CN108395625A - A kind of combined type shock resistance bumper raw material - Google Patents

A kind of combined type shock resistance bumper raw material Download PDF

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Publication number
CN108395625A
CN108395625A CN201810290175.9A CN201810290175A CN108395625A CN 108395625 A CN108395625 A CN 108395625A CN 201810290175 A CN201810290175 A CN 201810290175A CN 108395625 A CN108395625 A CN 108395625A
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CN
China
Prior art keywords
bumper
steel wire
stainless steel
shock resistance
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810290175.9A
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Chinese (zh)
Inventor
张伟
盛杰
霍洪军
严诏文
陆裕苗
廉杰
董朝阳
齐成锦
王雪峰
冯宝龙
吕小刚
徐富恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG HENG XIN JI PLASTICS Co Ltd
Original Assignee
SHANDONG HENG XIN JI PLASTICS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG HENG XIN JI PLASTICS Co Ltd filed Critical SHANDONG HENG XIN JI PLASTICS Co Ltd
Priority to CN201810290175.9A priority Critical patent/CN108395625A/en
Publication of CN108395625A publication Critical patent/CN108395625A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene

Abstract

The invention discloses a kind of combined type shock resistance bumper raw materials, are composed of the following raw materials by weight:100 parts of polypropylene, epoxylite compound DMDO0.3~0.5 part, 0.1~0.2 part of polyphenol antioxidant, 0.03~0.05 part of benzotriazole, 0.03~0.05 part of phenyl salicylate are double(1,2,2,6,6 pentamethvl)0.01~0.02 part of sebacate, 3~5 parts of stainless steel steel wire.The present invention in PP by the way of being added stainless steel steel wire and embedding, and it is docked by two sides insurance lever plate, stainless steel steel wire forms firm reinforcing rib structure in bumper, and using the method for hot steel wire insertion, ensure that the surface that each raw material can be adequately coarse with stainless steel steel wire contacts, crawl is more secured, preferably combines together with PP, to substantially increase whole shock resistance.

Description

A kind of combined type shock resistance bumper raw material
Technical field
The present invention relates to a kind of instrument board, specifically a kind of combined type shock resistance bumper raw material.
Background technology
Bumper has the effects that safeguard protection, decoration vehicle and the air dynamic behaviour for improving vehicle.From safety On see, automobile occurs to can play a buffer role in when low speed collision accident, protects front and back car body;It can be with when accident occurs with pedestrian Play the role of certain protection pedestrian.From the appearance point of view, with dicoration, become the important component of decoration car appearance;Together When, bumper also has certain aerodynamic action.In order to reach this purpose, the front/rear collision bumper of car is adopted at present With plastics, people are known as plastic bumper.
For PP materials increasingly close to people’s lives, the thing followed is the increase of PP bumper materials usage amounts, With PP bumpers materials mostly easy to aging, not impact resistance, not acid-alkali-corrosive-resisting and it is not wear-resisting, resistance to low temperature is low the problems such as Show.
Existing PP bumpers materials mainly use PP and POE, talcum powder to be formed by combining, Chinese patent CN102516665A discloses the preparation method of a kind of PP and copolymerization PP bumper PP Pipe Compounds, using PP and copolymerization PP, POE and bismaleimide are composed, but the Shortcomings in terms of shock resistance;Chinese patent CN101781424A is disclosed A kind of formula and processing technology of the bumper with metallic luster, is composed using PP, POE and aluminium powder, wear-resisting, but It is in terms of allowing for shock resistance or relatively low, therefore a kind of PP bumpers materials of design are very important.
Invention content
Technical problem to be solved by the invention is to provide a kind of combined type shock resistance bumper raw materials.
In order to solve the above technical problems, the technical scheme is that:A kind of combined type shock resistance bumper raw material, by with Lower raw material composition:100 parts of polypropylene, epoxylite compound DMDO0.3~0.5 part, polyphenol antioxidant 0.1~ 0.2 part, 0.03~0.05 part of benzotriazole, 0.03~0.05 part of phenyl salicylate, bis- (1,2,2,6,6- pentamethvl) last of the ten Heavenly stems Two 0.01~0.02 part of acid esters, 3~5 parts of stainless steel steel wire.
A kind of method that combined type shock resistance bumper raw material is used to process bumper, includes the following steps:
Step 1: according to weight by polypropylene, epoxylite compound DMDO, polyphenol antioxidant, benzo Triazole, phenyl salicylate, bis- (1,2,2,6,6- pentamethvl) sebacates are added in super mixer and stir, extruded machine Extruding pelletization;
Step 2: by the upper/lower die for being sent into bumper is granulated, it is processed into the bumper monolithic that thickness is 2~3mm respectively Plate;
Step 3: choosing the stainless steel steel wire of a diameter of 0.5mm, is gently polished on surface with sand paper or sander, make it 20~30um of surface roughness;
Step 4: according to several of the stainless steel steel wire that weight selecting step three is polished, every stainless steel steel wire Both ends are separately energized, until stainless steel wire temperature reaches 200 DEG C or more, rapid horizontal heat is embedded into one of bumper list In sheet;
Step 5: using mode of heating will respectively be embedded with stainless steel steel wire bumper single piece plate and another be not embedded into not The bumper single piece plate of rust steel steel wire thinks that opposite is heated, and is bonded together, and shock resistance bumper is made after cooling.
By adopting the above-described technical solution, the present invention using be added in PP stainless steel steel wire it is embedded by the way of, and by Two sides insurance lever plate is docked, and stainless steel steel wire forms firm reinforcing rib structure in bumper, and uses hot steel wire Embedded method, it is ensured that the surface that each raw material can be adequately coarse with stainless steel steel wire contacts, crawl it is more secured, preferably with PP combines together, to substantially increase whole shock resistance.
Specific implementation mode
Example 1
A kind of combined type shock resistance bumper raw material, is composed of the following raw materials by weight:100 parts of polypropylene, epoxies tree DMDO0.5 parts of compound, 0.2 part of polyphenol antioxidant, 0.04 part of benzotriazole, 0.04 part of phenyl salicylate, bis- (1,2,2, 6,6- pentamethvls) 0.02 part of sebacate, 4 parts of stainless steel steel wire.
The method that above-mentioned combined type shock resistance bumper raw material is used to process bumper, includes the following steps:
Step 1: according to weight by polypropylene, epoxylite compound DMDO, polyphenol antioxidant, benzo Triazole, phenyl salicylate, bis- (1,2,2,6,6- pentamethvl) sebacates are added in super mixer and stir, extruded machine Extruding pelletization;
Step 2: by the upper/lower die for being sent into bumper is granulated, it is processed into the bumper single piece plate that thickness is 3mm respectively;
Step 3: choosing the stainless steel steel wire of a diameter of 0.5mm, is gently polished on surface with sand paper or sander, make it 24~26um of surface roughness;
Step 4: according to several of the stainless steel steel wire that weight selecting step three is polished, every stainless steel steel wire Both ends are separately energized, until stainless steel wire temperature reaches 200 DEG C or more, rapid horizontal heat is embedded into one of bumper list In sheet;
Step 5: using mode of heating will respectively be embedded with stainless steel steel wire bumper single piece plate and another be not embedded into not The bumper single piece plate of rust steel steel wire thinks that opposite is heated, and is bonded together, and shock resistance bumper, and bumper is made after cooling Thickness is 6mm.
Example 2
A kind of combined type shock resistance bumper raw material, is composed of the following raw materials by weight:100 parts of polypropylene, epoxies tree DMDO0.5 parts of compound, 0.2 part of polyphenol antioxidant, 0.04 part of benzotriazole, 0.04 part of phenyl salicylate, bis- (1,2,2, 6,6- pentamethvls) 0.02 part of sebacate.
The method that above-mentioned combined type shock resistance bumper raw material is used to process bumper, includes the following steps:
Step 1: according to weight by polypropylene, epoxylite compound DMDO, polyphenol antioxidant, benzo Triazole, phenyl salicylate, bis- (1,2,2,6,6- pentamethvl) sebacates are added in super mixer and stir, extruded machine Extruding pelletization;
Step 2: by the mold for being sent into bumper is granulated, it is processed into the shock resistance bumper that thickness is 6mm respectively.
Example 3
Non-painted automobile bumper with metallic luster, in parts by weight, by 45 parts of trade mark K7726,15 parts of trades mark The PP mixing of EPS30R and 5 part of trade mark T30S, then by mixed PP and 12 part of POE, 1 part of silver dollar type aluminium powder and 20 parts of cunnings Mountain flour is blended, and mixture A is obtained after being sufficiently mixed;Mixture A is added in double screw extruder, in 170 DEG C, screw rod Melting and extruding pelletization, obtain plastic granule B in the case of rotating speed 300rad/min;Plastic granule B is added in injection molding machine Injection molding, obtains bumper C, and bumper thickness is 6mm.
Example 4
A kind of preparation method of PP and copolymerization PP bumper PP Pipe Compounds, this method comprises the following steps:By 170- 175 mass parts PP, 130-135 mass parts are copolymerized PP, 30-45 mass parts POE, 10-15 mass parts talcum powder, 10-20 mass parts Titanate coupling agent, 10 mass parts antioxidants, 10 mass parts bismaleimide and 10 mass parts adipic acids are stirred, will Uniformly mixed material is by double rod cocurrent and parallel plastic extruder, body temperature:170-200 DEG C, head temperature:180-195 DEG C, Material after extrusion is cooled down in water temperature is 30-45 DEG C of water to get and bumper thickness is also 6mm.
Each embodiment performance parameter such as following table:
It can be found by the above Experimental comparison, the bumper comprehensive mechanical property that embodiment 1 processes is more preferable, has good Better impact resistance.
The foregoing is merely the schematical specific implementation modes of the present invention, are not limited to the scope of the present invention.It is any Those skilled in the art, made equivalent variations and modification under the premise of not departing from design and the principle of the present invention, The scope of protection of the invention should be belonged to.

Claims (4)

1. a kind of combined type shock resistance bumper raw material, which is characterized in that be composed of the following raw materials by weight:100 parts of polypropylene, Epoxylite compound DMDO0.3~0.5 part, 0.1~0.2 part of polyphenol antioxidant, 0.03~0.05 part of benzotriazole, water 0.03~0.05 part of poplar acid phenenyl ester, it is double(1,2,2,6,6- pentamethvl)0.01~0.02 part of sebacate, stainless steel steel wire 3 ~5 parts.
2. a kind of combined type shock resistance bumper raw material as described in claim 1, it is characterised in that it is characterized in that, by following Raw material forms:100 parts of polypropylene, DMDO0.5 parts of epoxylite compound, 0.2 part of polyphenol antioxidant, benzo three 0.04 part of azoles, 0.04 part of phenyl salicylate are double(1,2,2,6,6- pentamethvl)0.02 part of sebacate, stainless steel steel wire 4 Part.
3. the method that a kind of combined type shock resistance bumper raw material as described in claim 1 is used to process bumper, feature It is, includes the following steps:
Step 1: according to weight by polypropylene, epoxylite compound DMDO, polyphenol antioxidant, benzotriazole, It is phenyl salicylate, double(1,2,2,6,6- pentamethvl)Sebacate is added in super mixer and stirs, and extruded machine squeezes out It is granulated;
Step 2: by the upper/lower die for being sent into bumper is granulated, it is processed into the bumper single piece plate that thickness is 2~3mm respectively;
Step 3: choosing the stainless steel steel wire of a diameter of 0.5mm, is gently polished on surface with sand paper or sander, make its surface 20~30um of roughness;
Step 4: according to several of the stainless steel steel wire that weight selecting step three is polished, every stainless steel steel wire both ends It is separately energized, until stainless steel wire temperature reaches 200 DEG C or more, rapid horizontal heat is embedded into one of bumper single piece plate In;
Step 5: using mode of heating will respectively be embedded with stainless steel steel wire bumper single piece plate and another be not embedded into stainless steel The bumper single piece plate of steel wire thinks that opposite is heated, and is bonded together, and shock resistance bumper is made after cooling.
4. the method that a kind of combined type shock resistance bumper raw material as claimed in claim 3 is used to process bumper, feature Be it is characterized in that:Its surface roughness is 24~26um after the polishing of stainless steel steel wire.
CN201810290175.9A 2018-04-03 2018-04-03 A kind of combined type shock resistance bumper raw material Pending CN108395625A (en)

Priority Applications (1)

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CN201810290175.9A CN108395625A (en) 2018-04-03 2018-04-03 A kind of combined type shock resistance bumper raw material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810290175.9A CN108395625A (en) 2018-04-03 2018-04-03 A kind of combined type shock resistance bumper raw material

Publications (1)

Publication Number Publication Date
CN108395625A true CN108395625A (en) 2018-08-14

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5989462A (en) * 1997-07-31 1999-11-23 Q2100, Inc. Method and composition for producing ultraviolent blocking lenses
CN103012970A (en) * 2012-12-03 2013-04-03 合肥杰事杰新材料股份有限公司 Weatherproof ageing-resistant polypropylene material and preparation method thereof
CN103240929A (en) * 2012-02-03 2013-08-14 上海杰事杰新材料(集团)股份有限公司 High-strength lightweight polypropylene composite board and making method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5989462A (en) * 1997-07-31 1999-11-23 Q2100, Inc. Method and composition for producing ultraviolent blocking lenses
CN103240929A (en) * 2012-02-03 2013-08-14 上海杰事杰新材料(集团)股份有限公司 High-strength lightweight polypropylene composite board and making method thereof
CN103012970A (en) * 2012-12-03 2013-04-03 合肥杰事杰新材料股份有限公司 Weatherproof ageing-resistant polypropylene material and preparation method thereof

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Application publication date: 20180814

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