CN108384519A - A kind of drilling fluid latex class lubricating collapse-resisting agent - Google Patents

A kind of drilling fluid latex class lubricating collapse-resisting agent Download PDF

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Publication number
CN108384519A
CN108384519A CN201810375597.6A CN201810375597A CN108384519A CN 108384519 A CN108384519 A CN 108384519A CN 201810375597 A CN201810375597 A CN 201810375597A CN 108384519 A CN108384519 A CN 108384519A
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CN
China
Prior art keywords
latex
parts
drilling fluid
agent
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810375597.6A
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Chinese (zh)
Inventor
冯丹
张洪伟
付跃华
张宇
喻化民
曹靖瑜
李海彪
张丽华
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CNPC Bohai Drilling Engineering Co Ltd
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CNPC Bohai Drilling Engineering Co Ltd
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Priority to CN201810375597.6A priority Critical patent/CN108384519A/en
Publication of CN108384519A publication Critical patent/CN108384519A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02Well-drilling compositions
    • C09K8/03Specific additives for general use in well-drilling compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2208/00Aspects relating to compositions of drilling or well treatment fluids
    • C09K2208/10Nanoparticle-containing well treatment fluids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2208/00Aspects relating to compositions of drilling or well treatment fluids
    • C09K2208/34Lubricant additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of drilling fluid latex class lubricating collapse-resisting agents, include following components by mass fraction:40 60 parts of latexes, 25 parts of latex stabilizers, 13 parts of antifoaming agent and 10 15 parts of micro-nano inertization agent;The latex is a kind of or their mixture of styrene-butadiene latex, butadiene latex, butyl latex, polychloroprene latex, ethylene propylene rubber latex, isoprene rubber latex, NBR latex, acrylic latex;The micro-nano inertization agent is a kind of or their mixture in micro-nano calcium carbonate, nano silicon dioxide.Its appearance is brown color viscous liquid, it is a kind of high-efficient drilling fluid lubricating collapse-resisting agent, the filter loss of drilling fluid system can be greatly reduced, enhances the lubricating ability of drilling fluid, raising system inhibits the ability of shale expansion, effectively solves the problems, such as that the serious of mud shale stratum is collapsed.

Description

A kind of drilling fluid latex class lubricating collapse-resisting agent
Technical field
The present invention relates to well liquid borehole wall stabilizers, are a kind of drilling fluid latex class lubricating collapse-resisting agents.
Background technology
Borehole well instability problem in Process of Oil Well Drilling is always to perplex the problem of drilling well circle, for falling in drilling process Block, the problems such as collapse, and has developed the anti-sloughing agents such as sulfonated gilsonite class inorganic agent, film forming class inorganic agent, emulsified asphalt class inorganic agent, But on some of complex well, borehole well instability problem does not still well solve.
Invention content
The technical problem to be solved by the invention is to provide one kind can aid in solve drilling process in borehole well instability ask The drilling fluid of topic latex class lubricating collapse-resisting agent.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is:A kind of drilling fluid is anti-with latex class lubrication It collapses agent, includes following components by mass fraction:40-60 parts of latexes, 2-5 parts of latex stabilizers, 1-3 parts of antifoaming agent and 10-15 parts Micro-nano inertization agent;The latex is styrene-butadiene latex, butadiene latex, butyl latex, polychloroprene latex, ethylene propylene rubber latex, different A kind of or their mixture of penta latex, NBR latex, acrylic latex;The micro-nano inertization agent is micro-nano A kind of or their mixture in calcium carbonate, nano silicon dioxide.
The latex stabilizer is a kind of or their mixture in sulfuric acid, sulfonate, carboxylate;
The antifoaming agent is silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether A kind of or their mixture in mixture.
The beneficial effects of the invention are as follows:Drilling fluid provided by the invention is brown color viscosity liquid with latex class lubricating collapse-resisting agent Body has good filtrate reducing ability, lubricating ability and the ability for inhibiting shale expansion, is that a kind of high-efficient drilling fluid borehole wall is steady Determine agent, the inhibition of system can be greatly improved, effectively solves the problems, such as that the serious of mud shale stratum is collapsed.
Specific implementation mode
Invention is further described in detail With reference to embodiment:
The drilling fluid latex class lubricating collapse-resisting agent of the present invention, includes following components by mass fraction:40-60 parts of latexes, 2-5 parts of latex stabilizers, 1-3 parts of antifoaming agent and 10-15 parts of micro-nano inertization agent;The latex is styrene-butadiene latex, fourth two Alkene latex, butyl latex, polychloroprene latex, ethylene propylene rubber latex, isoprene rubber latex, NBR latex, acrylic latex one kind or they Mixture;The micro-nano inertization agent is micro-nano calcium carbonate, a kind of in nano silicon dioxide or theirs is mixed Close object.
The latex stabilizer is a kind of or their mixture in sulfuric acid, sulfonate, carboxylate;
The antifoaming agent is silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether A kind of or their mixture in mixture.
40-60 parts of latexes are placed in reaction kettle under room temperature (25 DEG C), are then added under stirring successively in order 2-5 parts of latex stabilizers, 1-3 parts of antifoaming agent and 10-15 parts of micro-nano inertization agent, are thoroughly mixed uniformly to get one Kind drilling fluid latex class lubricating collapse-resisting agent, appearance are the suspension latex of brown color.
Compared with existing similar borehole wall stabilizer, the present invention has the following advantages:
1, latex class lubricating collapse-resisting agent provided by the invention is a kind of Multifunctional Additive, have fluid loss additive, lubrication and Anti-collapse effect.
2, the preparation method of latex class lubricating collapse-resisting agent provided by the invention, raw material is easy to get and cost is relatively low, more added with Conducive to the popularization and application at scene.
Embodiment 1 (formulation examples 1)
50 parts of butadiene-styrene latexes are placed in reaction kettle at room temperature, 2 parts of breasts are then added under stirring successively in order Gum stabilizing agents sodium sulfovinate, 2 parts of antifoaming agent silicone emulsions and 5 parts of micro-nano micro-nano calcium carbonate of inertization agent, are sufficiently stirred It is uniformly mixed to get a kind of drilling fluid latex class lubricating collapse-resisting agent, appearance is the suspension latex of brown color.
Embodiment 2 (formulation examples 2)
50 parts of butadiene latexes are placed in reaction kettle at room temperature, are then added 2 parts under stirring successively in order Latex stabilizer sodium sulfovinate, 5 parts of antifoaming agent silicone emulsions and 10 parts of micro-nano inertization agent nano silicon dioxides, are fully stirred It mixes and is uniformly mixed to get a kind of drilling fluid latex class lubricating collapse-resisting agent, appearance is the suspension latex of brown color.
Embodiment 3 (formulation examples 3)
50 parts of butadiene-styrene latexes are placed in reaction kettle at room temperature, 2 parts of breasts are then added under stirring successively in order Gum stabilizing agents sodium sulfovinate, 2 parts of antifoaming agent silicone emulsions and 5 parts of micro-nano inertization agent nano silicon dioxides, are sufficiently stirred It is uniformly mixed to get a kind of drilling fluid latex class lubricating collapse-resisting agent, appearance is the suspension latex of brown color.
Embodiment 4 (filtrate reducing evaluation)
Latex class lubricating collapse-resisting agent used in the example is product made from embodiment 1, is surveyed using API filtration test method Try the ability of the product filtrate reducing.Test method is:The bentonite base that the mass fraction for preparing 1000ml is 5% is starched, and 400ml is taken Base slurry is for use, and 400ml bases is separately taken to starch, and the product of mass fraction 2% is added under stirring, in six press filtration commit a breach of etiquette upper test The middle filter pressing loss of the slurry of product is starched and be added to base, reads 30min leak-off numerical quantities.Table 1 is the measurement result of filter loss, is added Filter loss is substantially reduced after entering product.
Table 1
Embodiment 5 (inhibits shale expansion performance)
Latex class lubricating collapse-resisting agent used in the example is product made from example 1.Using NP-1 shale expansion instrument, weigh 10g dries bentonite, and 5min is compacted under 4MPa, measures the filtrate 10ml of two kinds of slurries in example 2 respectively, tests 8h linear expansions Amount.Test result is shown in Table 2, and shale expansion amount is smaller, shows to inhibit the ability of shale expansion stronger.
Table 2
Embodiment 6 (improves drilling fluid lubricating performance)
Latex class lubricating collapse-resisting agent used in the example is product made from example 1.Using Fann extreme boundary lubrication instrument, respectively It tests bentonite base slurry and the extreme boundary lubrication coefficient of the bentonite slurry of 2% product is added.Test result is shown in Table 3, extreme boundary lubrication system Number is lower, shows that the lubricating ability of system is stronger.
Table 3
In conclusion present disclosure is not limited in the above embodiments, the knowledgeable people in same area can Can propose other embodiments easily within the technological guidance's thought of the present invention, but this embodiment is included in this hair Within the scope of bright.

Claims (3)

1. a kind of drilling fluid latex class lubricating collapse-resisting agent, which is characterized in that by mass fraction include following components:40-60 parts Latex, 2-5 parts of latex stabilizers, 1-3 parts of antifoaming agent and 10-15 parts of micro-nano inertization agent;The latex be styrene-butadiene latex, Butadiene latex, butyl latex, polychloroprene latex, ethylene propylene rubber latex, isoprene rubber latex, NBR latex, acrylic latex one kind or Their mixture;The micro-nano inertization agent be micro-nano calcium carbonate, one kind in nano silicon dioxide or they Mixture.
2. drilling fluid latex class lubricating collapse-resisting agent according to claim 1, which is characterized in that the latex stabilizer is sulphur A kind of or their mixture in acid esters salt, sulfonate, carboxylate.
3. drilling fluid latex class lubricating collapse-resisting agent according to claim 1, which is characterized in that the antifoaming agent is emulsification silicon A kind of in oil, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether mixture or theirs is mixed Close object.
CN201810375597.6A 2018-04-24 2018-04-24 A kind of drilling fluid latex class lubricating collapse-resisting agent Pending CN108384519A (en)

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CN201810375597.6A CN108384519A (en) 2018-04-24 2018-04-24 A kind of drilling fluid latex class lubricating collapse-resisting agent

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112358856A (en) * 2020-11-05 2021-02-12 中国石油集团渤海钻探工程有限公司 Lubricating anti-sloughing agent for drilling fluid and preparation method thereof
CN113195677A (en) * 2018-12-12 2021-07-30 切弗朗菲利浦化学公司 Wellbore drilling composition
CN115093837A (en) * 2022-07-13 2022-09-23 中海石油(中国)有限公司湛江分公司 Wall-fixing agent and preparation method and application thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113195677A (en) * 2018-12-12 2021-07-30 切弗朗菲利浦化学公司 Wellbore drilling composition
CN112358856A (en) * 2020-11-05 2021-02-12 中国石油集团渤海钻探工程有限公司 Lubricating anti-sloughing agent for drilling fluid and preparation method thereof
CN115093837A (en) * 2022-07-13 2022-09-23 中海石油(中国)有限公司湛江分公司 Wall-fixing agent and preparation method and application thereof
CN115093837B (en) * 2022-07-13 2023-11-10 中海石油(中国)有限公司湛江分公司 Wall fixing agent and preparation method and application thereof

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Application publication date: 20180810