CN108408873A - A kind of sewage disposal system and method that catalysis material is recyclable - Google Patents

A kind of sewage disposal system and method that catalysis material is recyclable Download PDF

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Publication number
CN108408873A
CN108408873A CN201810465768.4A CN201810465768A CN108408873A CN 108408873 A CN108408873 A CN 108408873A CN 201810465768 A CN201810465768 A CN 201810465768A CN 108408873 A CN108408873 A CN 108408873A
Authority
CN
China
Prior art keywords
catalysis material
pond
light
sewage
recyclable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810465768.4A
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Chinese (zh)
Inventor
李天琪
余海松
叶晨
汪杰明
黄琨
李卓益
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Lin Quan Environmental Protection & Technology Co Ltd
Original Assignee
Wuhan Lin Quan Environmental Protection & Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan Lin Quan Environmental Protection & Technology Co Ltd filed Critical Wuhan Lin Quan Environmental Protection & Technology Co Ltd
Priority to CN201810465768.4A priority Critical patent/CN108408873A/en
Publication of CN108408873A publication Critical patent/CN108408873A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/026Fenton's reagent
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

Abstract

The present invention relates to sewage disposal system and methods, more particularly, to a kind of sewage disposal system and method that catalysis material is recyclable, pond, light-catalyzed reaction pond and magnetic separator, magnetic separator are added including sequentially connected regulating reservoir, catalysis material finally to connect with clarifying basin;The magnetic separator includes the driving belt being obliquely installed, is arranged in the magnetic field offer plate of driving belt bottom, the driving mechanism of driving belt and the water distributor being arranged above driving belt.Therefore, the invention has the advantages that:1, catalysis material is in fluidization form, increases light-catalyzed reaction effect.2, catalysis material has magnetism, recyclable by magnetic separating apparatus, recycling.3, economic, environmental protection.

Description

A kind of sewage disposal system and method that catalysis material is recyclable
Technical field
The present invention relates to sewage disposal system and methods, more particularly, to a kind of sewage disposal that catalysis material is recyclable System and method.
Background technology
The use of photochemical catalyst is mostly at present titanium dioxide, bismuth based material, heavy metal material, transition metal etc..Its disadvantage is Recycling is difficult, expensive, may cause secondary pollution.A kind of patent No. CN201520180176 --- photochemical catalytic oxidation connection The difficult biotechnology industry waste water system of iron-carbon micro-electrolysis processing is closed, has sketched and industry difficult to degrade is handled with photocatalysis combination iron-carbon micro-electrolysis Waste water.
Invention content
The present invention is mainly the technical problem solved present in the prior art;Provide a kind of progress class Fenton under light illumination Reaction, solves the problems, such as a kind of recyclable sewage disposal of difficult to degrade, the lower Industrial Wastewater Treatment of biochemical catalysis material System and method.
The above-mentioned technical problem of the present invention is mainly to be addressed by following technical proposals:
A kind of sewage disposal system that catalysis material is recyclable, which is characterized in that including sequentially connected regulating reservoir, light Catalysis material adds pond, light-catalyzed reaction pond and magnetic separator, magnetic separator and is finally connect with clarifying basin;The Magneto separate Machine includes the driving belt being obliquely installed, is arranged and provides the driving mechanism of plate, driving belt in the magnetic field of driving belt bottom And the water distributor being arranged above driving belt.
As priority, the driving belt both ends being obliquely installed are respectively equipped with catalysis material accumulator tank and sewage recycling Slot.
As priority, the outlet in the light-catalyzed reaction pond and water distributor inlet communication.
As priority, regulating reservoir, catalysis material add pond and light-catalyzed reaction bottom of pond portion and are equipped with aeration head, and It is connect simultaneously with air blower.
As priority, regulating reservoir, catalysis material add in pond and light-catalyzed reaction pond and are equipped with blender;It is described Catalysis material, which adds, is equipped with catalysis material throwing mechanism above pond;Catalysis material dispenser is equipped with above light-catalyzed reaction pond Structure;The catalysis material throwing mechanism includes by the sequentially connected catalysis material storage bin of connecting pipe, photocatalysis material Material adds pump and valve;Catalysis material throwing mechanism includes by the sequentially connected catalysis material storage bin of connecting pipe, urges Change material and adds pump and valve.
As priority, catalysis material storage bin is connected to by connecting pipe with catalysis material accumulator tank, connecting pipe It is additionally provided with magnetic recovery pump.
As priority, light-catalyzed reaction pond inner wall is equipped with LED light strip.
A kind of sewage water treatment method that catalysis material is recyclable, which is characterized in that including:
Step 1, sewage are pumped into regulating reservoir by elevator pump, keep its mixing equal by mechanical agitation and air stirring in regulating reservoir It is even, photochemical catalyst is entered by gravity flow mode later and adds pond, photochemical catalyst dosage carries out core by amount of inlet water and water quality It calculates, and is replenished in time, dosage adds pump by catalysis material and controlled, and photochemical catalyst dosage is controlled in 0.2g/L- 5.0g/L;
Step 2, in photocatalysis adds pond, by mechanical agitation and air stirring, keep photochemical catalyst and sewage fully mixed It closes, maximizes and play photocatalysis effect;Uniformly mixed catalysis material enters light-catalyzed reaction pond, adds hydrogen peroxide herein, And provide illumination by LED light;Illumination wavelength can be adjusted by LED lamps, and section is 200nm -700nm;
Step 3, in light-catalyzed reaction pond, occur photocatalysis class Fenton's reaction, generate with strong oxidizing property hydroxyl from By base, to difficult to degrade, poisonous and harmful substance carries out chain rupture and breaks ring, increases biochemical sewage, achievees the effect that treated sewage;
The water outlet gravity flow of step 4, light-catalyzed reaction pond enters magnetic separation system, initially enters water distributor, anti-in this stage Sewage after answering enters magnetic separating device by slope surface, and magnetism is completed by gravity, Slag Scraping Device and flushing water in face toe The separation of catalysis material;Subsequent magnetic photocatalytic material enters accumulator tank, is pumped to photochemical catalyst and adds tank, treated Sewage enters follow-up clarifying basin, and the discharge system after finally precipitating completes sewage treatment works.
Therefore, the invention has the advantages that:1, catalysis material is in fluidization form, increases light-catalyzed reaction effect Fruit.2, catalysis material has magnetism, recyclable by magnetic separating apparatus, recycling.3, economic, environmental protection.
Description of the drawings
Attached drawing 1 is a kind of schematic diagram of the present invention.
Attached drawing 2 is the schematic diagram of the magnetic separator of the present invention.
Specific implementation mode
Below with reference to the embodiments and with reference to the accompanying drawing the technical solutions of the present invention will be further described.In figure, Regulating reservoir 1, blender 2, aeration head 3, air blower 4, catalysis material add pond 5, blender 6, aeration head 7, catalysis material Storage bin 8, catalysis material add pump 9, valve 10, light-catalyzed reaction pond 11, blender 12, aeration head 13, LED light strip 14, Catalyst adds pond 15, catalyst adds pump 16, valve 17, magnetic separator 18, clarifying basin 19, magnetic recovery pump 20, power section 21, driving belt 22, water distributor 23, catalysis material accumulator tank 24, sewage accumulator tank 25, magnetic field provide plate 26.
Embodiment:
One, introduce lower the device of the invention structure first, including sequentially connected regulating reservoir, catalysis material add pond, Light-catalyzed reaction pond and magnetic separator, magnetic separator are finally connect with clarifying basin;The magnetic separator includes being obliquely installed Driving belt is arranged in the magnetic field offer plate of driving belt bottom, the driving mechanism of driving belt and setting in transmission skin Water distributor with top.Regulating reservoir, catalysis material add pond and light-catalyzed reaction bottom of pond portion is equipped with aeration head, and same When connect with air blower.Catalysis material storage bin is connected to by connecting pipe with catalysis material accumulator tank, and connecting pipe is also Equipped with magnetic recovery pump, light-catalyzed reaction pond inner wall is equipped with LED light strip.
The driving belt both ends being obliquely installed are respectively equipped with catalysis material accumulator tank and sewage accumulator tank, photocatalysis are anti- The outlet of Ying Chi and water distributor inlet communication.
Regulating reservoir, catalysis material add in pond and light-catalyzed reaction pond and are equipped with blender;The catalysis material It adds and is equipped with catalysis material throwing mechanism above pond;Catalysis material throwing mechanism is equipped with above light-catalyzed reaction pond;The light Catalysis material throwing mechanism include by the sequentially connected catalysis material storage bin of connecting pipe, catalysis material add pump, And valve;Catalysis material throwing mechanism includes being thrown by the sequentially connected catalysis material storage bin of connecting pipe, catalysis material Add pump and valve.
Two, it is described below and sewage water treatment method is carried out using the present apparatus, specifically include:
Step 1, sewage are pumped into regulating reservoir by elevator pump, keep its mixing equal by mechanical agitation and air stirring in regulating reservoir It is even, photochemical catalyst is entered by gravity flow mode later and adds pond, photochemical catalyst dosage carries out core by amount of inlet water and water quality It calculates, and is replenished in time, dosage adds pump by catalysis material and controlled, and photochemical catalyst dosage is controlled in 0.2g/L- 5.0g/L;
Step 2, in photocatalysis adds pond, by mechanical agitation and air stirring, keep photochemical catalyst and sewage fully mixed It closes, maximizes and play photocatalysis effect;Uniformly mixed catalysis material enters light-catalyzed reaction pond, adds hydrogen peroxide herein, And provide illumination by LED light;Illumination wavelength can be adjusted by LED lamps, and section is 200nm -700nm;
Step 3, in light-catalyzed reaction pond, occur photocatalysis class Fenton's reaction, generate with strong oxidizing property hydroxyl from By base, to difficult to degrade, poisonous and harmful substance carries out chain rupture and breaks ring, increases biochemical sewage, achievees the effect that treated sewage;
The water outlet gravity flow of step 4, light-catalyzed reaction pond enters magnetic separation system, initially enters water distributor, anti-in this stage Sewage after answering enters magnetic separating device by slope surface, and magnetism is completed by gravity, Slag Scraping Device and flushing water in face toe The separation of catalysis material;Subsequent magnetic photocatalytic material enters accumulator tank, is pumped to photochemical catalyst and adds tank, treated Sewage enters follow-up clarifying basin, and the discharge system after finally precipitating completes sewage treatment works.
Specific embodiment described herein is only an example for the spirit of the invention.Technology belonging to the present invention is led The technical staff in domain can make various modifications or additions to the described embodiments or replace by a similar method In generation, however, it does not deviate from the spirit of the invention or beyond the scope of the appended claims.
Although regulating reservoir 1, blender 2, aeration head 3, air blower 4, catalysis material, which is used more herein, adds pond 5, blender 6, aeration head 7, catalysis material storage bin 8, catalysis material add pump 9, valve 10, light-catalyzed reaction pond 11, Blender 12, aeration head 13, LED light strip 14, catalyst add pond 15, catalyst adds pump 16, valve 17, magnetic separator 18, Clarifying basin 19, magnetic recovery pump 20, power section 21, driving belt 22, water distributor 23, catalysis material accumulator tank 24, sewage return The terms such as slot 25, magnetic field offer plate 26 are received, but it does not preclude the possibility of using other terms.It is only using these terms In order to more easily describe and explain the essence of the present invention;Being construed as any one of the additional limitations all is and the present invention What spirit was disagreed.

Claims (8)

1. a kind of sewage disposal system that catalysis material is recyclable, which is characterized in that urged including sequentially connected regulating reservoir, light Change material adds pond, light-catalyzed reaction pond and magnetic separator, magnetic separator and is finally connect with clarifying basin;The magnetic separator Including be obliquely installed driving belt, be arranged driving belt bottom magnetic field provide plate, driving belt driving mechanism with And the water distributor being arranged above driving belt.
2. a kind of recyclable sewage disposal system of catalysis material according to claim 1, which is characterized in that inclination is set The driving belt both ends set are respectively equipped with catalysis material accumulator tank and sewage accumulator tank.
3. a kind of recyclable sewage disposal system of catalysis material according to claim 1, which is characterized in that the light It is catalyzed outlet and the water distributor inlet communication of reaction tank.
4. a kind of recyclable sewage disposal system of catalysis material according to claim 1, which is characterized in that adjust Pond, catalysis material add pond and light-catalyzed reaction bottom of pond portion and are equipped with aeration head, and are connect simultaneously with air blower.
5. a kind of recyclable sewage disposal system of catalysis material according to claim 1, which is characterized in that adjust Pond, catalysis material add in pond and light-catalyzed reaction pond and are equipped with blender;The catalysis material adds to be set above pond There is catalysis material throwing mechanism;Catalysis material throwing mechanism is equipped with above light-catalyzed reaction pond;The catalysis material is launched Mechanism includes adding pump and valve by the sequentially connected catalysis material storage bin of connecting pipe, catalysis material;Catalysis Material throwing mechanism includes adding pump and valve by the sequentially connected catalysis material storage bin of connecting pipe, catalysis material.
6. a kind of recyclable sewage disposal system of catalysis material according to claim 2, which is characterized in that photocatalysis Material storage bin is connected to by connecting pipe with catalysis material accumulator tank, and connecting pipe is additionally provided with magnetic recovery pump.
7. a kind of recyclable sewage disposal system of catalysis material according to claim 1, which is characterized in that the light It is catalyzed reaction tank inner wall and is equipped with LED light strip.
8. a kind of sewage water treatment method that catalysis material is recyclable, which is characterized in that including:
Step 1, sewage are pumped into regulating reservoir by elevator pump, so that it is uniformly mixed by mechanical agitation and air stirring in regulating reservoir, Photochemical catalyst is entered by gravity flow mode later and adds pond, photochemical catalyst dosage is calculated by amount of inlet water and water quality, And be replenished in time, dosage adds pump by catalysis material and is controlled, and photochemical catalyst dosage is controlled in 0.2g/L- 5.0g/L;
Step 2, in photocatalysis adds pond, by mechanical agitation and air stirring, so that photochemical catalyst and sewage is sufficiently mixed, most Bigization plays photocatalysis effect;Uniformly mixed catalysis material enters light-catalyzed reaction pond, adds hydrogen peroxide herein, and pass through LED light provides illumination;Illumination wavelength can be adjusted by LED light, and section is 200nm -700nm;
Step 3, in light-catalyzed reaction pond, occur photocatalysis class Fenton's reaction, generate with strong oxidizing property hydroxyl radical free radical, To difficult to degrade, poisonous and harmful substance carries out chain rupture and breaks ring, increases biochemical sewage, achievees the effect that treated sewage;
The water outlet gravity flow of step 4, light-catalyzed reaction pond enters magnetic separation system, water distributor is initially entered, after this elementary reaction Sewage magnetic separating device is entered by slope surface, magnetic light is completed by gravity, Slag Scraping Device and flushing water in face toe and is urged Change the separation of material;Subsequent magnetic photocatalytic material enters accumulator tank, is pumped to photochemical catalyst and adds tank, treated sewage Into follow-up clarifying basin, the discharge system after finally precipitating completes sewage treatment works.
CN201810465768.4A 2018-05-16 2018-05-16 A kind of sewage disposal system and method that catalysis material is recyclable Pending CN108408873A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810465768.4A CN108408873A (en) 2018-05-16 2018-05-16 A kind of sewage disposal system and method that catalysis material is recyclable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810465768.4A CN108408873A (en) 2018-05-16 2018-05-16 A kind of sewage disposal system and method that catalysis material is recyclable

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Publication Number Publication Date
CN108408873A true CN108408873A (en) 2018-08-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111762969A (en) * 2020-06-30 2020-10-13 北京新林水务科技有限公司 Low-concentration degradation-resistant chemical wastewater treatment method and system
CN111871341A (en) * 2020-08-03 2020-11-03 扬州大学 Continuous flow Fenton reactor capable of recycling magnetic catalyst

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1966413A (en) * 2005-11-16 2007-05-23 北京理工大学 Magnetic separation and coupling air-lifting suspension photocatalytic treatment method and its device
CN102351654A (en) * 2011-06-15 2012-02-15 中北大学 Magnetic separation catalytic oxidation method and magnetic separation reaction apparatus
CN105032423A (en) * 2015-08-04 2015-11-11 张少旸 Multiphase magnetic Fenton-photocatalyst and preparation method thereof and application
CN107175112A (en) * 2017-05-09 2017-09-19 济南大学 A kind of micro motor photochemical catalyst and its preparation method and application
CN206680229U (en) * 2017-03-23 2017-11-28 湖北保灵华环保科技有限公司 A kind of recyclable sewage disposal system of magnetic kind

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1966413A (en) * 2005-11-16 2007-05-23 北京理工大学 Magnetic separation and coupling air-lifting suspension photocatalytic treatment method and its device
CN102351654A (en) * 2011-06-15 2012-02-15 中北大学 Magnetic separation catalytic oxidation method and magnetic separation reaction apparatus
CN105032423A (en) * 2015-08-04 2015-11-11 张少旸 Multiphase magnetic Fenton-photocatalyst and preparation method thereof and application
CN206680229U (en) * 2017-03-23 2017-11-28 湖北保灵华环保科技有限公司 A kind of recyclable sewage disposal system of magnetic kind
CN107175112A (en) * 2017-05-09 2017-09-19 济南大学 A kind of micro motor photochemical catalyst and its preparation method and application

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111762969A (en) * 2020-06-30 2020-10-13 北京新林水务科技有限公司 Low-concentration degradation-resistant chemical wastewater treatment method and system
CN111762969B (en) * 2020-06-30 2023-10-20 北京新林水务科技有限公司 Low-concentration degradation-resistant chemical wastewater treatment method and system
CN111871341A (en) * 2020-08-03 2020-11-03 扬州大学 Continuous flow Fenton reactor capable of recycling magnetic catalyst

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Application publication date: 20180817

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