CN108409046A - A kind of wastewater treatment equipment and method - Google Patents

A kind of wastewater treatment equipment and method Download PDF

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Publication number
CN108409046A
CN108409046A CN201810338593.0A CN201810338593A CN108409046A CN 108409046 A CN108409046 A CN 108409046A CN 201810338593 A CN201810338593 A CN 201810338593A CN 108409046 A CN108409046 A CN 108409046A
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CN
China
Prior art keywords
waste water
wastewater treatment
ozone
water
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810338593.0A
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Chinese (zh)
Inventor
史振宇
徐伟
王元月
李海涛
郭智
邱明建
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China Energy Saving Engineering Technology Research Institute Co Ltd
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China Energy Saving Engineering Technology Research Institute Co Ltd
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Filing date
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Application filed by China Energy Saving Engineering Technology Research Institute Co Ltd filed Critical China Energy Saving Engineering Technology Research Institute Co Ltd
Priority to CN201810338593.0A priority Critical patent/CN108409046A/en
Publication of CN108409046A publication Critical patent/CN108409046A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/30Nature of the water, waste water, sewage or sludge to be treated from the textile industry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes

Abstract

The present invention relates to a kind of wastewater treatment equipment and method, the wastewater treatment equipment includes:Sequentially connected coagulative precipitation device, one stage catalyzing oxidation reactor, two level catalyst oxidation reactor, release device, biological aerated filter.The present invention uses coagulating sedimentation catalytic ozonation biological aerated filter integration mode, to improve ozone utilization rate, reduces processing cost, improves contaminant degradation rate.

Description

A kind of wastewater treatment equipment and method
Technical field
The present invention relates to a kind of wastewater treatment equipment and methods, belong to industrial waste water treatment.
Background technology
In textile and dyeing industry production process, the process sections such as pretreatment, dyeing, stamp, decoloration, arrangement will produce largely Waste water, each process section waste water difference is larger, overall with organic pollution content is big, biodegradability is poor, variation water quality is big, coloration The features such as high.
The active charcoal absorption of currently used advanced treatment method for printing and dyeing wastewater, advanced oxidation, biological aerated filter and film Method etc.;Wherein, ozone high grade oxidation method is because it is strong, easy to operate with organic matter removal ability, is generated without chemical sludge, coloration The advantages that removal efficiency is high has received sewage advanced treatment field concern.But individually using ozone high grade oxidation method to printing and dyeing Waste water carry out advanced treating, ozone consumption is larger, and cost high efficiency is low, it is difficult to effective practical application, organically by physico-chemical process, Bioanalysis combination combination, is only the developing direction of dyeing waste water advanced treating.
CN106865911A is disclosed using physical-chemical-bioanalysis Combined Treatment waste water, enhances the denitrogenation work(of system Energy;However, it is directly aoxidized using Pre-Ozonation on Organic Matter, oxidation efficiency is relatively low, and system hydraulic detention time is longer. CN104003478A discloses a kind of method of double section ozone-biological aerated filter combined treatment industrial wastewater.This method utilizes Bioanalysis is combined with catalytic ozonation method, effectively reduces cost for wastewater treatment, but its can handle the COD concentration of waste water compared with Low, there are some problems for practical application.
Invention content
For current technology there are problem, the present invention provides one kind and can be used for advanced treatment apparatus for printing and dyeing wastewater and method. The device uses coagulating sedimentation-catalytic ozonation-biological aerated filter integration mode, to improve ozone utilization rate, reduces Processing cost improves contaminant degradation rate.
Technical solution of the present invention is as follows.
A kind of wastewater treatment equipment, including:Sequentially connected coagulative precipitation device, one stage catalyzing oxidation reactor, two level Catalyst oxidation reactor, release device, biological aerated filter;
Wherein, the water outlet of the one stage catalyzing oxidation reactor is also connect with the water inlet conduit of the release device.
Further, the coagulative precipitation device includes medicine machine, pipeline mixing apparatus and mixing plant.The coagulation The mud discharging mouth of settler is additionally provided with lateral, the sludge import for connecting coagulative precipitation device.
Further, nanometer aeration disk is equipped in the one stage catalyzing oxidation reactor;The one stage catalyzing oxidation reaction Equal filler particles shape filler in device and the two level catalyst oxidation reactor;The filler is different according to process object water quality and has Adjusted, such as when handling dyeing waste water, the preferred carried titanium dioxide of the filler, iron oxide complex solid catalyst.
Further, the release device is seal case, inside sets deflector, sludge pump etc..The release device is returned Head piece is connect with coagulative precipitation device pipeline.
Further, haydite is filled in the biological aerated filter;The water outlet of the biological aerated filter respectively with water Case, the connection of coagulative precipitation device pipeline;Water tank is additionally provided with backwash water outlet simultaneously, backwashes water outlet and biological aerated filter Backwash water inlet pipeline be connected.
The biological aerated filter is additionally provided with air inlet, is connected with backwash Fan pipeline.
The present invention also provides a kind of wastewater treatment methods, including:Waste water is through coagulating sedimentation, catalysis oxidation, ozone release, exposure Gas disposal.
Wastewater treatment method of the present invention is primarily adapted for use in the spies such as COD contents are higher, biochemical is poor, coloration is high The waste water of point, if COD contents are 200-400mg/L;In the present invention by taking dyeing waste water as an example.
The coagulating kinetics are specially:Waste water is mixed with coagulant, pH adjusting agent, is mixed under the state that mixes slowly Flco is formed, and is detached.
The coagulant, pH adjusting agent are the conventional dose that those skilled in the art are grasped.Wherein, the coagulant It is one or more in bodied ferric sulfate, aluminium polychloride, polyaluminium sulfate, polyacrylamide, calcium hydroxide.Specific choosing Select can be according to waste water quality depending on.
The catalytic oxidation treatment is specially:Waste water first passes through nanometer aeration, then mixes and carried out at catalysis oxidation with ozone Reason;One stage catalyzing oxidation effluent quality is detected, if water quality meets the requirements, water outlet is directly entered ozone release process;If water quality Undesirable, then ozone release process must be entered back into after two level catalytic oxidation treatment by being discharged.Waste water is in catalytic oxidation Hydraulic detention time is 40-60min in device.
During catalytic oxidation treatment of the present invention, ozone is partially converted into hydroxyl free under the action of catalyst Base, and with remaining ozone cooperative, persistent organic pollutants in waste water are aoxidized.The catalyst can be according to waste water quality situation It is selected.
The ozone release is handled:Also contain a small amount of ozone in waste water after catalysis oxidation, waste water is subjected to ozone Release is handled, and wherein residual ozone is made further to decompose, and suspended matter precipitates again in waste water, and sediment is back to as flocculation core Coagulating sedimentation process.Waterpower residence time in release device is 60-70min.
The Air Exposure is:Waste water passes through biological adsorption, decomposition, Physical entrapment effect, further organics removal;Through After processing, a part of direct discharging of waste water, backwash water of another part waste water as biological aerated filter.Waterpower is being aerated The biofilter residence time is 60-120min.
Compared with prior art, technical solution of the present invention obtains following advantageous effect:
1) present invention uses front end coagulation-settlement process, can effectively reduce the organic pollution in catalytic ozonation stage Load improves system entirety impact resistance, reduces ozone dosage, reduces operating cost.
2) present invention selects suitable catalyst in the catalytic ozonation stage, can enhance the oxidability of ozone, to Promote the removal effect of catalytic oxidation stage organic matter.
3) present invention is equipped with independent ozone release pond, is stopped by water conservancy in release pond or flow-shape, decomposition aoxidize Residual ozone avoids it from entering subsequent biological aerated filter, and harm is generated to the microorganism on filler surface.Moreover, waste water passes through After ozone oxidation, a small amount of precipitation can be generated again in ozone release pond, these precipitations are back to the coagulating sedimentation stage, can be used as The core that flocculates promotes flocculating effect, reduces added amount of chemical.
4) biological aerated filter operation is not necessarily to aerating system in the present invention.It is not fully converted into due to being used to prepare ozone Ozone, remaining oxygen will enter system with ozone, thus can directly be supplied oxygen using the oxygen that front end adds, and save equipment cost And operating cost.The biological aerated filter effectively removes the biochemical organic matter that generation is aoxidized in waste water, and operating cost is low, System unit COD is reduced on the whole removes expense.
5) waste water treatment process of the present invention has that strong shock resistance, hydraulic detention time be shorter, water quality adapts to The features such as range is wide.
Description of the drawings
Fig. 1 is the structural schematic diagram of wastewater treatment equipment of the present invention.
In figure:1- coagulative precipitation devices;2- ozone generating-devices;The one stage catalyzing oxidation reactors of 3-;4- two levels are catalyzed oxygen Change reactor;5- release devices;6- biological aerated filter;7- water tanks;8- backwashes wind turbine;9- dosing tanks I;10- dosing tanks II; 11- dosing tanks III;12- mixes slowly machine;13- electromagnetic flowmeters;14- spinner flowmeters;15- nanometer aeration disks;16- is intake Pump;17- sludge pumps;18- reflux pumps;19- dosings metering pump I;20- dosings metering pump II;21- dosings metering pump III;22- recoils Wash water pumps.
Specific implementation mode
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
A kind of 1 wastewater treatment equipment of embodiment
A kind of wastewater treatment equipment, including:Sequentially connected coagulative precipitation device, one stage catalyzing oxidation reactor, two level Catalyst oxidation reactor, release device, biological aerated filter;
Wherein, the water outlet of the one stage catalyzing oxidation reactor is also connect with the water inlet conduit of release device.
The coagulative precipitation device includes medicine machine, pipeline mixing apparatus and mixes slowly equipment.The coagulating sedimentation The mud discharging mouth of device is additionally provided with the sludge import of lateral connection coagulative precipitation device.
Nanometer aeration disk is equipped in the one stage catalyzing oxidation reactor;The one stage catalyzing oxidation reactor and described two Equal filler particles shape filler in grade catalyst oxidation reactor;The filler is different according to process object water quality and is adjusted, such as When handling dyeing waste water, the preferred carried titanium dioxide of the filler, iron oxide complex solid catalyst.
The release device is seal case, inside sets deflector, sludge pump etc..The refluxing opening and coagulation of the release device Settler pipeline connects.
Haydite is filled in the biological aerated filter;The water outlet of the biological aerated filter is heavy with water tank, coagulation respectively Shallow lake installs pipes connection;Water tank is additionally provided with backwash water outlet simultaneously, backwashes the backwash of water outlet and biological aerated filter Water inlet conduit is connected.
The biological aerated filter is additionally provided with air inlet, is connected with backwash Fan pipeline.
A kind of 2 wastewater treatment method of embodiment
A kind of wastewater treatment method, including:Waste water is through coagulating sedimentation, catalysis oxidation, ozone release, Air Exposure.
The coagulating kinetics are specially:Waste water is mixed with coagulant, pH adjusting agent, is mixed under the state that mixes slowly Flco is formed, and is detached.
The coagulant, pH adjusting agent are the conventional dose that those skilled in the art are grasped.Wherein, coagulant is selected from It is one or more in bodied ferric sulfate, aluminium polychloride, polyaluminium sulfate, polyacrylamide, calcium hydroxide.
The catalytic oxidation treatment is specially:Waste water first passes through nanometer aeration, then mixes and carried out at catalysis oxidation with ozone Reason;One stage catalyzing oxidation effluent quality is detected, if water quality meets the requirements, water outlet is directly entered ozone release process;If water quality Undesirable, then ozone release process must be entered back into after two level catalytic oxidation treatment by being discharged.Waste water is in catalytic oxidation Hydraulic detention time is 40-60min in device.
Under the effect of the catalyst, a part of ozone is converted into hydroxyl radical free radical in water, with ozone cooperative by waste water Middle persistent organic pollutants oxidation.
The ozone release is handled:Also contain a small amount of ozone in waste water after catalysis oxidation, waste water is subjected to ozone Release is handled, and makes wherein that residual ozone further decomposes, suspended matter precipitates again in waste water, and sediment is back to as the core that flocculates Coagulating sedimentation process.Waterpower residence time in release device is 60-70min.
The Air Exposure is:Waste water passes through biological adsorption, decomposition, Physical entrapment effect, further organics removal;Through After processing, a part of direct discharging of waste water, backwash water of another part waste water as biological aerated filter.Waterpower is being aerated The biofilter residence time is 60-120min.
The concrete application of 3 wastewater treatment equipment of embodiment and method
Jiangxi textile printing and dyeing plant effluent is handled using wastewater treatment equipment of the present invention.
Factory's technique is coagulation-multistage A/O- secondary precipitations.
Waste water treatment step:Secondary precipitation water outlet initially enters coagulative precipitation tank dosing coagulant, flocculation aid, coagulating sedimentation Water outlet enters ozone catalytic oxidation unit, enters release device after carrying out advanced oxidation to organic pollution, subsequently into aeration Further pollutant is decomposed and retained in biofilter.
Actual test conditions are as follows:Inflow 5L/h, raw water CODCr=674mg/L, pH=6.9, coloration=128 times are urged It is 50% that agent, which adds volume, and coagulative precipitation device medicament is using bodied ferric sulfate, cationic polyacrylamide, dosage difference For 200mg/L, 2 ‰, ozone concentration 23.5mg/L, biological aerated filter backwashing period is 7d, biological aerated filter biofilm Continuous processing 8d afterwards.
Waste water hydraulic detention time in catalyst oxidation reactor is 40-60min.Waterpower residence time in release device For 60-70min.Waterpower is 60-120min in the biological aerated filter residence time.
The average water quality index of water outlet is as follows:CODCr=169mg/L, pH=7.2, coloration<10 times, SS<10mg/L.
And use the processing method of coagulating sedimentation-ozone direct oxidation-BAF:Ozone oxidation section processing time needs 60- 90min, the BAF residence time need 3h or more, and it is reachable to be discharged average water quality index:CODCr≤200mg/L, pH=6-9, coloration<10 Times, SS<10mg/L.
The concrete application of 4 wastewater treatment of embodiment
Certain textile printing and dyeing plant effluent is handled using wastewater treatment equipment of the present invention.
Plant area's prior art is coagulation-biological fluidized bed-precipitation-air supporting.
Waste water treatment step:Air supporting water outlet initially enters coagulative precipitation tank dosing coagulant, flocculation aid, coagulating sedimentation water outlet Into ozone catalytic oxidation unit, enter release device after carrying out advanced oxidation to organic pollution, subsequently into aeration and biological Further pollutant is decomposed and retained in filter tank.
Actual test conditions are as follows:Inflow 5L/h, raw water CODCr=279mg/L, pH=6.2, coloration=64 times are urged It is 60% that agent, which adds volume, and coagulative precipitation device medicament is using bodied ferric sulfate, cationic polyacrylamide, dosage difference For 300mg/L, 2 ‰, ozone concentration 23.5mg/L, biological aerated filter backwashing period is 5d, biological aerated filter biofilm Continuous processing 10d afterwards.
Waste water hydraulic detention time in catalyst oxidation reactor is 40-60min.Waterpower residence time in release device For 60-70min.Waterpower is 60-120min in the biological aerated filter residence time.
The average water quality index of water outlet is as follows:CODCr=44.9mg/L, pH=6.9, coloration<10 times, SS<10mg/L.
And use existing conventional ozone oxidation-BAF treatment process, ozone oxidation section processing time will 90min with On, it is reachable to be discharged average water quality index:CODCr≤60mg/L, pH=6-9, coloration<10 times, SS<10mg/L.
Although above the present invention is described in detail with a general description of the specific embodiments, On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.

Claims (10)

1. a kind of wastewater treatment equipment, which is characterized in that including:Sequentially connected coagulative precipitation device, one stage catalyzing oxidation are anti- Answer device, two level catalyst oxidation reactor, release device, biological aerated filter;Wherein, the one stage catalyzing oxidation reactor goes out The mouth of a river is also connect with the water inlet conduit of the release device.
2. wastewater treatment equipment according to claim 1, which is characterized in that the coagulative precipitation device is set comprising dosing Standby, pipeline mixing apparatus, mixing plant;
The mud discharging mouth of the coagulative precipitation device is additionally provided with lateral, for connect the sludge of coagulative precipitation device into Mouthful.
3. wastewater treatment equipment according to claim 1 or 2, which is characterized in that in the one stage catalyzing oxidation reactor Equipped with nanometer aeration disk;
Filler is filled in the one stage catalyzing oxidation reactor and the two level catalyst oxidation reactor;The filler is according at Reason object water quality is different and is adjusted.
4. according to any wastewater treatment equipments of claim 1-3, which is characterized in that the release device is seal box Body inside sets deflector, sludge pump.
5. according to any wastewater treatment equipments of claim 1-4, which is characterized in that the refluxing opening of the release device with The coagulative precipitation device pipeline connection.
6. according to any wastewater treatment equipments of claim 1-5, which is characterized in that the water outlet of the biological aerated filter Mouth is connect with water tank, coagulative precipitation device pipeline respectively;
Water tank is additionally provided with backwash water outlet simultaneously, backwashes the backwash water inlet pipeline phase of water outlet and biological aerated filter Even.
7. a kind of wastewater treatment method, which is characterized in that including:Waste water is through coagulating sedimentation, catalysis oxidation, ozone release, aeration Processing.
8. wastewater treatment method according to claim 7, which is characterized in that the coagulating kinetics are specially:Waste water It is mixed with coagulant, pH adjusting agent, flco is mixed to form under the state that mixes slowly, and detach;
The catalytic oxidation treatment is specially:Waste water first passes through nanometer aeration, then is mixed with ozone and carry out catalytic oxidation treatment;
The ozone release is handled:Also contain a small amount of ozone in waste water after catalysis oxidation, waste water is subjected to ozone release Processing, makes wherein residual ozone further decompose, and suspended matter precipitates again in waste water, and sediment is back to coagulation as flocculation core Precipitate process;
The Air Exposure is:Waste water passes through biological adsorption, decomposition, Physical entrapment effect, further organics removal;Through processing Afterwards, a part of direct discharging of waste water, backwash water of another part waste water as biological aerated filter.
9. wastewater treatment method according to claim 8, which is characterized in that during the catalytic oxidation treatment, inspection One stage catalyzing oxidation effluent quality is surveyed, if water quality meets the requirements, water outlet is directly entered ozone release process;If water quality is not met It is required that ozone release process must be entered back into after two level catalytic oxidation treatment by being then discharged.
10. according to any wastewater treatment methods of claim 7-9, which is characterized in that the waste water is dyeing waste water.
CN201810338593.0A 2018-04-16 2018-04-16 A kind of wastewater treatment equipment and method Withdrawn CN108409046A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109292926A (en) * 2018-10-08 2019-02-01 中机铸材科技(福建)有限公司 Wastewater treatment method in discarded sodium silicate process cast used sand treatment process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102363549A (en) * 2011-06-30 2012-02-29 上海明诺环境科技有限公司 Deep treatment system of membraneless industrial organic wastewater
CN104496119A (en) * 2014-12-17 2015-04-08 武汉钢铁(集团)公司 Deep treatment method and device of coking wastewater
CN105236694A (en) * 2015-11-16 2016-01-13 南京大学盐城环保技术与工程研究院 System and method for deeply treating chemical wastewater and biochemical tail water

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102363549A (en) * 2011-06-30 2012-02-29 上海明诺环境科技有限公司 Deep treatment system of membraneless industrial organic wastewater
CN104496119A (en) * 2014-12-17 2015-04-08 武汉钢铁(集团)公司 Deep treatment method and device of coking wastewater
CN105236694A (en) * 2015-11-16 2016-01-13 南京大学盐城环保技术与工程研究院 System and method for deeply treating chemical wastewater and biochemical tail water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109292926A (en) * 2018-10-08 2019-02-01 中机铸材科技(福建)有限公司 Wastewater treatment method in discarded sodium silicate process cast used sand treatment process

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