CN108384375A - Environment-friendlyanti-corrosive anti-corrosive paint - Google Patents

Environment-friendlyanti-corrosive anti-corrosive paint Download PDF

Info

Publication number
CN108384375A
CN108384375A CN201810258695.1A CN201810258695A CN108384375A CN 108384375 A CN108384375 A CN 108384375A CN 201810258695 A CN201810258695 A CN 201810258695A CN 108384375 A CN108384375 A CN 108384375A
Authority
CN
China
Prior art keywords
parts
corrosive
friendlyanti
environment
paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810258695.1A
Other languages
Chinese (zh)
Inventor
占军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810258695.1A priority Critical patent/CN108384375A/en
Publication of CN108384375A publication Critical patent/CN108384375A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of Environment-friendlyanti-corrosive anti-corrosive paints, are prepared by the raw material of following weight parts：97 103 parts of fluorine silicon-modified acrylic ester emulsion, 5 15 parts of melamine, 22 38 parts of iron oxide red, 0.2 1.2 parts of corrosion inhibiter, 48 parts of filler, 13 parts of titanium dioxide, 24 parts of zinc molybdate, 0.5 1.5 parts of ammonium fluosilicate, 24 parts of aluminium triphosphate, 20 35 parts of water, 6 10 parts of coalescents, 24 parts of dispersant, 0.5 1 parts of antifoaming agent, 0.7 1.5 parts of 2 amino, 2 methyl, 1 propyl alcohol.Environment-friendlyanti-corrosive anti-corrosive paint of the present invention, have many advantages, such as that excellent adhesive force, wearability are strong, excellent in cushion effect, be avoided that contact and absorption with outside moisture and oxygen, can fundamentally prevent the generation of corrosion phenomenon, also have many advantages, such as easy for construction, anti-corrosion, favorable rust preventing effect simultaneously.

Description

Environment-friendlyanti-corrosive anti-corrosive paint
Technical field
The present invention relates to a kind of coating, and in particular to a kind of Environment-friendlyanti-corrosive anti-corrosive paint.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating be coated in the body surface being protected or decorated, and The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or lotion, add or do not add face Material, filler add corresponding additive, the thick liquid being formulated with organic solvent or water.
Chinese coating circle is more authoritative《Coating process》What one book was defined as：" coating is a kind of material, this material Material can be coated in object surface with different construction technologies, and formation adherency is secured, has some strength, continuous solid-state thin Film.The film common name film formed in this way, also known as paint film or coating.”
Anticorrosive paint is generally divided into conventional anticorrosive paint and anticorrosive paint, is essential one kind in paint Coating.Conventional anticorrosive paint is under general condition, to play the role of the longevity etch-proof, protection non-ferrous metal uses to metal etc. Life；It for anticorrosive paint refers to relatively conventional anticorrosive paint, can be applied in relatively harsh corrosive environment, and with can reach A kind of anticorrosive paint of protection period longer than conventional anticorrosive paint.
It can be divided into according to purposes：Rubber antifouling paint, ship antifouling paint, metal antifouling paint, automobile are anti- Rotten paint, pipeline antifouling paint, furniture antifouling paint, steel construction antifouling paint.
It is divided by resin film forming：Epoxy anticorrosion paint, Vinylidene Chloride antifouling paint, chlorinated rubber antifouling paint, polyurethane Antifouling paint, acrylic acid antifouling paint, inorganic anti-corrosion paint, highly-chlorinated polyethylene antifouling paint.
However, prior art anticorrosion with coat performance and bad.
Invention content
The present invention adopts the following technical scheme that：
A kind of Environment-friendlyanti-corrosive anti-corrosive paint is prepared by the raw material of following weight parts：Fluorine silicon-modified acrylic ester emulsion 97- 103 parts, 5-15 parts of melamine, 22-38 parts of iron oxide red, 0.2-1.2 parts of corrosion inhibiter, 4-8 parts of filler, 1-3 parts of titanium dioxide, 2-4 parts of zinc molybdate, 0.5-1.5 parts of ammonium fluosilicate, 2-4 parts of aluminium triphosphate, 20-35 parts of water, 6-10 parts of coalescents, dispersant 2-4 parts, 0.5-1 parts of antifoaming agent, 0.7-1.5 parts of 2-amino-2-methyl-1-propanol.
The dispersant is neopelex or alkyl phenol polyoxyethylene ether.
The antifoaming agent is dimethicone or silicon ether copolymer.
The filler is modified micaceous powder and/or modified magnesium hydroxide.Further, the filler is changed by 65-75wt% Property mica powder and 25-35wt% modified magnesium hydroxides composition.
The modified micaceous powder is prepared by following methods：By 75-85g acetone, 1-2g mica powders, 0.7-1.4g 3- ammonia third The chloro- 4,4,5,5- tetramethyls -1,3,2- dioxaphospholane of ethyl triethoxy silicane alkane, 0.5-1.3g 2-, 0.05-0.2g tri- It is that 60-150r/min stirrings 5-15min is uniformly mixed that n-propylamine, which is added in three-necked flask with rotating speed, then next time at 55-65 DEG C Stream reaction 2-6h, centrifugation, will be deposited in vacuum degree be 100-150Pa, at temperature is 45-55 DEG C dry 20-30h to get.
The modified magnesium hydroxide is prepared by following methods：By magnesium hydroxide microwave power be 200-400W, Microwave Frequency Rate is that microwave activates 1-3min, magnesium hydroxide, toluene, aluminate coupling agent after then activating microwave under 2400-2500MHz It is 1 in mass ratio：(5-15)：(0.1-0.5) is that 200-400r/min stirs 20-40min with rotating speed, and centrifugation will be deposited in true At reciprocal of duty cycle is 100-150Pa, temperature is 45-55 DEG C dry 20-30h to get.
The coalescents are ethylene glycol ethyl ether or lauryl alcohol ester or butyl glycol ether.
The corrosion inhibiter is naphthenic acid imidazoline.
The Environment-friendlyanti-corrosive anti-corrosive paint of the present invention, may be used industry universal method and is prepared.Further, the present invention also carries A kind of preparation method of Environment-friendlyanti-corrosive anti-corrosive paint has been supplied, has been included the following steps：
S1, by fluorine silicon-modified acrylic ester emulsion, melamine, iron oxide red, corrosion inhibiter with rotating speed it is 250-400r/ Min stirs 25-45min and is uniformly mixed, and obtains mixed liquor A；
S2, by filler, titanium dioxide, zinc molybdate, ammonium fluosilicate, aluminium triphosphate, water with rotating speed it is 250-400r/min It stirs 25-45min to be uniformly mixed, obtains mixed liquid B；
S3, mixed liquor A is added in mixed liquid B, adds coalescents, dispersant, antifoaming agent, 2- amino-2-methyls- 1- propyl alcohol with rotating speed be 250-400r/min stir 25-45min uniformly to get.
Environment-friendlyanti-corrosive anti-corrosive paint of the present invention has many advantages, such as that excellent adhesive force, wearability are strong, excellent in cushion effect, can keep away Exempt from contact and the absorption with outside moisture and oxygen, can fundamentally prevent the generation of corrosion phenomenon, while also having and applying The advantages that work is convenient, anti-corrosion, favorable rust preventing effect.
Specific implementation mode
Paint film impact resistance：GB/T1731-1993 standards are tested according to national standards.
The resistance to combustion time：GB/T15442.2-1995 is tested according to national standards.
Acid resistance is tested：With reference to GB/T1763-79, (50 × 100 × 0.2mm of iron plate specification) applies anti-corrosion on tinplate Coating prepares 3 pieces of model, makees parallel laboratory test, it is to be coated do solid work after, measured under the conditions of constant temperature and humidity.Prepare 30% mass point The H of Particle density2SO4Solution is dipped vertically into the H that temperature is 25 ± 1 DEG C in beaker, by the 2/3 of model2SO4In medium, capping, Regular moisturizing.Immerse H2SO4Model in medium is primary per observation for 24 hours, checks that model need to be rinsed through tap water, use filter paper every time After droplet is blotted, observes and records coating and start loss of gloss, discoloration, blistering, rust spot, the time to fall off.
Surface drying time measures, and GB/T 1728-89 paint films drying time measuring method carries out according to national standards.
Each raw material introduction in embodiment：
Melamine, No. CAS：108-78-1.
Iron oxide red is the iron oxide red that Xuzhou Heng Long pigment Co., Ltd provides, and granularity is 325 mesh, and grade is level-one Product, model 130.
The material of steel construction is Q345B.
Titanium dioxide is the rutile type nano dioxy for the model TTP-R20 that Nanjing Tian Hang new materials Co., Ltd provides Change titanium, primary particle size 20nm.
Ammonium fluosilicate, No. CAS：16919-19-0.
Aluminium triphosphate is the technical grade aluminium triphosphate that Hebei Chu Mu Chemical Industry Science Co., Ltd provides, granularity 400 Mesh.
2-amino-2-methyl-1-propanol, No. CAS：124-68-5.
Neopelex, No. CAS：25155-30-0.
Dimethicone is the dimethicone for the model PMX-200 that Dow corning provides, viscosity 1000CS.
Acetone, No. CAS：67-64-1.
Mica powder is the quiet mica powder processed for the model CJ-A2 that Shanghai Bo Tong Chemical Co., Ltd.s provide, granularity 1250 Mesh.
3- aminopropyl triethoxysilanes, No. CAS：3663-44-3.
2- chloro- 4,4,5,5- tetramethyls -1,3,2- dioxaphospholane, No. CAS：14812-59-0.
Tri-n-Propylamine, No. CAS：102-69-2.
Magnesium hydroxide is the magnesium hydroxide for the model GY915 that Guang Yuan Ultramicro-powders Co., Ltd of Jiangyin City provides, and specification is 1250 mesh.
Toluene, No. CAS：108-88-3.
Butyl glycol ether, No. CAS：111-76-2.
Fluorine silicon-modified acrylic ester emulsion is according to shown in embodiment in the Chinese patent application No. is 201210013514.1 2 It is prepared by method.
Zinc molybdate, No. CAS：13767-32-3.
Naphthenic acid imidazoline is according to method system shown in embodiment in the Chinese patent application No. is 200810226464.9 2 It is standby.
The Aluminate coupling that aluminate coupling agent is the model DL-411 that Shandong Jia Ying Chemical Industry Science Co., Ltd provides Agent DL-411.
Embodiment 1
The anticorrosive derusting construction technology of steel construction, includes the following steps：
(1) oxide skin on surface, rust, old coating, pollutant are cleaned out by steel construction with perching knife, steel surface is made to remove Rust grade reaches ST2 grades；
(2) to the steel structure surface after processing of rust removing, routinely technique sprays Environment-friendlyanti-corrosive anti-corrosive paint, and coating thickness is 20 μm, After natural drying paint film is formed in steel surface.
The Environment-friendlyanti-corrosive anti-corrosive paint is prepared by the raw material of following weight parts：Fluorine silicon-modified acrylic ester emulsion 100 Part, 8 parts of melamine, 30 parts of iron oxide red, 0.5 part of corrosion inhibiter, 6 parts of filler, 1.5 parts of titanium dioxide, 2.5 parts of zinc molybdate, fluorine 1 part of ammonium silicate, 3 parts of aluminium triphosphate, 25 parts of deionized water, 8 parts of coalescents, 3 parts of dispersant, 0.6 part of antifoaming agent, 2- ammonia Base -2- methyl-1s -0.9 part of propyl alcohol.
The dispersant is neopelex.
The antifoaming agent is dimethicone.
The filler is modified micaceous powder.
The modified micaceous powder is prepared by following methods：By 80g acetone, 1.4g mica powders, three ethoxy of 1.0g 3- aminopropyls Three mouthfuls of burnings are added in the chloro- 4,4,5,5- tetramethyls -1,3,2- dioxaphospholane of base silane, 0.85g 2-, 0.1g Tri-n-Propylamines 8min is stirred in bottle with rotating speed for 120r/min to be uniformly mixed, then the back flow reaction 4h at 60 DEG C, is 6000r/min with rotating speed Centrifuge 20min, will be deposited in vacuum degree be 130Pa, temperature be at 50 DEG C dry for 24 hours to get modified micaceous powder.
The coalescents are butyl glycol ether.
The corrosion inhibiter is naphthenic acid imidazoline.
The preparation method of the Environment-friendlyanti-corrosive anti-corrosive paint, includes the following steps：
S1, fluorine silicon-modified acrylic ester emulsion, melamine, iron oxide red, corrosion inhibiter are stirred with rotating speed for 300r/min It mixes 35min to be uniformly mixed, obtains mixed liquor A；
S2, by filler, titanium dioxide, zinc molybdate, ammonium fluosilicate, aluminium triphosphate, deionized water with rotating speed it is 300r/ Min stirs 35min and is uniformly mixed, and obtains mixed liquid B；
S3, mixed liquor A is added in mixed liquid B, adds coalescents, dispersant, antifoaming agent, 2- amino-2-methyls- 1- propyl alcohol is that 300r/min stirs 35min uniformly to get Environment-friendlyanti-corrosive anti-corrosive paint with rotating speed.
Embodiment 2
The anticorrosive derusting construction technology of steel construction, includes the following steps：
(1) oxide skin on surface, rust, old coating, pollutant are cleaned out by steel construction with perching knife, steel surface is made to remove Rust grade reaches ST2 grades；
(2) to the steel structure surface after processing of rust removing, routinely technique sprays Environment-friendlyanti-corrosive anti-corrosive paint, and coating thickness is 20 μm, After natural drying paint film is formed in steel surface.
The Environment-friendlyanti-corrosive anti-corrosive paint is prepared by the raw material of following weight parts：Fluorine silicon-modified acrylic ester emulsion 100 Part, 8 parts of melamine, 30 parts of iron oxide red, 0.5 part of corrosion inhibiter, 6 parts of filler, 1.5 parts of titanium dioxide, 2.5 parts of zinc molybdate, fluorine 1 part of ammonium silicate, 3 parts of aluminium triphosphate, 25 parts of deionized water, 8 parts of coalescents, 3 parts of dispersant, 0.6 part of antifoaming agent, 2- ammonia Base -2- methyl-1s -0.9 part of propyl alcohol.
The dispersant is neopelex.
The antifoaming agent is dimethicone.
The filler is mica powder.
The coalescents are butyl glycol ether.
The corrosion inhibiter is naphthenic acid imidazoline.
The preparation method of the Environment-friendlyanti-corrosive anti-corrosive paint, includes the following steps：
S1, fluorine silicon-modified acrylic ester emulsion, melamine, iron oxide red, corrosion inhibiter are stirred with rotating speed for 300r/min It mixes 35min to be uniformly mixed, obtains mixed liquor A；
S2, by filler, titanium dioxide, zinc molybdate, ammonium fluosilicate, aluminium triphosphate, deionized water with rotating speed it is 300r/ Min stirs 35min and is uniformly mixed, and obtains mixed liquid B；
S3, mixed liquor A is added in mixed liquid B, adds coalescents, dispersant, antifoaming agent, 2- amino-2-methyls- 1- propyl alcohol is that 300r/min stirs 35min uniformly to get Environment-friendlyanti-corrosive anti-corrosive paint with rotating speed.
Embodiment 3
The anticorrosive derusting construction technology of steel construction, includes the following steps：
(1) oxide skin on surface, rust, old coating, pollutant are cleaned out by steel construction with perching knife, steel surface is made to remove Rust grade reaches ST2 grades；
(2) to the steel structure surface after processing of rust removing, routinely technique sprays Environment-friendlyanti-corrosive anti-corrosive paint, and coating thickness is 20 μm, After natural drying paint film is formed in steel surface.
The Environment-friendlyanti-corrosive anti-corrosive paint is prepared by the raw material of following weight parts：Fluorine silicon-modified acrylic ester emulsion 100 Part, 8 parts of melamine, 30 parts of iron oxide red, 0.5 part of corrosion inhibiter, 6 parts of filler, 1.5 parts of titanium dioxide, 2.5 parts of zinc molybdate, fluorine 1 part of ammonium silicate, 3 parts of aluminium triphosphate, 25 parts of deionized water, 8 parts of coalescents, 3 parts of dispersant, 0.6 part of antifoaming agent, 2- ammonia Base -2- methyl-1s -0.9 part of propyl alcohol.
The dispersant is neopelex.
The antifoaming agent is dimethicone.
The filler is modified micaceous powder.
The modified micaceous powder is prepared by following methods：By 80g acetone, 1.4g mica powders, three ethoxy of 1.0g 3- aminopropyls It is that 120r/min stirrings 8min is uniformly mixed that base silane, 0.1g Tri-n-Propylamines, which are added in three-necked flask with rotating speed, then at 60 DEG C Lower back flow reaction 4h, with rotating speed be 6000r/min centrifuge 20min, will be deposited in vacuum degree be 130Pa, temperature be at 50 DEG C do It is dry for 24 hours to get modified micaceous powder.
The coalescents are butyl glycol ether.
The corrosion inhibiter is naphthenic acid imidazoline.
The preparation method of the Environment-friendlyanti-corrosive anti-corrosive paint, includes the following steps：
S1, fluorine silicon-modified acrylic ester emulsion, melamine, iron oxide red, corrosion inhibiter are stirred with rotating speed for 300r/min It mixes 35min to be uniformly mixed, obtains mixed liquor A；
S2, by filler, titanium dioxide, zinc molybdate, ammonium fluosilicate, aluminium triphosphate, deionized water with rotating speed it is 300r/ Min stirs 35min and is uniformly mixed, and obtains mixed liquid B；
S3, mixed liquor A is added in mixed liquid B, adds coalescents, dispersant, antifoaming agent, 2- amino-2-methyls- 1- propyl alcohol is that 300r/min stirs 35min uniformly to get Environment-friendlyanti-corrosive anti-corrosive paint with rotating speed.
Embodiment 4
The anticorrosive derusting construction technology of steel construction, includes the following steps：
(1) oxide skin on surface, rust, old coating, pollutant are cleaned out by steel construction with perching knife, steel surface is made to remove Rust grade reaches ST2 grades；
(2) to the steel structure surface after processing of rust removing, routinely technique sprays Environment-friendlyanti-corrosive anti-corrosive paint, and coating thickness is 20 μm, After natural drying paint film is formed in steel surface.
The Environment-friendlyanti-corrosive anti-corrosive paint is prepared by the raw material of following weight parts：Fluorine silicon-modified acrylic ester emulsion 100 Part, 8 parts of melamine, 30 parts of iron oxide red, 0.5 part of corrosion inhibiter, 6 parts of filler, 1.5 parts of titanium dioxide, 2.5 parts of zinc molybdate, fluorine 1 part of ammonium silicate, 3 parts of aluminium triphosphate, 25 parts of deionized water, 8 parts of coalescents, 3 parts of dispersant, 0.6 part of antifoaming agent, 2- ammonia Base -2- methyl-1s -0.9 part of propyl alcohol.
The dispersant is neopelex.
The antifoaming agent is dimethicone.
The filler is modified magnesium hydroxide.
The modified magnesium hydroxide is prepared by following methods：By magnesium hydroxide microwave power is 300W, microwave frequency is Microwave activates 2min under 2450MHz, and magnesium hydroxide, toluene, aluminate coupling agent after then activating microwave are in mass ratio 1：10：0.2 stirs 30min with rotating speed for 300r/min, is that 6000r/min centrifuges 20min with rotating speed, will be deposited in vacuum degree is 130Pa, temperature are to be dried for 24 hours to get modified magnesium hydroxide at 50 DEG C.
The coalescents are butyl glycol ether.
The corrosion inhibiter is naphthenic acid imidazoline.
The preparation method of the Environment-friendlyanti-corrosive anti-corrosive paint, includes the following steps：
S1, fluorine silicon-modified acrylic ester emulsion, melamine, iron oxide red, corrosion inhibiter are stirred with rotating speed for 300r/min It mixes 35min to be uniformly mixed, obtains mixed liquor A；
S2, by filler, titanium dioxide, zinc molybdate, ammonium fluosilicate, aluminium triphosphate, deionized water with rotating speed it is 300r/ Min stirs 35min and is uniformly mixed, and obtains mixed liquid B；
S3, mixed liquor A is added in mixed liquid B, adds coalescents, dispersant, antifoaming agent, 2- amino-2-methyls- 1- propyl alcohol is that 300r/min stirs 35min uniformly to get Environment-friendlyanti-corrosive anti-corrosive paint with rotating speed.
Embodiment 5
The anticorrosive derusting construction technology of steel construction, includes the following steps：
(1) oxide skin on surface, rust, old coating, pollutant are cleaned out by steel construction with perching knife, steel surface is made to remove Rust grade reaches ST2 grades；
(2) to the steel structure surface after processing of rust removing, routinely technique sprays Environment-friendlyanti-corrosive anti-corrosive paint, and coating thickness is 20 μm, After natural drying paint film is formed in steel surface.Paint film impact resistance is 297Ncm.
The Environment-friendlyanti-corrosive anti-corrosive paint is prepared by the raw material of following weight parts：Fluorine silicon-modified acrylic ester emulsion 100 Part, 8 parts of melamine, 30 parts of iron oxide red, 0.5 part of corrosion inhibiter, 6 parts of filler, 1.5 parts of titanium dioxide, 2.5 parts of zinc molybdate, fluorine 1 part of ammonium silicate, 3 parts of aluminium triphosphate, 25 parts of deionized water, 8 parts of coalescents, 3 parts of dispersant, 0.6 part of antifoaming agent, 2- ammonia Base -2- methyl-1s -0.9 part of propyl alcohol.
The dispersant is neopelex.
The antifoaming agent is dimethicone.
The filler is mixed by the modified micaceous powder of 70wt% and 30wt% modified magnesium hydroxides.
The modified micaceous powder is prepared by following methods：By 80g acetone, 1.4g mica powders, three ethoxy of 1.0g 3- aminopropyls Three mouthfuls of burnings are added in the chloro- 4,4,5,5- tetramethyls -1,3,2- dioxaphospholane of base silane, 0.85g 2-, 0.1g Tri-n-Propylamines 8min is stirred in bottle with rotating speed for 120r/min to be uniformly mixed, then the back flow reaction 4h at 60 DEG C, is 6000r/min with rotating speed Centrifuge 20min, will be deposited in vacuum degree be 130Pa, temperature be at 50 DEG C dry for 24 hours to get modified micaceous powder.
The modified magnesium hydroxide is prepared by following methods：By magnesium hydroxide microwave power is 300W, microwave frequency is Microwave activates 2min under 2450MHz, and magnesium hydroxide, toluene, aluminate coupling agent after then activating microwave are in mass ratio 1：10：0.2 stirs 30min with rotating speed for 300r/min, is that 6000r/min centrifuges 20min with rotating speed, will be deposited in vacuum degree is 130Pa, temperature are to be dried for 24 hours to get modified magnesium hydroxide at 50 DEG C.
The coalescents are butyl glycol ether.
The corrosion inhibiter is naphthenic acid imidazoline.
The preparation method of the Environment-friendlyanti-corrosive anti-corrosive paint, includes the following steps：
S1, fluorine silicon-modified acrylic ester emulsion, melamine, iron oxide red, corrosion inhibiter are stirred with rotating speed for 300r/min It mixes 35min to be uniformly mixed, obtains mixed liquor A；
S2, by filler, titanium dioxide, zinc molybdate, ammonium fluosilicate, aluminium triphosphate, deionized water with rotating speed it is 300r/ Min stirs 35min and is uniformly mixed, and obtains mixed liquid B；
S3, mixed liquor A is added in mixed liquid B, adds coalescents, dispersant, antifoaming agent, 2- amino-2-methyls- 1- propyl alcohol is that 300r/min stirs 35min uniformly to get Environment-friendlyanti-corrosive anti-corrosive paint with rotating speed.Environment-friendlyanti-corrosive anti-corrosive paint performance test knot Fruit：Surface drying time is 35min, 30%H2SO4For 2808h, the resistance to combustion time is 48min.
Test case 1
The paint film formed to the embodiment 1-4 Environment-friendlyanti-corrosive anti-corrosive paints prepared and step (2) steel structure surface carries out performance survey Examination, concrete outcome are shown in Table 1.
Table 1：Test result table
Environment-friendlyanti-corrosive anti-corrosive paint of the present invention has many advantages, such as that excellent adhesive force, wearability are strong, excellent in cushion effect, can keep away Exempt from contact and the absorption with outside moisture and oxygen, can fundamentally prevent the generation of corrosion phenomenon, while also having and applying The advantages that work is convenient, anti-corrosion, favorable rust preventing effect.

Claims (8)

1. a kind of Environment-friendlyanti-corrosive anti-corrosive paint is prepared by the raw material of following weight parts：Fluorine silicon-modified acrylic ester emulsion 97-103 Part, 5-15 parts of melamine, 22-38 parts of iron oxide red, 0.2-1.2 parts of corrosion inhibiter, 4-8 parts of filler, 1-3 parts of titanium dioxide, molybdenum Sour zinc 2-4 parts, 0.5-1.5 parts of ammonium fluosilicate, 2-4 parts of aluminium triphosphate, 20-35 parts of water, 6-10 parts of coalescents, dispersant 2- 4 parts, 0.5-1 parts of antifoaming agent, 0.7-1.5 parts of 2-amino-2-methyl-1-propanol.
2. Environment-friendlyanti-corrosive anti-corrosive paint as described in claim 1, which is characterized in that the dispersant be neopelex or Alkyl phenol polyoxyethylene ether.
3. Environment-friendlyanti-corrosive anti-corrosive paint as described in claim 1, which is characterized in that the antifoaming agent is that dimethicone or silicon ether are total Polymers.
4. Environment-friendlyanti-corrosive anti-corrosive paint as described in claim 1, which is characterized in that the filler is modified micaceous powder and/or modification Magnesium hydroxide；Preferably, the filler is made of the modified micaceous powder of 65-75wt% and 25-35wt% modified magnesium hydroxides.
5. Environment-friendlyanti-corrosive anti-corrosive paint as claimed in claim 4, which is characterized in that the modified micaceous powder is prepared by following methods： By 75-85g acetone, 1-2g mica powders, 0.7-1.4g 3- aminopropyl triethoxysilanes, the chloro- 4,4,5,5- of 0.5-1.3g 2- It is 60-150r/ that tetramethyl -1,3,2- dioxaphospholane, 0.05-0.2g Tri-n-Propylamines, which are added in three-necked flask with rotating speed, Min stirs 5-15min and is uniformly mixed, then the back flow reaction 2-6h at 55-65 DEG C, centrifugation, and will be deposited in vacuum degree is 100- 150Pa, temperature be at 45-55 DEG C dry 20-30h to get.
6. Environment-friendlyanti-corrosive anti-corrosive paint as claimed in claim 4, which is characterized in that the modified magnesium hydroxide is by following methods system It is standby：By magnesium hydroxide, in the case where microwave power is 200-400W, microwave frequency is 2400-2500MHz, microwave activates 1-3min, then Magnesium hydroxide, toluene, aluminate coupling agent after microwave is activated are 1 in mass ratio：(5-15)：(0.1-0.5) is with rotating speed 200-400r/min stirs 20-40min, centrifugation, will be deposited in vacuum degree be 100-150Pa, it is dry at temperature is 45-55 DEG C 20-30h to get.
7. Environment-friendlyanti-corrosive anti-corrosive paint as described in claim 1, which is characterized in that the coalescents are ethylene glycol ethyl ether or 12 Alcohol ester or butyl glycol ether.
8. Environment-friendlyanti-corrosive anti-corrosive paint as described in claim 1, which is characterized in that the corrosion inhibiter is naphthenic acid imidazoline.
CN201810258695.1A 2018-03-27 2018-03-27 Environment-friendlyanti-corrosive anti-corrosive paint Pending CN108384375A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810258695.1A CN108384375A (en) 2018-03-27 2018-03-27 Environment-friendlyanti-corrosive anti-corrosive paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810258695.1A CN108384375A (en) 2018-03-27 2018-03-27 Environment-friendlyanti-corrosive anti-corrosive paint

Publications (1)

Publication Number Publication Date
CN108384375A true CN108384375A (en) 2018-08-10

Family

ID=63072817

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810258695.1A Pending CN108384375A (en) 2018-03-27 2018-03-27 Environment-friendlyanti-corrosive anti-corrosive paint

Country Status (1)

Country Link
CN (1) CN108384375A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116426174A (en) * 2023-03-02 2023-07-14 龙南县彩艺装饰材料厂 Preparation method of high-flame-retardance high-weather-resistance stone-like coating
CN117625027A (en) * 2023-12-18 2024-03-01 山东冠彩包装印务有限公司 High-strength chemical barrel corrosion inhibitor for ocean transportation and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103627286A (en) * 2013-11-29 2014-03-12 深圳市安品有机硅材料有限公司 Water-based finishing coat for heavy-duty coating and preparation method of water-based finishing coat
CN104277652A (en) * 2014-10-20 2015-01-14 芜湖县双宝建材有限公司 Water-based anticorrosive paint
CN104673039A (en) * 2015-02-04 2015-06-03 浙江天女集团制漆有限公司 Organic-silicon organic-fluorine modified acrylic heavy anti-corrosion coating and preparation method thereof
CN106978017A (en) * 2017-05-24 2017-07-25 佛山实瑞先导材料研究院（普通合伙） A kind of environment-friendlywater-based water-based anticorrosive paint and preparation method thereof
CN107474664A (en) * 2017-09-04 2017-12-15 宁国市润丰金属制品有限公司 A kind of anti-corrosive antirusting paint for vehicle-carrying foodstuff detection device stirring wheel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103627286A (en) * 2013-11-29 2014-03-12 深圳市安品有机硅材料有限公司 Water-based finishing coat for heavy-duty coating and preparation method of water-based finishing coat
CN104277652A (en) * 2014-10-20 2015-01-14 芜湖县双宝建材有限公司 Water-based anticorrosive paint
CN104673039A (en) * 2015-02-04 2015-06-03 浙江天女集团制漆有限公司 Organic-silicon organic-fluorine modified acrylic heavy anti-corrosion coating and preparation method thereof
CN106978017A (en) * 2017-05-24 2017-07-25 佛山实瑞先导材料研究院（普通合伙） A kind of environment-friendlywater-based water-based anticorrosive paint and preparation method thereof
CN107474664A (en) * 2017-09-04 2017-12-15 宁国市润丰金属制品有限公司 A kind of anti-corrosive antirusting paint for vehicle-carrying foodstuff detection device stirring wheel

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116426174A (en) * 2023-03-02 2023-07-14 龙南县彩艺装饰材料厂 Preparation method of high-flame-retardance high-weather-resistance stone-like coating
CN116426174B (en) * 2023-03-02 2024-02-20 龙南县彩艺装饰材料厂 Preparation method of high-flame-retardance high-weather-resistance stone-like coating
CN117625027A (en) * 2023-12-18 2024-03-01 山东冠彩包装印务有限公司 High-strength chemical barrel corrosion inhibitor for ocean transportation and preparation method thereof
CN117625027B (en) * 2023-12-18 2024-07-19 浙江上青元电力科技有限公司 High-strength chemical barrel corrosion inhibitor for ocean transportation and preparation method thereof

Similar Documents

Publication Publication Date Title
CN107964351B (en) Water-based composite zinc-aluminum anticorrosive paint
CN103450719B (en) A kind of long-acting aqueous, environmental protective steel construction protection coating
US7138184B2 (en) Coating composition
CN101633808B (en) High chlorinated polyethylene coating containing stainless steel flakes and preparation method thereof
CN108441085B (en) Water-based super-amphiphobic long-acting anticorrosive coating and preparation method thereof
CN108192403B (en) Solvent type zinc-aluminum coating
RU2741551C2 (en) Weld-through primer
CN106085070A (en) A kind of low-surface-energy micro nano-coatings material and preparation method thereof
CN105925178B (en) A kind of aqueous organic inorganic hybridization anticorrosive paint composition and preparation method
CN111253832B (en) Heavy-duty anticorrosive paint and application thereof
CN110885574B (en) Water-based inorganic silicate zinc-rich coating and preparation method thereof
US5747561A (en) Solid surface modifier
CN103122186B (en) Environment-friendly treating fluid for preventing steel rails from corrosion and steel rail corrosion prevention material
CN102358804A (en) Special binder for waterbrone inorganic zinc-rich anti-corrosion coating
CN108610847B (en) Graphene rust curing coating with high salt spray resistance and preparation method thereof
CN108395808A (en) A kind of high heat conductance high temperature resistant heavy anti-corrosion paint and preparation method thereof
CN108384375A (en) Environment-friendlyanti-corrosive anti-corrosive paint
CN112552779B (en) Environment-friendly low-surface-treatment water-based epoxy thick paste acid-alkali-resistant coating and preparation method thereof
CN104403435B (en) Aqueous rust-conversion rust-inhibiting primer
CN110885617A (en) Rust conversion coating and preparation method thereof
CN108588696B (en) Organic passivator free of chromium and nickel heavy metals
CN113773722A (en) Environment-friendly water-based epoxy rusty anticorrosive paint for steel structure and preparation method thereof
CN113174186A (en) High-heat-resistance anticorrosive paint and preparation method thereof
CN109294296B (en) Super-stain-resistant water-based single-component transparent enamel coating and preparation method and construction process thereof
CA2147144A1 (en) Solid surface modifier

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180810