CN108380006A - A kind of flame retardant type formaldehyde exhaust gas processing device - Google Patents
A kind of flame retardant type formaldehyde exhaust gas processing device Download PDFInfo
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- CN108380006A CN108380006A CN201810079417.XA CN201810079417A CN108380006A CN 108380006 A CN108380006 A CN 108380006A CN 201810079417 A CN201810079417 A CN 201810079417A CN 108380006 A CN108380006 A CN 108380006A
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- tank body
- flame retardant
- processing device
- exhaust gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/56—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition
- B01D46/62—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in series
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/10—Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/30—Particle separators, e.g. dust precipitators, using loose filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/108—Hydrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treating Waste Gases (AREA)
Abstract
A kind of flame retardant type formaldehyde exhaust gas processing device of the present invention, including liquid seal trough and combustion furnace, liquid seal trough is arranged between absorption tower and combustion furnace, the liquid seal trough includes tank body and the explosion stack positioned at top of the tank, it is connected with control valve on the explosion stack, the connection position of explosion stack and tank body is provided with pressure sensor, when pressure sensor detects that pressure is more than the limiting value of setting in tank body, control valve automatically opens, it is exhausted by explosion stack, described device is connect with automatic control system, automatic control system includes infrared spectrometer and display screen and picture recognition module, fluid flowing in whole device is included on display screen by infrared spectrometer, picture recognition module identifies the image on the display screen, and it is operated accordingly according to all parts of the flow regime control system of fluid.
Description
Technical field
The present invention relates to Formaldehyde Production technical fields, more specifically to a kind of flame retardant type formaldehyde exhaust gas processing device.
Background technology
The production of industrial formol at present is produced using circulation of tail gas method using methanol as raw material, after absorbing when production
Tail gas be partly recycled to reactor and do heat stabilizer, to achieve the purpose that necessary thermodynamical equilibrium and safety in production, use
This method, can produce the high-concentration formaldehyde of 37%~55% (mass fraction) in the case of no distillation, and methanol content is small
In 1.2%, compared with conventional silver method, this Division A League Matches of French Football alcohol unit consumption declines, and formic acid content is low.In industrial formol production process, generation
Tail gas contains hydrogen, formaldehyde gas, methanol and a small amount of methane gas etc., and industrial formol tail gas direct emission can cause environment dirty
Dye, influences personnel's health, meanwhile, imflammable gas direct emission can cause security risk, and therefore, mostly at present is to tail
It burns after gas filtering, on the one hand can remove imflammable gas, reduce environmental hazard, it on the other hand can be calory burning
It is collected into drum, can be used for the manufacturing of formaldehyde, realizes the recycling of energy.In order to facilitate absorption tower discharge tail gas into
Enter into combustion furnace, and ensure the safety of pipeline, liquid seal trough can be generally set between absorption tower and combustion furnace, to anti-
Only its body flows back.But in actual production, still there can be gas backstreaming phenomenon in combustion furnace, lead to occur open fire in liquid seal trough
Burning, such case can only cut off the air inlet pipe of liquid seal trough at present, but once handle not in time, and air pressure is excessive in liquid seal trough, very
Explosion accident may be will produce, there are some potential safety problemss.Chinese patent (205216411U) discloses a kind of formaldehyde tail gas
Recycle device, includes the tail gas air inlet pipe being connect with tail gas roots blower, and the tail gas air inlet pipe other end is connected with methanol and catches
Storage, methanol trap are connected with hydrogen gas segregator by pipeline, and hydrogen gas segregator is connected separately with hydrogen gas storage by pipeline
Tank and water sealed tank, water sealed tank are connected with tail-gas combustion stove by pipeline, steam engine, exhaust combustion furnace roof are equipped in tail-gas combustion stove
Portion is equipped with exhaust pipe, and steam engine is connected with steam drum.The program between tail gas air inlet pipe and tail-gas combustion stove by being arranged
Methanol remaining in tail gas and formaldehyde trapping recycling will be had very big utilization by methanol catcher and hydrogen gas segregator in tail gas
The Hydrogen Separation of value recycles.This method can recycle a part of gas, but there is no solve for existing security risk
Certainly.On the other hand, the liquid in liquid seal trough also has certain absorption cleaning effect to tail gas, and is absorption cleaning tail gas
Therefore how last procedure further increases its purification efficiency, and the problem faced at present.
Invention content
Technical problems to be solved by the inivention
It is an object of the invention to overcome the shortcomings of that there are security risks in overvoltage condition for liquid seal trough in the prior art, provide
A kind of flame retardant type formaldehyde exhaust gas processing device, the present invention are matched by pressure sensor with control valve, can be utilized explosion-proof
Decompression is exhausted in pipe, avoids risk of explosion existing for liquid seal trough.Further, the present invention also slows down gas by buffer
Body flow velocity contributes to the further absorption cleaning to gas is discharged.
In order to achieve the above objectives, technical solution provided by the invention is technical solution:A kind of flame retardant type formaldehyde of the present invention
Exhaust gas processing device, including liquid seal trough and combustion furnace, liquid seal trough are arranged between absorption tower and combustion furnace, and the liquid seal trough includes
Tank body and explosion stack positioned at top of the tank, are connected with control valve on the explosion stack, and the connection position of explosion stack and tank body is arranged
There is pressure sensor, when pressure sensor detects that pressure is more than the limiting value of setting in tank body, control valve automatically opens, and leads to
It crosses explosion stack to be exhausted, described device is connect with automatic control system, and automatic control system includes infrared spectrometer and display
Fluid flowing in whole device is included the image recognition mould on display screen by screen and picture recognition module, infrared spectrometer
Block identifies the image on the display screen, and is grasped accordingly according to all parts of the flow regime control system of fluid
Make.
As further improvement of the present invention, the top of the tank is additionally provided with buffer, the import on the buffer
Pipeline is connected with absorption tower, and tail gas flow velocity is reduced by buffer.
As further improvement of the present invention, the buffer is mainly made of annular chamber and buffering connecting leg, the ring
Shape chamber upper end is connected with inlet pipeline, and the buffering connecting leg of annular chamber lower end is passed through tank base;Ring lumen diameter is more than inlet tube
Road, the diameter for buffering connecting leg.
As further improvement of the present invention, the tank body is connected with water circulation system, is cycle aqueous in tank body.Make
For further improvement of the present invention, it is provided with sieve in the annular chamber, is located at the inlet of buffering connecting leg.
As further improvement of the present invention, it is provided with sieve in the annular chamber, is located in the middle part of annular chamber, is sieving
Online side is provided with buffering filler.
As further improvement of the present invention, the buffering filler is steel wool.
As further improvement of the present invention, the tank wall is provided with liquid level gauge.
As further improvement of the present invention, outflow valve is provided on the tank body.
As further improvement of the present invention, the tank wall is provided with U-shaped control position pipe.
Advantageous effect
Using technical solution provided by the invention, compared with prior art, have the advantages that:(1) of the invention
A kind of flame retardant type formaldehyde exhaust gas processing device is internally provided with sensor in the junction of explosion stack and tank body, the sensor with
Control valve matches, and when pressure is more than load limit, control valve automatically opens, and then can be by explosion stack by gas in tank body
Body is discharged, and can contain the diffusion of burning gases, eliminate the risk of explosion of tank body.(2) a kind of flame retardant type formaldehyde tail of the invention
Flash Gas Compression Skid System is connected with buffer on inlet pipeline, which can slow down air-flow velocity, and gas is formed by after outflow
It steeps relatively small, the contact area with liquid can be increased, to make internal gas further be absorbed, reduce the flammable of discharge
Property gas flow, realize to be discharged tail gas further absorption cleaning.(3) a kind of flame retardant type formaldehyde vent gas treatment of the invention dress
It sets, sieve is provided in annular chamber, which can further stop air-flow, while have certain filtration;In addition,
By the way that steel wool is arranged on sieve, its filter effect is substantially increased, is obviously improved on flow control, and will not
The circulation of entire pipeline gas is influenced, there is higher practical value.(4) at a kind of flame retardant type formaldehyde tail gas of the invention
Device is managed, the automation mechanized operation of device is realized by the control of automatic control system.
Description of the drawings
Fig. 1 is the structural schematic diagram of the exhaust gas processing device of the present invention;
Fig. 2 is the composition mechanism schematic diagram of liquid seal trough in the present invention;
Fig. 3 is the structural schematic diagram of buffer in the present invention;
Fig. 4 is the structural schematic diagram of U-shaped control position pipe in the present invention.
Label declaration in schematic diagram:1, liquid seal trough;11, tank body;12, buffer;121, annular chamber;122, steel wool;
123, sieve;124, connecting leg is buffered;13, inlet pipeline;14, explosion stack;15, control valve;16, outlet conduit;17, liquid level gauge;
18, outflow valve;2, absorption tower;3, combustion furnace.
Specific implementation mode
To further appreciate that present disclosure, the present invention is described in detail in conjunction with the accompanying drawings and embodiments.
Embodiment 1
In conjunction with Fig. 1, Fig. 2, a kind of flame retardant type formaldehyde exhaust gas processing device of the present embodiment, including liquid seal trough 1 and combustion furnace
3, liquid seal trough 1 is arranged between absorption tower 2 and combustion furnace 3, and absorption tower 2 is the equipment of formaldehyde preparation system indispensability, for absorbing
Formaldehyde in tail gas, if being provided with multistage absorption tower, the absorption tower 2 in the present embodiment refers generally to the last one absorption tower,
The tail gas of discharge needs to carry out burning processing.Set combustion furnace 3 to the tail gas of discharge for carrying out burning processing, Formaldehyde Production
When the tail gas that is discharged include a large amount of imflammable gas and pernicious gas, environmental pollution is enough lowered by burning, is reduced flammable
Security risk existing for property gas.Liquid seal trough 1 is set between absorption tower 2 and combustion furnace 3, and gas passes through liquid in liquid seal trough 1
Absorbing and filtering after be just discharged.Explosion stack 14 of the liquid seal trough 1 including tank body 11 and positioned at 11 top of tank body in the present embodiment,
It is connected with control valve 15 on the explosion stack 14, the break-make for controlling 14 pipeline of explosion stack.The connection of explosion stack 14 and tank body 11
Position is provided with pressure sensor, i.e., after control valve 15 is closed, one section of the lower section of explosion stack 14 is connected to 11 inside of tank body, at this
Pressure sensor, the pressure for detecting tank interior is arranged in connected component.Can also liquid level gauge 17 be set in 11 side wall of tank body, use
Liquid level in observation tank body.It can be equipped with outflow valve 18 simultaneously, for adjusting liquid level.In course of normal operation, with
The connected inlet pipeline 13 in absorption tower 2 extend into 11 bottom of tank body, and outlet is liquid-immersed, Liquid level in a certain range,
The gas being then discharged is located at the top in tank body, and is delivered to 3 bottom of combustion furnace by outlet conduit 16 and burns.If combustion
Burning stove 3, there are failures, and the gas lighted to be caused to enter tank body 11 from outlet conduit 16 there are certain failure or other parts
It is interior, it will so that pressure in tank body 11 is increased sharply, and this dangerous due to being in closed state, it is difficult to be found, if not
It can effectively solve the problem that, fire spreading may be made to other parts, or even tank body 11 can be made to explode.And the present embodiment due to
It is provided with pressure sensor, when pressure sensor detects that pressure is more than the limiting value of setting in tank body 11, signal can be passed
It send to processor, processor promotes control valve 15 to open, then can be exhausted by explosion stack 14, although gas may be
Explosion stack nozzle burns away, but will not affect greatly in a short time.It can be carried out by effective mode in this period
Fire extinguishing is handled, and can be returned to normal production in the short time, be avoided the deterioration of accident, and can effectively reduce loss.The dress
It sets and is connect with automatic control system, automatic control system includes infrared spectrometer and display screen and picture recognition module, infrared
Fluid flowing in whole device is included on display screen by spectrometer, and picture recognition module identifies the figure on the display screen
Picture, and operated accordingly according to all parts of the flow regime control system of fluid.
Embodiment 2
A kind of flame retardant type formaldehyde exhaust gas processing device of the present embodiment, basic structure is same as Example 1, difference
Be in:11 top of tank body is additionally provided with buffer 12, and the inlet pipeline 13 on the buffer 12 is connected with absorption tower 2, passes through
Buffer 12 reduces tail gas flow velocity.In conjunction with Fig. 3, buffer 12 is mainly made of annular chamber 121 and buffering connecting leg 124, annular chamber
121 upper ends are connected with inlet pipeline 13, and 121 lower end of annular chamber connection buffering connecting leg 124, the buffering connecting leg 124 is passed through tank body 11
Bottom.The diameter that 121 diameter of annular chamber is more than inlet pipeline 13, buffers connecting leg 124, diameter mentioned here refers to internal diameter,
In the case that wall thickness is equal, outer diameter can form cylindrical protrusions.Since 121 internal diameter of annular chamber is larger, when the gas of inlet pipeline 13
After flowing into annular chamber 121, flow velocity reduces, since the internal diameter of buffering connecting leg 124 is less than 121 internal diameter of annular chamber, air-flow
Certain vortex can be formed, the air-flow velocity into buffering connecting leg 124 reduces.Due to flow velocity reduce, air-flow from buffering connecting leg 124
After bottom enters in liquid, it is formed by the specific surface area increase that bubble is relatively small, is contacted with liquid, helps to inhale
Pernicious gas in getter body.In addition, if not buffering setting, air-flow directly impacts 11 bottom of tank body, has one to tank body 11
Fixed damage, and pass through after buffering, this damage can be reduced, the service life of tank body is extended.
Embodiment 3
A kind of flame retardant type formaldehyde exhaust gas processing device of the present embodiment, basic structure is same as Example 2, difference
Be in:Tank body 11 is connected with water circulation system in the present embodiment, is cycle aqueous in tank body 11, then can be made by recirculated water
It is in unsaturated state, has stronger adsorption capacity, improves assimilation effect.Further, in order to improve buffering effect,
It is provided with sieve 123 in annular chamber 121, is located at the inlet of buffering connecting leg 124.Sieve 123 has air-flow certain blocking
Effect.In addition, the gas of discharge is gas liquid mixture, air-flow can be filtered by set sieve.
Embodiment 4
A kind of flame retardant type formaldehyde exhaust gas processing device of the present embodiment, basic structure is same as Example 3, and difference exists
In:It is provided with sieve 123 in annular chamber 121, is located at 121 middle part of annular chamber, as shown in figure 3, being provided with above sieve 123
Filler is buffered, which is steel wool 122.It is worth noting that steel wool 122 is finer and closely woven relative to sieve, have more
Good choked flow effect, can be improved buffering effect.But if steel wool is arranged in the inlet of buffering connecting leg 124, the pressure of air-flow
Power can make its have it is certain pile up, be easy to block buffering 124 entrance of connecting leg, then air-flow is difficult to enter in buffering connecting leg 124.And this
Embodiment is arranged sieve 123 at the middle part of annular chamber 121, and downside still has larger circulation area, into row buffering
Meanwhile Airflow obstruction will not be caused, structure setting is reasonable.
Embodiment 5
In conjunction with Fig. 4, a kind of flame retardant type formaldehyde exhaust gas processing device of the present embodiment, basic structure is same as Example 4,
The difference is that:11 side wall of tank body is provided with U-shaped control position pipe.U-shaped control position pipe is connected to tank interior, can be according to need
It is arranged in specified altitude assignment, when liquid level amount increases, liquid can be flowed outwardly automatically by the U-shaped control position pipe, can be very
Good control liquid level, does not need manual adjustment.
Automatic control system includes infrared spectrometer and display screen and picture recognition module, and infrared spectrometer will be filled entirely
Fluid flowing in setting is shown on display screen, and picture recognition module identifies the image on display screen, and according to the flowing of fluid
The information such as the flow regime of gas and flow in each container of condition adjudgement and pipeline, each portion based on this management information system
Part is operated accordingly.By way of automatically controlling, the processing procedure of tail gas can be efficiently and accurately handled, and can be in detail
The parameter storage of each process is recorded on ground, is used for analysis;Due to eliminating the operation of people, whole process is using automation
Processing mode ensure that the accuracy of parameters control.
Schematically the present invention and embodiments thereof are described above, description is not limiting, institute in attached drawing
What is shown is also one of embodiments of the present invention, and actual structure is not limited to this.So if the common skill of this field
Art personnel are enlightened by it, without departing from the spirit of the invention, are not inventively designed and the technical solution
Similar frame mode and embodiment, are within the scope of protection of the invention.
Claims (10)
1. a kind of flame retardant type formaldehyde exhaust gas processing device, including liquid seal trough (1) and combustion furnace (3), liquid seal trough (1) setting is absorbing
Between tower (2) and combustion furnace (3), it is characterised in that:The liquid seal trough (1) includes tank body (11) and is located at the top of tank body (11)
Explosion stack (14), control valve (15) is connected on the explosion stack (14), and explosion stack (14) and the connection position of tank body (11) are arranged
There is pressure sensor, when pressure sensor detects that tank body (11) interior pressure is more than the limiting value of setting, control valve (15) is certainly
It is dynamic to open, it is exhausted by explosion stack (14), described device is connect with automatic control system, and automatic control system includes infrared
Fluid flowing in whole device is included in display screen by spectrometer and display screen and picture recognition module, infrared spectrometer
On, picture recognition module identifies the image on the display screen, and all parts of the flow regime control system according to fluid
It is operated accordingly.
2. a kind of flame retardant type formaldehyde exhaust gas processing device according to claim 1, it is characterised in that:Tank body (11) top
Portion is additionally provided with buffer (12), and the inlet pipeline (13) on the buffer (12) is connected with absorption tower (2), passes through buffer
(12) tail gas flow velocity is reduced.
3. a kind of flame retardant type formaldehyde exhaust gas processing device according to claim 2, it is characterised in that:The buffer (12)
It is mainly made of annular chamber (121) and buffering connecting leg (124), annular chamber (121) upper end is connected with inlet pipeline (13), ring
The buffering connecting leg (124) of shape chamber (121) lower end is passed through tank body (11) bottom;Annular chamber (121) diameter be more than inlet pipeline (13),
Buffer the diameter of connecting leg (124).
4. a kind of flame retardant type formaldehyde exhaust gas processing device according to claim 3, it is characterised in that:The tank body (11) with
Water circulation system is connected, and is cycle aqueous in tank body (11).
5. a kind of flame retardant type formaldehyde exhaust gas processing device according to claim 3, it is characterised in that:The annular chamber
(121) it is provided with sieve (123) in, is located at the inlet of buffering connecting leg (124).
6. a kind of flame retardant type formaldehyde exhaust gas processing device according to claim 3, it is characterised in that:The annular chamber
(121) it is provided with sieve (123) in, is located in the middle part of annular chamber (121), buffering filler is provided with above sieve (123).
7. a kind of flame retardant type formaldehyde exhaust gas processing device according to claim 6, it is characterised in that:The buffering filler is
Steel wool (122).
8. a kind of flame retardant type formaldehyde exhaust gas processing device according to any one of claims 1 to 7, it is characterised in that:Institute
It states tank body (11) side wall and is provided with liquid level gauge (17).
9. a kind of flame retardant type formaldehyde exhaust gas processing device according to any one of claims 1 to 7, it is characterised in that:Institute
It states and is provided with outflow valve (18) on tank body (11).
10. a kind of flame retardant type formaldehyde exhaust gas processing device according to any one of claims 1 to 7, it is characterised in that:Institute
It states tank body (11) side wall and is provided with U-shaped control position pipe.
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CN201810079417.XA CN108380006A (en) | 2018-01-26 | 2018-01-26 | A kind of flame retardant type formaldehyde exhaust gas processing device |
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CN201810079417.XA CN108380006A (en) | 2018-01-26 | 2018-01-26 | A kind of flame retardant type formaldehyde exhaust gas processing device |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110698084A (en) * | 2019-12-06 | 2020-01-17 | 浙江工商职业技术学院 | Safe calcium oxide preparation device |
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