CN108384420A - Water-proof polyurethane composite coating - Google Patents

Water-proof polyurethane composite coating Download PDF

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Publication number
CN108384420A
CN108384420A CN201810234075.4A CN201810234075A CN108384420A CN 108384420 A CN108384420 A CN 108384420A CN 201810234075 A CN201810234075 A CN 201810234075A CN 108384420 A CN108384420 A CN 108384420A
Authority
CN
China
Prior art keywords
parts
water
agent
composite coating
polyurethane composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810234075.4A
Other languages
Chinese (zh)
Inventor
汪琦
郭元
章波
汪鹏
黄浩
许飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Pioneer Technology Co Ltd
Original Assignee
Hefei Pioneer Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Pioneer Technology Co Ltd filed Critical Hefei Pioneer Technology Co Ltd
Priority to CN201810234075.4A priority Critical patent/CN108384420A/en
Publication of CN108384420A publication Critical patent/CN108384420A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses water-proof polyurethane composite coatings, including following components:Polyurethane resin, alkyd resin, novolac epoxy resin, amino silane, Si acrylate lotion, acrylic polyol lotion, polytetrafluoroethylene (PTFE), bentonite, chlorinated paraffin, polyether polyol, toluene di-isocyanate(TDI), plasticizer, waterproofing agent, auxiliary agent.The auxiliary agent includes adhesion promoter, dispersant, advection agent, chain extender, antifoaming agent.The present invention has excellent water resistance, solves existing coating, poor waterproof properties, the short problem of service life.

Description

Water-proof polyurethane composite coating
Technical field
The present invention relates to a kind of coating, and in particular to water-proof polyurethane composite coating.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating be coated in the body surface being protected or decorated, and The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or lotion, add or do not add face Material, filler add corresponding additive, the thick liquid being formulated with organic solvent or water.
Coating is the necessity of building trade, most of coating water-proof poor performances on the market, when being used for skin, Through rain drop erosion and moisture erosion be easy for causing in a short time aging, it is dry and cracked, deform, fracture, be layered, not only influence beautiful It sees, and there are great security risks;Whens for interior architecture such as kitchen, bathroom etc., also there is constructional difficulties, leakage frequency Hair, can not effective protection wall the problems such as.
Invention content
The technical problem to be solved by the present invention is to coating water-proof poor performance, and it is an object of the present invention to provide water-proof polyurethane is compound Coating solves the problems, such as coating water-proof poor performance.
The present invention is achieved through the following technical solutions:
Water-proof polyurethane composite coating, including following components:Polyurethane resin, alkyd resin, phenolic aldehyde-epoxy resin, Amino silane, Si acrylate lotion, acrylic polyol lotion, polytetrafluoroethylene (PTFE), bentonite, chlorinated paraffin, polyether polyols Alcohol, toluene di-isocyanate(TDI), plasticizer, waterproofing agent, auxiliary agent.
The present invention uses polyurethane resin, alkyd resin, phenolic aldehyde-epoxy resin as film forming matter, can be full cross-linked Complementation forms the splendid film of hydrophobic performance, to greatly improve the water resistance of coating of the present invention;Amino silane, silica acrylic acid Ester lotion, acrylic polyol lotion, polytetrafluoroethylene (PTFE), bentonite, chlorinated paraffin, polyether polyol, toluene di-isocyanate(TDI), Plasticizer, waterproofing agent, auxiliary agent improve intensity, temperature tolerance, weatherability, corrosion resistance and the water proofing property of coating, in addition to this, apply Material has high adhesive strength, and service life is long, solves existing coating, poor waterproof properties, the short problem of service life.This hair Bright coating intensity is high, adhesive force is good, has excellent water resistance.
Water-proof polyurethane composite coating includes the component of following parts by weight:30-40 parts of polyurethane resins, 30-40 parts Alkyd resin, 20-25 parts of phenolic aldehyde-epoxy resin, 5-10 parts of amino silanes, 10-15 parts of Si acrylate lotions, 10-15 parts third Olefin(e) acid polyalcohol emulsion, 8-20 part polytetrafluoroethylene (PTFE), 10-20 parts of bentonites, 3-5 parts of chlorinated paraffins, 5-10 parts of polyether polyol, 10-15 parts of toluene di-isocyanate(TDI)s, 3-5 parts of plasticizer, 1-5 parts of waterproofing agents, 1-3 parts of auxiliary agents.The synthesis of present invention combination coating Performance, preferably best component proportion range.
Water-proof polyurethane composite coating includes the component of following parts by weight:40 parts of polyurethane resins, 35 parts of alkyd trees Fat, 23 parts of phenolic aldehyde-epoxy resin, 8 parts of amino silanes, 13 parts of Si acrylate lotions, 13 parts of acrylic polyol lotions, 18 parts Polytetrafluoroethylene (PTFE), 15 parts of bentonites, 4 parts of chlorinated paraffins, 8 parts of polyether polyol, 13 parts of toluene di-isocyanate(TDI)s, 4 parts of plasticizer, 3 parts of waterproofing agents, 2 parts of auxiliary agents.The comprehensive performance of present invention combination coating, preferably best component proportion.
The auxiliary agent includes adhesion promoter, dispersant, advection agent, chain extender, antifoaming agent.
The plasticizer includes following components:Tricresyl phosphate, methyl methacrylate, polyvinyl chloride, O-phthalic Dibutyl phthalate.The synergistic effect of tricresyl phosphate, methyl methacrylate, polyvinyl chloride, dibutyl phthalate, plasticising Effect is good.
Compared with prior art, the present invention having the following advantages and advantages:
1, water-proof polyurethane composite coating of the present invention has excellent water resistance, solves existing coating, water proofing property It can poor, the short problem of service life;
2, water-proof polyurethane composite coating intensity of the present invention is high, adhesive force is good, and service life is long;
3, water-proof polyurethane composite coating of the present invention has excellent temperature tolerance, weatherability, corrosion resistance.
Specific implementation mode
To make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiment, the present invention is made Further to be described in detail, exemplary embodiment of the invention and its explanation are only used for explaining the present invention, are not intended as to this The restriction of invention.
Embodiment 1
Water-proof polyurethane composite coating of the present invention, including following components:Polyurethane resin, alkyd resin, phenolic aldehyde-epoxy Resin, amino silane, Si acrylate lotion, acrylic polyol lotion, polytetrafluoroethylene (PTFE), bentonite, chlorinated paraffin, polyethers Polyalcohol, toluene di-isocyanate(TDI), plasticizer, waterproofing agent, auxiliary agent.The auxiliary agent includes adhesion promoter, dispersant, advection Agent, chain extender, antifoaming agent.The plasticizer includes following components:Tricresyl phosphate, methyl methacrylate, polyvinyl chloride, Dibutyl phthalate.The collaboration of tricresyl phosphate, methyl methacrylate, polyvinyl chloride, dibutyl phthalate Effect, plasticization effect are good.
The present invention uses polyurethane resin, alkyd resin, phenolic aldehyde-epoxy resin as film forming matter, can be full cross-linked Complementation forms the splendid film of hydrophobic performance, to greatly improve the water resistance of coating of the present invention;Amino silane, silica acrylic acid Ester lotion, acrylic polyol lotion, polytetrafluoroethylene (PTFE), bentonite, chlorinated paraffin, polyether polyol, toluene di-isocyanate(TDI), Plasticizer, waterproofing agent, auxiliary agent improve intensity, temperature tolerance, weatherability, corrosion resistance and the water proofing property of coating, in addition to this, apply Material has high adhesive strength, and service life is long, solves existing coating, poor waterproof properties, the short problem of service life.This hair Bright coating intensity is high, adhesive force is good, has excellent water resistance.
Embodiment 2
Based on embodiment 1, water-proof polyurethane composite coating includes the component of following parts by weight:30-40 parts of polyurethane Resin, 30-40 part alkyd resin, 20-25 parts of phenolic aldehyde-epoxy resin, 5-10 parts of amino silanes, 10-15 parts of Si acrylate breasts Liquid, 10-15 parts of acrylic polyol lotions, 8-20 parts of polytetrafluoroethylene (PTFE), 10-20 parts of bentonites, 3-5 parts of chlorinated paraffins, 5-10 Part polyether polyol, 10-15 parts of toluene di-isocyanate(TDI)s, 3-5 parts of plasticizer, 1-5 parts of waterproofing agents, 1-3 parts of auxiliary agents.Knot of the present invention Close the comprehensive performance of coating, preferably best component proportion range.
Embodiment 3
Based on above-described embodiment, water-proof polyurethane composite coating includes the component of following parts by weight:40 parts of polyurethane Resin, 35 parts of alkyd resins, 23 parts of phenolic aldehyde-epoxy resin, 8 parts of amino silanes, 13 parts of Si acrylate lotions, 13 parts of acrylic acid Polyalcohol emulsion, 18 parts of polytetrafluoroethylene (PTFE), 15 parts of bentonites, 4 parts of chlorinated paraffins, 8 parts of polyether polyol, 13 parts of toluene diisocyanates Acid esters, 4 parts of plasticizer, 3 parts of waterproofing agents, 2 parts of auxiliary agents.The comprehensive performance of present invention combination coating, the distribution of preferably best group Than.
Coating surface drying time of the present invention is not more than 7h, does solid work the time no more than 22h, and adhesion strength is more than 1.1Mpa, fracture Elongation is more than 600%, and tearing strength is more than 30N/mm, and water proofing property is excellent.
Above-described specific implementation mode has carried out further the purpose of the present invention, technical solution and advantageous effect It is described in detail, it should be understood that the foregoing is merely the specific implementation mode of the present invention, is not intended to limit the present invention Protection domain, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include Within protection scope of the present invention.

Claims (5)

1. water-proof polyurethane composite coating, which is characterized in that including following components:Polyurethane resin, alkyd resin, phenolic aldehyde- Epoxy resin, amino silane, Si acrylate lotion, acrylic polyol lotion, polytetrafluoroethylene (PTFE), bentonite, chlorinated paraffin, Polyether polyol, toluene di-isocyanate(TDI), plasticizer, waterproofing agent, auxiliary agent.
2. water-proof polyurethane composite coating according to claim 1, which is characterized in that include the group of following parts by weight Point:30-40 parts of polyurethane resins, 30-40 parts of alkyd resins, 20-25 parts of phenolic aldehyde-epoxy resin, 5-10 parts of amino silanes, 10- 15 parts of Si acrylate lotions, 10-15 parts of acrylic polyol lotions, 8-20 parts of polytetrafluoroethylene (PTFE), 10-20 parts of bentonites, 3-5 Part chlorinated paraffin, 5-10 parts of polyether polyol, 10-15 parts of toluene di-isocyanate(TDI)s, 3-5 parts of plasticizer, 1-5 parts of waterproofing agents, 1-3 Part auxiliary agent.
3. water-proof polyurethane composite coating according to claim 2, which is characterized in that include the group of following parts by weight Point:40 parts of polyurethane resins, 35 parts of alkyd resins, 23 parts of phenolic aldehyde-epoxy resin, 8 parts of amino silanes, 13 parts of Si acrylate breasts Liquid, 13 parts of acrylic polyol lotions, 18 parts of polytetrafluoroethylene (PTFE), 15 parts of bentonites, 4 parts of chlorinated paraffins, 8 parts of polyether polyol, 13 parts of toluene di-isocyanate(TDI)s, 4 parts of plasticizer, 3 parts of waterproofing agents, 2 parts of auxiliary agents.
4. water-proof polyurethane composite coating according to claim 1, which is characterized in that the auxiliary agent includes that adhesive force increases Into agent, dispersant, advection agent, chain extender, antifoaming agent.
5. water-proof polyurethane composite coating according to claim 1, which is characterized in that the plasticizer includes with the following group Point:Tricresyl phosphate, methyl methacrylate, polyvinyl chloride, dibutyl phthalate.
CN201810234075.4A 2018-03-21 2018-03-21 Water-proof polyurethane composite coating Withdrawn CN108384420A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810234075.4A CN108384420A (en) 2018-03-21 2018-03-21 Water-proof polyurethane composite coating

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Application Number Priority Date Filing Date Title
CN201810234075.4A CN108384420A (en) 2018-03-21 2018-03-21 Water-proof polyurethane composite coating

Publications (1)

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CN108384420A true CN108384420A (en) 2018-08-10

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CN201810234075.4A Withdrawn CN108384420A (en) 2018-03-21 2018-03-21 Water-proof polyurethane composite coating

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112208177A (en) * 2020-10-10 2021-01-12 江苏厚生新能源科技有限公司 High-breathability PE composite fabric and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104327712A (en) * 2014-11-05 2015-02-04 侨健新能源科技(苏州)有限公司 High-adhesion and wear-resistant engineering mechanical waterproof paint
CN105199589A (en) * 2015-09-22 2015-12-30 天长市开林化工有限公司 Weather-resistant anti-abrasion modified polyurethane waterborne paint
CN106243979A (en) * 2016-08-26 2016-12-21 江苏格桑花涂料有限公司 A kind of PU EP type dam water-repellent paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104327712A (en) * 2014-11-05 2015-02-04 侨健新能源科技(苏州)有限公司 High-adhesion and wear-resistant engineering mechanical waterproof paint
CN105199589A (en) * 2015-09-22 2015-12-30 天长市开林化工有限公司 Weather-resistant anti-abrasion modified polyurethane waterborne paint
CN106243979A (en) * 2016-08-26 2016-12-21 江苏格桑花涂料有限公司 A kind of PU EP type dam water-repellent paint and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
蔡素德主编: "《有机化学(第三版)》", 31 October 2006, 中国建筑工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112208177A (en) * 2020-10-10 2021-01-12 江苏厚生新能源科技有限公司 High-breathability PE composite fabric and preparation method thereof
CN112208177B (en) * 2020-10-10 2022-07-22 江苏厚生新能源科技有限公司 High-breathability PE composite fabric and preparation method thereof

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Application publication date: 20180810

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