CN108384062A - Rigid toughening nucleating agent of a kind of polypropylene increasing and preparation method thereof - Google Patents
Rigid toughening nucleating agent of a kind of polypropylene increasing and preparation method thereof Download PDFInfo
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Abstract
The present invention provides rigid toughening nucleating agent of a kind of polypropylene increasing and preparation method thereof, includes the raw material of following parts by weight:35 ~ 65 parts of dibenzal sorbitol, increases rigid 5 ~ 10 parts of auxiliary agent, 1 ~ 5 part of dispersant, 5 ~ 10 parts of suberate, 1 ~ 5 part of stearic acid salt at 25 ~ 45 parts of Phthalate;Wherein, it is 1 ~ 10 that the rigid auxiliary agent of increasing, which is weight ratio,:5~8:3~6:2 ~ 6 nano silicon oxide, the mixture of sodium metasilicate, glass fibre and calcium carbonate.The embodiment of the invention also discloses the preparation methods that a kind of polypropylene increases rigid toughening nucleating agent.The composite nucleating agent prepared using the present invention has the characteristics that nucleation is efficient, at low cost, and while keeping homopolypropylene rigidity and elongation at break, substantially increases the toughness of homopolypropylene.
Description
Technical field
The invention belongs to macromolecule chemical industry auxiliary agent technical fields, and in particular to a kind of polypropylene increase rigid toughening nucleating agent and its
Preparation method.
Background technology
Polypropylene is a kind of high crystalline polymer, and melt crystallization speed is slower in process, easily forms spherocrystal, thus
Influence the transparency of product and the impact strength of product.Nucleating agent it is effective addition can make polypropylene at relatively high temperatures out-phase at
Core improves crystalline rate, while improving the polyacrylic transparency and surface gloss and impact strength, tensile strength, modulus
And heat distortion temperature, and then the quality of product is improved, and simultaneously because crystallization rate is accelerated, molding cycle is shortened, thus it is big
The big benefit for improving enterprise.It is modified simple for process due to adding nucleating agent in polypropylene, additive amount is few, modified effect
Fruit is apparent, therefore the use of nucleating agent is increasingly extensive.Polypropylene nucleater need to have fine uniform structure distribution, insoluble, nontoxic or low
Poison has the features such as crystal plane by polypropylene quick adsorption.Polyacrylic crystal habit mainly has α (monoclinic crystal) and β (six sides
It is brilliant) etc. four kinds of crystalline forms, wherein α crystalline substances are most commonly seen and most stable of a kind of crystalline forms in crystalling propylene.α crystalline substance density is 0.94g/
cm3, fusing point is about 165 DEG C, it has the effects that increasing rigid, raising heat distortion temperature, creep resistant, reduction turbidity.β crystalline substances are common
Content is brilliant much smaller than α in crystalling propylene, and β crystalline substance density is 0.92g/cm3, fusing point is about 155 DEG C, in order degree and thermostabilization
Aspect of performance can improve the shock resistance and heat distortion temperature of polypropylene articles, make polypropylene simultaneously also below α crystalline substances, beta crystal
This for the shock resistance and heat distortion temperature while raising being difficult to realize present in preparation reaches organic unification to contradiction.
In addition, beta crystal also assigns polypropylene articles good porous structure, improve its gas permeability, impressionability etc..Alpha-crystal form nucleating agent
It is that there is induction acrylic resin to be nucleated with alpha-crystal form, improves the crystallization temperature of product, crystallinity, crystallization rate simultaneously makes crystal grain ruler
The nucleating agent of very little imperceptibility function, beta crystal-type nucleater is then that acrylic resin can be induced to be crystallized with beta crystal, and product can be improved
Impact resistance, heat distortion temperature and porosity rate.After adding beta crystal-type nucleater, impact strength can obtain significantly polypropylene
Raising, i.e. toughness increases, but polyacrylic tensile property and bending property are often declined at this time, and alpha-crystal form nucleating agent
Addition can significantly improve polyacrylic stretching and bending property, but its impact strength can decline.How polypropylene is improved simultaneously
Rigidity and toughness become a critical issue.
Invention content
Based on the above prior art, increasing rigid and all strong toughening performance polypropylene increasing the purpose of the present invention is to provide a kind of
Rigid toughening nucleating agent.
In order to achieve the goal above, the technical solution adopted by the present invention is:A kind of rigid toughening nucleating agent of polypropylene increasing, including
The raw material of following parts by weight:35~65 parts of dibenzal sorbitol, 25-45 parts of Phthalate increase rigid 5~15 parts of auxiliary agent, dispersion
1~6 part of agent, 5~10 parts of suberate, 1~5 part of stearic acid salt.
Preferably, polypropylene reinforcement nucleating agent, includes the raw material of following parts by weight:55 parts of dibenzal sorbitol, to benzene
35 parts of diformate increases 8 parts of rigid auxiliary agent, 4 parts of dispersant, 8 parts of suberate, 3 parts of stearic acid salt;Wherein, described to increase rigid auxiliary agent
It is 5 for weight ratio:7:4:4 nano silicon oxide, the mixture of sodium metasilicate, glass fibre and calcium carbonate.
The present invention is using the principle of above-mentioned raw materials:Polypropylene provided by the invention increases rigid toughening nucleating agent, using two
Main component of the benzylidene sorbitol as reinforcement nucleating agent, dibenzal sorbitol are α crystalline substance nucleating agents, have make polypropylene at
The basic function of core, and easily dispersion, but its increasing rigidity can be general;Increasing rigid auxiliary agent can rigidly be added the increasing of dibenzal sorbitol
By force, the rigid auxiliary agent of increasing being mixed to get especially with nano silicon oxide, sodium metasilicate, glass fibre and calcium carbonate, with two benzals
Sorbierite can make 1.5 times of polyacrylic strength enhancing or more after combining;Dispersant makes the inorganic constituents in raw material and organic principle
Can be evenly dispersed, Phthalate, suberate, stearate are carboxylate, and beta crystal is can act as in polypropylene
Nucleating agent acts on, and with synergistic effect, polypropylene impact strength is enable to be greatly enhanced.With dibenzal sorbitol,
After increasing rigid auxiliary agent combination, polyacrylic mechanical property can be further promoted.
As an optimization, the Phthalate is M-phthalic acid zinc, M-phthalic acid calcium, M-phthalic acid magnesium, isophthalic
Aluminum diformate, terephthalic acid (TPA) magnesium, terephthalic acid (TPA) calcium, terephthalic acid (TPA) zinc, at least one of terephthalic acid (TPA) aluminium.
The dispersant is polyethers, polyglycols, titanate coupling agent, dimethylsiloxane methyl cellulose, polyethylene glycol
At least one of.
As an optimization, the suberate is suberic acid magnesium, at least one in calcium suberate, suberic acid aluminium, suberic acid zinc
Kind.
As an optimization, the stearate is odium stearate, in calcium stearate, magnesium stearate, zinc stearate, aluminum stearate
It is at least one.
As an optimization, the particle size of the nano silicon oxide is 100 nanometers hereinafter, the granularity of nano silicon oxide is smaller,
It is more easily dispersed in increasing rigid toughening nucleating agent, and the increasing for increasing rigid toughening nucleating agent rigidly can be stronger.
The present invention also provides a kind of methods for preparing polypropylene and increasing rigid toughening nucleating agent, include the following steps:
Step 1 weighs each raw material according to parts by weight respectively, spare;
Step 2, a certain amount of water, water temperature will be added after dibenzal sorbitol, stearic acid salt and dispersant in step 2
It is 60 DEG C, is stirred 30 minutes with the rate of 150~300r/min or more, then sequentially add Phthalate, increases rigid auxiliary agent, pungent
Diacid salt and a certain amount of water, are made into the solution of 20-25%, and polypropylene increasing is obtained after stirring 0.5 hour or more stirring
Rigid toughening nucleating agent mixed liquor.
The mixed liquor that step 2 is prepared is ground by step 3 with grinder, and grinder rotating speed 600-700r/min is ground
Time consuming is 30-45 minutes.
Step 4 filters the mixed liquor after grinding, filter cake drying, at final finished.
As an optimization, the polypropylene reinforcement nucleating agent grinding grain size is less than 15um.
As advanced optimizing, the polypropylene obtained in the step 4 increases rigid toughening nucleating agent filter cake, by it in 100-
140 DEG C of drying increase rigid toughening nucleating agent to get to powdered polypropylene.
Advantageous effect
Beneficial effects of the present invention are as follows:
(1), polypropylene provided by the invention increases rigid toughening nucleating agent, using dibenzal sorbitol as reinforcement nucleating agent
Main component, dibenzal sorbitol are α crystalline substance nucleating agents, have the basic function for making polypropylene be nucleated, and easily dispersion, but its
Increasing rigidity can be general;Increasing rigid auxiliary agent can rigidly reinforce the increasing of dibenzal sorbitol, especially with nano silicon oxide, silicon
The rigid auxiliary agent of increasing that sour sodium, glass fibre and calcium carbonate are mixed to get can make polyacrylic strong after being combined with dibenzal sorbitol
Degree promotes 1.5 times or more;Dispersant keeps inorganic constituents in raw material and organic principle evenly dispersed, Phthalate, pungent
Diacid salt, stearate are carboxylate, beta crystal-type nucleater effect are can act as in polypropylene, and have synergistic effect,
Polypropylene impact strength is set to be greatly enhanced.After being combined with dibenzal sorbitol, the rigid auxiliary agent of increasing, further promoted
Polyacrylic mechanical property.
(2), the method provided by the invention for preparing polypropylene and increasing rigid toughening nucleating agent, first by dibenzal sorbitol and hard ester
Add water after hydrochlorate and dispersant and high-speed stirred obtains suspension, then sequentially adds Phthalate, increase rigid auxiliary agent, is pungent
Diacid salt and water, each mutual scattering and permeating of feed particles in whipping process, finally obtain finely dispersed mixed liquor, be placed on
It is ground in grinder, each component is made further to be sufficiently mixed, grinding makes the grain size of composite nucleating agent be less than 15 micron levels,
Polypropylene composite materials nucleating agent is contributed to be uniformly dispersed in polypropylene.Have it is more about nucleating agent grain size to Polypropylene structural
Can influence studies have shown that crystalline rate increases, the polyacrylic modulus of elasticity in static bending, bending with the reduction of nucleating agent grain size
Intensity and stretching can be slightly improved, but are nucleated grain size and also affected its dispersibility in polypropylene, be caused certain
Reunite, the effective at nuclear concentration of nucleating agent is reduced, to weaken the nucleation of nucleating agent.The present invention will increase rigid toughening at
Core agent is ground, and reduces grain size, while the dispersant in formula can prevent the reunion between particle, and two in formula
Benzylidene sorbitol can also effectively coat the salt particle in formula, its dispersibility in polypropylene is made to greatly improve,
Interface cohesion is more preferable, generates synergistic effect, further improves polyacrylic mechanical property.
Specific implementation mode
With reference to specific embodiment, invention is further described in detail.
Embodiment 1
The present embodiment provides a kind of polypropylene to increase rigid toughening nucleating agent, includes the raw material of following parts by weight:Two benzal sorbs
65 parts of alcohol, increases rigid 6 parts of auxiliary agent, 4 parts of dispersant, 8 parts of suberate, 3 parts of stearic acid salt at 25 parts of Phthalate;Wherein, described
Phthalate is terephthalic acid (TPA) calcium, and it is 1 that the rigid auxiliary agent of increasing, which is weight ratio,:5:3:2 nano silicon oxide, sodium metasilicate, glass
The mixture of glass fiber and calcium carbonate, the dispersant are polyethylene glycol, and the suberate is calcium suberate, the stearic acid
Salt is calcium stearate, and the particle size of the nano silicon oxide is 100 nanometers or less.
The present embodiment also provides a kind of method for preparing polypropylene and increasing rigid toughening nucleating agent, includes the following steps:
Step 1 weighs each raw material according to parts by weight respectively, spare;
A certain amount of water, water is added after mixing dibenzal sorbitol, calcium stearate and polyethylene glycol in step 2, step 2
Temperature is 60 DEG C, stirred 30 minutes with the rate of 150~300r/min or more, terephthalic acid (TPA) calcium is then sequentially added, increasing just helps
Agent, calcium suberate and a certain amount of water are made into the solution of 20-25%, stir 0.5 hour or more, gathered after stirring
Propylene increases rigid toughening nucleating agent mixed liquor.
The mixed liquor that step 2 is prepared is ground by step 3 with grinder, and grinder rotating speed 600-700r/min is ground
Time consuming is 30-45 minutes.
Step 4 filters the mixed liquor after grinding, and filter cake is dried 2-4 hours at 120 DEG C, at final finished.
Embodiment 2
The present embodiment provides a kind of polypropylene to increase rigid toughening nucleating agent, includes the raw material of following parts by weight:Two benzal sorbs
60 parts of alcohol, increases rigid 6 parts of auxiliary agent, 4 parts of dispersant, 8 parts of suberate, 3 parts of stearic acid salt at 30 parts of Phthalate;Wherein, described
Phthalate is terephthalic acid (TPA) calcium, and it is 1 that the rigid auxiliary agent of increasing, which is weight ratio,:5:3:2 nano silicon oxide, sodium metasilicate, glass
The mixture of glass fiber and calcium carbonate, the dispersant are polyethylene glycol, and the suberate is calcium suberate, the stearic acid
Salt is calcium stearate, and the particle size of the nano silicon oxide is 100 nanometers or less.
The present embodiment also provides a kind of method for preparing polypropylene and increasing rigid toughening composite nucleating agent, includes the following steps:
A certain amount of water, water is added after mixing dibenzal sorbitol, calcium stearate and polyethylene glycol in step 2, step 2
Temperature is 60 DEG C, stirred 30 minutes with the rate of 150~300r/min or more, terephthalic acid (TPA) calcium is then sequentially added, increasing just helps
Agent, calcium suberate and a certain amount of water are made into the solution of 20-25%, stir 0.5 hour or more, gathered after stirring
Propylene increases rigid toughening nucleating agent mixed liquor.
The mixed liquor that step 2 is prepared is ground by step 3 with grinder, and grinder rotating speed 600-700r/min is ground
Time consuming is 30-45 minutes.
Step 4 filters the mixed liquor after grinding, and filter cake is dried 2-4 hours at 120 DEG C, at final finished.
Embodiment 3
The present embodiment provides a kind of polypropylene to increase rigid toughening nucleating agent, includes the raw material of following parts by weight:Two benzal sorbs
55 parts of alcohol, increases rigid 8 parts of auxiliary agent, 4 parts of dispersant, 8 parts of suberate, 3 parts of calcium stearate at 35 parts of Phthalate;Wherein, described
Phthalate is terephthalic acid (TPA) calcium, and it is 1 that the rigid auxiliary agent of increasing, which is weight ratio,:5:3:2 nano silicon oxide, sodium metasilicate, glass
The mixture of glass fiber and calcium carbonate, the dispersant are polyethylene glycol, and the suberate is calcium suberate, the stearic acid
Salt is calcium stearate, and the particle size of the nano silicon oxide is 100 nanometers or less.
The present embodiment also provides a kind of method for preparing polypropylene and increasing rigid toughening nucleating agent, includes the following steps:
Step 1 weighs each raw material according to parts by weight respectively, spare;
A certain amount of water, water is added after mixing dibenzal sorbitol, calcium stearate and polyethylene glycol in step 2, step 2
Temperature is 60 DEG C, stirred 30 minutes with the rate of 150~300r/min or more, terephthalic acid (TPA) calcium is then sequentially added, increasing just helps
Agent, calcium suberate and a certain amount of water are made into the solution of 20-25%, stir 0.5 hour or more, gathered after stirring
Propylene increases rigid toughening composite nucleating agent mixed liquor.
The mixed liquor that step 2 is prepared is ground by step 3 with grinder, and grinder rotating speed 600-700r/min is ground
Time consuming is 30-45 minutes.
Step 4 filters the mixed liquor after grinding, and filter cake is dried 2-4 hours at 120 DEG C, at final finished.
Embodiment 4
The present embodiment provides a kind of polypropylene to increase rigid toughening nucleating agent, includes the raw material of following parts by weight:Two benzal sorbs
50 parts of alcohol, increases rigid 10 parts of auxiliary agent, 6 parts of dispersant, 4 parts of suberate, 3 parts of stearic acid salt at 40 parts of Phthalate;Wherein, institute
It is terephthalic acid (TPA) calcium to state Phthalate, and it is 1 that the rigid auxiliary agent of increasing, which is weight ratio,:5:3:2 nano silicon oxide, sodium metasilicate,
The mixture of glass fibre and calcium carbonate, the dispersant are polyglycols, and the suberate is calcium suberate, the stearic acid
Salt is calcium stearate, and the particle size of the nano silicon oxide is 100 nanometers or less.
The present embodiment also provides a kind of method preparing polypropylene reinforcement nucleating agent, includes the following steps:
Step 1 weighs each raw material according to parts by weight respectively, spare;
A certain amount of water, water is added after mixing dibenzal sorbitol, calcium stearate and polyethylene glycol in step 2, step 2
Temperature is 60 DEG C, is stirred 60 minutes with the rate of 220r/min, then sequentially adds terephthalic acid (TPA) calcium, increase rigid auxiliary agent, suberic acid
Calcium and a certain amount of water are made into the solution 22 of 20-25%, stir 2 hours, and polypropylene reinforcement nucleating agent is obtained after stirring
Mixed liquor.
The mixed liquor that step 2 is prepared is ground, grinder rotating speed 600-700r/min5 by step 3 with grinder,
Milling time is 30-45 minutes 40.
Step 4 filters the mixed liquor after grinding, and filter cake is dried 2-4 hours at 130 DEG C, at final finished.
Embodiment 5
The present embodiment provides a kind of polypropylene to increase rigid toughening nucleating agent, includes the raw material of following parts by weight:Two benzal sorbs
45 parts of alcohol, increases rigid 10 parts of auxiliary agent, 6 parts of dispersant, 4 parts of suberate, 3 parts of calcium stearate at 40 parts of Phthalate;Wherein, institute
It is terephthalic acid (TPA) calcium to state Phthalate, and it is 1 that the rigid auxiliary agent of increasing, which is weight ratio,:5:3:2 nano silicon oxide, sodium metasilicate,
The mixture of glass fibre and calcium carbonate, the dispersant are polyethylene glycol, and the suberate is calcium suberate, the tristearin
Hydrochlorate is calcium stearate, and the particle size of the nano silicon oxide is 100 nanometers or less.
The present embodiment also provides a kind of method preparing polypropylene reinforcement nucleating agent, includes the following steps:
Step 1 weighs each raw material according to parts by weight respectively, spare;
A certain amount of water, water is added after mixing dibenzal sorbitol, calcium stearate and polyethylene glycol in step 2, step 2
Temperature is 60 DEG C, is stirred 50 minutes with the rate of 150~300r/min, then sequentially adds terephthalic acid (TPA) calcium, increases rigid auxiliary agent, pungent
Diacid calcium and a certain amount of water are made into the solution of 20-25%, and polypropylene is obtained after stirring stirring in 0.5 hour and increases rigid increase
Tough nucleating agent mixed liquor.
The mixed liquor that step 2 is prepared is ground, grinder rotating speed 600-700r/min8 by step 3 with grinder,
Milling time is 30-45 minutes 40.
Step 4 filters the mixed liquor after grinding, and filter cake is dried 2-4 hours at 125 DEG C, at final finished 3.
Embodiment 6
The present embodiment provides a kind of polypropylene to increase rigid toughening nucleating agent, includes the raw material of following parts by weight:Two benzal sorbs
55 parts of alcohol, increases rigid 5 parts of auxiliary agent, 4 parts of dispersant, 2 parts of suberate, 1 part of calcium stearate at 35 parts of Phthalate;Wherein, described
Phthalate is terephthalic acid (TPA) calcium, and it is 1 that the rigid auxiliary agent of increasing, which is weight ratio,:5:3:2 nano silicon oxide, sodium metasilicate, glass
The mixture of glass fiber and calcium carbonate, the dispersant are polyethylene glycol, and the suberate is calcium suberate, the stearic acid
Salt is calcium stearate, and the particle size of the nano silicon oxide is 100 nanometers or less.
The present embodiment also provides a kind of method for preparing polypropylene and increasing rigid toughening nucleating agent, includes the following steps:
Step 1 weighs each raw material according to parts by weight respectively, spare;
A certain amount of water, water is added after mixing dibenzal sorbitol, calcium stearate and polyethylene glycol in step 2, step 2
Temperature is 60 DEG C, stirred 30 minutes with the rate of 150~300r/min or more, terephthalic acid (TPA) calcium is then sequentially added, increasing just helps
Agent, calcium suberate and a certain amount of water are made into the solution of 20-25%, stir 0.5 hour or more, gathered after stirring
Propylene increases rigid toughening nucleating agent mixed liquor.
The mixed liquor that step 2 is prepared is ground by step 3 with grinder, and grinder rotating speed 600-700r/min is ground
Time consuming is 30-45 minutes.
Step 4 filters the mixed liquor after grinding, and filter cake is dried 2-4 hours at 120 DEG C, at final finished.
The raw material used in above-described embodiment 1 to 5 and parts by weight are as shown in table 1 below:
Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
Dibenzal sorbitol | 65 parts | 60 parts | 55 parts | 50 parts | 45 parts | 55 parts |
Terephthalate | 25 parts | 30 parts | 35 parts | 40 parts | 45 parts | 35 parts |
Increase rigid auxiliary agent | 6 parts | 6 parts | 8 parts | 10 parts | 10 parts | 5 parts |
Dispersant | 4 parts | 4 parts | 4 parts | 6 parts | 6 parts | 4 parts |
Suberate | 8 parts | 8 parts | 8 parts | 4 parts | 4 parts | 2 parts |
Stearic acid salt | 3 parts | 3 parts | 3 parts | 3 parts | 3 parts | 1 part |
Rigid toughening nucleating agent is increased with polypropylene according to 0.3 using the polypropylene obtained in above-described embodiment 1 to 6:100 weight
Part is measured, mixes to be mixed with the polypropylene of nucleating agent after five minutes and by double screw extruder squeeze out in high-speed mixer and make
Grain.It opens wide to place 48 hours and removes moisture, polypropylene batten is then made by injection molding machine.Extrusion temperature is 190~210 DEG C,
220~230 DEG C of injection moulding machine temperature of each section obtains sample 1#, 2#, 3#, 4#, 5#, 6#.Batten is placed 24 hours at room temperature
Afterwards, Mechanics Performance Testing is carried out, also batten is made with same process in blank polypropylene, as a comparison case, carries out mechanical property survey
Examination.
Test result is as follows for it shown in table 2:
Above-mentioned test result shows after the rigid toughening nucleating agent of polypropylene provided by the invention increasing is added to polypropylene, right
Polyacrylic increasing is just and toughening effect is apparent, wherein the sample provided with embodiment 3 increases rigid toughening effect most to polyacrylic
It is good, it is most preferred embodiment,
Finally it should be noted that:The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's
Within protection domain.
Claims (10)
1. a kind of polypropylene increases rigid toughening nucleating agent and preparation method thereof, which is characterized in that include the raw material of following parts by weight:Two
35~65 parts of benzylidene sorbitol, 25-45 parts of Phthalate, increase 5~15 parts of rigid auxiliary agent, 1~6 part of dispersant, suberate 5~
10 parts, 1~5 part of stearic acid salt;Wherein, it is 1~10 that the rigid auxiliary agent of increasing, which is weight ratio,:5~8:3~6:2~6 it is nano oxidized
The mixture of silicon, sodium metasilicate, glass fibre and calcium carbonate.
2. polypropylene according to claim 1 increases rigid toughening nucleating agent, which is characterized in that include the original of following parts by weight
Material:55 parts of dibenzal sorbitol, 35 parts of Phthalate increase 8 parts of rigid auxiliary agent, 4 parts of dispersant, 8 parts of suberate, stearic acid salt
3 parts;Wherein, it is 5 that the rigid auxiliary agent of increasing, which is weight ratio,:7:4:4 nano silicon oxide, sodium metasilicate, glass fibre and calcium carbonate
Mixture.
3. polypropylene according to claim 1 or 2 increases rigid toughening nucleating agent, which is characterized in that Phthalate is isophthalic
Dioctyl phthalate zinc, M-phthalic acid calcium, M-phthalic acid magnesium, M-phthalic acid aluminium, terephthalic acid (TPA) magnesium, terephthalic acid (TPA) calcium are right
Phthalic acid zinc, at least one of terephthalic acid (TPA) aluminium.
4. polypropylene according to claim 1 or 2 increases rigid toughening nucleating agent, which is characterized in that the dispersant be polyethers,
At least one of polyglycols, titanate coupling agent, dimethylsiloxane methyl cellulose, polyethylene glycol.
5. polypropylene according to claim 1 or 2 increases rigid toughening composite nucleating agent, which is characterized in that described nano oxidized
The particle size of silicon is 100 nanometers or less.
6. polypropylene according to claim 1 or 2 increases rigid toughening nucleating agent, which is characterized in that the suberate is pungent
Diacid magnesium, at least one of calcium suberate, suberic acid aluminium, suberic acid zinc.
7. polypropylene according to claim 1 or 2 increases rigid toughening nucleating agent, which is characterized in that the stearate is tristearin
Sour sodium, at least one of calcium stearate, magnesium stearate, zinc stearate, aluminum stearate.
8. a kind of claim 1 to 5 polypropylene for preparing increases rigid toughening nucleating agent and preparation method thereof, which is characterized in that packet
Include following steps:
Step 1 weighs each raw material according to parts by weight respectively, spare;
A certain amount of water will be added in step 2 after dibenzal sorbitol, calcium stearate and dispersant, water temperature is 60 DEG C, with
The rate of 150~300r/min stirs 30 minutes or more, then sequentially adds Phthalate, increase rigid auxiliary agent, suberate and
A certain amount of water, is made into the solution of 20-25%, stirring 0.5 hour or more, obtained after stirring polypropylene increase rigid toughening at
Core agent mixed liquor.
The mixed liquor that step 2 is prepared is ground, grinder rotating speed 600-700r/min by step 3 with grinder, when grinding
Between be 30-45 minutes.
Step 4 filters the mixed liquor after grinding, and filter cake was in drying 2-4 hours, at final finished.
9. the method according to claim 6 for preparing polypropylene and increasing rigid toughening nucleating agent, which is characterized in that polypropylene increases rigid
Toughening nucleating agent grinds grain size and is less than 15um.
10. the method according to claim 6 for preparing polypropylene and increasing rigid toughening nucleating agent, which is characterized in that the step 4
In obtained filter cake, it is dried at 100-140 DEG C and increases rigid toughening nucleating agent to get to powdered polypropylene.
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