CN108410110A - A kind of optical instrument fiber panel functional glass - Google Patents
A kind of optical instrument fiber panel functional glass Download PDFInfo
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- CN108410110A CN108410110A CN201810505210.4A CN201810505210A CN108410110A CN 108410110 A CN108410110 A CN 108410110A CN 201810505210 A CN201810505210 A CN 201810505210A CN 108410110 A CN108410110 A CN 108410110A
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- 239000011521 glass Substances 0.000 title claims abstract description 44
- 239000000835 fiber Substances 0.000 title claims abstract description 21
- 230000003287 optical effect Effects 0.000 title claims abstract description 19
- 239000003365 glass fiber Substances 0.000 claims abstract description 66
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 15
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 230000000640 hydroxylating effect Effects 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 4
- 229940071870 hydroiodic acid Drugs 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000005491 wire drawing Methods 0.000 claims description 4
- 102000009027 Albumins Human genes 0.000 claims description 3
- 108010088751 Albumins Proteins 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000008280 blood Substances 0.000 claims description 3
- 210000004369 blood Anatomy 0.000 claims description 3
- 238000012662 bulk polymerization Methods 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000008236 heating water Substances 0.000 claims description 3
- 238000007781 pre-processing Methods 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 2
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- VWSUVZVPDQDVRT-UHFFFAOYSA-N phenylperoxybenzene Chemical class C=1C=CC=CC=1OOC1=CC=CC=C1 VWSUVZVPDQDVRT-UHFFFAOYSA-N 0.000 claims description 2
- 238000005498 polishing Methods 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 235000019353 potassium silicate Nutrition 0.000 claims 1
- 239000005394 sealing glass Substances 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 abstract description 4
- 230000009467 reduction Effects 0.000 abstract description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 241000282898 Sus scrofa Species 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses a kind of optical instrument fiber panel functional glass, including organic glass and modified glass-fiber film layer, the modified glass-fiber film layer is covered in the surface of organic glass, and the thickness of the modified glass-fiber film layer is 1 ~ 3mm, and the thickness of the organic glass is 6 ~ 12mm.In one layer of modified glass fibre film layer of surface inserting of organic glass, glass fibre is after by being modified, with better electric conductivity, pretreated process is also very important, and glass fibre is being more prone to be adsorbed with the graphene oxide with negative electrical charge after pretreatment, and last graphene oxide reduction is coated on fiberglass surfacing later, with good toughness and electric conductivity, for the preparation of optical instrument fiber panel, there is high temperature resistant, safe and reliable feature.
Description
Technical field
The present invention relates to the technical field of optical instrument more particularly to a kind of optical instrument fiber panel functional glass.
Background technology
Glass fibre as a kind of technical fiber material, be by glass raw material under high temperature fused state wire drawing prepare and
At with a series of excellent performances such as high temperature resistant, resist chemical, intensity height, modulus height.It is multiple that glass fibre has become resin base
One of most important reinforcing material of condensation material has obtained abundant application in fields such as Aeronautics and Astronautics, naval vessel, chemical industry metallurgicals.
With the fast development of large scale integrated circuit and becoming increasingly popular for electronic equipment, electromagnetic wave not only influences equipment
Normal work, but also the leakage of information can be caused, but the engineering plastics as electronic component shell are to electronic product
The electromagnetic wave of generation is without any shielding action.Therefore, electromagnetic shielding material also has been to be concerned by more and more people, and assigns macromolecule
Composite material will effectively solve the problems, such as electromagnetic shielding with electric conductivity.
The glass fibre membrane that general organic glass surface plates is made when glass fibre is by pretreated process
For optical instrument fiber panel functional glass, often under the high temperature conditions, application effect is poor, is extremely difficult to expected effect
Fruit, the present invention mainly improve the modification of glass fibre/graphene, and application of the modified glass-fiber on organic glass surface is turned up and imitates
Fruit.
Invention content
In view of the deficiencies of the prior art, the present invention provides a kind of optical instrument fiber panel functional glass, have resistance to height
Temperature, electric conductivity are more preferable, the longer advantage of physical life.
The present invention is realized by following technological means solves above-mentioned technical problem：
A kind of optical instrument fiber panel functional glass, including organic glass and modified glass-fiber film layer, the modified glass
Glass fiber film layer is covered in the surface of organic glass, and the thickness of the modified glass-fiber film layer is 1 ~ 3mm, the organic glass
Thickness be 6 ~ 12mm.
Preferably, a kind of preparation method of optical instrument fiber panel functional glass includes following steps,
（1）In reaction kettle, Methyl Methacrylate Bulk Polymerization material, the 50 ~ 100g diphenyl peroxides of 30 ~ 80L is first added
The dibutyl phthalate catalyst of formyl initiator and 2 ~ 4L, after dibenzoyl peroxide solid powder is completely dissolved,
Reaction kettle is placed under water bath condition, heating water bath keeps the temperature and is stirred continuously to 85 ~ 95 DEG C, obtains sticky slurries, finally exists
It fills and is cooled to 40 ~ 50 DEG C in the cooling bay of cold water, pour into mold, seal material filling mouth；
（2）Low temperature pre-polymerization：It will（1）The mold for being marked with slurries is put into 50 DEG C of baking oven, and it is poly- that 5 ~ 10h of heat preservation carries out low temperature
It closes；
（3）High temperature polymerization：When（2）Polymerization after the completion of obtain soft and transparent solid, be warming up at 100 ~ 120 DEG C continue polymerization 2 ~
4h is allowed to react completely, uniformly sprays powdery modified glass-fiber after the completion, and carrying out pressing processing makes organic glass surface and change
Property glass fibre powder combine together, be cooled to 30 ~ 40 DEG C, put it into water and impregnate, finally using be sanded wheel carry out it is organic
Glass surface is polishing to smooth formation modified glass-fiber film layer.
Preferably, the modified glass-fiber powder is that wire drawing prepares glass fibers under high temperature fused state by glass raw material
Dimension crushes, and the length that is ground into of gained glass fibre is the powdered of 1 ~ 2mm, by glass fibre powder by pre-processing, then
Carry out the modification of graphene.
Preferably, the pretreatment of the glass fibre powder is to calcine 90 ~ 110min under the conditions of 450 ~ 500 DEG C to remove table
Face size, then soaking and washing handles 45 ~ 60min in acetone soln, and the hydrochloric acid solution of 3mol/L is used to carry out after the completion
Hydroxylating handles 60 ~ 70min, is dried for standby at 60 DEG C after washing, and the glass fiber sample of gained hydroxylating processing is immersed in
60 ~ 100min in pig blood albumin soln, is cleaned after the completion, and is dried for standby in draught cupboard.
Preferably, the modifying process of the graphene is the graphene oxide dispersion for configuring 0.1wt%, adjusts pH and is
5.0 ~ 5.5, pretreated glass fibre is added into graphene oxide dispersion, 30 ~ 40min is stood, during which suitably stirs
It mixes, is dried for standby to obtain glass fibre/graphene oxide with distilled water flushing and at 60 DEG C after the completion, configure hydroiodic acid:Acetic acid
1:The mixed liquor of 2.5 volume ratio, holds in reaction kettle, glass fibre/graphene oxide is added, after sealing under the conditions of 40 DEG C
Modified glass-fiber powder is obtained after being restored.
Preferably, the graphene oxide is the graphene oxide prepared using Hummers methods.
The diffraction maximum of graphene oxide sample is measured using x ray diffractometer x, it is found that diffraction maximum is sharp, illustrated graphene
Crystal property is good, space structure arranged regular, and remaining graphene, the figure that graphene oxide passes through infrared analysis collection of illustrative plates is not present
In as can be seen that functional group of the graphite through peroxidating rear surface become abundant, after strong acid aoxidizes, graphene oxide mainly contains
There are hydroxyl, carbonyl, carboxyl functional group, these functional groups are easily and hydrone forms hydrogen bond, show good hydrophily.
Using the protein modified fiberglass surfacing of Swine serum, the glass fibre that surface is in positive charge is obtained, is inhaled by electrostatic
Graphene oxide with negative electrical charge is coated on the surface of glass fibre by attached effect, then, is coated on using hydroiodic acid reduction
The graphene oxide of fiberglass surfacing obtains the glass fibre composite conducting material of graphene coated, and conductivity is in 4.5S/
M or more reaches conducting grades, can be used for weaving anti-electromagnetic-radiation conductive fabric, and gained electroconductive glass fibre material has certain
Flexibility, after being bent different angle, conductivity has almost no change, while electroconductive glass fibre also has certain heat steady
It is qualitative, it can use at relatively high temperatures, relative to other electroconductive molecule fibers, have and be more widely applied range.
The advantage of the invention is that：In one layer of modified glass fibre film layer of surface inserting of organic glass, glass fibers
Dimension has better electric conductivity after by being modified, and pretreated process is also very important, and glass fibre is by pre-
What is be more prone to after processing is adsorbed with the graphene oxide with negative electrical charge, and last graphene oxide reduction is coated on later
Fiberglass surfacing has good toughness and electric conductivity, is used for the preparation of optical instrument fiber panel, has high temperature resistant,
Safe and reliable feature.
Description of the drawings
Fig. 1：For schematic structural view of the invention.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention
In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is
A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art
The every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
Embodiment：
As shown in Figure 1：A kind of optical instrument fiber panel functional glass, including organic glass 1 and modified glass-fiber film layer
2, the modified glass-fiber film layer 2 is covered in the surface of organic glass 1, and the thickness of the modified glass-fiber film layer 2 is 1 ~
The thickness of 3mm, the organic glass 1 are 6 ~ 12mm.
The preparation method of the optical instrument fiber panel functional glass, including following steps,
（1）In reaction kettle, the Methyl Methacrylate Bulk Polymerization material of 50L is first added, 60g dibenzoyl peroxides cause
The dibutyl phthalate catalyst of agent and 2 ~ 4L, after dibenzoyl peroxide solid powder is completely dissolved, by reaction kettle
It is placed under water bath condition, heating water bath keeps the temperature and is stirred continuously to 85 ~ 95 DEG C, obtains sticky slurries, is finally filling cold water
Cooling bay in be cooled to 45 DEG C, pour into mold, seal material filling mouth；
（2）Low temperature pre-polymerization：It will（1）The mold for being marked with slurries is put into 50 DEG C of baking oven, and heat preservation 6h carries out low temperature polymerization；
（3）High temperature polymerization：When（2）Soft and transparent solid is obtained after the completion of polymerization, continuation polyase 13 h at 110 DEG C is warming up to, is allowed to
Powdery modified glass-fiber is uniformly sprayed in reaction completely after the completion, and carrying out pressing processing makes organic glass surface and modified glass
Fiber dust combines together, is cooled to 35 DEG C, puts it into water and impregnate, and finally takes turns progress organic glass surface using sand milling and beats
It is milled to smooth formation modified glass-fiber film layer.
The modified glass-fiber powder is that wire drawing prepares glass fibre, powder under high temperature fused state by glass raw material
Broken, the length that is ground into of gained glass fibre is then the powdered of 1 ~ 2mm carries out by glass fibre powder by pre-processing
The modification of graphene.
The pretreatment of the glass fibre powder is to calcine 90min under the conditions of 500 DEG C to remove surface size, is then existed
Soaking and washing handles 45min in acetone soln, uses the hydrochloric acid solution of 3mol/L to carry out hydroxylating after the completion and handles 70min, water
It being dried for standby at 60 DEG C after washing, the glass fiber sample of gained hydroxylating processing is immersed in 80min in pig blood albumin soln,
It cleans, and is dried for standby in draught cupboard after the completion.
The modifying process of the graphene is the graphene oxide dispersion for configuring 0.1wt%, and it is 5.0 to adjust pH, will be pre-
Treated, and glass fibre is added into graphene oxide dispersion, stands 40min, during which suitably stirs, after the completion with distillation
Water rinses and is dried for standby at 60 DEG C to obtain glass fibre/graphene oxide, configures hydroiodic acid:Acetic acid 1:2.5 volume ratio
Mixed liquor is held in reaction kettle, and glass fibre/graphene oxide is added, is obtained after being restored under the conditions of 40 DEG C after sealing
Modified glass-fiber powder.
The graphene oxide is the graphene oxide prepared using Hummers methods.
It should be noted that herein, if there are first and second or the like relational terms to be used merely to one
A entity or operation with another entity or operate distinguish, without necessarily requiring or implying these entities or operation it
Between there are any actual relationship or orders.Moreover, the terms "include", "comprise" or its any other variant are intended to
Cover non-exclusive inclusion, so that the process, method, article or equipment including a series of elements includes not only those
Element, but also include other elements that are not explicitly listed, or further include for this process, method, article or setting
Standby intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in the process, method, article or apparatus that includes the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, it will be understood by those of ordinary skill in the art that：It still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features；And these modification or
It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.
Claims (6)
1. a kind of optical instrument fiber panel functional glass, it is characterised in that：Including organic glass and modified glass-fiber film
Layer, the modified glass-fiber film layer are covered in the surface of organic glass, and the thickness of the modified glass-fiber film layer is 1 ~
The thickness of 3mm, the organic glass are 6 ~ 12mm.
2. a kind of preparation method of optical instrument fiber panel functional glass according to claim 1, it is characterised in that：Packet
Include following steps,
（1）In reaction kettle, Methyl Methacrylate Bulk Polymerization material, the 50 ~ 100g diphenyl peroxides of 30 ~ 80L is first added
The dibutyl phthalate catalyst of formyl initiator and 2 ~ 4L, after dibenzoyl peroxide solid powder is completely dissolved,
Reaction kettle is placed under water bath condition, heating water bath keeps the temperature and is stirred continuously to 85 ~ 95 DEG C, obtains sticky slurries, finally exists
It fills and is cooled to 40 ~ 50 DEG C in the cooling bay of cold water, pour into mold, seal material filling mouth；
（2）Low temperature pre-polymerization：It will（1）The mold for being marked with slurries is put into 50 DEG C of baking oven, and it is poly- that 5 ~ 10h of heat preservation carries out low temperature
It closes；
（3）High temperature polymerization：When（2）Polymerization after the completion of obtain soft and transparent solid, be warming up at 100 ~ 120 DEG C continue polymerization 2 ~
4h is allowed to react completely, uniformly sprays powdery modified glass-fiber after the completion, and carrying out pressing processing makes organic glass surface and change
Property glass fibre powder combine together, be cooled to 30 ~ 40 DEG C, put it into water and impregnate, finally using be sanded wheel carry out it is organic
Glass surface is polishing to smooth formation modified glass-fiber film layer.
3. a kind of preparation method of optical instrument fiber panel functional glass according to claim 2, it is characterised in that：Institute
It is that wire drawing prepares glass fibre under high temperature fused state by glass raw material to state modified glass-fiber powder, is crushed, gained glass
The length that is ground into of fiber is the powdered of 1 ~ 2mm, by glass fibre powder by pre-processing, then carries out changing for graphene
Property.
4. a kind of preparation method of optical instrument fiber panel functional glass according to claim 3, it is characterised in that：Institute
The pretreatment for stating glass fibre powder is to calcine 90 ~ 110min under the conditions of 450 ~ 500 DEG C to remove surface size, then third
In ketone solution soaking and washing handle 45 ~ 60min, after the completion use 3mol/L hydrochloric acid solution carry out hydroxylating processing 60 ~
70min is dried for standby after washing at 60 DEG C, and the glass fiber sample of gained hydroxylating processing is immersed in pig blood albumin soln
In 60 ~ 100min, clean after the completion, and be dried for standby in draught cupboard.
5. a kind of preparation method of optical instrument fiber panel functional glass according to claim 3, it is characterised in that：Institute
The modifying process for stating graphene is the graphene oxide dispersion for configuring 0.1wt%, and it is 5.0 ~ 5.5 to adjust pH, after pretreatment
Glass fibre be added into graphene oxide dispersion, stand 30 ~ 40min, during which suitably stir, rushed after the completion with distilled water
Glass fibre/graphene oxide is washed and be dried for standby at 60 DEG C to obtain, hydroiodic acid is configured:Acetic acid 1:The mixing of 2.5 volume ratio
Liquid is held in reaction kettle, and glass fibre/graphene oxide is added, is modified after being restored under the conditions of 40 DEG C after sealing
Glass fibre powder.
6. a kind of preparation method of optical instrument fiber panel functional glass according to claim 5, it is characterised in that：Institute
It is the graphene oxide prepared using Hummers methods to state graphene oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810505210.4A CN108410110B (en) | 2018-05-24 | 2018-05-24 | Functional glass for optical instrument fiber panel |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810505210.4A CN108410110B (en) | 2018-05-24 | 2018-05-24 | Functional glass for optical instrument fiber panel |
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| Publication Number | Publication Date |
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| CN108410110A true CN108410110A (en) | 2018-08-17 |
| CN108410110B CN108410110B (en) | 2020-07-17 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102092163A (en) * | 2010-12-09 | 2011-06-15 | 苏州工业园区科逸卫浴设备有限公司 | Glassfibre reinforced plastics and preparation method thereof |
| CN104520793A (en) * | 2012-09-27 | 2015-04-15 | 东丽株式会社 | Transparent conductive laminate |
| CN105294959A (en) * | 2015-07-31 | 2016-02-03 | 泰山玻璃纤维有限公司 | Preparation method of anti-static organic glass |
-
2018
- 2018-05-24 CN CN201810505210.4A patent/CN108410110B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102092163A (en) * | 2010-12-09 | 2011-06-15 | 苏州工业园区科逸卫浴设备有限公司 | Glassfibre reinforced plastics and preparation method thereof |
| CN104520793A (en) * | 2012-09-27 | 2015-04-15 | 东丽株式会社 | Transparent conductive laminate |
| CN105294959A (en) * | 2015-07-31 | 2016-02-03 | 泰山玻璃纤维有限公司 | Preparation method of anti-static organic glass |
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