CN108384207A - A kind of dress materials with flame retarding function for 3D printing - Google Patents
A kind of dress materials with flame retarding function for 3D printing Download PDFInfo
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- CN108384207A CN108384207A CN201810207332.5A CN201810207332A CN108384207A CN 108384207 A CN108384207 A CN 108384207A CN 201810207332 A CN201810207332 A CN 201810207332A CN 108384207 A CN108384207 A CN 108384207A
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- parts
- printing
- dress materials
- flame retarding
- hygroscopic agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to garment material processing technique fields, provide a kind of dress materials with flame retarding function for 3D printing, the requirement of the practicability of dress materials, comfort etc. is considered provided by the present invention for the dress materials with flame retarding function of 3D printing, in conjunction with the characteristic of existing high molecular material, the adjustment of science has been carried out to the formula of dress materials.Using PBS, PLA as major ingredient, compound graphene, Sodium Polyacrylate, rare-earth stabilizer, fire retardant, hygroscopic agent, nano-attapulgite powder, high hydroscopic resin, make the hydroscopicity of dress materials improve 8 12% due to adding hygroscopic agent, makes dress materials that there is fabulous flame retardant property due to adding graphene, rare-earth stabilizer, fire retardant.
Description
Technical field
The invention belongs to garment material processing technique fields, and in particular, to a kind of to have fire-retardant work(for 3D printing
The dress materials of energy.
Background technology
3D printing technique has 3DP technologies, FDM melt-laminated molding technologies, SLA stereolithography techniques, the constituencies SLS to swash
Light sintering, DLP laser forming technologies and UV UV molding technologies, technology difference material therefor is then entirely different, and general old hundred
Surname it is daily in the family be considered as safety first principle using material, selected materials want environmental protection, as PLA, PCL, PHA, PBS,
Biological PA, and ABS, PC, PS, POM, PVC etc. are unsuitable for being used for domestic applications, because this technology is usually on the table
Printing, smell caused by the high molecular material of melting or decompose generate harmful substance directly with our people and kinsfolk
Contact, be easy to cause safety problem.
The 3D printing material of clothes in currently available technology, there are the deficiencies that hydroscopicity both performances are poor.
In order to overcome above-mentioned deficiency, the present invention to provide a kind of dress materials with flame retarding function for 3D printing.
Invention content
For the defects in the prior art, the object of the present invention is to provide a kind of for 3D printing with flame retarding function
Dress materials.
It is described to be used for 3D printing according to a kind of dress materials with flame retarding function for 3D printing provided by the invention
The dress materials with flame retarding function include following parts by weight raw material：156-201 parts of PBS, 65-80 parts of PLA, graphite
2-6 parts of alkene, 2-6 parts of Sodium Polyacrylate, 1.3-2.8 parts of rare-earth stabilizer, 2.1-2.8 parts of fire retardant, 1.5-2.8 parts of hygroscopic agent,
5-8 parts of nano-attapulgite powder, 3.8-6.9 parts of high hydroscopic resin.
Preferably, the dress materials with flame retarding function for 3D printing include the raw material of following parts by weight：
176-201 parts of PBS, 75-80 parts of PLA, 4-6 parts of graphene, 4-6 parts of Sodium Polyacrylate, 1.7-2.8 parts of rare-earth stabilizer, resistance
Fire 2.3-2.8 parts of agent, 1.7-2.8 parts of hygroscopic agent, 6-8 parts of nano-attapulgite powder, 4.8-6.9 parts of high hydroscopic resin.
Preferably, the dress materials with flame retarding function for 3D printing include the raw material of following parts by weight：
180 parts of PBS, 77 parts of PLA, 5 parts of graphene, 5 parts of Sodium Polyacrylate, 2.3 parts of rare-earth stabilizer, 2.6 parts of fire retardant, hygroscopic agent
2.5 parts, 7 parts of nano-attapulgite powder, 5.7 parts of high hydroscopic resin.
Preferably, the fire retardant includes the raw material of following parts by weight：10-28 parts of 2-Butoxyethyl acetate, sulfuric acid
6-15 parts of magnesium, 2-13 parts of antimony oxide, 3-7 parts of calcium hydroxide, 1-7 parts of silane, 2-3 parts of fatty alcohol polyoxyethylene ether；Chlorination
2-4 parts of sodium.
Preferably, the hygroscopic agent includes component A, and remaining part is porous hygroscopic agent, and the component A is crystal violet and quinaldine
The red mixture formed with 1: 5-11 weight ratio, the component A are uniformly distributed in porous hygroscopic agent.
Preferably, the porous hygroscopic agent is Nano sepiolite powder.
Preferably, the preparation method of the hygroscopic agent is as follows：
Step 1: preparing coating fluid, crystal violet and quinaldine red is taken to be dissolved in acid with the mixture that 1: 5-11 weight ratio is formed
In property aqueous solution and it is adjusted to coating fluid, it is spare；
Step 2: coating, is impregnated with the coating fluid or sprays porous hygroscopic agent, coating fluid is made to be uniformly distributed in porous hygroscopic agent
Surface；
Step 3: it is dry, by the acidic aqueous solution evaporative removal.
Preferably, the acidic aqueous solution is the hydrochloric acid solution that mass fraction is 2-10.
Compared with prior art, the present invention has following advantageous effect：
1, a kind of dress materials with flame retarding function for 3D printing provided by the invention, beat provided by the present invention for 3D
The dress materials with flame retarding function of print consider the requirement of the practicability of dress materials, comfort etc., in conjunction with existing
The characteristic of high molecular material has carried out the adjustment of science to the formula of dress materials.Using PBS, PLA as major ingredient, compounding graphene,
Sodium Polyacrylate, rare-earth stabilizer, fire retardant, hygroscopic agent, nano-attapulgite powder, high hydroscopic resin, due to adding hygroscopic agent
So that the hydroscopicity of dress materials improves 8-12%, make clothes material due to adding graphene, rare-earth stabilizer, fire retardant
Material has fabulous flame retardant property.
2, a kind of dress materials with flame retarding function for 3D printing provided by the invention are added in material prescription
Hygroscopicity can absorb the sweat and steam of human skin surface's discharge in time, and the another side of fabric can be passed to by fiber,
It is discharged into air.The hydroscopicity of dress materials is improved, and then improves the comfort level of human body.
Specific implementation mode
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.
Embodiment 1
A kind of dress materials with flame retarding function for 3D printing provided in this embodiment, the having for 3D printing
The dress materials of flame retarding function include the raw material of following parts by weight：201 parts of PBS, 65 parts of PLA, 6 parts of graphene, polypropylene
2 parts of sour sodium, 2.8 parts of rare-earth stabilizer, 2.1 parts of fire retardant, 2.8 parts of hygroscopic agent, 5 parts of nano-attapulgite powder, high hydroscopic resin 6.9
Part.
Preferably, the fire retardant includes the raw material of following parts by weight：28 parts of 2-Butoxyethyl acetate, sulphur
6 parts of sour magnesium, 13 parts of antimony oxide, 3 parts of calcium hydroxide, 7 parts of silane, 2 parts of fatty alcohol polyoxyethylene ether；4 parts of sodium chloride.
Preferably, the hygroscopic agent includes component A, and remaining part is porous hygroscopic agent, the component A be crystal violet and
The mixture that quinaldine red is formed with 1: 11 weight ratio, the component A are uniformly distributed in porous hygroscopic agent.
Preferably, the porous hygroscopic agent is Nano sepiolite powder.
Preferably, the preparation method of the hygroscopic agent is as follows：
Step 1: preparing coating fluid, crystal violet and quinaldine red is taken to be dissolved in acidity with the mixture that 1: 11 weight ratio is formed
In aqueous solution and it is adjusted to coating fluid, it is spare；
Step 2: coating, is impregnated with the coating fluid or sprays porous hygroscopic agent, coating fluid is made to be uniformly distributed in porous hygroscopic agent
Surface；
Step 3: it is dry, by the acidic aqueous solution evaporative removal.
Preferably, the acidic aqueous solution is the hydrochloric acid solution that mass fraction is 10.
Embodiment 2
A kind of dress materials with flame retarding function for 3D printing provided in this embodiment, the having for 3D printing
The dress materials of flame retarding function include the raw material of following parts by weight：156 parts of PBS, PLA80 parts, 2 parts of graphene, polyacrylic acid
6 parts of sodium, 1.3 parts of rare-earth stabilizer, 2.8 parts of fire retardant, 1.5 parts of hygroscopic agent, 8 parts of nano-attapulgite powder, high hydroscopic resin 3.8
Part.
Preferably, the fire retardant includes the raw material of following parts by weight：2-Butoxyethyl acetate 10-28
Part, 6 parts of magnesium sulfate, 13 parts of antimony oxide, 3 parts of calcium hydroxide, 7 parts of silane, 2 parts of fatty alcohol polyoxyethylene ether；Sodium chloride 4
Part.
Preferably, the hygroscopic agent includes component A, and remaining part is porous hygroscopic agent, the component A be crystal violet and
The mixture that quinaldine red is formed with 1: 5 weight ratio, the component A are uniformly distributed in porous hygroscopic agent.
Preferably, the porous hygroscopic agent is Nano sepiolite powder.
Preferably, the preparation method of the hygroscopic agent is as follows：
Step 1: preparing coating fluid, crystal violet and quinaldine red is taken to be dissolved in acid water with the mixture that 1: 5 weight ratio is formed
In solution and it is adjusted to coating fluid, it is spare；
Step 2: coating, is impregnated with the coating fluid or sprays porous hygroscopic agent, coating fluid is made to be uniformly distributed in porous hygroscopic agent
Surface；
Step 3: it is dry, by the acidic aqueous solution evaporative removal.
Preferably, the acidic aqueous solution is the hydrochloric acid solution that mass fraction is 2.
Embodiment 3
A kind of dress materials with flame retarding function for 3D printing provided in this embodiment, the having for 3D printing
The dress materials of flame retarding function include the raw material of following parts by weight：201 parts of PBS, 75 parts of PLA, 6 parts of graphene, polypropylene
4 parts of sour sodium, 2.8 parts of rare-earth stabilizer, 2.3 parts of fire retardant, 2.8 parts of hygroscopic agent, 6 parts of nano-attapulgite powder, high hydroscopic resin 6.9
Part.
Preferably, the fire retardant includes the raw material of following parts by weight：28 parts of 2-Butoxyethyl acetate, sulphur
15 parts of sour magnesium, 13 parts of antimony oxide, 7 parts of calcium hydroxide, 7 parts of silane, 3 parts of fatty alcohol polyoxyethylene ether,；4 parts of sodium chloride.
Preferably, the hygroscopic agent includes component A, and remaining part is porous hygroscopic agent, the component A be crystal violet and
The mixture that quinaldine red is formed with 1: 11 weight ratio, the component A are uniformly distributed in porous hygroscopic agent.
Preferably, the porous hygroscopic agent is Nano sepiolite powder.
Preferably, the preparation method of the hygroscopic agent is as follows：
Step 1: preparing coating fluid, crystal violet and quinaldine red is taken to be dissolved in acidity with the mixture that 1: 11 weight ratio is formed
In aqueous solution and it is adjusted to coating fluid, it is spare；
Step 2: coating, is impregnated with the coating fluid or sprays porous hygroscopic agent, coating fluid is made to be uniformly distributed in porous hygroscopic agent
Surface；
Step 3: it is dry, by the acidic aqueous solution evaporative removal.
Preferably, the acidic aqueous solution is the hydrochloric acid solution that mass fraction is 10.
Embodiment 4
A kind of dress materials with flame retarding function for 3D printing provided in this embodiment, the having for 3D printing
The dress materials of flame retarding function include the raw material of following parts by weight：176 parts of PBS, 80 parts of PLA, 4 parts of graphene, polypropylene
6 parts of sour sodium, 1.7 parts of rare-earth stabilizer, 2.8 parts of fire retardant, 1.7 parts of hygroscopic agent, 8 parts of nano-attapulgite powder, high hydroscopic resin 4.8
Part.
Preferably, the fire retardant includes the raw material of following parts by weight：10 parts of 2-Butoxyethyl acetate, sulphur
6 parts of sour magnesium, 2 parts of antimony oxide, 3 parts of calcium hydroxide, 1 part of silane, 2 parts of fatty alcohol polyoxyethylene ether,；2 parts of sodium chloride.
Preferably, the hygroscopic agent includes component A, and remaining part is porous hygroscopic agent, the component A be crystal violet and
The mixture that quinaldine red is formed with 1: 5 weight ratio, the component A are uniformly distributed in porous hygroscopic agent.
Preferably, the porous hygroscopic agent is Nano sepiolite powder.
Preferably, the preparation method of the hygroscopic agent is as follows：
Step 1: preparing coating fluid, crystal violet and quinaldine red is taken to be dissolved in acid water with the mixture that 1: 5 weight ratio is formed
In solution and it is adjusted to coating fluid, it is spare；
Step 2: coating, is impregnated with the coating fluid or sprays porous hygroscopic agent, coating fluid is made to be uniformly distributed in porous hygroscopic agent
Surface；
Step 3: it is dry, by the acidic aqueous solution evaporative removal.
Preferably, the acidic aqueous solution is the hydrochloric acid solution that mass fraction is 5.
Embodiment 5
A kind of dress materials with flame retarding function for 3D printing provided in this embodiment, the having for 3D printing
The dress materials of flame retarding function include the raw material of following parts by weight：180 parts of PBS, 77 parts of PLA, 5 parts of graphene, polypropylene
5 parts of sour sodium, 2.3 parts of rare-earth stabilizer, 2.6 parts of fire retardant, 2.5 parts of hygroscopic agent, 7 parts of nano-attapulgite powder, high hydroscopic resin 5.7
Part.
Preferably, the fire retardant includes the raw material of following parts by weight：18 parts of 2-Butoxyethyl acetate, sulphur
8 parts of sour magnesium, 5 parts of antimony oxide, 6 parts of calcium hydroxide, 3 parts of silane, 2 parts of fatty alcohol polyoxyethylene ether；3 parts of sodium chloride.
Preferably, the hygroscopic agent includes component A, and remaining part is porous hygroscopic agent, the component A be crystal violet and
The mixture that quinaldine red is formed with 1: 7 weight ratio, the component A are uniformly distributed in porous hygroscopic agent.
Preferably, the porous hygroscopic agent is Nano sepiolite powder.
Preferably, the preparation method of the hygroscopic agent is as follows：
Step 1: preparing coating fluid, crystal violet and quinaldine red is taken to be dissolved in acid water with the mixture that 1: 7 weight ratio is formed
In solution and it is adjusted to coating fluid, it is spare；
Step 2: coating, is impregnated with the coating fluid or sprays porous hygroscopic agent, coating fluid is made to be uniformly distributed in porous hygroscopic agent
Surface；
Step 3: it is dry, by the acidic aqueous solution evaporative removal.
Preferably, the acidic aqueous solution is the hydrochloric acid solution that mass fraction is 8.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of dress materials with flame retarding function for 3D printing, it is characterised in that：The having for 3D printing
The dress materials of flame retarding function include the raw material of following parts by weight：156-201 parts of PBS, 65-80 parts of PLA, graphene 2-6
Part, 2-6 parts of Sodium Polyacrylate, 1.3-2.8 parts of rare-earth stabilizer, 2.1-2.8 parts of fire retardant, 1.5-2.8 parts of hygroscopic agent, nanometer are recessed
5-8 parts of convex stick powder, 3.8-6.9 parts of high hydroscopic resin.
2. the dress materials with flame retarding function according to claim 1 for 3D printing, it is characterised in that：The use
In the dress materials with flame retarding function of 3D printing include the raw material of following parts by weight：176-201 parts of PBS, PLA 75-
80 parts, 4-6 parts of graphene, 4-6 parts of Sodium Polyacrylate, 1.7-2.8 parts of rare-earth stabilizer, 2.3-2.8 parts of fire retardant, hygroscopic agent
1.7-2.8 parts, 6-8 parts of nano-attapulgite powder, 4.8-6.9 parts of high hydroscopic resin.
3. the dress materials with flame retarding function according to claim 1 for 3D printing, it is characterised in that：The use
In the dress materials with flame retarding function of 3D printing include the raw material of following parts by weight：180 parts of PBS, 77 parts of PLA, stone
5 parts of black alkene, 5 parts of Sodium Polyacrylate, 2.3 parts of rare-earth stabilizer, 2.6 parts of fire retardant, 2.5 parts of hygroscopic agent, nano-attapulgite powder 7
Part, 5.7 parts of high hydroscopic resin.
4. the dress materials with flame retarding function according to claim 3 for 3D printing, it is characterised in that：The resistance
Combustion agent includes the raw material of following parts by weight：10-28 parts of 2-Butoxyethyl acetate, 6-15 parts of magnesium sulfate, antimony oxide 2-
13 parts, 3-7 parts of calcium hydroxide, 1-7 parts of silane, 2-3 parts of fatty alcohol polyoxyethylene ether；2-4 parts of sodium chloride.
5. the dress materials with flame retarding function according to claim 1 for 3D printing, it is characterised in that：The suction
Humectant includes component A, and remaining part is porous hygroscopic agent, and the component A is crystal violet and quinaldine red with 1: 5-11 weight ratio shape
At mixture, the component A is uniformly distributed in porous hygroscopic agent.
6. the dress materials with flame retarding function according to claim 5 for 3D printing, it is characterised in that：It is described more
Hole hygroscopic agent is Nano sepiolite powder.
7. the dress materials with flame retarding function according to claim 5 for 3D printing, it is characterised in that：The suction
The preparation method of humectant is as follows：
Step 1: preparing coating fluid, crystal violet and quinaldine red is taken to be dissolved in acid with the mixture that 1: 5-11 weight ratio is formed
In property aqueous solution and it is adjusted to coating fluid, it is spare；
Step 2: coating, is impregnated with the coating fluid or sprays porous hygroscopic agent, coating fluid is made to be uniformly distributed in porous hygroscopic agent
Surface；
Step 3: it is dry, by the acidic aqueous solution evaporative removal.
8. the dress materials with flame retarding function according to claim 1 for 3D printing, it is characterised in that：The acid
Property aqueous solution is the hydrochloric acid solution that mass fraction is 2-10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810207332.5A CN108384207A (en) | 2018-03-14 | 2018-03-14 | A kind of dress materials with flame retarding function for 3D printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810207332.5A CN108384207A (en) | 2018-03-14 | 2018-03-14 | A kind of dress materials with flame retarding function for 3D printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108384207A true CN108384207A (en) | 2018-08-10 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810207332.5A Withdrawn CN108384207A (en) | 2018-03-14 | 2018-03-14 | A kind of dress materials with flame retarding function for 3D printing |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101995447A (en) * | 2009-08-12 | 2011-03-30 | 株式会社互盛化学 | Moisture absorbent having self- and multi-indicating ability and preparation method thereof |
| CN107383801A (en) * | 2017-08-05 | 2017-11-24 | 广西筑梦三体科技有限公司 | A kind of 3D printing dress materials with fire resistance |
-
2018
- 2018-03-14 CN CN201810207332.5A patent/CN108384207A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101995447A (en) * | 2009-08-12 | 2011-03-30 | 株式会社互盛化学 | Moisture absorbent having self- and multi-indicating ability and preparation method thereof |
| CN107383801A (en) * | 2017-08-05 | 2017-11-24 | 广西筑梦三体科技有限公司 | A kind of 3D printing dress materials with fire resistance |
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Application publication date: 20180810 |
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