CN108378433A - A kind of bionical brassiere and preparation method thereof with natural disinfection health care breast protecting function - Google Patents

A kind of bionical brassiere and preparation method thereof with natural disinfection health care breast protecting function Download PDF

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Publication number
CN108378433A
CN108378433A CN201810077985.6A CN201810077985A CN108378433A CN 108378433 A CN108378433 A CN 108378433A CN 201810077985 A CN201810077985 A CN 201810077985A CN 108378433 A CN108378433 A CN 108378433A
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China
Prior art keywords
brassiere
emulsion layer
bionical
cup
layer
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CN201810077985.6A
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CN108378433B (en
Inventor
翁创杰
黄福开
郑燕玉
金华
黄忠诚
孟雄飞
林壮丰
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Hongji Underwear Industry Co Ltd
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Hongji Underwear Industry Co Ltd
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41CCORSETS; BRASSIERES
    • A41C3/00Brassieres
    • A41C3/12Component parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/12Layered products comprising a layer of natural or synthetic rubber comprising natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0033Use of organic additives containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/104Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof
    • C08J9/105Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof containing sulfur
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/04N2 releasing, ex azodicarbonamide or nitroso compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00Characterised by the use of natural rubber
    • C08J2307/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2405/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2405/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
    • C08J2405/04Alginic acid; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/39Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
    • C08K5/40Thiurams, i.e. compounds containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45Heterocyclic compounds having sulfur in the ring
    • C08K5/46Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
    • C08K5/47Thiazoles

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Corsets Or Brassieres (AREA)

Abstract

The present invention relates to underwear brassiere technical fields, more particularly to a kind of bionical brassiere and preparation method thereof with natural disinfection health care breast protecting function, the bionical brassiere includes cup parts, the cup parts include heart and are symmetrically connected to the cup of the heart both sides, the cup includes the first emulsion layer, upright cotton layer and the second emulsion layer set gradually from outside to inside, glue stratum reticulare is equipped between the upright cotton layer and second emulsion layer, the glue stratum reticulare is disposed in proximity to the side of the heart, and the side of the upright cotton floor far from the heart is convexly equipped with hand push area.The brassiere of the present invention uses genuine milk glue-line, it is natural harmless, antibacterial mite-inhibiting effect is good, improves the anti-microbial property of brassiere, and elasticity is high, pliability is high, pro-skin degree is high, gas permeability is strong, the gas permeability of brassiere is improved using upright cotton layer, the supporting and shaping effect that brassiere is improved using glue stratum reticulare, is unlikely to deform, and durability is good, it hand push area is set improves the support of brassiere and gather effect, practicability is high.

Description

A kind of bionical brassiere and preparation method thereof with natural disinfection health care breast protecting function
Technical field
The present invention relates to underwear brassiere technical fields, and in particular to a kind of bionical with natural disinfection health care breast protecting function Brassiere and preparation method thereof.
Background technology
Brassiere underwear is one of essential product of women, to the effect that female chest plays support and gathers, but at present Bra cup mostly use sponge fabric greatly, but the promotion with the development and people of society to health community degree, people are gradually The poor air permeability of sponge is solved, and is easy to grow bacterium, adverse effect mostly is generated to the health of female chest, and prepare sponge There is the substance used in the process certain volatility, dress brassiere made from harmful sponge to be easy to cause female chest Disease, or even cause cancer.
And gradually there is the brassiere using upright cotton face fabric with its excellent permeability in upright cotton, improves the ventilative of brassiere Property, but the wash durability of upright cotton and supporting and shaping are ineffective, are easy that brassiere is made to deform and flat problem of collapsing, in addition Fail to solve the problems, such as easily to grow bacterium so that there are still health problems for brassiere.
Natural emulsion is the milky white liquid flowed out when notch is tapped rubber from rubber tree, has natural pure and fresh frankincense taste, Have the characteristics that natural antibacterial mite-inhibiting and deodorization, natural emulsion material obtained have preferable elasticity, flexibility, gas permeability and The performances such as film forming, but the performances such as the ageing-resistant performance of current natural emulsion, durability, heat resistance, water-wash resistance are poor, it is difficult To meet market needs.
Invention content
In order to overcome shortcoming and defect existing in the prior art, has the purpose of the present invention is to provide one kind and naturally kill The bionical brassiere of bacterium health care breast protecting function, it is natural harmless using natural emulsion as emulsion layer, have preferable antibacterial mite-inhibiting, Deodorization improves the antibacterial and deodouring performance of brassiere, and elasticity is high, pliability is high, pro-skin degree is high, gas permeability is strong, and passes through Using upright cotton layer, the gas permeability of brassiere is improved, using glue stratum reticulare, the supporting and shaping effect of brassiere is improved, is unlikely to deform, Durability is good.
Another object of the present invention is to provide a kind of preparations of the bionical brassiere with natural disinfection health care breast protecting function Method, the preparation method convenient operation and control, stable quality, production efficiency is high, will not destroy the structure and performance of natural emulsion, Brassiere made from energy has preferable antibiotic property, elasticity, supportive, flexibility and gas permeability.
The purpose of the invention is achieved by the following technical solution:A kind of bionical text with natural disinfection health care breast protecting function Chest, including cup parts, the cup parts include heart and are symmetrically connected to the cup of the heart both sides, the cup include by Outer the first emulsion layer, upright cotton layer and the second emulsion layer set gradually in, the upright cotton layer and second emulsion layer Between be equipped with glue stratum reticulare, the glue stratum reticulare is disposed in proximity to the side of the heart, and the upright cotton layer is far from the heart Side is convexly equipped with hand push area.
The bionical brassiere of the present invention is used as emulsion layer by using natural emulsion, natural harmless, and there is preferable antibacterial to press down Mite, deodorization improve antibacterial, the deodoriging properties of brassiere, and elasticity is high, pliability is high, pro-skin degree is high, because of natural emulsion The non-uniform characteristic of pore size distribution so that emulsion layer has the characteristics that gas permeability is strong, bibulous, and is unlikely to deform, texture and people Body skin is similar, and bionical effect is good;And the upright cotton layer used improves the gas permeability of brassiere, the glue stratum reticulare of use improves text The supporting and shaping effect of chest, wash durability is good, is unlikely to deform, and durability is good, and the hand push area of setting improves the support of brassiere Gather effect, practicability is high.In addition, the bionical brassiere of the application is detected through 100 standard authentications of Oeko-Tex Standard, (certificate number 17.HCN.22396), the emulsion layer of use are made by all natural latex, natural harmless.
Preferably, the area of the glue stratum reticulare is the 1/4 to 3/5 of the cup area.
The present invention can improve the support performance and gas permeability of brassiere, if glue stratum reticulare by strictly controlling the area of glue stratum reticulare Area it is excessive, then reduce the soft comfortable degree of brassiere, if the area of glue stratum reticulare is too small, reduce cup support make With being susceptible to flat the phenomenon that collapsing.
Preferably, the thickness of first emulsion layer and second emulsion layer is 1.5-5mm, the thickness of the glue stratum reticulare Degree is 1-3mm, and the mesh density of glue stratum reticulare is 18-40/cm2
The present invention can be such that bionical brassiere has preferable by strictly controlling the thickness of the first emulsion layer and the second emulsion layer Antibacterial mite-inhibiting, deodoriging properties, elasticity is high, pliability is high, pro-skin degree is high, gas permeability is strong, if the thinner thickness of emulsion layer, reduces The elasticity and flexibility of emulsion layer if the thickness of emulsion layer is thicker reduce the gas permeability and snugness of fit of emulsion layer, Therefore the thickness of preferably the first emulsion layer and second emulsion layer is 1.5-5mm.
And the present invention can make glue stratum reticulare that there is preferably support to make by strictly controlling the thickness and mesh density of glue stratum reticulare With and gas permeability can reduce the support performance of glue stratum reticulare if the thickness of glue stratum reticulare is smaller, mesh density is larger, if glue stratum reticulare Thickness is larger, mesh density is smaller, then the hardness of glue stratum reticulare can be made larger, gas permeability is relatively low, reduces the dress of brassiere Comfort, therefore the thickness of preferably glue stratum reticulare is 1-3mm, the mesh density of glue stratum reticulare is 18-40/cm2
Preferably, first emulsion layer and second emulsion layer offer several through the saturating of its surfaces externally and internally The distribution density of stomata, a diameter of 0.15-0.95mm of the air hole, air hole is 75-135/dm2
The present invention strictly controls the diameter of air hole by opening up air hole on the first emulsion layer and the second emulsion layer And distribution density, the gas permeability of emulsion layer is improved, is combined with the strong upright cotton layer of gas permeability, brassiere can be greatly improved Gas permeability, the feeling of oppression and heat generated when brassiere being avoided to wear is comfortable and easy to wear;In addition, if the diameter of air hole is smaller, distribution density It is smaller, then the gas permeability of emulsion layer is reduced, if the diameter of air hole is excessive, distribution density is excessive, then reduces emulsion layer Support performance is susceptible to deformation, flat the phenomenon that collapsing.
Preferably, the hand push area includes several hand push parts, and the hand push part is radial from upper centered on heart Setting is arranged in order under.
The present invention is by being arranged hand push part, and radial be arranged in order from top to bottom sets centered on heart by hand push part It sets, hand push part can be made from cup outer end to inner support, play the role of inwardly pushing away to chest, like both hands encircle chest, by chest Portion inwardly boosts the effect gathered, and improves supporting role and the gather effect of brassiere.
Preferably, the glue stratum reticulare is silica gel stratum reticulare.
The present invention has preferable pliability and support performance by using silica gel stratum reticulare.
Preferably, the volume of several hand push parts successively increases from top to bottom.
The present invention is successively increased from top to bottom by strictly controlling the volume of hand push part, can with chest be adapted, chest because Gravity makes the gravity of chest bottom be more than the gravity on chest top, thus hand push part volume successively increases, hand push part Volume it is bigger, supporting role is bigger, can play the role of more preferably supporting to the lower part of chest, gathers.
Preferably, the projection height in the hand push area is 0.5-3.2mm.
The present invention can play chest preferably support and gather effect by strictly controlling the projection height in hand push area, If projection height is relatively low, relatively low to the supporting role of chest, if projection height is higher, certain compressing is caused to chest Sense, it is therefore preferable that projection height is 0.5-3.2mm.
Preferably, first emulsion layer and the second emulsion layer include the raw material of following parts by weight:
Requirement of the first emulsion layer and the second emulsion layer of the present invention to production equipment is low, and the equal nothing of raw material of emulsion layer Poison, environmental protection, it is harmless, it can be used to prepare the personal clothing such as brassiere field, and improve the intensity, ageing-resistant of latex material Performances, the washing-resistant effects such as property, durability are good.
Wherein, methyl methacrylate is stablized as foaming monomer, performance, improves stability and the foaming of latex material Effect.
Sodium alginate is the by-product extracted from the kelp or sargassum of brown algae, and natural environmental-protective is harmless, Play the role of preferably stablizing in latex system, emulsification, suspend, dispersion, makes latex material that there is preferable foaming effect, and The preferable stability of latex material, permeability and plasticity are assigned, emulsion layer crocking resistance obtained is good, pliability is high, surely It is qualitative good, moreover it is possible to make emulsion layer obtained that can be in preferable molten condition at high temperature, be easy to mutually press with upright cotton layer, carry The high layer stability of cup.
Xanthans natural environmental-protective, it is harmless, played in latex system preferably stablize, emulsification, suspend, dispersion Effect, viscosity is good, can make to be made emulsion layer with preferable stability, resistance to ag(e)ing, and latex material can be made in foaming process Middle generation exquisiteness, small abscess, are made the emulsion layer with fine and smooth air hole, moreover it is possible to emulsion layer obtained be made at high temperature In preferable molten condition, it is easy to mutually press with upright cotton layer, improves the layer stability of cup.
Zinc oxide and zinc stearate are nontoxic to human body, can be mixed with other raw materials, concerted reaction, in latex material system The foaming process and vulcanization process of middle energy activation system, play the role of inspiring infusion, improve the crosslink density of latex material, energy Make emulsion layer obtained that there is preferable elasticity, resistance to ag(e)ing, wearability and resistance to tearing, improves comprising the bionical of emulsion layer The wash durability and durability of brassiere.
By using crosslinking agent, and it is 1-3 parts strictly to control its dosage, can effectively improve the anti-stress cracking of emulsion layer Energy and wearability, improve the wash durability and durability of bionical brassiere.
By using foaming agent, and it is 5-10 parts strictly to control its dosage, can effectively improve the foaming of latex material system Process and foaming effect can make latex material generate fine and smooth, small abscess in foaming process, and being made has fine and smooth air hole Emulsion layer, improve the elasticity, flexibility and gas permeability of bionical brassiere.
By using vulcanization accelerator, and it is 1.5-2.5 parts strictly to control its dosage, can improve the vulcanization effect of latex material Fruit can make latex material generate fine and smooth, small, equally distributed abscess in foaming process, improve emulsion layer gas permeability, Elasticity, flexibility and supporting role avoid emulsion layer from generating feeling of oppression and heat to chest, improve the snugness of fit of bionical brassiere.
Preferably, the crosslinking agent be cumyl peroxide and/or 2,5- dimethyl -2,5- di-tert-butyl peroxide oneself Alkane;The foaming agent is at least one of azodicarbonamide, diisopropyl azodiformate and unifor;It is described Vulcanization accelerator is tetramethylthiuram monosulfide and/or N- cyclohexyl -2- benzene thiazolyl sulfenamides.
The present invention makees by using cumyl peroxide and/or 2,5- dimethyl -2,5- di-t-butyl hexane peroxides It is environment-friendly and low-toxicity for crosslinking agent, it can be used for preparing the personal clothing such as brassiere field, it is harmless, it is used in combination with zinc oxide, it can be effective The intensity and resistance to ag(e)ing of latex material system are improved, and it is fine and smooth, small, uniform that latex material can be made to be generated in foaming process The abscess of distribution improves resistance to ag(e)ing, gas permeability, elasticity, flexibility and the supporting role of emulsion layer so that bionical brassiere is worn It comfortable.More preferably, the crosslinking agent is by cumyl peroxide and 2,5- dimethyl -2,5- di-tert-butyl peroxides Hexane is with weight ratio for 1:1.5-2.5 the mixture of composition.
The present invention is by using azodicarbonamide, diisopropyl azodiformate and unifor as foaming Agent, it is environment-protecting and non-poisonous, it can be used for preparing the personal clothing such as brassiere field, it is harmless, and foaming condition is combined, latex material can be made Material generates fine and smooth, small, equally distributed abscess in foaming process, improves resistance to ag(e)ing, the tearing toughness of emulsion layer, Improve the durability and water-wash resistance of bionical brassiere.More preferably, the foaming agent is by azodicarbonamide, azo two Formic acid diisopropyl ester and unifor are 2.4-3.2 with weight ratio:1:1.0-1.5 the mixture of composition.
The present invention is by using tetramethylthiuram monosulfide and/or N- cyclohexyl -2- benzene thiazolyl sulfenamide conducts Vulcanization accelerator, it is environment-friendly and low-toxicity, it can be used for preparing the personal clothing such as brassiere field, it is harmless, latex material can be improved Vulcanization effect can make latex material generate fine and smooth, small, equally distributed abscess in foaming process, improve emulsion layer Gas permeability, elasticity, flexibility and supporting role avoid emulsion layer from generating feeling of oppression and heat to chest, improve the dress of bionical brassiere Comfort.More preferably, the vulcanization accelerator is by tetramethylthiuram monosulfide and N- cyclohexyl -2- benzene thiazolyl Sulfonamide is with weight ratio for 1:The mixture of 0.8-1.2 compositions.
Preferably, the thickener is methylcellulose, hydroxymethyl cellulose, hydroxymethyl cellulose and hydroxyethyl cellulose At least one of sodium;The natural emulsion solution, methyl methacrylate, sodium alginate and xanthans mixed proportion be 13.75-16:1:1:1.78-2;The solvent is at least one of ethyl alcohol, ether, petroleum ether, acetone and isopropanol.
The present invention makes newborn material have preferable foaming effect, and assign latex by using the thickener of mentioned kind The preferable stability of material, permeability and plasticity, emulsion layer crocking resistance obtained is good, pliability is high, and stability is good.More To be preferred, the thickener is with weight ratio by methylcellulose and sodium hydroxyethyl cellulose for 1:1.5-2.0 composition is mixed Close object.
The emulsion layer that is prepared of latex material of the present invention directly acts on brassiere underwear, for a long time and human skin Intimate contact, thus need it is environment-protecting and non-poisonous, harmless, therefore by strictly control natural emulsion solution, methyl methacrylate, The mixed proportion of sodium alginate and xanthans can make the preferable foaming effect of latex material, stability, permeability, plasticity, So that latex material is generated fine and smooth, small abscess in foaming process, but can make emulsion layer obtained have preferable stability, The performances such as resistance to ag(e)ing, crocking resistance and pliability, and can make latex material that there is certain viscosity, make emulsion layer obtained It can be in preferable molten condition at high temperature, be easy to mutually press with upright cotton layer, improve the layer stability of cup.
The present invention can mix with other raw materials by using the solvent of mentioned kind and react, act synergistically, improve breast The compatibility of each raw material of glue material system, and can maximum journey by boiling, drying, drying and other steps during preparing emulsion layer Degree ground removes, for harmless in brassiere underwear field.
Preferably, the preparation method of first emulsion layer and the second emulsion layer includes the following steps:
A, methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent are added to genuine milk peptization according to parts by weight In liquid, 15-20min is stirred at 20-25 DEG C, is then gradually added into sodium alginate, xanthans, vulcanization accelerator and solvent, 25-28 10-20min is stirred at DEG C, is eventually adding foaming agent and thickener, is stirred evenly, and mixture is obtained;
B, air, stirring, hair are added in the mixture obtained to step A under conditions of 2-4 atmospheric pressure, 15-25 DEG C Bubble, and by the mixture injection moulding mold after foaming, cooked at 105-125 DEG C, latex first product is made;
C, latex first product made from step B is dehydrated, dried, obtain emulsion layer.
The performances such as tear-resistant, water-fastness, ageing-resistant of natural emulsion also fail to meet the current market demand, therefore this hair It is bright by being first added methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent, and strictly control be mixed temperature and when Between, the cross-linking reaction of natural emulsion solution and methyl methacrylate can be promoted, improve crosslink density and the foaming of latex material Effect can make emulsion layer obtained have preferable elasticity, resistance to ag(e)ing, wearability and resistance to tearing, improve comprising latex The wash durability and durability of the bionical brassiere of layer;Then sodium alginate, xanthans, vulcanization accelerator and solvent are added, And strictly temperature and time is mixed in control, improves dispersibility, emulsibility and the stability of latex material cross-linking reaction system, So that latex material is uniformly dispersed, improve foaming effect, can make emulsion layer obtained that can be in preferable molten condition at high temperature, It is easy to mutually press with upright cotton layer, improves the layer stability of cup, and so that emulsion layer obtained is had by vulcanizing treatment Preferable crocking resistance, pliability and stability;It is eventually adding foaming agent and thickener, latex material system is made fully to send out Bubble generates fine and smooth, small abscess, so that emulsion layer is had preferable gas permeability, flexibility and elasticity, improves the resistance to of emulsion layer and tear Fragility energy, crocking resistance and resistance to ag(e)ing.
In addition, the preparation method of emulsion layer of the present invention is easy to operate, the quality of production is stablized, and production efficiency is high, by stringent It controls foaming condition and cooks condition, latex material system can be made fully to foam, generate fine and smooth, small, equally distributed abscess, The emulsion layer with fine and smooth air hole is made, improves the elasticity, flexibility and gas permeability of bionical brassiere.
Another object of the present invention is achieved through the following technical solutions:It is a kind of imitative with natural disinfection health care breast protecting function The preparation method of raw brassiere, including following preparation process:
Step (1):One piece of latex cotton material is taken, progress pressing mold is preforming, obtains the first emulsion layer, mould temperature 140- 160 DEG C, molding pressure is 4-6 atmospheric pressure, and the pressing mold time is 110-130s;
Step (2):One piece of upright cotton material is taken, progress pressing mold is preforming, and pressing mold goes out hand push area, obtains the upright cotton of plane Layer;
Step (3):The upright cotton layer for taking glue stratum reticulare, another latex cotton material and step (2) to obtain, by upright cotton layer, glue Stratum reticulare and latex cotton material overlap successively, and progress pressing mold is preforming, obtain composite layer, and mould temperature is 140-160 DEG C, pressing mold pressure Power is 4-6 atmospheric pressure, and the pressing mold time is 190-210s;
Step (4):By the upright cotton layer outer surface of the first emulsion layer inner surface of step (1) and step (3) composite layer into Row hot pressing, obtains cup blank, and hot pressing temperature is 140-160 DEG C, and molding pressure is 4-6 atmospheric pressure, and the pressing mold time is 100-140s;
Step (5):The cup blank that step (4) obtains is subjected to cooling pressing mold molding, mould temperature is 5-15 DEG C, pressing mold Pressure is 4-6 atmospheric pressure, and the pressing mold time is 50-60s, then obtains cup after cropped;
Step (6):It sews the cup that step (5) obtains to obtain cup parts, portion will be enclosed with the back of the body and shoulder belt is sewed and imitated Raw brassiere.
Natural emulsion includes the natural resin ingredient and 0.2- of the water of 44-70%, the rubber constituent of 24-42%, 2-5% 4.5% protein component, rubber constituent therein and protein component can inhibit the preceding width of bacterium germ and anaphylactogen, reach The effect of natural antibacterial, if but natural emulsion be easily destroyed after multiple high temp heats natural emulsion structure and destroy rubber The constituent of glue, protein, and the comprehensive performances such as antibiotic property, fatigue durability, elasticity and flexibility for reducing natural emulsion are held It is easier that natural emulsion hardness is larger, comfort is relatively low, easily tears, service life is relatively low, therefore to the processing item of natural emulsion Part has stringent control.
And the present invention processing such as vulcanizes natural emulsion, foams by using the raw material of nontoxic low toxicity, improves latex The comprehensive performances such as rub resistance, tear resistance, durability, gas permeability, elasticity, pliability and the stability of layer;Then by first Emulsion layer carries out pressing mold, upright cotton layer-the-the second emulsion layer of glue stratum reticulare is in addition carried out pressing mold, and by strictly controlling composite layer Mould temperature, pressure and time, the outer surface of upright cotton layer, glue stratum reticulare and the second emulsion layer can be made in molten condition, In the second emulsion layer it is heated after be in semi-molten state, have preferably viscosity, be easy to bonding with glue stratum reticulare and be compression molded into Type, upright cotton layer and the second emulsion layer can be stablized with glue stratum reticulare is bonded pressing mold, improves the layer stability of composite layer, is not easy Delamination;After the first emulsion layer pressing mold semi-molten is in after the first emulsion layer is heated with the composite layer hot pressing after pressing mold State, characteristic have preferably viscosity, the bonding stabilization of upright cotton layer of molten condition can be in surface so that the first breast It is not required to be coated the glue layer containing volatile hazardous substances between glue-line and upright cotton layer and realizes bonding, improve bra cup Natural environmental-protective performance, it is harmless, can be used in the skin compatible materials such as brassiere underwear field.
If being carried out at the same time high temperature hot pressing conjunction after the first emulsion layer, upright cotton layer, glue stratum reticulare and the second emulsion layer are overlapped, need Intermediate upright cotton layer and the realization of glue stratum reticulare could be stably connected with by high temperature that will be far above 140-160 DEG C, cross high temperature then at this time The natural emulsion structure and performance of the first emulsion layer and the second emulsion layer can be destroyed, natural rubber compositions and protein component are destroyed Structure, reduce the performances such as antibiotic property, elasticity, pliability, the supportive of emulsion layer, therefore the present invention passes through first to composite layer Carry out pressing mold processing, by upright cotton layer, the second emulsion layer respectively be connected with glue stratum reticulare stablize after, then with the first emulsion layer hot pressing It closes, avoids excessive temperature to the ingredient of natural emulsion, the damage of structure, Bionic bra cup obtained can be made to have preferably anti- The comprehensive performances such as bacterium property, elasticity, flexibility, stability, rub resistance, tear resistance, durability and gas permeability are suitable for brassiere In the pro-skins such as underwear field.
And the bionical brassiere preparation method of the present invention is easy to operate, the quality of production is stablized, and production efficiency is high, is suitable for big rule Mould production in, bionical brassiere obtained have preferable antibiotic property, elasticity, flexibility, stability, rub resistance, tear resistance, The performances such as durability and gas permeability.
The beneficial effects of the present invention are:The present invention bionical brassiere by using natural emulsion as emulsion layer, naturally It is harmless, there is preferable antibacterial mite-inhibiting, deodorization, improve antibacterial, the deodoriging properties of brassiere, and elasticity is high, pliability is high, Pro-skin degree is high, gas permeability is strong, and texture is similar to human skin, and bionical effect is good;And the upright cotton layer used improves brassiere The glue stratum reticulare of gas permeability, use improves the supporting and shaping effect of brassiere, and repeatedly dress is unlikely to deform, and durability is good, setting Effect is gathered in the support that hand push area improves brassiere, and practicability is high.
The bionical brassiere preparation method of the present invention is easy to operate, and the quality of production is stablized, and production efficiency is high, is suitable for extensive In production, and by first carrying out pressing mold processing to composite layer, upright cotton layer, the second emulsion layer are connected surely with glue stratum reticulare respectively After fixed, then with the first emulsion layer hot pressing, avoid excessive temperature to the ingredient of natural emulsion, the damage of structure, it is obtained bionical Brassiere has the property such as preferable antibiotic property, elasticity, flexibility, stability, rub resistance, tear resistance, durability and gas permeability Energy.
Description of the drawings
Fig. 1 is the structural schematic diagram of cup parts inner surface of the present invention;
Fig. 2 is the structural schematic diagram of cup of the present invention;
Fig. 3 is the decomposition diagram of cup of the present invention.
Reference numeral is:1-cup parts, 11-hearts, 12-cups, the 121-the first emulsion layer, 122-upright cotton layers, 123-glue stratum reticulares, the 124-the second emulsion layer, 125-hand push areas, 1251-hand push parts.
Specific implementation mode
For the ease of the understanding of those skilled in the art, make with reference to 1~3 couple of present invention of embodiment and attached drawing further Explanation, the content that embodiment refers to not is limitation of the invention.
Embodiment 1
See Fig. 1-3, a kind of bionical brassiere with natural disinfection health care breast protecting function, including cup parts 1, the cup parts 1 includes heart 11 and is symmetrically connected to the cups 12 of 11 both sides of the heart, and the cup 12 including setting gradually from outside to inside The first emulsion layer 121, upright cotton layer 122 and the second emulsion layer 124, the upright cotton layer 122 and second emulsion layer 124 Between be equipped with glue stratum reticulare 123, the glue stratum reticulare 123 is disposed in proximity to the side of the heart 11, and the upright cotton layer 122 is separate The side of the heart 11 is convexly equipped with hand push area 125.
The area of the glue stratum reticulare 123 is the 1/4 to 3/5 of 12 area of the cup.
The thickness of first emulsion layer 121 and second emulsion layer 124 is 1.5-5mm.
The hand push area 125 includes several hand push parts 1251, and the hand push part 1251 is centered on heart 11 in radiation Shape is arranged in order setting from top to bottom.
Embodiment 2
The present embodiment and embodiment 1 difference lies in:
The glue stratum reticulare 123 is silica gel stratum reticulare 123, and the thickness of the glue stratum reticulare 123 is 1-3mm, the mesh of glue stratum reticulare 123 Density is 18-40/cm2
First emulsion layer 121 and second emulsion layer 124 offer several through the saturating of its surfaces externally and internally The distribution density of stomata, a diameter of 0.15-0.95mm of the air hole, air hole is 75-135/dm2
The volume of several hand push parts 1251 successively increases from top to bottom.
The projection height in the hand push area 125 is 0.5-3.2mm.
Embodiment 3
The present embodiment and embodiment 1 or embodiment 2 difference lies in:
First emulsion layer, 121 and second emulsion layer 124 includes the raw material of following parts by weight:
The crosslinking agent is cumyl peroxide;The foaming agent is diisopropyl azodiformate;The vulcanization promotees It is tetramethylthiuram monosulfide into agent.
The thickener is methylcellulose;The natural emulsion solution, methyl methacrylate, sodium alginate and xanthan The mixed proportion of glue is 16:1:1:2;The solvent is ethyl alcohol.
The preparation method of first emulsion layer, 121 and second emulsion layer 124 includes the following steps:
A, methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent are added to genuine milk peptization according to parts by weight In liquid, 20min is stirred at 20 DEG C, is then gradually added into sodium alginate, xanthans, vulcanization accelerator and solvent, is stirred at 25 DEG C 20min is eventually adding foaming agent and thickener, stirs evenly, and obtains mixture;
B, air is added in the mixture obtained to step A under conditions of 2 atmospheric pressure, 25 DEG C, stirring is foamed, and It by the mixture injection moulding mold after foaming, is cooked at 105 DEG C, latex first product is made;
C, latex first product made from step B is dehydrated, dried, obtain emulsion layer.
Embodiment 4
The present embodiment and embodiment 1 or embodiment 2 difference lies in:
First emulsion layer, 121 and second emulsion layer 124 includes the raw material of following parts by weight:
The crosslinking agent is cumyl peroxide;The foaming agent is unifor;The vulcanization accelerator is Tetramethylthiuram monosulfide.
The thickener is hydroxymethyl cellulose;The natural emulsion solution, methyl methacrylate, sodium alginate and Huang The mixed proportion of virgin rubber is 15:1:1:1.9;The solvent is ether.
The preparation method of first emulsion layer, 121 and second emulsion layer 124 includes the following steps:
A, methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent are added to genuine milk peptization according to parts by weight In liquid, 19min is stirred at 21 DEG C, is then gradually added into sodium alginate, xanthans, vulcanization accelerator and solvent, is stirred at 25.8 DEG C 18min is mixed, foaming agent and thickener are eventually adding, is stirred evenly, mixture is obtained;
B, air is added in the mixture obtained to step A under conditions of 2.5 atmospheric pressure, 23 DEG C, stirring is foamed, And by the mixture injection moulding mold after foaming, cooked at 110 DEG C, latex first product is made;
C, latex first product made from step B is dehydrated, dried, obtain emulsion layer.
Embodiment 5
The present embodiment and embodiment 1 or embodiment 2 difference lies in:
First emulsion layer, 121 and second emulsion layer 124 includes the raw material of following parts by weight:
The crosslinking agent is cumyl peroxide;The foaming agent is azodicarbonamide;The vulcanization accelerator is Tetramethylthiuram monosulfide.
The thickener is sodium hydroxyethyl cellulose;The natural emulsion solution, methyl methacrylate, sodium alginate and The mixed proportion of xanthans is 14.6:1:1:1.85;The solvent is acetone.
The preparation method of first emulsion layer, 121 and second emulsion layer 124 includes the following steps:
A, methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent are added to genuine milk peptization according to parts by weight In liquid, 18min is stirred at 22 DEG C, is then gradually added into sodium alginate, xanthans, vulcanization accelerator and solvent, is stirred at 26.5 DEG C 15min is mixed, foaming agent and thickener are eventually adding, is stirred evenly, mixture is obtained;
B, air is added in the mixture obtained to step A under conditions of 3 atmospheric pressure, 20 DEG C, stirring is foamed, and It by the mixture injection moulding mold after foaming, is cooked at 115 DEG C, latex first product is made;
C, latex first product made from step B is dehydrated, dried, obtain emulsion layer.
Embodiment 6
The present embodiment and embodiment 1 or embodiment 2 difference lies in:
First emulsion layer, 121 and second emulsion layer 124 includes the raw material of following parts by weight:
The crosslinking agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxides;The foaming agent is azoformic acid Diisopropyl ester;The vulcanization accelerator is N- cyclohexyl -2- benzene thiazolyl sulfenamides.
The thickener is hydroxymethyl cellulose;The natural emulsion solution, methyl methacrylate, sodium alginate and Huang The mixed proportion of virgin rubber is 14:1:1:1.78;The solvent is petroleum ether.
The preparation method of first emulsion layer, 121 and second emulsion layer 124 includes the following steps:
A, methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent are added to genuine milk peptization according to parts by weight In liquid, 16min is stirred at 23 DEG C, is then gradually added into sodium alginate, xanthans, vulcanization accelerator and solvent, is stirred at 27.2 DEG C 12min is mixed, foaming agent and thickener are eventually adding, is stirred evenly, mixture is obtained;
B, air is added in the mixture obtained to step A under conditions of 3.5 atmospheric pressure, 18 DEG C, stirring is foamed, And by the mixture injection moulding mold after foaming, cooked at 120 DEG C, latex first product is made;
C, latex first product made from step B is dehydrated, dried, obtain emulsion layer.
Embodiment 7
The present embodiment and embodiment 1 or embodiment 2 difference lies in:
First emulsion layer, 121 and second emulsion layer 124 includes the raw material of following parts by weight:
The crosslinking agent is 2,5- dimethyl -2,5- di-t-butyl hexane peroxides;The foaming agent is tolysulfonyl Hydrazine;The vulcanization accelerator is N- cyclohexyl -2- benzene thiazolyl sulfenamides.
The thickener is sodium hydroxyethyl cellulose;The natural emulsion solution, methyl methacrylate, sodium alginate and The mixed proportion of xanthans is 13.75:1:1:1.86;The solvent is isopropanol.
The preparation method of first emulsion layer, 121 and second emulsion layer 124 includes the following steps:
A, methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent are added to genuine milk peptization according to parts by weight In liquid, 15min is stirred at 25 DEG C, is then gradually added into sodium alginate, xanthans, vulcanization accelerator and solvent, is stirred at 28 DEG C 10min is eventually adding foaming agent and thickener, stirs evenly, and obtains mixture;
B, air is added in the mixture obtained to step A under conditions of 4 atmospheric pressure, 15 DEG C, stirring is foamed, and It by the mixture injection moulding mold after foaming, is cooked at 125 DEG C, latex first product is made;
C, latex first product made from step B is dehydrated, dried, obtain emulsion layer.
Embodiment 8
The present embodiment and embodiment 3 difference lies in:
The crosslinking agent is by cumyl peroxide and 2,5- dimethyl -2,5- di-t-butyl hexane peroxides with weight Than being 1:The mixture of 1.5 compositions.
The foaming agent is to be with weight ratio by azodicarbonamide, diisopropyl azodiformate and unifor 3.2:1:The mixture of 1.0 compositions.
The vulcanization accelerator is by tetramethylthiuram monosulfide and N- cyclohexyl -2- benzene thiazolyl sulfenamides with weight Amount is than being 1:The mixture of 1.2 compositions.
The thickener is with weight ratio by methylcellulose and sodium hydroxyethyl cellulose for 1:The mixture of 1.5 compositions.
Embodiment 9
The present embodiment and embodiment 4 difference lies in:
The crosslinking agent is by cumyl peroxide and 2,5- dimethyl -2,5- di-t-butyl hexane peroxides with weight Than being 1:The mixture of 1.8 compositions.
The foaming agent is to be with weight ratio by azodicarbonamide, diisopropyl azodiformate and unifor 3:1:The mixture of 1.1 compositions.
The vulcanization accelerator is by tetramethylthiuram monosulfide and N- cyclohexyl -2- benzene thiazolyl sulfenamides with weight Amount is than being 1:The mixture of 1.1 compositions.
The thickener is with weight ratio by methylcellulose and sodium hydroxyethyl cellulose for 1:The mixture of 1.6 compositions.
Embodiment 10
The present embodiment and embodiment 5 difference lies in:
The crosslinking agent is by cumyl peroxide and 2,5- dimethyl -2,5- di-t-butyl hexane peroxides with weight Than being 1:The mixture of 2 compositions.
The foaming agent is to be with weight ratio by azodicarbonamide, diisopropyl azodiformate and unifor 2.8:1:The mixture of 1.2 compositions.
The vulcanization accelerator is by tetramethylthiuram monosulfide and N- cyclohexyl -2- benzene thiazolyl sulfenamides with weight Amount is than being 1:The mixture of 1.0 compositions.
The thickener is with weight ratio by methylcellulose and sodium hydroxyethyl cellulose for 1:The mixture of 1.8 compositions.
Embodiment 11
The present embodiment and embodiment 6 difference lies in:
The crosslinking agent is by cumyl peroxide and 2,5- dimethyl -2,5- di-t-butyl hexane peroxides with weight Than being 1:The mixture of 2.3 compositions.
The foaming agent is to be with weight ratio by azodicarbonamide, diisopropyl azodiformate and unifor 2.6:1:The mixture of 1.3 compositions.
The vulcanization accelerator is by tetramethylthiuram monosulfide and N- cyclohexyl -2- benzene thiazolyl sulfenamides with weight Amount is than being 1:The mixture of 0.9 composition.
The thickener is with weight ratio by methylcellulose and sodium hydroxyethyl cellulose for 1:The mixture of 1.9 compositions.
Embodiment 12
The present embodiment and embodiment 7 difference lies in:
The crosslinking agent is by cumyl peroxide and 2,5- dimethyl -2,5- di-t-butyl hexane peroxides with weight Than being 1:The mixture of 2.5 compositions.
The foaming agent is to be with weight ratio by azodicarbonamide, diisopropyl azodiformate and unifor 2.4:1:The mixture of 1.5 compositions.
The vulcanization accelerator is by tetramethylthiuram monosulfide and N- cyclohexyl -2- benzene thiazolyl sulfenamides with weight Amount is than being 1:The mixture of 0.8 composition.
The thickener is with weight ratio by methylcellulose and sodium hydroxyethyl cellulose for 1:The mixture of 2.0 compositions.
Embodiment 13
A kind of preparation method of the bionical brassiere with natural disinfection health care breast protecting function, including following preparation process:
Step (1):One piece of latex cotton material is taken, progress pressing mold is preforming, obtains the first emulsion layer 121, mould temperature is 140 DEG C, molding pressure is 6 atmospheric pressure, and the pressing mold time is 110s;
Step (2):One piece of upright cotton material is taken, progress pressing mold is preforming, and pressing mold goes out hand push area 125, obtains the straight of plane Vertical cotton layer 122;
Step (3):The upright cotton layer 122 for taking glue stratum reticulare 123, another latex cotton material and step (2) to obtain, by upright cotton Layer 122, glue stratum reticulare 123 and latex cotton material overlap successively, and progress pressing mold is preforming, obtains composite layer, mould temperature 140 DEG C, molding pressure is 6 atmospheric pressure, and the pressing mold time is 190s;
Step (4):It will be outside the upright cotton layer 122 of 121 inner surface of the first emulsion layer of step (1) and step (3) composite layer Surface carries out hot pressing, obtains 12 blank of cup, and hot pressing temperature is 140 DEG C, and molding pressure is 6 atmospheric pressure, pressing mold time For 100s;
Step (5):12 blank of cup that step (4) obtains is subjected to cooling pressing mold molding, mould temperature is 5 DEG C, pressing mold Pressure is 6 atmospheric pressure, and the pressing mold time is 50s, then obtains cup 12 after cropped;
Step (6):The sewing of cup 12 that step (5) obtains is obtained into cup parts 1, portion will be enclosed with the back of the body and shoulder belt sews to obtain Bionical brassiere.
Embodiment 14
The present embodiment and embodiment 13 difference lies in:
A kind of preparation method of the bionical brassiere with natural disinfection health care breast protecting function, including following preparation process:
Step (1):One piece of latex cotton material is taken, progress pressing mold is preforming, obtains the first emulsion layer 121, mould temperature is 145 DEG C, molding pressure is 5.5 atmospheric pressure, and the pressing mold time is 115s;
Step (2):One piece of upright cotton material is taken, progress pressing mold is preforming, and pressing mold goes out hand push area 125, obtains the straight of plane Vertical cotton layer 122;
Step (3):The upright cotton layer 122 for taking glue stratum reticulare 123, another latex cotton material and step (2) to obtain, by upright cotton Layer 122, glue stratum reticulare 123 and latex cotton material overlap successively, and progress pressing mold is preforming, obtains composite layer, mould temperature 145 DEG C, molding pressure is 5.5 atmospheric pressure, and the pressing mold time is 195s;
Step (4):It will be outside the upright cotton layer 122 of 121 inner surface of the first emulsion layer of step (1) and step (3) composite layer Surface carries out hot pressing, obtains 12 blank of cup, and hot pressing temperature is 145 DEG C, and molding pressure is 5.5 atmospheric pressure, when pressing mold Between be 110s;
Step (5):12 blank of cup that step (4) obtains is subjected to cooling pressing mold molding, mould temperature is 8 DEG C, pressing mold Pressure is 5.5 atmospheric pressure, and the pressing mold time is 52s, then obtains cup 12 after cropped;
Step (6):The sewing of cup 12 that step (5) obtains is obtained into cup parts 1, portion will be enclosed with the back of the body and shoulder belt sews to obtain Bionical brassiere.
Embodiment 15
The present embodiment and embodiment 13 difference lies in:
A kind of preparation method of the bionical brassiere with natural disinfection health care breast protecting function, including following preparation process:
Step (1):One piece of latex cotton material is taken, progress pressing mold is preforming, obtains the first emulsion layer 121, mould temperature is 150 DEG C, molding pressure is 5 atmospheric pressure, and the pressing mold time is 120s;
Step (2):One piece of upright cotton material is taken, progress pressing mold is preforming, and pressing mold goes out hand push area 125, obtains the straight of plane Vertical cotton layer 122;
Step (3):The upright cotton layer 122 for taking glue stratum reticulare 123, another latex cotton material and step (2) to obtain, by upright cotton Layer 122, glue stratum reticulare 123 and latex cotton material overlap successively, and progress pressing mold is preforming, obtains composite layer, mould temperature 150 DEG C, molding pressure is 5 atmospheric pressure, and the pressing mold time is 200s;
Step (4):It will be outside the upright cotton layer 122 of 121 inner surface of the first emulsion layer of step (1) and step (3) composite layer Surface carries out hot pressing, obtains 12 blank of cup, and hot pressing temperature is 150 DEG C, and molding pressure is 5 atmospheric pressure, pressing mold time For 120s;
Step (5):12 blank of cup that step (4) obtains is subjected to cooling pressing mold molding, mould temperature is 10 DEG C, pressing mold Pressure is 5 atmospheric pressure, and the pressing mold time is 55s, then obtains cup 12 after cropped;
Step (6):The sewing of cup 12 that step (5) obtains is obtained into cup parts 1, portion will be enclosed with the back of the body and shoulder belt sews to obtain Bionical brassiere.
Embodiment 16
The present embodiment and embodiment 13 difference lies in:
A kind of preparation method of the bionical brassiere with natural disinfection health care breast protecting function, including following preparation process:
Step (1):One piece of latex cotton material is taken, progress pressing mold is preforming, obtains the first emulsion layer 121, mould temperature is 155 DEG C, molding pressure is 4.5 atmospheric pressure, and the pressing mold time is 125s;
Step (2):One piece of upright cotton material is taken, progress pressing mold is preforming, and pressing mold goes out hand push area 125, obtains the straight of plane Vertical cotton layer 122;
Step (3):The upright cotton layer 122 for taking glue stratum reticulare 123, another latex cotton material and step (2) to obtain, by upright cotton Layer 122, glue stratum reticulare 123 and latex cotton material overlap successively, and progress pressing mold is preforming, obtains composite layer, mould temperature 155 DEG C, molding pressure is 4.5 atmospheric pressure, and the pressing mold time is 205s;
Step (4):It will be outside the upright cotton layer 122 of 121 inner surface of the first emulsion layer of step (1) and step (3) composite layer Surface carries out hot pressing, obtains 12 blank of cup, and hot pressing temperature is 155 DEG C, and molding pressure is 4.5 atmospheric pressure, when pressing mold Between be 130s;
Step (5):12 blank of cup that step (4) obtains is subjected to cooling pressing mold molding, mould temperature is 13 DEG C, pressing mold Pressure is 4.5 atmospheric pressure, and the pressing mold time is 58s, then obtains cup 12 after cropped;
Step (6):The sewing of cup 12 that step (5) obtains is obtained into cup parts 1, portion will be enclosed with the back of the body and shoulder belt sews to obtain Bionical brassiere.
Embodiment 17
The present embodiment and embodiment 13 difference lies in:
A kind of preparation method of the bionical brassiere with natural disinfection health care breast protecting function, including following preparation process:
Step (1):One piece of latex cotton material is taken, progress pressing mold is preforming, obtains the first emulsion layer 121, mould temperature is 160 DEG C, molding pressure is 4 atmospheric pressure, and the pressing mold time is 130s;
Step (2):One piece of upright cotton material is taken, progress pressing mold is preforming, and pressing mold goes out hand push area 125, obtains the straight of plane Vertical cotton layer 122;
Step (3):The upright cotton layer 122 for taking glue stratum reticulare 123, another latex cotton material and step (2) to obtain, by upright cotton Layer 122, glue stratum reticulare 123 and latex cotton material overlap successively, and progress pressing mold is preforming, obtains composite layer, mould temperature 160 DEG C, molding pressure is 4 atmospheric pressure, and the pressing mold time is 210s;
Step (4):It will be outside the upright cotton layer 122 of 121 inner surface of the first emulsion layer of step (1) and step (3) composite layer Surface carries out hot pressing, obtains 12 blank of cup, and hot pressing temperature is 160 DEG C, and molding pressure is 4 atmospheric pressure, pressing mold time For 140s;
Step (5):12 blank of cup that step (4) obtains is subjected to cooling pressing mold molding, mould temperature is 15 DEG C, pressing mold Pressure is 4 atmospheric pressure, and the pressing mold time is 60s, then obtains cup 12 after cropped;
Step (6):The sewing of cup 12 that step (5) obtains is obtained into cup parts 1, portion will be enclosed with the back of the body and shoulder belt sews to obtain Bionical brassiere.
Bionic bra cup 12 produced by the present invention is carried out the performances such as tear-proof, antibiotic property, gas permeability, harmful substance to survey Examination, concrete operation method and test result is as follows:
1. tear-proof is tested:
Bionic bra cup 12 produced by the present invention is tested into tearing toughness using Different Tear Test instrument, the result is that brassiere cover There is the crack that length is 2.3cm at the tearing resistance lower edge of 6380g in cup 12, and the integrity degree of cup 12 reaches 99.2%, Prove that the bra cup 12 of the present invention has preferable tear resistance, durability good.
2. antibiotic property is tested:
By Bionic bra cup 12 produced by the present invention after wearing 1-2 times, temperature be 28-42 DEG C, humidity 68- It is placed 3-4 days in 88% climatic chamber, then takes out bra cup 12, to cup 12 inner surface (i.e. the second emulsion layer 124) observation of the bacteriums such as submicroscopic, test are carried out, as a result show that the bacteria containing rate of 12 inner surface of bra cup is 1.2-4.0%, card The Bionic bra cup 12 of the bright present invention has preferable antibacterial bacteriostatic by using the natural emulsion with antibacterial mite-inhibiting effect Effect.
3. permeability test:
Bionic bra cup 12 produced by the present invention is placed in steam engine outlet air discharge surface, air output 15-18cm, in text Its air output of 12 surface test of bra top is 11.8-13.5cm, and outlet air rate is 75-80%, it was demonstrated that bionical cup 12 of the invention The air permeability effect of brassiere is good.
4. water-fastness test:
Bionic bra cup 12 produced by the present invention is tested by 800-1000 washing, the result is that bra cup 12 Structure not and deform, surface fiber is complete, and supporting degree is preferable, and integrity degree reaches 98-99.5%, it was demonstrated that brassiere cover of the invention The washing-resistant effect of cup 12 is good, repeatedly still has preferable support effect after washing.
5. volatile hazardous substances are tested:
Bionic bra cup 12 produced by the present invention is placed in baking oven and is toasted 22-25 hours for 40-45 DEG C, in test oven Harmful substance be zero, it was demonstrated that Bionic bra cup 12 of the invention has preferable heat resistance, and environment-protecting and non-poisonous, strong to human body Health is harmless.
Above-described embodiment is the preferable implementation of the present invention, and in addition to this, the present invention can be realized with other manner, Any obvious replacement is not departed under the premise of present inventive concept within protection scope of the present invention.

Claims (10)

1. a kind of bionical brassiere with natural disinfection health care breast protecting function, it is characterised in that:Including cup parts, the cup parts It including heart and is symmetrically connected to the cup of the heart both sides, the cup includes the first latex set gradually from outside to inside Layer, upright cotton layer and the second emulsion layer are equipped with glue stratum reticulare, the glue stratum reticulare between the upright cotton layer and second emulsion layer It is disposed in proximity to the side of the heart, the side of the upright cotton floor far from the heart is convexly equipped with hand push area.
2. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 1, it is characterised in that:Institute The area for stating glue stratum reticulare is the 1/4 to 3/5 of the cup area.
3. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 1, it is characterised in that:Institute The thickness for stating the first emulsion layer and second emulsion layer is 1.5-5mm, and the thickness of the glue stratum reticulare is 1-3mm, glue stratum reticulare Mesh density be 18-40/cm2
4. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 1, it is characterised in that:Institute It states the first emulsion layer and second emulsion layer offers several air holes for running through its surfaces externally and internally, the air hole The distribution density of a diameter of 0.15-0.95mm, air hole are 75-135/dm2
5. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 1, it is characterised in that:Institute It includes several hand push parts to state hand push area, and the hand push part is radial centered on heart to be arranged in order setting from top to bottom.
6. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 1, it is characterised in that:Institute State the raw material that the first emulsion layer and the second emulsion layer include following parts by weight:
7. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 6, it is characterised in that:Institute It is cumyl peroxide and/or 2,5- dimethyl -2,5- di-t-butyl hexane peroxides to state crosslinking agent;The foaming agent is even At least one of nitrogen diformamide, diisopropyl azodiformate and unifor;The vulcanization accelerator is a sulphur Change tetra methylthiuram and/or N- cyclohexyl -2- benzene thiazolyl sulfenamides.
8. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 6, it is characterised in that:Institute It is at least one of methylcellulose, hydroxymethyl cellulose, hydroxymethyl cellulose and sodium hydroxyethyl cellulose to state thickener;Institute The mixed proportion for stating natural emulsion solution, methyl methacrylate, sodium alginate and xanthans is 13.75-16:1:1:1.78- 2;The solvent is at least one of ethyl alcohol, ether, petroleum ether, acetone and isopropanol.
9. a kind of bionical brassiere with natural disinfection health care breast protecting function according to claim 6, it is characterised in that:Institute The preparation method for stating the first emulsion layer and the second emulsion layer includes the following steps:
A, methyl methacrylate, zinc oxide, zinc stearate and crosslinking agent are added into natural emulsion solution according to parts by weight, 15-20min is stirred at 20-25 DEG C, is then gradually added into sodium alginate, xanthans, vulcanization accelerator and solvent, at 25-28 DEG C 10-20min is stirred, foaming agent and thickener is eventually adding, stirs evenly, obtain mixture;
B, air is added in the mixture obtained to step A under conditions of 2-4 atmospheric pressure, 15-25 DEG C, stirring is foamed, and It by the mixture injection moulding mold after foaming, is cooked at 105-125 DEG C, latex first product is made;
C, latex first product made from step B is dehydrated, dried, obtain emulsion layer.
10. the preparation method of the bionical brassiere with natural disinfection health care breast protecting function described in a kind of any one of claim 1-9, It is characterized in that:Including following preparation process:
Step (1):One piece of latex cotton material is taken, progress pressing mold is preforming, obtains the first emulsion layer, mould temperature 140-160 DEG C, molding pressure is 4-6 atmospheric pressure, and the pressing mold time is 110-130s;
Step (2):One piece of upright cotton material is taken, progress pressing mold is preforming, and pressing mold goes out hand push area, obtains the upright cotton layer of plane;
Step (3):The upright cotton layer for taking glue stratum reticulare, another latex cotton material and step (2) to obtain, by upright cotton layer, glue stratum reticulare It is overlapped successively with latex cotton material, progress pressing mold is preforming, obtains composite layer, and mould temperature is 140-160 DEG C, and molding pressure is 4-6 atmospheric pressure, pressing mold time are 190-210s;
Step (4):The upright cotton layer outer surface of the first emulsion layer inner surface of step (1) and step (3) composite layer is subjected to heat Pressing obtains cup blank, and hot pressing temperature is 140-160 DEG C, and molding pressure is 4-6 atmospheric pressure, and the pressing mold time is 100- 140s;
Step (5):The cup blank that step (4) obtains is subjected to cooling pressing mold molding, mould temperature is 5-15 DEG C, molding pressure For 4-6 atmospheric pressure, the pressing mold time is 50-60s, then obtains cup after cropped;
Step (6):It sews the cup that step (5) obtains to obtain cup parts, portion will be enclosed with the back of the body and shoulder belt sews to obtain bionical text Chest.
CN201810077985.6A 2018-01-26 2018-01-26 Bionic bra with natural sterilization, health care and breast protection functions and preparation method thereof Active CN108378433B (en)

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CN109880191A (en) * 2019-02-20 2019-06-14 四川汉莫尼机械设备有限公司 A kind of integrated molding natural emulsion cup and preparation method thereof
CN110432560A (en) * 2019-06-14 2019-11-12 黄湾湾 Moulding Poromeric bra

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CN109880191A (en) * 2019-02-20 2019-06-14 四川汉莫尼机械设备有限公司 A kind of integrated molding natural emulsion cup and preparation method thereof
CN110432560A (en) * 2019-06-14 2019-11-12 黄湾湾 Moulding Poromeric bra

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