffer solution is added dropwise, 1~1.5h of insulated and stirred is added 2.06
2.06~2.08 parts by weight rongalite are added in~2.08 parts by weight tert-butyl hydroperoxide aqueous solutions, 10~20min of insulated and stirred
Aqueous solution, 10~20min of insulated and stirred are finally down to (20~30 DEG C) dischargings of room temperature to get the silicone acrylic emulsion；
The 4.3 parts by weight of inorganic peroxide initiator solution is dissolved in 4 by 0.3 parts by weight of inorganic peroxide initiator
It is obtained in parts by weight of deionized water；
11.2~12 parts by weight of inorganic peroxide initiator solution is caused by 1.2~2 parts by weight of inorganic peroxides
Agent is dissolved in 10 parts by weight of deionized water and obtains；
6.2~6.4 parts by weight pH buffer aqueous solution is dissolved in 6 parts by weight by 0.2~0.4 parts by weight pH buffer
It is obtained in deionized water；
2.06~2.08 parts by weight tert-butyl hydroperoxide aqueous solution is by 0.06~0.08 parts by weight t-butyl peroxy
Change hydrogen, which is dissolved in 2 parts by weight of deionized water, to be obtained；
2.06~2.08 parts by weight rongalite aqueous solution is dissolved in 2 parts by weight by 0.06~0.08 parts by weight rongalite
It is obtained in deionized water.
Compared with prior art, the beneficial effects of the present invention are：
1, select the homemade silicone acrylic emulsion with " interior crosslinking core-siliceous shell " unique texture as water-based gloss oil at
Film resin, the resin pollution resistance is good, and water resistance is good, ensure that water-fast, the oil resistance of water-based gloss oil product of the present invention.
2, organosilicon acrylic resin and wax assistant are used cooperatively, and are conducive to the film compactness on enhancing gloss oil surface, are ensured film
Adhesive force and resistance to marring；The fissility of resistance to adhesive tape of product of the present invention is substantially better than commercially available oiliness gloss oil product.
3, it is used, ensure the storage stability of water-based gloss oil product of the present invention and good anti-sticked by the collocation of each auxiliary agent
Lian Xing.
(4) specific implementation mode
With reference to specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in
This.
The bin stability of gloss oil refers to that gloss oil stands 9 days under the conditions of 60 DEG C, not precipitate, it is not stratified represent gloss oil storage
Deposit stability>6 months.
Gloss oil resists adhesive test method as follows：This is sent out with the print speed printing speed of 40m/min with KPP gravure proof press
Bright water-based gloss oil or commercially available oiliness gloss oil are printed on polywood paper, are dried through 50 DEG C；By the back of the body of printing surface and another polywood paper
Face overlaps, and is placed under 2kg weights, and after hot pressing for 24 hours in 80 DEG C of air dry ovens, whether two polywood papers of observation are adhered feelings
Condition；If not being adhered, it was demonstrated that resisting for gloss oil is adhesive good.
The fissility of the resistance to adhesive tape test method of gloss oil is as follows：It will with the print speed printing speed of 40m/min with KPP gravure proof press
Water-based gloss oil of the present invention or commercially available oiliness gloss oil are printed on polywood paper, are dried through 50 DEG C；By adhesive tape sticking in gloss oil printing surface,
It tears rapidly, repeatedly, every time with new adhesive tape test；If adhesive tape removes 500 times or more printing surfaces still without breakage, it was demonstrated that
The gloss oil fissility of resistance to adhesive tape is excellent, and stripping just occurs for 100 times or more damaged, it was demonstrated that the gloss oil fissility of resistance to adhesive tape is good, removes 100
Following printing surface occurs as soon as breakage, and judgement gloss oil is removed intolerant to adhesive tape.
The water resistance test of gloss oil is measured by the assay method of GB/T 1733-1993.
The resistance to oil stains test method of gloss oil is as follows：This is sent out with the print speed printing speed of 40m/min with KPP gravure proof press
Bright water-based gloss oil or commercially available oiliness gloss oil are printed on polywood paper, are dried through 50 DEG C；Existed with the disposable dropper feeding oil droplets of 3mL
On gloss oil printing surface, if edible oil is impermeable, it was demonstrated that gloss oil is resistance to oil stains to be passed through.
Embodiment 1 prepares silicone acrylic emulsion
The raw material manufacturer used below：
(Noah's ark (Fugang) chemical material is limited by n-butyl acrylate monomer (Guangzhou Zhong Ye Chemical Co., Ltd.s), AC-76
Company), methyl methacrylate monomer (Guangzhou Zhong Ye Chemical Co., Ltd.s), isopropyl benzene hydroperoxide (SIGMA-ALDRICH
Company), N, N- dimethyl toluidines (Tianjin Zhong Xinkaitai Chemical Co., Ltd.s), NE-10 (ADEKA companies), SE-1025A
(China's chemistry scientific and technological (Jiangsu) is limited forever for (ADEKA companies), sodium peroxydisulfate (Suzhou Chemical Industry Science Co., Ltd of China Airlines Limited), isopropanol
Company), sodium bicarbonate (Shanghai Ai Bi chemical reagent Co., Ltd), tert-butyl hydroperoxide (the limited public affairs of 101 chemical industry of Shanghai
Department), rongalite (the auspicious Chemical Co., Ltd.s of Shanghai Feng).
The preparation of silicone acrylic emulsion：
(1) preparation of phase is added dropwise in shell monomers：
By 5g n-butyl acrylate monomers, 20g AC-76,7g methyl methacrylate monomers, 0.7g isopropylbenzene peroxidating
Hydrogen, 0.6g N, N- dimethyl toluidine, 1g NE-10 mixing, and in the stirring and dissolving under stirring speed of 200rpm, obtain shell list
Phase is added dropwise in body；
(2) 2g SE-1025A, 1g NE-10,5g n-butyl acrylate monomers are added in 106g deionized waters,
87 DEG C are stirred and be warming up to stirring under speed for 400rpm, and reduction stirs speed to 150rpm, and 4.3g sodium persulfate aqueous solutions (0.3g is added
Sodium peroxydisulfate is dissolved in 4g deionized waters and obtains), after apparent blue light occurs in reaction system, while 60g acrylic acid is added dropwise just
Butyl ester monomer and 12g sodium persulfate aqueous solutions (2g sodium peroxydisulfates are dissolved in 10g deionized waters and obtain), the two drips off simultaneously,
Temperature of reaction system is down to 68 DEG C by time for adding later in 5h, and 1.2g isopropanols are added, and then a dropping step (1) is made simultaneously
Phase and 6.2g sodium bicarbonate aqueous solutions (0.2g sodium bicarbonates are dissolved in 6g deionized waters and obtain), shell is added dropwise in standby shell monomers
The time for adding of layer monomer dropping phase in 2h, the rate of addition of sodium bicarbonate aqueous solution with maintain pH value of reaction system 5.5~
It is adjusted subject to 7.5, the pH value of reaction system is surveyed once every 20min, when phase and sodium bicarbonate water is added dropwise in shell monomers
After solution is added dropwise, 2.06g tert-butyl hydroperoxide aqueous solution (0.06g tert-butyl hydroperoxide is added in insulated and stirred 1.2h
It is dissolved in 2g deionized waters and obtains), insulated and stirred 10min, 2.06g rongalite aqueous solution is added, and (0.06g rongalite is dissolved in
Obtained in 2g deionized waters), insulated and stirred 10min, being finally down to room temperature discharging, (organic silicon monomer accounts for always to get silicone acrylic emulsion
Content of monomer 20.6%).
Embodiment 2 prepares silicone acrylic emulsion
The raw material manufacturer used below：
(Noah's ark (Fugang) chemical material is limited by n-butyl acrylate monomer (Guangzhou Zhong Ye Chemical Co., Ltd.s), AC-76
Company), methyl methacrylate monomer (Guangzhou Zhong Ye Chemical Co., Ltd.s), isopropyl benzene hydroperoxide (SIGMA-ALDRICH
Company), N, N- dimethyl toluidines (Tianjin Zhong Xinkaitai Chemical Co., Ltd.s), NE-10 (ADEKA companies), SE-1025A
(China's chemistry scientific and technological (Jiangsu) is limited forever for (ADEKA companies), sodium peroxydisulfate (Suzhou Chemical Industry Science Co., Ltd of China Airlines Limited), isopropanol
Company), sodium bicarbonate (Shanghai Ai Bi chemical reagent Co., Ltd), tert-butyl hydroperoxide (the limited public affairs of 101 chemical industry of Shanghai
Department), rongalite (the auspicious Chemical Co., Ltd.s of Shanghai Feng).
The preparation of silicone acrylic emulsion：
(1) preparation of phase is added dropwise in shell monomers：
By 5g n-butyl acrylate monomers, 21g AC-76,7g methyl methacrylate monomers, 0.6g isopropylbenzene peroxidating
Hydrogen, 0.55g N, N- dimethyl toluidine, 1.1g NE-10 mixing, and in the stirring and dissolving under stirring speed of 250rpm, obtain shell
Monomer dropping phase；
(2) 3g SE-1025A, 0.8g NE-10,5g n-butyl acrylate monomers are added in 103g deionized waters,
88 DEG C are stirred and be warming up to stirring under speed for 600rpm, and reduction stirs speed to 200rpm, and 4.3g sodium persulfate aqueous solutions (0.3g is added
Sodium peroxydisulfate is dissolved in 4g deionized waters and obtains), after apparent blue light occurs in reaction system, while 58g acrylic acid is added dropwise just
Butyl ester monomer and 11.2g sodium persulfate aqueous solutions (1.2g sodium peroxydisulfates are dissolved in 10g deionized waters and obtain), the two is dripped simultaneously
Complete, temperature of reaction system is down to 64 DEG C by time for adding later in 6h, and 1.5g isopropanols are added, then a dropping step (1) simultaneously
Phase and 6.2g sodium bicarbonate aqueous solutions (0.2g sodium bicarbonates are dissolved in 6g deionized waters and obtain) is added dropwise in the shell monomers of preparation,
The time for adding of phase is added dropwise in 2h in shell monomers, and the rate of addition of sodium bicarbonate aqueous solution is to maintain pH value of reaction system 5.5
It is adjusted subject to~7.5, the pH value of reaction system is surveyed once every 20min, when phase and sodium bicarbonate is added dropwise in shell monomers
After aqueous solution is added dropwise, 2.06g tert-butyl hydroperoxide aqueous solution (0.06g tert-butyl hydroperoxide is added in insulated and stirred 1h
It is dissolved in 2g deionized waters and obtains), insulated and stirred 20min, 2.06g rongalite aqueous solution is added, and (0.06g rongalite dissolves
Obtained in 2g deionized waters), insulated and stirred 20min, being finally down to room temperature discharging, (organic silicon monomer accounts for get silicone acrylic emulsion
Total monomer content 21.9%).
Embodiment 3 prepares silicone acrylic emulsion
The raw material manufacturer used below：
(Noah's ark (Fugang) chemical material is limited by n-butyl acrylate monomer (Guangzhou Zhong Ye Chemical Co., Ltd.s), AC-76
Company), methyl methacrylate monomer (Guangzhou Zhong Ye Chemical Co., Ltd.s), isopropyl benzene hydroperoxide (SIGMA-ALDRICH
Company), N, N- dimethyl toluidines (Tianjin Zhong Xinkaitai Chemical Co., Ltd.s), NE-10 (ADEKA companies), SE-1025A
(China's chemistry scientific and technological (Jiangsu) is limited forever for (ADEKA companies), sodium peroxydisulfate (Suzhou Chemical Industry Science Co., Ltd of China Airlines Limited), isopropanol
Company), sodium bicarbonate (Shanghai Ai Bi chemical reagent Co., Ltd), tert-butyl hydroperoxide (the limited public affairs of 101 chemical industry of Shanghai
Department), rongalite (the auspicious Chemical Co., Ltd.s of Shanghai Feng).
The preparation of silicone acrylic emulsion：
(1) preparation of phase is added dropwise in shell monomers：
By 5g n-butyl acrylate monomers, 25g AC-76,10g methyl methacrylate monomers, 0.8g isopropylbenzene peroxidating
Hydrogen, 0.6g N, N- dimethyl toluidine, 2g NE-10 mixing, and in the stirring and dissolving under stirring speed of 250rpm, obtain shell list
Phase is added dropwise in body；
(2) 4g SE-1025A, 1.1g NE-10,5g n-butyl acrylate monomers are added in 102g deionized waters,
88 DEG C are stirred and be warming up to stirring under speed for 750rpm, and reduction stirs speed to 250rpm, and 4.3g sodium persulfate aqueous solutions (0.3g is added
Sodium peroxydisulfate is dissolved in 4g deionized waters and obtains), after apparent blue light occurs in reaction system, while 62g acrylic acid is added dropwise just
Butyl ester monomer and 12g sodium persulfate aqueous solutions (2g sodium peroxydisulfates are dissolved in 10g deionized waters and obtain), the two drips off simultaneously,
Temperature of reaction system is down to 63 DEG C by time for adding later in 7h, and 1.5g isopropanols are added, and then a dropping step (1) is made simultaneously
Phase and 6.4g sodium bicarbonate aqueous solutions (0.4g sodium bicarbonates are dissolved in 6g deionized waters and obtain), shell is added dropwise in standby shell monomers
The time for adding of layer monomer dropping phase in 2h, the rate of addition of sodium bicarbonate aqueous solution with maintain pH value of reaction system 5.5~
It is adjusted subject to 7.5, the pH value of reaction system is surveyed once every 20min, when phase and sodium bicarbonate water is added dropwise in shell monomers
After solution is added dropwise, 2.08g tert-butyl hydroperoxide aqueous solution (0.08g tert-butyl hydroperoxide is added in insulated and stirred 1.5h
It is dissolved in 2g deionized waters and obtains), insulated and stirred 10min, 2.08g rongalite aqueous solution is added, and (0.08g rongalite is dissolved in
Obtained in 2g deionized waters), insulated and stirred 10min, being finally down to room temperature discharging, (organic silicon monomer accounts for always to get silicone acrylic emulsion
Content of monomer 23.4%).
Embodiment 4 prepares polywood paper water-based gloss oil
The raw material used below and instrument manufacturer facility man：
SF-337 (Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.), Levaslip W-461 (ELEMENTIS companies), isopropyl
Alcohol (scientific and technological (Jiangsu) Co., Ltd of China's chemistry forever), MD-2042 (KEIM companies)；
Disperse sand mill (SDF400 experiment dispersion sand mills, Shuan Feng chemical machineries Co., Ltd of Jiangyin City).
The preparation of polywood paper water-based gloss oil
(1) 2g SF-337,0.05g Levaslip W-461,17g isopropanols, 10g deionized waters dispersion is added to be sanded
In machine, 0.5h is stirred with the rate of 2000rpm, obtains dispersion liquid, is taken out spare；
(2) silicone acrylic emulsion, 8g MD-2042,12.95g deionized waters prepared by 50g embodiments 1 are added to dispersion sand mill
In, it is uniformly mixed with the rate of 400rpm；Then dispersion liquid obtained by step (1) is slowly added into dispersion sand mill, is kept
Rotating speed stirs 0.5h filtering and dischargings, obtains polywood paper water-based gloss oil.
Embodiment 5 prepares polywood paper water-based gloss oil
The raw material used below and instrument manufacturer facility man：
SF-337 (Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.), Levaslip W-461 (ELEMENTIS companies), isopropyl
Alcohol (scientific and technological (Jiangsu) Co., Ltd of China's chemistry forever), MD-2042 (KEIM companies)；
Disperse sand mill (SDF400 experiment dispersion sand mills, Shuan Feng chemical machineries Co., Ltd of Jiangyin City).
The preparation of polywood paper water-based gloss oil
(1) 1g SF-337,0.1g Levaslip W-461,16g isopropanols, 8g deionized waters are added to dispersion sand mill
In, 1h is stirred with the rate of 3000rpm, obtains dispersion liquid, is taken out spare；
(2) silicone acrylic emulsion, 7g MD-2042,7.9g deionized waters prepared by 60g embodiments 2 are added to dispersion sand mill
In, it is uniformly mixed with the rate of 500rpm；Then dispersion liquid obtained by step (1) is slowly added into dispersion sand mill, is kept
Rotating speed stirs 1h filtering and dischargings, obtains polywood paper water-based gloss oil.
Embodiment 6 prepares polywood paper water-based gloss oil
The raw material used below and instrument manufacturer facility man：
SF-337 (Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.), Levaslip W-461 (ELEMENTIS companies), isopropyl
Alcohol (scientific and technological (Jiangsu) Co., Ltd of China's chemistry forever), MD-2042 (KEIM companies)；
Disperse sand mill (SDF400 experiment dispersion sand mills, Shuan Feng chemical machineries Co., Ltd of Jiangyin City).
The preparation of polywood paper water-based gloss oil
(1) 0.6g SF-337,0.1g Levaslip W-461,13g isopropanols, 8g deionized waters dispersion is added to be sanded
In machine, 1h is stirred with the rate of 3000rpm, obtains dispersion liquid, is taken out spare；
(2) silicone acrylic emulsion, 7g MD-2042,8.3g deionized waters prepared by 63g embodiments 3 are added to dispersion sand mill
In, it is uniformly mixed with the rate of 300rpm；Then dispersion liquid obtained by step (1) is slowly added into dispersion sand mill, is kept
Rotating speed stirs 0.5h filtering and dischargings, obtains polywood paper water-based gloss oil.
Embodiment 7 prepares polywood paper water-based gloss oil
The raw material used below and instrument manufacturer facility man：
SF-337 (Guangdong Biaomei Silicon and Fluoride New Materials Co., Ltd.), Levaslip W-461 (ELEMENTIS companies), isopropyl
Alcohol (scientific and technological (Jiangsu) Co., Ltd of China's chemistry forever), MD-2042 (KEIM companies)；
Disperse sand mill (SDF400 experiment dispersion sand mills, Shuan Feng chemical machineries Co., Ltd of Jiangyin City).
The preparation of polywood paper water-based gloss oil
(1) 0.5g SF-337,0.15g Levaslip W-461,10g isopropanols, 8g deionized waters are added to dispersion sand
In grinding machine, 1h is stirred with the rate of 3000rpm, obtains dispersion liquid, is taken out spare；
(2) silicone acrylic emulsion, 5g MD-2042,8.35g deionized waters prepared by 68g embodiments 3 are added to dispersion sand mill
In, it is uniformly mixed with the rate of 500rpm；Then dispersion liquid obtained by step (1) is slowly added into dispersion sand mill, is kept
Rotating speed stirs 1h filtering and dischargings, obtains polywood paper water-based gloss oil.
1. embodiment of table, 4~7 experimental result
As seen from the results in Table 1, polywood paper water-based gloss oil storage stability of the present invention is good, and product resists adhesive, water resistance
And it is resistance to oil stains suitable with commercially available oiliness gloss oil, water-based gloss oil product, the fissility of resistance to adhesive tape is better than oiliness gloss oil, water-based gloss oil
Product is expected to that commercially available oiliness gloss oil, water-based gloss oil is replaced to be applied in polywood paper printing industry.
Above-described embodiment is used for illustrating the present invention, rather than limits the invention, the present invention spirit and
In scope of the claims, to any modifications and changes that the present invention makes, protection scope of the present invention is both fallen within.
Claims (8)
1. a kind of polywood paper water-based gloss oil, which is characterized in that be composed of the following raw materials in parts by weight：
50-68 parts of silicone acrylic emulsion, 5-8 parts of wax assistant, 0.5-2 parts of hand feeling agent, 0.05-0.15 parts of wetting agent, low mass molecule alcohol 10-17
Part, 15.9-22.95 parts of deionized water；
Wherein, the wax assistant is the mixed of one or more of oxypolymer wax, modified poly ester type wax arbitrary proportion
Close object；
The hand feeling agent is organic silicon hand feeling agent；
The wetting agent is modified poly- alcoxyl alkane wetting agent；
The silicone acrylic emulsion is composed of the following raw materials in parts by weight：2~4 parts of response type anion emulsifier, response type nonionic
1.8~3.1 parts of emulsifier, 0.2~0.4 part of pH buffer, 1.5~2.3 parts of inorganic peroxy class initiator, oxidizing initiators 0.6
~0.8 part, reduction 0.55~0.6 part of initiator, 7~10 parts of methyl methacrylate monomer, n-butyl acrylate monomer 68~
72 parts, 20~25 parts of organosiloxane monomer, 1.2~1.5 parts of C1-C3 alcohol, 0.06~0.08 part of tert-butyl hydroperoxide, carving it is white
0.06~0.08 part of powder, 126~130 parts of deionized water.
2. polywood paper water-based gloss oil as described in claim 1, which is characterized in that the wax assistant be VISCOCER 1017,
The mixing of one or more of VISCOCER 2016, MD-2042, ADDIMER 696, ADDIMER 697 arbitrary proportions
Object.
3. polywood paper water-based gloss oil as described in claim 1, which is characterized in that the hand feeling agent be SF-337, SF-337,
The mixture of one or more of DL-203 arbitrary proportions.
4. polywood paper water-based gloss oil as described in claim 1, which is characterized in that the wetting agent be Levaslip W-461,
The mixture of one or more of Levelol W-469, DW-390 arbitrary proportions.
5. polywood paper water-based gloss oil as described in claim 1, which is characterized in that the low mass molecule alcohol is in ethyl alcohol, isopropanol
A kind of or both arbitrary proportion mixture.
6. polywood paper water-based gloss oil as described in claim 1, which is characterized in that in the raw material composition of the silicone acrylic emulsion：
Any one of the response type anion emulsifier in SE-10N, SE-1025A or both is with the mixed of arbitrary proportion
Close object；
The response type nonionic emulsifier appointing in ER-10, ER-20, ER-30, ER-40, NE-10, NE-20, NE-30
The mixture of the one or more kinds of arbitrary proportions of meaning；
Any one of the pH buffer in sodium bicarbonate, sodium carbonate；
Any one of the inorganic peroxy class initiator in ammonium persulfate, potassium peroxydisulfate, sodium peroxydisulfate；
The oxidizing initiators are selected from hydroperoxide kind initiator, dialkyl class initiator, peroxidating two acyl base class and draw
Send out any one in agent；
Reduction initiator the appointing in tertiary amines initiator, thio-alcohol initiator, organo-metallic compound class initiator
Meaning is a kind of；
The organosiloxane monomer is vinyl silane triisopropoxide；
The mixture of any one or two or more arbitrary proportion of the C1-C3 alcohol in methanol, ethyl alcohol, isopropanol.
7. polywood paper water-based gloss oil as described in claim 1, which is characterized in that the preparation method of the silicone acrylic emulsion is：
(1) by 5 parts by weight of acrylic acid N-butyl monomers, 20~25 parts by weight organosiloxane monomers, 7~10 parts by weight methyl-props
E pioic acid methyl ester monomer, 0.6~0.8 parts by weight oxidizing initiators, 0.55~0.6 parts by weight reduction initiator, 1~2 parts by weight are anti-
It answers type nonionic emulsifier to mix, and in the stirring and dissolving under stirring speed of 200~250rpm, obtains shell monomers and phase is added dropwise；
(2) by 2~4 parts by weight response type anion emulsifiers, 0.8~1.1 parts by weight response type nonionic emulsifier, 5 weight
Part n-butyl acrylate monomer is added in 102~106 parts by weight of deionized water, 400~750rpm stir speed under stir and rise
For temperature to 86~88 DEG C, reduction stirs speed to 150~250rpm, and 4.3 parts by weight of inorganic peroxide initiator solutions are added, wait reacting
After apparent blue light occurs in system, while 58~62 parts by weight of acrylic acid N-butyl monomers and 11.2~12 parts by weight of inorganic mistakes are added dropwise
Oxygen class initiator solution, the two drip off simultaneously, and temperature of reaction system is down to 63~68 DEG C by time for adding later in 5~7h,
1.2~1.5 parts by weight C1-C3 alcohol are added, phase and 6.2~6.4 weights are added dropwise in the shell monomers that then simultaneously prepared by a dropping step (1)
Part pH buffer aqueous solution is measured, the time for adding of phase is added dropwise in 2~3h, the drop of the pH buffer aqueous solution in the shell monomers
Acceleration, which is subject to, maintains pH value of reaction system to be adjusted 5.5~7.5, and the pH value of reaction system surveys one every 20min
Secondary, after shell monomers are added dropwise mutually and pH buffer solution is added dropwise, 2.06~2.08 weights are added in 1~1.5h of insulated and stirred
Part tert-butyl hydroperoxide aqueous solution is measured, 2.06~2.08 parts by weight rongalite aqueous solutions are added in 10~20min of insulated and stirred,
10~20min of insulated and stirred is finally down to room temperature discharging to get the silicone acrylic emulsion；
The 4.3 parts by weight of inorganic peroxide initiator solution is dissolved in 4 weight by 0.3 parts by weight of inorganic peroxide initiator
It is obtained in part deionized water；
11.2~12 parts by weight of inorganic peroxide initiator solution is molten by 1.2~2 parts by weight of inorganic peroxide initiators
Solution obtains in 10 parts by weight of deionized water；
6.2~6.4 parts by weight pH buffer aqueous solution by 0.2~0.4 parts by weight pH buffer be dissolved in 6 parts by weight go from
It is obtained in sub- water；
2.06~2.08 parts by weight tert-butyl hydroperoxide aqueous solution is by 0.06~0.08 parts by weight tert-butyl hydroperoxide
It is dissolved in 2 parts by weight of deionized water and obtains；
2.06~2.08 parts by weight rongalite aqueous solution by 0.06~0.08 parts by weight rongalite be dissolved in 2 parts by weight go from
It is obtained in sub- water.
8. the preparation method of polywood paper water-based gloss oil as described in claim 1, which is characterized in that the preparation method is that：
(1) 0.5-2 parts of hand feeling agents, 0.05-0.15 parts of wetting agents, 10-17 parts of low mass molecule alcohols, 8-10 parts of deionized waters are added to point
In loose sand grinding machine, 0.5-1h is stirred with the rate of 2000-3000rpm, obtains dispersion liquid, it is spare；
(2) 50-68 parts of silicone acrylic emulsions, 5-8 parts of wax assistants, 7.9-12.95 parts of deionized waters are added in dispersion sand mill, with
The rate of 300-500rpm is uniformly mixed, and then adds dispersion liquid obtained by step (1), and rotating speed is kept to continue to stir 0.5-
1h, filtering and discharging is to get the polywood paper water-based gloss oil.
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| CN111334152A (en) * | 2020-04-17 | 2020-06-26 | 杭州海维特化工科技有限公司 | Water-based flame-retardant gloss oil and preparation method thereof |
| CN115368799A (en) * | 2022-09-26 | 2022-11-22 | 杭州海维特化工科技有限公司 | Degradable water-based antibacterial gloss oil and preparation method thereof |
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