CN108395647A - A kind of high fire-retardance PVC board - Google Patents

A kind of high fire-retardance PVC board Download PDF

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Publication number
CN108395647A
CN108395647A CN201810284371.5A CN201810284371A CN108395647A CN 108395647 A CN108395647 A CN 108395647A CN 201810284371 A CN201810284371 A CN 201810284371A CN 108395647 A CN108395647 A CN 108395647A
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China
Prior art keywords
parts
raw material
extruder
high fire
pvc board
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201810284371.5A
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Chinese (zh)
Inventor
徐乐
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Guilin Quanzhou Liaoyuan Science & Technology Co Ltd
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Guilin Quanzhou Liaoyuan Science & Technology Co Ltd
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Priority to CN201810284371.5A priority Critical patent/CN108395647A/en
Publication of CN108395647A publication Critical patent/CN108395647A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The present invention relates to a kind of high fire-retardance PVC boards, test a kind of high fire-retardance PVC board of the present invention, and Shore durometer number is more than 77.1, and hardness is high;Its fire-protection rating meets the requirement of 0 ranks of UL94V, good flame retardation effect;The test result obtained after being placed 24 hours during temperature is the environment that 90 DEG C of humidity are 33% is that sample does not find the sign of deformation, and color and luster is normal, and high temperature resistance is good.

Description

A kind of high fire-retardance PVC board
Technical field
The present invention relates to PVC board technical field more particularly to a kind of high fire-retardance PVC boards.
Background technology
PVC board is using PVC as plank that section made of raw material is honeycomb eyed structure.Also known as decorating film, attached glue Film is a kind of vacuum forming film, and the surface layer for all kinds of panels is packed, and all conglomeraties such as building materials, packaging, medicine are applied to.PVC Plate is maximum in the proportion that building material industry accounts for, and is 60%, followed by packaging industry, the also industry of other several small range applications.It presses It can be divided into soft pvc and hard PVC according to soft or hard degree.It can be divided into PVC foams plate and PVC Free Foaming Panels by manufacture craft.It presses It is transparent and opaque be divided into PVC transparent plate and PVC board.
Current PVC board flame retardant effect is poor, and security performance is low.
Invention content
It is an object of the invention to:In view of the above problems, the high resistant that a kind of performance is stable, manufacturing cost is low is provided Fire PVC board.
The present invention is achieved by the following technical solutions:
A kind of high fire-retardance PVC board is grouped as by the group of following parts by weight:120~130 parts of PVC waste materials, 40~65 parts of calcium powder, 10~15 parts of stabilizer, 5~8 parts of tribasic lead sulfate, 3~5 parts of chlorinated paraffin, 1~3 part of foaming agent, white hair infusion 0.3 ~0.5 part, 4~6 parts of fire retardant, 0.1~0.3 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
Preferably, a kind of high fire-retardance PVC board is grouped as by the group of following parts by weight:120 parts of PVC waste materials, calcium powder 40 Part, 10 parts of stabilizer, 5 parts of tribasic lead sulfate, 3 parts of chlorinated paraffin, 1 part of foaming agent, 0.3 part of white hair infusion, fire retardant 4 Part, 0.1 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
Preferably, a kind of high fire-retardance PVC board is grouped as by the group of following parts by weight:130 parts of PVC waste materials, calcium powder 65 Part, 15 parts of stabilizer, 8 parts of tribasic lead sulfate, 5 parts of chlorinated paraffin, 3 parts of foaming agent, 0.5 part of white hair infusion, fire retardant 6 Part, 0.3 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
Preferably, a kind of high fire-retardance PVC board is grouped as by the group of following parts by weight:125 parts of PVC waste materials, calcium powder 63 Part, 11 parts of stabilizer, 7 parts of tribasic lead sulfate, 4 parts of chlorinated paraffin, 2 parts of foaming agent, 0.4 part of white hair infusion, fire retardant 5 Part, 0.2 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
The raw material being related in this application can be obtained in buying on the market.
The beneficial effects of the invention are as follows:
A kind of high fire-retardance PVC board of the present invention, which is tested, and Shore durometer number is more than 77.1, and hardness is high;It is anti- Fiery grade meets the requirement of UL94V-0 ranks, good flame retardation effect;It is placed 24 hours in temperature is the environment that 90 DEG C of humidity are 33% The test result obtained afterwards is that sample does not find the sign of deformation, and color and luster is normal, and high temperature resistance is good.
Specific implementation mode
This specification(Including any accessory claim, abstract)Disclosed in any feature, unless specifically stated, It is replaced by other equivalent or with similar purpose alternative features.That is, unless specifically stated, each feature is a series of An example in equivalent or similar characteristics.
Embodiment 1:
A kind of high fire-retardance PVC board is grouped as by the group of following parts by weight:120 parts of PVC waste materials, 40 parts of calcium powder, stabilizer 10 Part, 5 parts of tribasic lead sulfate, 3 parts of chlorinated paraffin, 1 part of foaming agent, 0.3 part of white hair infusion, 4 parts of fire retardant, pigment 0.1 Part;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
Embodiment 2:
A kind of high fire-retardance PVC board is grouped as by the group of following parts by weight:130 parts of PVC waste materials, 65 parts of calcium powder, stabilizer 15 Part, 8 parts of tribasic lead sulfate, 5 parts of chlorinated paraffin, 3 parts of foaming agent, 0.5 part of white hair infusion, 6 parts of fire retardant, pigment 0.3 Part;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
Embodiment 3:
A kind of high fire-retardance PVC board is grouped as by the group of following parts by weight:125 parts of PVC waste materials, 63 parts of calcium powder, stabilizer 11 Part, 7 parts of tribasic lead sulfate, 4 parts of chlorinated paraffin, 2 parts of foaming agent, 0.4 part of white hair infusion, 5 parts of fire retardant, pigment 0.2 Part;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
Although above the present invention is described in detail with a general description of the specific embodiments, On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.

Claims (4)

1. a kind of high fire-retardance PVC board, it is characterised in that:It is to be grouped as by the group of following parts by weight:120~130 parts of PVC waste materials, 40~65 parts of calcium powder, 10~15 parts of stabilizer, 5~8 parts of tribasic lead sulfate, 3~5 parts of chlorinated paraffin, 1~3 part of foaming agent, 0.3~0.5 part of white hair infusion, 4~6 parts of fire retardant, 0.1~0.3 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
2. a kind of high fire-retardance PVC board according to claim 1, it is characterised in that:It is to be grouped as by the group of following parts by weight: It is 120 parts of PVC waste materials, 40 parts of calcium powder, 10 parts of stabilizer, 5 parts of tribasic lead sulfate, 3 parts of chlorinated paraffin, 1 part of foaming agent, white 0.3 part of foaming agent, 4 parts of fire retardant, 0.1 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
3. a kind of high fire-retardance PVC board according to claim 1, it is characterised in that:It is to be grouped as by the group of following parts by weight: It is 130 parts of PVC waste materials, 65 parts of calcium powder, 15 parts of stabilizer, 8 parts of tribasic lead sulfate, 5 parts of chlorinated paraffin, 3 parts of foaming agent, white 0.5 part of foaming agent, 6 parts of fire retardant, 0.3 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
4. a kind of high fire-retardance PVC board according to claim 1, it is characterised in that:It is to be grouped as by the group of following parts by weight: It is 125 parts of PVC waste materials, 63 parts of calcium powder, 11 parts of stabilizer, 7 parts of tribasic lead sulfate, 4 parts of chlorinated paraffin, 2 parts of foaming agent, white 0.4 part of foaming agent, 5 parts of fire retardant, 0.2 part of pigment;
Preparation process is as follows:
(1)Raw material are weighed by weight, and raw material are uniformly mixed at 65 DEG C;
(2)Uniformly mixed raw material is sent in extruder and is foamed, then extruded die head squeezes out, and controls the temperature of extruder It it is 185 DEG C, the temperature for being passed through the cooling water of extrusion die is 12 DEG C;
(3)Fused materials to leaving extrusion die carry out cooling, shape to get the high fire-retardance PVC board.
CN201810284371.5A 2018-04-02 2018-04-02 A kind of high fire-retardance PVC board Withdrawn CN108395647A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810284371.5A CN108395647A (en) 2018-04-02 2018-04-02 A kind of high fire-retardance PVC board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810284371.5A CN108395647A (en) 2018-04-02 2018-04-02 A kind of high fire-retardance PVC board

Publications (1)

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CN108395647A true CN108395647A (en) 2018-08-14

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115926342A (en) * 2022-12-30 2023-04-07 山东博拓新材料科技股份有限公司 Combined PVC (polyvinyl chloride) automobile board with fireproof function and production process thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115926342A (en) * 2022-12-30 2023-04-07 山东博拓新材料科技股份有限公司 Combined PVC (polyvinyl chloride) automobile board with fireproof function and production process thereof

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Application publication date: 20180814

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